Wet Cleaning Only (epo) Patents (Class 257/E21.228)
  • Patent number: 12209314
    Abstract: A technique enabling to heat a plating liquid rapidly while suppressing thermal deterioration of the plating liquid is provided. A substrate liquid processing apparatus includes a substrate holder configured to hold a substrate; a plating liquid supply configured to supply the plating liquid on a processing surface of the substrate; and a heating element, configured to heat at least one of the plating liquid on the processing surface or the substrate, including a heater, a liquid flow path through which pure water flows, and a vapor discharge opening which is connected to the liquid flow path and through which water vapor produced as the pure water is vaporized by heat from the heater is ejected.
    Type: Grant
    Filed: September 23, 2020
    Date of Patent: January 28, 2025
    Assignee: TOKYO ELECTRON LIMITED
    Inventor: Satoshi Kaneko
  • Patent number: 12205833
    Abstract: The inventive concept provides an apparatus and method for removing a film formed on a substrate. A method for treating the substrate includes a primary solvent dispensing step of dispensing an organic solvent onto the substrate to remove a photoresist film on the substrate and an ozone dispensing step of dispensing a liquid containing ozone onto the substrate to remove organic residue on the substrate, after the primary solvent dispensing step.
    Type: Grant
    Filed: May 26, 2023
    Date of Patent: January 21, 2025
    Assignee: SEMES CO., LTD.
    Inventors: Sun Mi Kim, Jisu Hong, Moonsik Choi, Oh Jin Kwon
  • Patent number: 12187387
    Abstract: Described herein are polymers and associated methods to occlude structures and malformations of the vasculature with polymers with delayed controlled rates of expansion. Methods of forming such devices are also disclosed.
    Type: Grant
    Filed: August 2, 2023
    Date of Patent: January 7, 2025
    Assignee: MicroVention, Inc.
    Inventor: Aaron Baldwin
  • Patent number: 12180101
    Abstract: The present disclosure describes a process for producing a reducing liquid comprising providing a liquid: providing a reducing gas and/or a metasilicate; and infusing the reducing gas and/or the metasilicate to the liquid, for the reducing gas and/or metasilicate to react with the liquid to produce a reducing liquid that has an oxidation reduction potential (ORP) value of about ?100 mV or more negative. Further described is the process for preparing a reducing gas, which includes the steps of preparing an activator, introducing the activator into an electrolytic reactor, adding water, and applying a direct current to produce the reducing gas. Also described is a system for producing a reducing liquid.
    Type: Grant
    Filed: May 31, 2019
    Date of Patent: December 31, 2024
    Assignee: Altered Labs LLC
    Inventor: Dario Echeverry Campos
  • Patent number: 12165887
    Abstract: The present disclosure describes an apparatus for wafer cleaning. The apparatus includes an enclosure made of a noncombustible material, a wafer holder, a cleaning nozzle, at least one sensor, and an exhaust unit. The wafer holder can hold and heat a wafer. The cleaning nozzle can supply a flow of a cleaning fluid onto a surface of the wafer. The at least one sensor can detect attributes of the wafer. The exhaust unit can expel a vapor generated by the cleaning fluid in the enclosure. The exhaust unit can include a rinse nozzle to rinse the vapor passing through the exhaust unit with a mist.
    Type: Grant
    Filed: July 31, 2023
    Date of Patent: December 10, 2024
    Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.
    Inventors: Jieh-Chau Huang, Ying Ting Hsia, Ping-Jung Huang, Pei Yen Hsia, Bi-Ming Yen, Hung-Lung Hu
  • Patent number: 12128550
    Abstract: A vacuum transfer device, which is arranged between a process chamber and a load lock chamber and transfers a substrate between the process chamber and the load lock chamber, includes a container, a transfer device, an exhaust device, a dew-point meter, and a control device. The container is connected to each of the process chamber and the load lock chamber via a gate valve. The transfer device is provided inside the container and transfers the substrate between the process chamber and the load lock chamber. The exhaust device exhausts a gas in the container. The dew-point meter measures a dew-point temperature of the gas in the container. The control device determines whether a process is ready to be executed, based on the dew-point temperature measured by the dew-point meter, and when the process is ready to be executed, notifies that fact to a user of the vacuum transfer device.
    Type: Grant
    Filed: September 11, 2020
    Date of Patent: October 29, 2024
    Assignee: TOKYO ELECTRON LIMITED
    Inventors: Seiji Ishibashi, Hayato Itomi, Hiroyuki Takahashi
  • Patent number: 12109597
    Abstract: According to one embodiment, a substrate treatment device includes a placement stand configured to rotate the substrate, a cooling part configured to supply a cooling gas into a space between the placement stand and the substrate, a first liquid supplier configured to supply a first liquid on a surface of the substrate, a second liquid supplier configured to supply a second liquid on the surface, and a controller controlling rotation of the substrate, supply of the cooling gas, the first and second liquids. The controller performs a preliminary process of supplying the second liquid on the surface, and supplying the cooling gas into the space, a liquid film forming process by supplying the first liquid toward the surface after the preliminary process, a supercooling process of the liquid film on the surface, and a freezing process of at least a part of the liquid film on the surface.
