Sulfur Or Sulfur Containing Component Patents (Class 423/242.1)
  • Patent number: 8715380
    Abstract: A method for deep desulfurization of synthesis gas comprising introducing carbonaceous material and optionally steam into a gasifier comprising a heat transfer media, extracting a first heat transfer stream comprising heat transfer media and optionally unconverted carbonaceous material from the gasifier, and introducing at least a portion of the first heat transfer stream into a combustor, introducing oxidant and optionally a fuel into the combustor, extracting a second heat transfer stream comprising heat transfer media from the combustor, and introducing at least a portion of the second heat transfer stream into the gasifier, introducing a compound capable of reacting with sulfur to produce sulfate, sulfide or both, extracting a purge stream comprising ash, sulfate, halide, or a combination thereof from the second heat transfer stream, extracting a flue gas from the combustor, and extracting a gasifier product synthesis gas stream comprising less than 1000 ppm sulfur from the gasifier.
    Type: Grant
    Filed: August 8, 2013
    Date of Patent: May 6, 2014
    Assignee: Rentech, Inc.
    Inventors: George Apanel, Harold A. Wright
  • Patent number: 8703081
    Abstract: Sorbent compositions containing halogen and calcium are added to coal to mitigate the release of sulfur and/or other harmful elements, including mercury, into the environment during combustion of coal containing natural levels of mercury.
    Type: Grant
    Filed: September 25, 2013
    Date of Patent: April 22, 2014
    Assignee: NOx II, Ltd.
    Inventor: Douglas C. Comrie
  • Patent number: 8703084
    Abstract: A method and apparatus for eliminating COS and/or CS2 from a hydrocarbon-containing feed stream, and further eliminating H2S from such feed stream or converting all sulfur species in such feed stream to H2S and SO2 to allow for easy subsequent conversion of such H2S and SO2 to elemental sulfur in a Claus reaction. The method comprises: (i) injecting water so that the feed stream contains greater than 10 vol % (water equivalent); (ii) passing the feed stream through catalyst means which hydrogenates COS and/or CS2 to H2S; (iii) injecting O2 so that the stoichiometric ratio of O2 to H2S is at least 0.5:1.0; (iv) passing the stream though a reaction zone having oxidation catalyst means which oxidizes H2S to elemental sulfur or SO2 (depending on the amount of oxygen and water added); where the temperature of the reaction zone is above the elemental sulfur dew point.
    Type: Grant
    Filed: February 17, 2012
    Date of Patent: April 22, 2014
    Assignee: Archon Technologies Ltd.
    Inventors: Conrad Ayasse, Ahmed M. Shahin, Alan Ayasse
  • Patent number: 8696931
    Abstract: A method of production of activated carbon for removal of mercury gas which provides activated carbon impregnated with both sulfur and iodine which gives a higher mercury gas adsorption performance compared with a conventional activated carbon adsorbent and also enables the prime cost of manufacture to be kept down, that is, a method of production provided with a sulfur impregnation step which adds sulfur to activated carbon and heats the mixture to obtain sulfur-impregnated activated carbon comprised of activated carbon to 100 parts by weight of which sulfur is impregnated in 5 to 20 parts by weight and, after the sulfur impregnation step, an iodine substance impregnation step which adds an aqueous solution containing iodine and an iodine salt to the sulfur-impregnated activated carbon.
    Type: Grant
    Filed: October 10, 2011
    Date of Patent: April 15, 2014
    Assignee: Futamura Kagaku Kabushiki Kaisha
    Inventors: Hideto Mamiya, Sunao Inada
  • Patent number: 8691167
    Abstract: The present invention provides for a process for handling carbonyl sulfide waste and waste metal halides produced in industrial processes and, more particularly chlorination processes. The process includes the steps of hydrolyzing the carbonyl sulfide to produce a waste stream containing hydrogen sulfide and sulfidizing the resulting hydrogen sulfide containing stream with a solution of the waste metal halides. The resulting metal sulfide and metal halide-containing stream can be neutralized before disposal of the produced waste solids.
    Type: Grant
    Filed: July 19, 2012
    Date of Patent: April 8, 2014
    Assignee: Tronox LLC
    Inventor: Harry Eugene Flynn
  • Patent number: 8679432
    Abstract: The invention relates to an adsorber, including a reaction chamber, an adsorbent having adsorption properties enabling the at least partial removal of water from a gas stream including NOx and/or SOx, and a coating essentially consisting of a polymer material on at least a portion of the inner metal wall of the reaction chamber, said polymer being resistant to the acidic liquids at temperatures above 150° C.
    Type: Grant
    Filed: July 5, 2011
    Date of Patent: March 25, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Ivan Sanchez-Molinero, Serge Moreau
  • Patent number: 8679431
    Abstract: An air pollution control system comprises a SOx removal equipment for reducing sulfur oxides from flue gas from a boiler, a cooler for reducing the sulfur oxides that remain in the flue gas and for decreasing a gas temperature, CO2 recovery equipment including an absorber for bringing CO2 in the flue gas into contact with a CO2 absorption liquid so as to be reduced, a regenerator for causing the CO2 absorption liquid to emit CO2 so as to recover CO2 and regenerate the CO2 absorption liquid, a heat exchanger which for decreasing a temperature of the flue gas, and calcium carbonate spraying equipment for spraying calcium carbonate between the heat exchanger and an electric dust collector, wherein a mist generation material in the flue gas is converted from a gas state to a mist state to arrest and reduce the mist generation material in the mist state using calcium carbonate.
    Type: Grant
    Filed: May 31, 2011
    Date of Patent: March 25, 2014
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Tatsuto Nagayasu, Takashi Kamijo, Masayuki Inui, Tsuyoshi Oishi, Hiromitsu Nagayasu, Hiroshi Tanaka, Takuya Hirata, Tatsuya Tsujiuchi, Susumu Okino, Naoyuki Kamiyama, Seiji Yoshihara
  • Publication number: 20140072892
    Abstract: A hydrogen generation apparatus including: a first desulfurizer; a second desulfurizer; a reformer to generate a hydrogen-containing reformed gas from a raw material gas from which sulfur has been removed by at least one of the first desulfurizer and the second desulfurizer; and a recycle passage through which a part of the reformed gas generated by the reformer is mixed into the raw material gas to be supplied to the second desulfurizer. After installation or maintenance of the hydrogen generation apparatus, the raw material gas is supplied to the reformer through the first desulfurizer until a catalyst in the second desulfurizer is activated by a mixed gas of the reformed gas supplied through the recycle passage and the raw material gas, and after the catalyst in the second desulfurizer is activated, the raw material gas is supplied to the reformer through the second desulfurizer.
    Type: Application
    Filed: June 7, 2012
    Publication date: March 13, 2014
    Inventors: Akira Maenishi, Hidenobu Wakita, Seiji Fujihara, Masaki Nobuoka, Youji Kawaguchi, Kiyoshi Taguchi, Satoru Narita, Kunihiro Ukai
  • Patent number: 8658555
    Abstract: Compositions and methods useful for removing toxic industrial compounds from air are disclosed, wherein said composition comprises a mixture of hydrous metal oxide and graphite oxide. In a most preferred embodiment the composition comprises a mixture of zirconium hydroxide and graphene oxide.
    Type: Grant
    Filed: November 4, 2011
    Date of Patent: February 25, 2014
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventors: Teresa J. Bandosz, Mykola Seredych, Gregory W. Peterson, Christopher J. Karwacki
  • Publication number: 20140050643
    Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, and an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.
    Type: Application
    Filed: August 5, 2013
    Publication date: February 20, 2014
    Inventors: Baoquan Zhang, Xiaoqing Zhang
  • Publication number: 20140050645
    Abstract: A wet scrubber (8) for cleaning a process gas containing sulphur dioxide comprises an absorption vessel (40) operative for bringing the process gas into contact with an absorption liquid to absorb sulphur dioxide from the process gas. The wet scrubber (8) further comprises an acidification system (90) operative for mixing absorption liquid that has absorbed sulphur dioxide from the process gas with a carbon dioxide containing gas, an absorbent dissolution tank (54) operative for adding an absorbent material to at least a portion of the absorption liquid, and a return pipe (104) operative for returning to the absorption vessel (40) at least a portion of the absorption liquid that has been mixed with the carbon dioxide containing gas.
    Type: Application
    Filed: November 10, 2011
    Publication date: February 20, 2014
    Applicant: ALSTOM TECHNOLOGY, LTD.
    Inventor: Stefan O.H. Åhman
  • Patent number: 8636968
    Abstract: A method and apparatus for separating gaseous emission pollutants from a scrubber by using a narrow band of UV light energy emitted from an LED light source. The method includes sweeping the evolved gas away from the flow of liquid containing the pollutant using a non-reactive gas. The pollutant can be CO2, NOx, SOx, or other pollutants. The method can operate on multiple pollutants the gas stream, using different banks of LEDs, specifically tuned for a certain pollutant.