    Type: Grant
    Filed: April 14, 2021
    Date of Patent: October 8, 2024
    Assignee: SHIBAURA MECHATRONICS CORPORATION
    Inventors: Daisuke Matsushima, Kensuke Demura, Satoshi Nakamura, Masaya Kamiya, Minami Nakamura
  • Patent number: 12090527
    Abstract: A method of processing a substrate in semiconductor fabrication is provided. The method includes supplying a mixture from a storage module to a chamber via an inlet conduit. The method further includes detecting the concentration of a substance in the mixture. The method also includes dispensing the mixture over a substrate disposed in the chamber. In addition, the method includes supplying a supply solution including the substance to the chamber via the inlet conduit and dispensing the supply solution over the substrate when the concentration of the substance in the mixture is less than a desired value. The supply solution is supplied to the inlet conduit at a first position that is at a portion of the inlet conduit extending in the chamber.
    Type: Grant
    Filed: June 23, 2020
    Date of Patent: September 17, 2024
    Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD
    Inventors: Chun-Syuan Jhuan, Ming-Jung Chen, Shao-Yen Ku, Tsai-Pao Su
  • Patent number: 12074020
    Abstract: The present disclosure is directed to etching compositions that are useful for, e.g., selectively removing silicon germanium (SiGe) from a semiconductor substrate as an intermediate step in a multistep semiconductor manufacturing process.
    Type: Grant
    Filed: October 6, 2022
    Date of Patent: August 27, 2024
    Assignee: Fujifilm Electronic Materials U.S.A., Inc.
    Inventors: Mick Bjelopavlic, Carl Ballesteros
  • Patent number: 12043592
    Abstract: The present disclosure is directed to methods and systems of purifying solvents. The purified solvents can be used for cleaning a semiconductor substrate in a multistep semiconductor manufacturing process.
    Type: Grant
    Filed: March 26, 2021
    Date of Patent: July 23, 2024
    Assignee: Fujifilm Electronic Materials U.S.A., Inc.
    Inventors: Eduardo Ramirez Romero, David Bollinger
  • Patent number: 12045037
    Abstract: It is an object of the present invention to reduce the amount of data used in an apparatus, a system, and a method for performing a substrate processing. In order to achieve this object, a substrate processing apparatus includes one or more processing units each for performing a processing on a substrate and one or more arithmetic processing parts. One or more arithmetic processing parts generate a flow recipe defining a flow of a series of processings for a substrate by combining two or more processing recipes among a plurality of processing recipes each defining a processing condition relating to a processing to be performed on a substrate in the one or more processing units. The plurality of processing recipes include a plurality of liquid processing recipes each defining a condition of a processing to be performed on a substrate by using a processing liquid.
    Type: Grant
    Filed: September 7, 2023
    Date of Patent: July 23, 2024
    Assignee: SCREEN Holdings Co., Ltd.
    Inventors: Koji Hashimoto, Shinji Shimizu, Hiroshi Horiguchi, Masahiro Yamamoto
  • Patent number: 12033951
    Abstract: The reflectance of a low-reflectance alignment mark is increased by coating the alignment mark with a high-reflectance film layer. This improves the strength of the light signal and reduces variation in the light signal.
    Type: Grant
    Filed: August 17, 2021
    Date of Patent: July 9, 2024
    Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.
    Inventors: Tzu-Hao Yeh, Kuan-Jung Chen, Tsung-Lin Lee, Shiuan-Jeng Lin, Hung-Lin Chen
  • Patent number: 11992915
    Abstract: A system (5) includes a heat exchanging member (11) and a liquid supply unit (30). The liquid supply unit (30) includes a pump device (32) that adjusts the flow amount of a liquid flowing through a heating liquid supply line (HSL), a needle valve (MNV) that is attached to a cooling liquid supply line (CSL), and a control device (40) that controls operations of the pump device (32) and the needle valve (MNV).
    Type: Grant
    Filed: December 8, 2020
    Date of Patent: May 28, 2024
    Assignee: EBARA CORPORATION
    Inventors: Shuji Uozumi, Toru Maruyama, Mitsunori Komatsu
  • Patent number: 11946148
    Abstract: Described herein is an etching solution suitable for the selective removal of TiSiN over hafnium oxide from a microelectronic device, which consists essentially of: water; at least one alkaline ammonium compound selected from the group consisting of ammonium hydroxide, a quaternary ammonium hydroxide, ammonium fluoride, and a quaternary ammonium fluoride; at least one peroxide compound; a water-miscible organic solvent; at least one nitrogen containing compound selected from the group consisting of a C4-12 alkylamine, a polyalkylenimine, and a polyamine; and optionally at least one chelating agent.
    Type: Grant
    Filed: January 10, 2020
    Date of Patent: April 2, 2024
    Assignee: Versum Materials US, LLC
    Inventors: Wen Dar Liu, Yi-Chia Lee
  • Patent number: 11942337
    Abstract: The apparatus includes a support unit to support the substrate in a treatment space of a process chamber, a first fluid supply unit to supply a supercritical fluid having an organic solvent dissolved in the supercritical fluid, to the treatment space, a second fluid supply unit to supply the supercritical fluid having no organic solvent dissolved in the supercritical fluid, to the treatment space, an exhaust unit to exhaust the treatment space, a controller to control the first fluid supply unit, the second fluid supply unit, and the exhaust unit. The controller controls the first and second fluid supply units such that the supercritical fluid having no organic solvent dissolved in the supercritical fluid is supplied to the treatment space through the second fluid supply unit, after the supercritical fluid mixed with the organic solvent is supplied to the treatment space through the first fluid supply unit.
    Type: Grant
    Filed: October 6, 2020
    Date of Patent: March 26, 2024
    Assignee: SEMES CO., LTD.
    Inventors: Eui Sang Lim, Young Hun Lee, Jinwoo Jung, Miso Park, Byongwook Ahn, Yong Hee Lee
  • Patent number: 11923210
    Abstract: In an embodiment, a method includes: immersing a wafer in a bath within a cleaning chamber; removing the wafer out of the bath through a solvent and into a gas within the cleaning chamber; determining a parameter value from the gas; and performing remediation within the cleaning chamber in response to determining that the parameter value is beyond a threshold value.
    Type: Grant
    Filed: August 21, 2019
    Date of Patent: March 5, 2024
    Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.
    Inventors: Wei-Chun Hsu, Shu-Yen Wang, Chui-Ya Peng
  • Patent number: 11881831
    Abstract: A method of manufacture for an acoustic resonator device. The method includes forming a nucleation layer characterized by nucleation growth parameters overlying a substrate and forming a strained piezoelectric layer overlying the nucleation layer. The strained piezoelectric layer is characterized by a strain condition and piezoelectric layer parameters. The process of forming the strained piezoelectric layer can include an epitaxial growth process configured by nucleation growth parameters and piezoelectric layer parameters to modulate the strain condition in the strained piezoelectric layer. By modulating the strain condition, the piezoelectric properties of the resulting piezoelectric layer can be adjusted and improved for specific applications.
    Type: Grant
    Filed: January 29, 2020
    Date of Patent: January 23, 2024
    Assignee: Akoustis, Inc.
    Inventors: Shawn R. Gibb, Alexander Y. Feldman, Mark D. Boomgarden, Michael P. Lewis, Ramakrishna Vetury, Jeffrey B. Shealy
  • Patent number: 11854841
    Abstract: The disclosed techniques include a space filling device to be used with a wet bench in chemical replacement procedures. The space filling device has an overall density that is higher than the chemicals used to purge the wet bench. As such, when embedded into the wet bench, or more specifically, the chemical tank of the wet bench, the space filling device will occupy a portion of the interior volume space. As a result, less purging chemicals are used to fill and bath the wet bench.
    Type: Grant
    Filed: July 25, 2022
    Date of Patent: December 26, 2023
    Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.
    Inventors: Yen-Ji Chen, Chih-Shen Yang, Cheng-Yi Huang
  • Patent number: 11817309
    Abstract: Provided are: a method of producing heated ozone water, the method capable of producing heated ozone water having an extremely high ozone concentration by suppressing a reduction in the ozone concentration in high-concentration heated ozone water; heated ozone water; and a semiconductor wafer-cleaning liquid using the heated ozone water. A method of producing heated ozone water obtained by dissolving ozone in pure water, the method being characterized by including: adjusting a pH of the pure water to 3 or less by adding acid to the pure water; to obtain an acid water, dissolving an ozone gas in the acid water; and heating the pure water, the acid water or the ozone water, to 60° C. or more.
    Type: Grant
    Filed: October 23, 2020
    Date of Patent: November 14, 2023
    Assignees: TOHOKU UNIVERSITY, NOMURA MICRO SCIENCE CO., LTD.
    Inventors: Yasuyuki Shirai, Takeshi Sakai, Takayuki Jizaimaru
  • Patent number: 11798802
    Abstract: Methods for removing an oxide film and for cleaning silicon-on-insulator structures are disclosed. The methods may involve immersing the silicon-on-insulator structure in a stripping bath to strip an oxide film from the surface of the silicon-on-insulator structure. The stripped silicon-on-insulator structure is immersed in an ozone bath comprising ozone. The ozone-treated silicon-on-insulator structure may be immersed in an SC-1 bath comprising ammonium hydroxide and hydrogen peroxide to clean the structure.
    Type: Grant
    Filed: February 11, 2022
    Date of Patent: October 24, 2023
    Assignee: GlobalWafers Co., Ltd.
    Inventors: Qingmin Liu, Haihe Liang, Junting Yang
  • Patent number: 11769661
    Abstract: A substrate processing method includes a first cleaning process and a second cleaning process. In the first cleaning process, a substrate is cleaned with a first cleaning solution. In the second cleaning process, the substrate is cleaned with a second cleaning solution having a lower cleanliness than the first cleaning solution after the first cleaning process.