    Type: Grant
    Filed: January 13, 2011
    Date of Patent: January 28, 2014
    Inventor: Bamidele A. Omotowa
  • Publication number: 20140017129
    Abstract: Provided is an oxidation method and oxygen apparatus of sulfur compounds in a gas in which stable sulfur compounds such as carbonyl sulfide can be easily converted into sulfur oxide, and an analysis apparatus of sulfur compounds to which the oxidation method and the oxidation apparatus are applied. Sulfur compounds other than sulfur dioxide contained in a gas is subjected to a silent discharge treatment, whereby those sulfur compounds are oxidized and converted into sulfur dioxide. The analysis apparatus includes a silent discharge treatment unit in which a gas containing sulfur compounds is subjected to a silent discharge treatment to oxidize sulfur compounds other than sulfur dioxide to be converted into sulfur dioxide, and an analyzing unit in which the concentration of sulfur dioxide contained in the gas which has been subjected to silent discharge treatment in the silent discharge treatment unit is measured.
    Type: Application
    Filed: July 10, 2013
    Publication date: January 16, 2014
    Inventors: Yusuke Miki, Yasuo Hirose
  • Patent number: 8628741
    Abstract: This invention relates to a method and apparatus for treating a flue gas stream containing oxygen containing greenhouse gases. In particular, the method comprises reacting a flue gas steam with a molten aluminum or aluminum alloy bath, creating alumina and elemental carbon, elemental sulfur, and molecular nitrogen. The apparatus includes a reaction vessel for carrying out the reaction, as well as other equipment necessary for capturing and removing the reaction products. Further, the process can be used to cogenerate electricity using the excess heat generated by the process.
    Type: Grant
    Filed: April 26, 2011
    Date of Patent: January 14, 2014
    Inventors: Ronald G. Presswood, Jr., Ian C. Bishop
  • Patent number: 8623308
    Abstract: The invention provides a process for removing mercaptans from a gas stream comprising natural gas or inert gas and mercaptans, the process comprising the steps of: (a) contacting a first gas stream comprising natural gas or inert gas and mercaptans with a hydrodesulphurization catalyst in the presence of hydrogen in a hydrodesulphurization unit to obtain a second gas stream comprising natural gas or inert gas, which is depleted of mercaptans and enriched in H2S; (b) removing H2S from the second gas stream comprising natural gas or inert gas in a H2S removal unit to obtain a purified gas stream comprising natural gas or inert gas, which is depleted of mercaptans.
    Type: Grant
    Filed: August 2, 2005
    Date of Patent: January 7, 2014
    Assignee: Shell Oil Company
    Inventors: Anders Carlsson, Gijsbert Jan Van Heeringen
  • Patent number: 8617494
    Abstract: An apparatus and method to clean flue gases. As shown in FIG. 1, a condenser 10 is provided having two packed beds (20/26) and two condensate loops. The condensate loops are configured such that anti-corrosive agent (40/41) may injected. Corrosives are removed from flue gases as condensate containing anti-corrosive agents passes over the flue gases.
    Type: Grant
    Filed: April 2, 2012
    Date of Patent: December 31, 2013
    Assignee: ALSTOM Technology Ltd
    Inventors: Wuyin Wang, Stefan Ahman
  • Publication number: 20130343978
    Abstract: Methods for removing sulfur from a gas stream prior to sending the gas stream to a gas separation membrane system are provided. Two schemes are available. When the sulfur content is high or flow is relatively high, a scheme including two columns where one tower is regenerated if the sulfur concentration exceeds a preset value can be used. When the sulfur content is low or flow is relatively low, a scheme including one column and an absorption bed.
    Type: Application
    Filed: August 26, 2013
    Publication date: December 26, 2013
    Applicant: Saudi Arabian Oil Company
    Inventors: Jean-Pierre R. Ballaguet, Milind M. Vaidya, Sebastien A. Duval, Anwar H. Khawajah
  • Publication number: 20130336868
    Abstract: Dry processes, apparatus, compositions and systems are provided for reducing emissions of sulfur oxides, and sulfur dioxide in particular, and/or HCl in a process employing a combination of a dolomite hydrate sorbent and a sorbent doping agent administered to achieve coverage of a three-dimensional cross section of a passage carrying SOx and/or HCl-containing gases with a short but effective residence time at a temperature effective to provide significant sulfur dioxide and/or HCl reductions with high rates of reaction and sorbent utilization. The once-through, dry process can advantageously introduce the sorbent and sorbent doping agent dry or preferably as a slurry to enable uniform treatment. Preferred sorbent doping agents include water-soluble or water-dispersible copper and/or iron compositions which can be heated to an active form in situ by the flue gases being treated.
    Type: Application
    Filed: April 1, 2013
    Publication date: December 19, 2013
    Inventor: Fuel Tech, Inc.
  • Patent number: 8591846
    Abstract: A method and apparatus for processing a sour gas rich in carbon dioxide in a Claus process, so sulfur compounds are removed by a selective solvent in a gas scrubbing process. Sulfur components and carbon dioxide, are separated into at least two sour gas fractions, wherein at least one sour gas fraction having a higher content of sulfur components is obtained, wherein the fraction having the highest hydrogen sulfide content is introduced in the thermal reaction stage of the Claus furnace with a gas containing oxygen by means of a burner. The sulfur is converted to sulfur dioxide in the thermal reaction stage of the Claus furnace and exhaust gases are discharged into the closed Claus reaction chamber behind the burner. The remaining sour gas fractions stripped of sulfur components are fed to the Claus reaction chamber and are mixed with the combustion gases leaving the burner.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: November 26, 2013
    Assignee: Thyssenkrupp UHDE GmbH
    Inventor: Johannes Menzel
  • Patent number: 8591767
    Abstract: A functional fluid for the removal of contaminates such as but not limited to, acid causing components in gas, sulfur components and carbon oxides from fluid streams, and removal and treatment of NOX & SOX from post combustion emissions. Also described is the manufacturing process to produce the functional fluid both in a batch atmospheric process system as well as a closed system capable of operating at above or below atmospheric conditions.
    Type: Grant
    Filed: December 1, 2011
    Date of Patent: November 26, 2013
    Assignee: Specialist Process Technologies Limited
    Inventors: Theodore E. Dickinson, David John Parkinson, Kevin E. Collier
  • Patent number: 8591843
    Abstract: The invention relates to the use of a liquid, containing 0.1 to 100% of an amine or several amines of formula H2N—CH2(CHR2)x—(OCH2(CHR3)y)z—OR1, where R1=C1 to C6 alkyl, R2=H or CH3, R3=H or CH3, x=0 to 3, y=0 to 3, z=0 to 10 and 0 to 99.9% of any further solvent including piperazine and/or water for separating acid gas components from technical gases.
    Type: Grant
    Filed: February 28, 2007
    Date of Patent: November 26, 2013
    Assignee: UHDE GmbH
    Inventors: Johannes Menzel, Alexander Snell
  • Publication number: 20130309157
    Abstract: The present disclose is directed to a method for controlling iodine levels in wet scrubbers, and, in particular, recirculating wet scrubbers.
    Type: Application
    Filed: April 11, 2013
    Publication date: November 21, 2013
    Applicant: ADA-ES, INC.
    Inventors: Sharon Sjostrom, Kenneth E. Baldrey, Constance Senior
  • Patent number: 8580222
    Abstract: A single step process for degrading plastic waste by converting the plastic waste into carbonaceous products via thermal decomposition of the plastic waste by placing the plastic waste into a reactor, heating the plastic waste under an inert or air atmosphere until the temperature of about 700° C. is achieved, allowing the reactor to cool down, and recovering the resulting decomposition products therefrom. The decomposition products that this process yields are carbonaceous materials, and more specifically carbon nanotubes having a partially filled core (encapsulated) adjacent to one end of the nanotube. Additionally, in the presence of a transition metal compound, this thermal decomposition process produces multi-walled carbon nanotubes.
    Type: Grant
    Filed: March 16, 2012
    Date of Patent: November 12, 2013
    Assignee: Uchicago Argonne, LLC
    Inventors: Vilas G. Pol, Pappannan Thiyagarajan
  • Patent number: 8574453
    Abstract: One aspect of the present invention relates to salts that are room-temperature ionic liquids (RTILs), methods of making them, and methods of using them in connection with temporary or permanent gas sequestration. Another aspect of the present invention relates to a class of solvents which can be transformed into RTILs by exposure to a gas, and methods of using them in connection with temporary or permanent gas sequestration.
    Type: Grant
    Filed: January 28, 2008
    Date of Patent: November 5, 2013
    Assignee: Georgetown University
    Inventors: Tao Yu, Richard G. Weiss, Taisuke Yamada, Mathew George
  • Patent number: 8568676
    Abstract: A process for workup of an industrial carbon dioxide-rich gas to be freed of sulfur components, in which an industrial gas to be freed of sulfur components is purified by a gas scrubbing, and the laden solvent is freed of carbon dioxide and hydrogen sulfide by a regeneration to obtain at least one acid gas fraction having a relatively high content of sulfur components, and the fraction with the highest hydrogen sulfide (H2S) content is supplied to a Claus plant with downstream Claus process gas hydrogenation, and at least one carbon dioxide-laden, low-hydrogen sulfide acid gas fraction from the regeneration device, which has a reduced sulfur content compared to the fraction with the highest hydrogen sulfide (H2S) content, is combined with the hydrogenated Claus process gas to give a combined process gas stream, which is supplied to further processing or to recycling into the process.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: October 29, 2013
    Assignee: Thyssenkrupp Uhde GmbH
    Inventor: Johannes Menzel
  • Patent number: 8568679
    Abstract: Disclosed is a process for the removal of sulfur from a fuel gas stream that additionally contains carbon dioxide and a light olefin as well as an organic sulfur compound. The process includes hydrotreating the fuel gas stream followed by a catalytic reduction of the resulting hydrotreated fuel gas to remove the carbonyl sulfide contained therein that is yielded in the hydrotreating step as a result of the equilibrium reaction of hydrogen disulfide with carbon dioxide to yield carbonyl sulfide and water.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: October 29, 2013
    Assignee: Shell Oil Company
    Inventor: Gary Lee Ripperger
  • Publication number: 20130280155
    Abstract: Amine compositions comprising sterically hindered amines and associated methods are provided. In some embodiments, amine compositions of the present disclosure may be useful for selective removal of H2S from an acidic gas stream.