    Type: Grant
    Filed: May 22, 2020
    Date of Patent: September 26, 2023
    Assignee: TOKYO ELECTRON LIMITED
    Inventors: Hirofumi Takeguchi, Kazuyoshi Shinohara, Takahisa Otsuka, Suguen Lee
  • Patent number: 11752529
    Abstract: A method for controlling damages in cleaning a semiconductor wafer comprising features of patterned structures, the method comprising: delivering a cleaning liquid over a surface of a semiconductor wafer during a cleaning process; and imparting sonic energy to the cleaning liquid from a sonic transducer during the cleaning process, wherein power is alternately supplied to the sonic transducer at a first frequency and a first power level for a first predetermined period of time and at a second frequency and a second power level for a second predetermined period of time, the first predetermined period of time and the second predetermined period of time consecutively following one another, wherein at least one of the cleaning parameters is determined such that a percentage of damaged features as a result of the imparting sonic energy is lower than a predetermined threshold.
    Type: Grant
    Filed: November 15, 2017
    Date of Patent: September 12, 2023
    Assignee: ACM Research (Shanghai) Inc.
    Inventors: Hui Wang, Fufa Chen, Fuping Chen, Jian Wang, Xi Wang, Xiaoyan Zhang, Yinuo Jin, Zhaowei Jia, Liangzhi Xie, Jun Wang, Xuejun Li
  • Patent number: 11740559
    Abstract: Apparatuses and methods are described for removing edge bead on a wafer associated with a resist coating comprising a metal containing resist compositions. The methods can comprise applying a first bead edge rinse solution along a wafer edge following spin coating of the wafer with the metal based resist composition, wherein the edge bead solution comprises an organic solvent and an additive comprising a carboxylic acid, an inorganic fluorinated acid, a tetraalkylammonium compound, or a mixture thereof. Alternatively or additionally, the methods can comprise applying a protective composition to the wafer prior to performing an edge bead rinse. The protective composition can be a sacrificial material or an anti-adhesion material and can be applied only to the wafer edge or across the entire wafer in the case of the protective composition. Corresponding apparatuses for processing the wafers using these methods are presented.
    Type: Grant
    Filed: October 11, 2021
    Date of Patent: August 29, 2023
    Assignee: Inpria Corporation
    Inventors: Mollie Waller, Brian J. Cardineau, Kai Jiang, Alan J. Telecky, Stephen T. Meyers, Benjamin L. Clark
  • Patent number: 11699601
    Abstract: A substrate processing device includes a processing tank, a substrate holding unit, a fluid supply unit, and a control unit. The processing tank stores a processing liquid for processing a substrate. The substrate holding unit holds the substrate in the processing liquid in the processing tank. The fluid supply unit supplies a fluid to the processing tank. The control unit controls the fluid supply unit. The control unit controls the fluid supply unit such that the fluid supply unit changes supply of the fluid during a period from a start of supply of the fluid to the processing tank storing the processing liquid in which the substrate is immersed to an end of supply of the fluid to the processing tank storing the processing liquid in which the substrate is immersed.
    Type: Grant
    Filed: June 27, 2021
    Date of Patent: July 11, 2023
    Assignee: SCREEN Holdings Co., Ltd.
    Inventors: Tomohiro Takahashi, Kei Takechi, Mitsutoshi Sasaki, Takashi Akiyama
  • Patent number: 11673830
    Abstract: In a method for removing an organic adhesive from a glass carrier in a semiconductor manufacturing process, the glass carrier is placed into a process chamber. The glass carrier is rotated and heated sulfuric acid is applied or sprayed onto the glass carrier. Ozone is introduced into the process chamber. The ozone diffuses through the sulfuric acid to the organic adhesive on the surface of the glass carrier. The sulfuric acid and the ozone chemically react with the organic adhesive and remove it from the glass carrier.
    Type: Grant
    Filed: November 11, 2020
    Date of Patent: June 13, 2023
    Assignee: APPLIED MATERIALS, INC.
    Inventors: Eric J. Bergman, David P. Surdock, Graeme Bell
  • Patent number: 11676828
    Abstract: A semiconductor manufacturing apparatus according to the present embodiment includes a tank, a heater, a bubble supplier, a sensor and a controller. The tank stores a chemical solution for processing a substrate. The heater heats the chemical solution. The bubble supplier supplies bubbles to the chemical solution in the tank. The sensor detects at least one of a concentration of the chemical solution, a water concentration of the chemical solution, specific gravity of the chemical solution and a vapor concentration of a gas discharged from the tank. The controller controls the supply of bubbles by the bubble supplier based on a detection result of the sensor.
    Type: Grant
    Filed: December 11, 2020
    Date of Patent: June 13, 2023
    Assignee: Kioxia Corporation
    Inventors: Shinsuke Muraki, Satoshi Nakaoka
  • Patent number: 11670499
    Abstract: A method of forming a semiconductor device includes forming a first conductive feature on a bottom surface of an opening through a dielectric layer. The forming the first conductive feature leaves seeds on sidewalls of the opening. A treatment process is performed on the seeds to form treated seeds. The treated seeds are removed with a cleaning process. The cleaning process may include a rinse with deionized water. A second conductive feature is formed to fill the opening.