    Type: Application
    Filed: November 21, 2011
    Publication date: October 24, 2013
    Applicant: HUNTSMAN PETROCHEMICAL LLC
    Inventors: Wei-Yang Su, Robert A. Grigsby, JR., Jingjun Zhou
  • Publication number: 20130259788
    Abstract: An apparatus and method to clean flue gases. As shown in FIG. 1, a condenser 10 is provided having two packed beds (20/26) and two condensate loops. The condensate loops are configured such that anti-corrosive agent (40/41) may injected. Corrosives are removed from flue gases as condensate containing anti-corrosive agents passes over the flue gases.
    Type: Application
    Filed: April 2, 2012
    Publication date: October 3, 2013
    Applicant: Alstom Power, Inc.
    Inventors: Wuyin Wang, Stefan Ahman
  • Patent number: 8545778
    Abstract: Sorbent compositions containing halogen and calcium are added to coal to mitigate the release of sulfur and/or other harmful elements, including mercury, into the environment during combustion of coal containing natural levels of mercury.
    Type: Grant
    Filed: November 16, 2012
    Date of Patent: October 1, 2013
    Assignee: NOx II, Ltd.
    Inventor: Douglas C. Comrie
  • Patent number: 8535630
    Abstract: The present invention relates to a method for combined SO2 and CO2 removal from flue gas, which includes removing both CO2 and SO2 in a primary fractionation column and two polishing columns, the method comprising: a) hot flue as pretreatment, including flue gas SO3 removal by dry sorbent injection; b) compressing the treated hot flue gas by a multi-stage compressor; c) separation of CO2, SO2 and non-condensable gases; d) subjecting the CO2 and SO2 to separate polishing columns; and e) combining streams from the primary fractionation column and the two polishing columns for power recovery.
    Type: Grant
    Filed: November 6, 2012
    Date of Patent: September 17, 2013
    Assignee: Bechtel Power Corporation
    Inventors: Harvey Wen, Charles L. Kimtantas
  • Patent number: 8529852
    Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, and an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.
    Type: Grant
    Filed: March 26, 2012
    Date of Patent: September 10, 2013
    Inventors: Baoquan Zhang, Xiaoqing Zhang
  • Patent number: 8518356
    Abstract: A feed gas comprising CO2, H2S and H2 is treated to produce an H2-enriched product and an H2S-lean, CO2 product. The feed gas is separated to provide the H2-enriched product and a stream of sour gas. The stream of sour gas is divided into two parts, one of which is processed in an H2S removal system to form one or more streams of sweetened gas, and the other of which bypasses the H2S removal system, the stream(s) of sweetened gas and the sour gas bypassing the H2S removal system then being recombined to form the H2S-lean, CO2 product gas. The division of the sour gas between being sent to and bypassing the H2S removal system is adjusted responsive to changes in the H2S content of the sour gas, so as to dampen or cancel the effects of said changes on the H2S content of the H2S-lean, CO2 product gas.
    Type: Grant
    Filed: July 27, 2010
    Date of Patent: August 27, 2013
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Charles Linford Schaffer, Andrew David Wright, Kevin Boyle Fogash, Jeffrey William Kloosterman, Jeffrey Raymond Hufton
  • Publication number: 20130216460
    Abstract: A method of reducing sulfur compounds from an incoming gas stream, comprising flowing the gas stream over a hydrolysis catalyst to convert COS and CS2 to H2S and reduce SO2 to elemental sulfur to form an effluent stream; providing an acidic gas removal unit comprising an absorbent; flowing said effluent stream over said absorbent to produce a stream free of acidic gases; applying an acidic-gas desorption mode to said acidic-gas rich absorbent to produce an acidic gas stream; introducing oxygen to said acidic gas-rich stream; providing a direct oxidation vessel containing catalyst suitable for catalyzing the oxidation of the H2S to sulfur wherein the temperature of the vessel is at or above the sulfur dew point at the reaction pressure; and flowing said acidic gas-rich stream over said catalyst to produce a processed stream having a reduced level of sulfur compounds.
    Type: Application
    Filed: July 10, 2012
    Publication date: August 22, 2013
    Applicant: ARCHON TECHNOLOGIES LTD.
    Inventors: Alan AYASSE, Ahmed M. SHAHIN, Conrad AYASSE
  • Patent number: 8512661
    Abstract: A process for the efficient capture of CO2 and sulfur from combustion flue gas streams and gasification based fuel gas mixtures using regenerable and recyclable calcium based sorbents. The regeneration of the calcium sorbent is accomplished by hydrating the sorbent at high temperatures of about 600° C. and a pressure higher than 6 bars to lower the parasitic energy consumption.
    Type: Grant
    Filed: May 19, 2011
    Date of Patent: August 20, 2013
    Assignee: The Ohio State University Research Foundation
    Inventors: Liang-Shih Fan, Shwetha Ramkumar, William Wang, Robert Statnick
  • Patent number: 8501135
    Abstract: A method of reducing sulfur compounds from an incoming gas stream, comprising flowing the gas stream over a hydrolysis catalyst to convert COS and CS2 to H2S and reduce SO2 to elemental sulfur to form an effluent stream; providing an acidic gas removal unit comprising an absorbent; flowing said effluent stream over said absorbent to produce a stream free of acidic gases; applying an acidic-gas desorption mode to said acidic-gas rich absorbent to produce an acidic gas stream; introducing oxygen to said acidic gas-rich stream; providing a direct oxidation vessel containing catalyst suitable for catalyzing the oxidation of the H2S to sulfur wherein the temperature of the vessel is at or above the sulfur dew point at the reaction pressure; and flowing said acidic gas-rich stream over said catalyst to produce a processed stream having a reduced level of sulfur compounds.
    Type: Grant
    Filed: July 10, 2012
    Date of Patent: August 6, 2013
    Assignee: Archon Technologies Ltd.
    Inventors: Alan Ayasse, Ahmed M. Shahin, Conrad Ayasse
  • Patent number: 8501127
    Abstract: An neutralization system includes a main chamber and a secondary chamber linked by a tube, wherein main chamber includes a gas main inlet duct and a gas outlet tube; a tube with nozzles that allows passage of steam in form of steam curtain; a propeller located at a center portion of main chamber; a first flexible tube placed on an upper side and exiting out of a top face of main chamber and rejoining main chamber in a main entrance of gases; at least two additional flexible tubes exiting a side of main chamber; an electric motor that extracts gases and allows pressurized gas to enter flexible tubes; an eviction-tube of liquid waste located at a bottom portion and inwardly of main chamber; an exhaust duct for treated gases located in a rear portion of main chamber which connects through a tube main chamber to secondary chamber.
    Type: Grant
    Filed: January 10, 2011
    Date of Patent: August 6, 2013
    Assignee: Masteridea S.A.
    Inventors: Luis Vicente Gonzalez Portales, Jean Paul Oliger Gonzalez
  • Patent number: 8501134
    Abstract: The invention relates to a process and catalyst for the oxidative desulfurization of hydrocarbonaceous oil. In one aspect, solid carbon materials are provided having stable sulfur trioxide and nitrogen dioxide oxidative species on the surface thereof. Such materials are useful in the production of low sulfur hydrocarbon feedstocks and in the removal of refractory sulfur compounds.
    Type: Grant
    Filed: November 28, 2011
    Date of Patent: August 6, 2013
    Assignee: Saudi Arabian Oil Company
    Inventor: Ki-Hyouk Choi
  • Patent number: 8500881
    Abstract: The present invention discloses a carbon dioxide capture power generation system provided with a boiler to combust a fuel in the oxygen atmosphere, a carbon dioxide capture equipment to remove carbon dioxide in the wake flow of the boiler, a piping branching from the wake flow of the boiler to recycle the combustion exhaust gas to the boiler, and a desulfurization equipment to remove sulfur oxides and a sulfuric acid removal equipment to remove a sulfuric acid gas in the upstream of carbon dioxide capture equipment and in the wake flow of the boiler.
    Type: Grant
    Filed: August 19, 2010
    Date of Patent: August 6, 2013
    Assignee: Hitachi, Ltd.
    Inventors: Hisayuki Orita, Masaaki Mukaide, Nobuyuki Hokari, Tsuyoshi Shibata, Masayuki Taniguchi
  • Patent number: 8496895
    Abstract: Disclosed are an exhaust gas treating apparatus and a treating method for a carbon dioxide capture process, in which harmful substances remaining in the exhaust gas discharged from the conventional flue-gas desulfurization process are additionally removed for efficient performance of the carbon dioxide capture process. According to the exhaust gas treating apparatus for a carbon dioxide capture process, it has the effects of minimizing the installation space of desulfurization equipment and reducing the process cost. In addition, by keeping the contaminants contained in the gas introduced in the carbon dioxide capture equipment below a proper level, absorption performance can be improved as degradation of the absorbent used in the carbon dioxide capture process is prevented. After all, it has an advantage of preventing the pollution by the exhaust gas discharged into the atmosphere.