    Type: Grant
    Filed: March 18, 2021
    Date of Patent: June 6, 2023
    Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
    Inventors: Cheng-Wei Chang, Min-Hsiu Hung, Chun-I Tsai, Ken-Yu Chang, Yi-Ying Liu
  • Patent number: 11660644
    Abstract: A substrate processing method includes a substrate holding step of holding a substrate having a front surface on which a metal is exposed, an inert gas replacing step of replacing an atmosphere around the front surface of the substrate with an inert gas by supplying an inert gas to a vicinity of the front surface of the substrate, an adjusting step of adjusting a pH of the rinsing liquid so as to form an inactive state in which the metal does not react with the rinsing liquid or so as to form a passive state by allowing the metal to react with the rinsing liquid, and a rinsing liquid supplying step of supplying the rinsing liquid whose pH has been adjusted to the front surface of the substrate after the atmosphere around the front surface of the substrate has been replaced with the inert gas.
    Type: Grant
    Filed: April 10, 2018
    Date of Patent: May 30, 2023
    Inventors: Akihisa Iwasaki, Hiroaki Takahashi
  • Patent number: 11640115
    Abstract: A substrate processing apparatus includes a processing chamber providing a processing space for processing a substrate and processing a substrate, a substrate support configured to support the substrate, a blocking plate below the substrate support and configured to prevent supercritical fluid from being directly sprayed onto the substrate, a first supply device configured to supply supercritical fluid under a first condition to the processing chamber, a second supply device configured to supply supercritical fluid under a second condition at a higher temperature than that of supercritical fluid under the first condition to the processing chamber, a discharge device configured to discharge supercritical fluid from the processing chamber, and a control device configured to control operations of the first supply device, the second supply device, and the discharge device. The control device is configured to direct the first supply device to supply supercritical fluid prior to the second supply device.
    Type: Grant
    Filed: September 3, 2021
    Date of Patent: May 2, 2023
    Inventors: Jihoon Jeong, Seohyun Kim, Sukhoon Kim, Younghoo Kim, Sangjine Park, Kuntack Lee
  • Patent number: 11618060
    Abstract: An ultrasonic cleaning apparatus capable of cleaning large-sized objects includes: a casing having a bottom surface that forms a tilted surface to oppose the object to be cleaned and having an ultrasonic transducer provided at an inner lower surface; a cleaning liquid supply device configured to supply cleaning liquid to a casing bottom surface; and a flow-speed accelerator that ejects the cleaning liquid by accelerating the flow speed of the cleaning liquid from the cleaning liquid supply device. The casing is formed by a main body including an upper plate, a projected part attached to a lower part of the upper plate, an outer lateral face extended from the projected part in a downward direction, and the bottom surface connected integrally at a lower end part of the outer lateral face. The bottom surface is formed to be tilted at a prescribed angle with respect to a horizontal plane.
    Type: Grant
    Filed: August 21, 2018
    Date of Patent: April 4, 2023
    Assignee: KAIJO CORPORATION
    Inventors: Keisuke Ohata, Noriyuki Sakamoto
  • Patent number: 11615986
    Abstract: Methods and apparatuses for processing substrates, such as during metal silicide applications, are provided. In one or more embodiments, a method of processing a substrate includes depositing an epitaxial layer on the substrate, depositing a metal silicide seed layer on the epitaxial layer, and exposing the metal silicide seed layer to a nitridation process to produce a metal silicide nitride layer from at least a portion of the metal silicide seed layer. The method also includes depositing a metal silicide bulk layer on the metal silicide nitride layer and forming or depositing a nitride capping layer on the metal silicide bulk layer, where the nitride capping layer contains a metal nitride, a silicon nitride, a metal silicide nitride, or a combination thereof.
    Type: Grant
    Filed: September 17, 2021
    Date of Patent: March 28, 2023
    Assignee: APPLIED MATERIALS, INC.
    Inventors: Xuebin Li, Wei Liu, Gaurav Thareja, Shashank Sharma, Patricia M. Liu, Schubert Chu
  • Patent number: 11610773
    Abstract: Embodiments described herein relate to a high pressure processing system with a condenser and methods for utilizing the same. The processing system includes a process chamber, a boiler, a condenser, and one or more heat exchangers. The boiler generates a fluid, such as a vapor or supercritical fluid, and delivers the fluid to the process chamber where a substrate is processed. After processing the substrate, the system is depressurized and the fluid is delivered to the condenser where the fluid is condensed.
    Type: Grant
    Filed: March 26, 2020
    Date of Patent: March 21, 2023
    Assignee: Applied Materials, Inc.
    Inventor: Jean Delmas
  • Patent number: 11600502
    Abstract: A substrate liquid processing apparatus includes a processing tub configured to store a processing liquid therein; a processing liquid supply configured to supply the processing liquid into the processing tub; a processing liquid drain device configured to drain the processing liquid from the processing tub; and a controller configured to control the processing liquid supply and the processing liquid drain device. The controller calculates, in response to an instruction to change a concentration of a preset component of the processing liquid stored in the processing tub, a drain amount and a feed amount of the processing liquid from/into the processing tub based on information upon a current concentration of the preset component, information upon a concentration increment thereof per unit time and information upon the changed concentration thereof, and controls the processing liquid supply and the processing liquid drain device based on the calculation result.
    Type: Grant
    Filed: August 21, 2019
    Date of Patent: March 7, 2023
    Assignee: TOKYO ELECTRON LIMITED
    Inventors: Hiroshi Yoshida, Yuki Ishii
  • Patent number: 11569085
    Abstract: The natural oxidation film of polysilicon, which is exposed at a side surface of a recess portion 83 provided in a substrate W, is removed and a thin film 84 of polysilicon is exposed at the side surface of the recess portion 83. Liquid IPA is brought into contact with the thin film 84 of polysilicon after the natural oxidation film of polysilicon is removed. Diluted ammonia water is supplied to the substrate W and the thin film 84 of polysilicon is etched after IPA comes into contact with the thin film 84 of polysilicon.
    Type: Grant
    Filed: June 29, 2018
    Date of Patent: January 31, 2023
    Inventors: Taiki Hinode, Sadamu Fujii
  • Patent number: 11538697
    Abstract: A substrate processing apparatus, including a processing chamber including a first internal space and a second internal space arranged in a vertical direction, the first internal space being configured to receive process gas to generate plasma; an induction electrode configured to divide the processing chamber, and having a plurality of through-holes arranged to connect the first internal space and the second internal space, wherein the plurality of through-holes are configured to induce an ion beam extracted from ions included in the plasma generated in the first internal space; a radical supply located in the second internal space, and including a reservoir configured to receive chemical liquid in which an object to be processed is immersed, and a lower electrode configured to apply nanopulses to the reservoir to generate radicals from the chemical liquid; and a chemical liquid supply configured to supply the chemical liquid to the reservoir.
    Type: Grant
    Filed: September 10, 2020
    Date of Patent: December 27, 2022
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Sang Ki Nam, Jang-Yeob Lee, Sungyeol Kim, Sunghyup Kim, Soonam Park, Siqing Lu
  • Patent number: 11523921
    Abstract: The present disclosure provides a method for producing a multifunctional implantable structure, the method having: preparing an implantable base; coating a polymer layer on the base, wherein the polymer layer is partially curable; curing the polymer layer such that the polymer layer has cured and non-cured portions; and dry-etching the polymer layer to remove the non-cured portion thereof, to allow the polymer layer to have a nano-turf structure having pores defined therein.
    Type: Grant
    Filed: April 4, 2018
    Date of Patent: December 13, 2022
    Assignee: Research & Business Foundation Sungkyunkwan University
    Inventors: Tae Il Kim, So Ri Lee, Ji Yeon Lee, Gyo Yeon Hwang
  • Patent number: 11476130
    Abstract: A substrate processing apparatus includes a liquid processing tank, a movement mechanism, an ejector, and a controller. The liquid processing tank stores a processing liquid. The movement mechanism moves a plurality of substrates immersed in the liquid processing tank to a position above the liquid surface of the processing liquid. The ejector ejects a vapor of an organic solvent toward portions of the plurality of substrates that are exposed from the liquid surface. The controller changes an ejection flow rate of the vapor ejected by the ejector as the plurality of substrates are moved up.
    Type: Grant
    Filed: March 2, 2020
    Date of Patent: October 18, 2022
    Assignee: TOKYO ELECTRON LIMITED
    Inventors: Kotaro Tsurusaki, Koji Yamashita, Kazuya Koyama, Kouzou Kanagawa
  • Patent number: 11443963
    Abstract: A substrate processing method includes a process of cooling a substrate to below a freezing point of a processing liquid using a cooling fluid brought into contact with the substrate opposite. While the substrate is cooled to below the freezing point of the processing liquid, a droplet of processing liquid is dispensed onto a surface of the substrate at a specified location of a foreign substance. The droplet then forms a frozen droplet portion at the specified location. The frozen droplet portion is then thawed.
    Type: Grant
    Filed: August 30, 2019
    Date of Patent: September 13, 2022
    Assignee: KIOXIA CORPORATION
    Inventors: Mana Tanabe, Kosuke Takai, Kenji Masui, Kaori Umezawa
  • Patent number: 11417511
    Abstract: A method for drying a wafer at room temperature includes a cleaning step, a reacting step and a pressure releasing step. The cleaning step includes putting a processing workpiece into a cleaning solvent. The reacting step includes putting the processing workpiece along with the cleaning solvent into a reaction chamber, implanting a supercritical fluid into the reaction chamber, and increasing a pressure of the reaction chamber to dissolve the cleaning solvent in the supercritical fluid. A critical temperature of the supercritical fluid is below room temperature. The pressure releasing step includes releasing the pressure of the reaction chamber and discharging the supercritical fluid together with the cleaning solvent out of the reaction chamber, after completely dissolving the cleaning solvent in the supercritical fluid.
    Type: Grant
    Filed: July 23, 2021
    Date of Patent: August 16, 2022
    Assignee: NATIONAL SUN YAT-SEN UNIVERSITY
    Inventors: Ting-Chang Chang, Chih-Cheng Yang, Wen-Chung Chen, Chuan-Wei Kuo, Pei-Yu Wu, Chun-Chu Lin
  • Patent number: 11175585
    Abstract: An object of the present invention is to provide a treatment liquid which is capable of suppressing the generation of defects of a semiconductor device and has excellent corrosion resistance and wettability. The treatment liquid of the present invention is a treatment liquid for a semiconductor device, containing at least one organic solvent selected from the group consisting of ethers, ketones, and lactones, water, and a metal component including at least one metal element selected from the group consisting of Na, K, Ca, Fe, Cu, Mg, Mn, Li, Al, Cr, Ni, Ti, and Zn, in which the content of water in the treatment liquid is 100 ppb by mass to 100 ppm by mass and the content of the metal component in the treatment liquid is 10 ppq by mass to 10 ppb by mass.