    Type: Grant
    Filed: January 27, 2012
    Date of Patent: July 30, 2013
    Assignee: Korea Institute of Energy Research
    Inventors: Hyung-Keun Lee, Won-Kil Choi, Hang-Dae Jo, Chang-Keun Yi, Sung-Ho Jo, Young-Cheol Park
  • Patent number: 8486366
    Abstract: Concentrated aqueous hydrogen peroxide or another reactive compound in a liquid carrier is activated by atomization and contact with a suitable catalyst that is concurrently atomized in a carrier liquid. Concentrated hydrogen peroxide and a hydrogen peroxide activation catalyst are atomized into a droplet spray for catalytic activation of the hydrogen peroxide in this invention, useful for treatment of a combustion flue gas containing contaminants such as NO? and/or Hg.
    Type: Grant
    Filed: July 29, 2010
    Date of Patent: July 16, 2013
    Assignees: FMC Corporation, Indigo Technologies Group Pty Ltd
    Inventors: Henry A. Pfeffer, Timothy A. Holtz, Rodney J. Truce, JoAnn Pacinelli, Luke F. Wilkinson
  • Patent number: 8480982
    Abstract: A syngas treatment plant is configured to remove sulfurous compounds and carbon dioxide from shifted or un-shifted syngas in a configuration having a decarbonization section and a desulfurization section. Most preferably, the solvent in the decarbonization section is regenerated and cooled by flashing, while the solvent is regenerated in the desulfurization section via stripping using external heat, and it is still further preferred that carbonylsulfide is removed in the desulfurization section via hydrolysis, and that the so produced hydrogen sulfide is removed in a downstream absorber.
    Type: Grant
    Filed: February 22, 2008
    Date of Patent: July 9, 2013
    Assignee: Fluor Technologies Corporation
    Inventors: John Mak, Richard Nielsen
  • Patent number: 8475570
    Abstract: The invention provides a process for producing purified gas from feed gas comprising H2S, CO2 and HCN and/or COS, the process comprising the steps of: (a) contacting feed gas comprising H2S, CO2 and HCN and/or COS with a HCN/COS hydrolysis sorbent in the presence of water in a HCN/COS hydrolysis unit, thereby obtaining gas depleted in HCN and/or COS; (b) contacting the gas depleted in HCN and/or COS with absorbing liquid in an H2S/CO2 absorber to remove H2S and CO2, thereby obtaining the purified gas and absorbing liquid rich in H2S and CO2; (c) heating and de-pressurizing at least part of the absorbing liquid rich in H2S and CO2 to obtain hot flash gas enriched in CO2 and absorbing liquid enriched in H2S; (d) contacting the absorbing liquid enriched in H2S at elevated temperature with a stripping gas, thereby transferring H2S to the stripping gas to obtain regenerated absorbing liquid and stripping gas rich in H2S; and (e) leading at least part of the flash gas enriched in CO2 to the HCN/COS hydrolysis unit
    Type: Grant
    Filed: July 28, 2008
    Date of Patent: July 2, 2013
    Assignee: Shell Oil Company
    Inventors: Anthonius Maria Demmers, Sandra Schreuder
  • Publication number: 20130139738
    Abstract: A gas cleaning system (8) for cleaning a carbon dioxide rich flue gas containing sulphur dioxide generated in a boiler (2) comprises a first gas cleaning device (10) being operative for removing at least 80% of the sulphur dioxide content of the flue gas generated in the boiler (2), thereby generating a partly cleaned carbon dioxide rich flue gas, and a second gas cleaning device (12), being separate from the first gas cleaning device (10) and being operative for receiving at least a portion of the partly cleaned carbon dioxide rich flue gas that passed through the first gas cleaning device (10). The second gas cleaning device (12) is operative for removing at least a portion of the water content of the partly cleaned carbon dioxide rich flue gas by means of cooling the partly cleaned carbon dioxide rich flue gas to condense water there from.
    Type: Application
    Filed: October 26, 2010
    Publication date: June 6, 2013
    Inventors: Jörgen P. Grubbström, Wuyin Wang
  • Patent number: 8449653
    Abstract: A system for enhancing the efficiency of an electrostatic precipitator in a flue gas stream that withdraws a selected amount of combustion gas from a main flue gas stream at a location downstream of the electrostatic precipitator; typically heats the selected amount of combustion gas to a predetermined temperature; passes the selected amount of combustion gas through a catalyst to convert sulfur dioxide to sulfur trioxide producing a mixture of flue gas enriched with sulfur trioxide; and returns the mixture of the flue gas enriched with the sulfur trioxide back into the main flue gas stream at a point upstream of the electrostatic precipitator. A controller can control fans, heaters and dampers as well as make computations as the required amount of sulfur trioxide needed.