    Type: Grant
    Filed: October 26, 2018
    Date of Patent: November 16, 2021
    Assignee: FUJIFILM Corporation
    Inventors: Satoru Murayama, Tetsuya Shimizu, Tetsuya Kamimura
  • Patent number: 10940228
    Abstract: Aqueous compositions, methods of manufacturing such aqueous compositions, and methods of removing reducing and/or suppressing malodours using such aqueous compositions are described. These compositions utilize a combination of hydrogen peroxide, a source of copper II, nonionic surfactant and alcohol to provide a highly effective and stable malodour removing, reducing and/or suppressing composition. The compositions are particularly useful as aerosol compositions for effective malodour removal, reduction and/or suppression in particular malodours from open sites such as landfill and in closed domestic environments such as the home. Also described is a stabilized hydrogen peroxide solution, which is stable on the addition of copper (II) salts.
    Type: Grant
    Filed: June 5, 2017
    Date of Patent: March 9, 2021
    Assignee: 2PURE PRODUCTS LIMITED
    Inventor: Peter Carty
  • Patent number: 10685868
    Abstract: A method of fabricating a contact hole includes the steps of providing a conductive line, a mask layer covering and contacting the conductive line, a high-k dielectric layer covering and contacting the mask layer, and a first silicon oxide layer covering and contacting the high-k dielectric layer, wherein the high-k dielectric layer includes a first metal oxide layer, a second metal oxide layer and a third metal oxide layer stacked from bottom to top. A dry etching process is performed to etch the first silicon oxide layer, the high-k dielectric layer, and the mask layer to expose the conductive line and form a contact hole. Finally, a wet etching process is performed to etch the first silicon oxide layer, the third metal oxide layer and the second metal oxide layer to widen the contact hole, and the first metal oxide layer remains after the wet etching process.
    Type: Grant
    Filed: August 28, 2019
    Date of Patent: June 16, 2020
    Assignees: UNITED MICROELECTRONICS CORP., Fujian Jinhua Integrated Circuit Co., Ltd.
    Inventors: Feng-Yi Chang, Shih-Fang Tzou, Fu-Che Lee, Hsin-Yu Chiang, Yu-Ching Chen
  • Patent number: 10627161
    Abstract: A laboratory equipment having an inlet and outlet tube for gas to enter and exit using specific shaped tubes with multi-outlet apertures in form of a network to allow the gas to enter the drying chamber to dry the material. The specific shaped tubes are in crescent shape and cross each other to have maximum surface area exposure to the drying chamber and effectively contact the material that is being dried. A gas inlet valve and outlet valve control the flow, pressure and temperature of the gas that is being used for drying the material to make nano material. A method of using the laboratory equipment with special gas inlet tubes is used for drying the material in form a slurry to make dry nano material.
    Type: Grant
    Filed: January 24, 2018
    Date of Patent: April 21, 2020
    Assignee: KING ABDULAZIZ CITY FOR SCIENCE AND TECHNOLOGY (KACST)
    Inventors: Mohammed Ahmad S. Alshamsi, Sulaiman Mohammed Alfadul
  • Patent number: 10546762
    Abstract: Methods of drying a semiconductor substrate may include applying a drying agent to a semiconductor substrate, where the drying agent wets the semiconductor substrate. The methods may include heating a chamber housing the semiconductor substrate to a temperature above an atmospheric pressure boiling point of the drying agent until a vapor-liquid equilibrium of the drying agent within the chamber has been reached. The methods may further include venting the chamber, where the venting vaporizes the liquid phase of the drying agent from the semiconductor substrate.
    Type: Grant
    Filed: November 15, 2017
    Date of Patent: January 28, 2020
    Assignee: Applied Materials, Inc.
    Inventors: Eric J. Bergman, John L. Klocke, Paul McHugh, Stuart Crane, Richard W. Plavidal
  • Patent number: 10541131
    Abstract: A semiconductor structure, a method, and an apparatus for in-situ sulfur vapor passivation of an interface surface of an indium gallium arsenide layer of the semiconductor structure. A method includes elemental sulfur-vapor passivation of an interface surface of an indium gallium arsenide layer disposed on a substrate. A dielectric layer can be deposited on the sulfur-vapor passivated interface surface. An annealing process can be performed after the deposition of the dielectric layer. The annealing process anneals the indium gallium arsenide layer including the sulfur-vapor passivated interface surface and the dielectric layer disposed on the sulfur-vapor passivated interface surface. The sulfur-vapor passivation, the deposition of the dielectric layer, and the anneal, can be performed in-situ in a vacuum chamber without breaking a vacuum of the vacuum chamber following a III-V material growth process in the vacuum chamber to form the indium gallium arsenide layer.
    Type: Grant
    Filed: June 5, 2018
    Date of Patent: January 21, 2020
    Assignee: International Business Machines Corporation
    Inventors: Yun Seog Lee, Talia S. Gershon, Joel P. De Souza, Devendra K. Sadana
  • Patent number: 10541130
    Abstract: A semiconductor structure, a method, and an apparatus for in-situ sulfur vapor passivation of an interface surface of an indium gallium arsenide layer of the semiconductor structure. A method includes elemental sulfur-vapor passivation of an interface surface of an indium gallium arsenide layer disposed on a substrate. A dielectric layer can be deposited on the sulfur-vapor passivated interface surface. An annealing process can be performed after the deposition of the dielectric layer. The annealing process anneals the indium gallium arsenide layer including the sulfur-vapor passivated interface surface and the dielectric layer disposed on the sulfur-vapor passivated interface surface. The sulfur-vapor passivation, the deposition of the dielectric layer, and the anneal, can be performed in-situ in a vacuum chamber without breaking a vacuum of the vacuum chamber following a III-V material growth process in the vacuum chamber to form the indium gallium arsenide layer.
    Type: Grant
    Filed: June 5, 2018
    Date of Patent: January 21, 2020
    Assignee: International Business Machines Corporation
    Inventors: Yun Seog Lee, Talia S. Gershon, Joel P. De Souza, Devendra K. Sadana
  • Patent number: 10541129
    Abstract: A semiconductor structure, a method, and an apparatus for in-situ sulfur vapor passivation of an interface surface of an indium gallium arsenide layer of the semiconductor structure. A method includes elemental sulfur-vapor passivation of an interface surface of an indium gallium arsenide layer disposed on a substrate. A dielectric layer can be deposited on the sulfur-vapor passivated interface surface. An annealing process can be performed after the deposition of the dielectric layer. The annealing process anneals the indium gallium arsenide layer including the sulfur-vapor passivated interface surface and the dielectric layer disposed on the sulfur-vapor passivated interface surface. The sulfur-vapor passivation, the deposition of the dielectric layer, and the anneal, can be performed in-situ in a vacuum chamber without breaking a vacuum of the vacuum chamber following a III-V material growth process in the vacuum chamber to form the indium gallium arsenide layer.
    Type: Grant
    Filed: August 7, 2017
    Date of Patent: January 21, 2020
    Assignee: International Business Machines Corporation
    Inventors: Yun Seog Lee, Talia S. Gershon, Joel P. De Souza, Devendra K. Sadana
  • Patent number: 10494715
    Abstract: Methods and apparatuses for removing photoresist patterning scum from patterning mandrel structures without damaging other features or structures on a semiconductor substrate are desirable for patterning precision. Methods involve cleaning carbon-containing features on a semiconductor substrate by an atomic layer cleaning (ALC) process to descum the carbon-containing features without substantially modifying feature critical dimensions. The ALC process involves exposing the carbon-containing features to an oxidant or reductant in absence of a plasma, or other energetic activation, to modify scum on the surface of the carbon-containing features. The modified scum on the surface of the carbon-containing features is then exposed to an inert gas along with a plasma ignited at a pressure between 0.1 Torr and 10 Torr and a power of less than 200 W to remove the modified scum from the surface of the carbon-containing features.
    Type: Grant
    Filed: July 19, 2017
    Date of Patent: December 3, 2019
    Assignee: LAM RESEARCH CORPORATION
    Inventors: Pulkit Agarwal, Purushottam Kumar, Adrien LaVoie
  • Patent number: 10283345
    Abstract: Methods for processing a substrate are provided herein. In some embodiments, a method of processing a substrate includes: heating a substrate disposed within a processing volume of a substrate processing chamber to a temperature of up to about 400 degrees Celsius, wherein the substrate comprises a first surface, an opposing second surface, and an opening formed in the first surface and extending towards the opposing second surface, and wherein the second surface comprises a conductive material disposed in the second surface and aligned with the opening; and exposing the substrate to a process gas comprising about 80 to about 100 wt. % of an alcohol to reduce a contaminated surface of the conductive material.
    Type: Grant
    Filed: September 29, 2016
    Date of Patent: May 7, 2019
    Assignee: APPLIED MATERIALS, INC.
    Inventors: Xiangjin Xie, Feng Q. Liu, Daping Yao, Alexander Jansen, Joung Joo Lee, Adolph Miller Allen, Xianmin Tang, Mei Chang
  • Patent number: 10236381
    Abstract: A method of manufacturing an integrated circuit is provided. According to the method, a layered fin including a plurality of sacrificial layers and semiconductor layers wherein two adjacent semiconductor layers are separated by the sacrificial layer is provided on a semiconductor substrate. A gate over the layered fin and a spacer surrounding a sidewall of the gate are then formed. The sacrificial layers are subsequently removed to provide a structure in which two adjacent semiconductor layers are separated by a gap. The method further includes forming an insulator in the gap and forming source and drain regions located on the layered fin. The insulator includes a high-K dielectric material surrounded by a low-K dielectric material, both of which are in contact with the two adjacent semiconductor layers.
    Type: Grant
    Filed: May 30, 2017
    Date of Patent: March 19, 2019
    Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventors: Kangguo Cheng, Juntao Li, Geng Wang, Qintao Zhang