    Type: Grant
    Filed: June 27, 2011
    Date of Patent: May 28, 2013
    Inventor: Henry Krigmont
  • Publication number: 20130129588
    Abstract: Systems and methods directed to cleaning a flue gas are described, in which a column housing can be configured to receive a feed stream, and includes an absorber configured to produce a clean stream that is substantially depleted of at least one of SOx and CO2. The absorber can comprise at least one of (1) a primary CO2 capture system disposed downstream of a gas conditioning system and (2) a primary acid gas removal system disposed upstream of a gas conditioning system. The gas conditioning system can also be disposed in the column housing.
    Type: Application
    Filed: November 22, 2011
    Publication date: May 23, 2013
    Applicant: FLUOR TECHNOLOGIES CORPORATION
    Inventors: Dennis W. Johnson, James H. Brown
  • Patent number: 8444943
    Abstract: Apparatus and methods for recovering sulfur from acid gases. Acid gases containing relatively high amounts of carbonyl sulfide and/or one or more types of mercaptans can be treated in a sulfur recovery system employing an acid gas enrichment zone and a tail gas treatment zone, where partially-loaded sulfur absorbing solvent from the tail gas treatment zone is employed for sulfur absorption in the acid gas enrichment zone. Off-gas from the acid gas enrichment zone can be combined and hydrogenated with a sulfur recovery unit tail gas thereby increasing the total amount of sulfur recovery from the initial acid gas.
    Type: Grant
    Filed: April 30, 2010
    Date of Patent: May 21, 2013
    Assignee: Black & Veatch Corporation
    Inventor: Justin A. Lamar
  • Publication number: 20130115155
    Abstract: The invention relates to an adsorber, including a reaction chamber, an adsorbent having adsorption properties enabling the at least partial removal of water from a gas stream including NOx and/or SOx, and a coating essentially consisting of a polymer material on at least a portion of the inner metal wall of the reaction chamber, said polymer being resistant to the acidic liquids at temperatures above 150° C.
    Type: Application
    Filed: July 5, 2011
    Publication date: May 9, 2013
    Applicant: L'AIR LIQUIDE SOCIETE ANONYME POUR I'ETUDE ET I'EXPLOITATION DES PROCEDES GEORGE CLAUDE
    Inventors: Ivan Sanchez-Molinero, Serge Moreau
  • Publication number: 20130101486
    Abstract: An online monitoring and controlling system is used for monitoring and controlling sulfur content in heat stable salts or in a flue gas stream. The system comprises valves, sensors and analyzers that are operated by a valve flow and control system that regulates the valves to redirect flow of the heat stable salt or the flue gas stream to reduce the sulfur to below a desirable value. The valve and flow control system is automated and uses a feedback loop to control the sulfur content.
    Type: Application
    Filed: October 19, 2011
    Publication date: April 25, 2013
    Applicant: ALSTOM TECHNOLOGY LTD.
    Inventors: Zheng Liu, Naresh Handagama, Barath Baburao
  • Publication number: 20130095015
    Abstract: The present invention provides a method and apparatus for the treatment of process gas from an anaerobic digestion system or a landfill gas system. In one embodiment, the system comprises a caustic scrubber including a vertical column having a top and a bottom and including a counter current flow system, wherein a process gas stream flows up vertically through the column in counter current flow to a caustic liquid solution that flows downward through the column.
    Type: Application
    Filed: March 30, 2012
    Publication date: April 18, 2013
    Inventor: Jeffrey J. Grill
  • Patent number: 8420037
    Abstract: An air pollution control system includes a desulfurization apparatus 13 that reduces sulfur oxide contained in flue gas 12 supplied from a boiler 11; and a CO2 recovery apparatus 15 including a CO2 absorber 21 that reduces CO2 contained in flue gas 12 that has been desulfurized by the desulfurization apparatus, with the aid of an amine absorbent and an absorbent regenerator 22 that regenerates the amine absorbent. Part 14a of desulfurized flue gas 14 containing SOx is supplied to treated flue gas 16, from which CO2 has been reduced and which is discharged from a top portion of the CO2 absorber 21, so that remaining mist amine accompanying the treated flue gas 16 is neutralized to amine sulfate or amine sulfite.
    Type: Grant
    Filed: November 28, 2011
    Date of Patent: April 16, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Masaki Iijima, Tsuyoshi Oishi, Takashi Kamijo, Hiroshi Tanaka, Hiromitsu Nagayasu, Naohiko Ukawa