Fe-base Component Patents (Class 428/681)
  • Patent number: 7510777
    Abstract: A thermal barrier coating (TBC) for a component intended for use in a hostile environment, such as a component of a gas turbine engine. The TBC exhibits improved impact and erosion resistance as a result of being a composite material consisting essentially of particles of a ceramic reinforcement material dispersed in a ceramic matrix material. The ceramic reinforcement material has a yield strength greater than the ceramic matrix material at about 1100° C., and the particles of the ceramic reinforcement material have an average maximum dimension of greater than five micrometers.
    Type: Grant
    Filed: December 16, 2005
    Date of Patent: March 31, 2009
    Assignee: General Electric Company
    Inventors: Ramgopal Darolia, Brian Thomas Hazel
  • Publication number: 20090081478
    Abstract: A method for preparing a protective layer (38) on a surface of the substrate (36) that requires a bonding temperature (BT) above a detrimental phase transformation temperature range (28) of the substrate, and then cooling the layer and substrate without cracking the layer or detrimentally transforming the substrate. The protective layer (38) and the substrate (36) are cooled from the bonding temperature (BT) to a temperature (46) above the detrimental phase transformation range (28) at a first cooling rate (30) slow enough to avoid cracking the protective layer. Next, the protective layer and the substrate are cooled to a temperature below the detrimental phase transformation range of the substrate at a second cooling rate (27) fast enough to pass the detrimental phase transformation range before a substantial transformation of the substrate into the detrimental phase can occur.
    Type: Application
    Filed: September 21, 2007
    Publication date: March 26, 2009
    Applicant: SIEMENS POWER GENERATION, INC.
    Inventor: Brij B. Seth
  • Publication number: 20090075118
    Abstract: Provided are metal structures and methods of forming such structures for use in oil, gas and/or petrochemical applications that are joined with non-ferrous weld metal compositions or a high alloy weld metal compositions. The welded metal structures include two or more segments of ferrous or non-ferrous components, and fusion welds, friction stir welds or a combination thereof bonding adjacent segments of the components together, wherein the welds comprise a non-ferrous weld metal composition or a high alloy weld metal composition that is substantially different from the metal composition of the two or more components. The resultant welded structures exhibit improvements in fatigue resistance, toughness, strain capacity, strength, stress corrosion cracking resistance, and hydrogen embrittlement resistance compared to traditional iron-based weld compositions.
    Type: Application
    Filed: September 18, 2007
    Publication date: March 19, 2009
    Inventors: Raghavan Ayer, Neeraj S. Thirumalai, Daniel B. Lillig, Steven J. Ford, Douglas P. Fairchild
  • Patent number: 7479329
    Abstract: Hematin, a hydroxyferriprotoporphyrin, is derivatized with one or more non-proteinaceous amphipathic groups. The derivatized hematin can serve as a mimic of horseradish peroxidase in polymerizing aromatic monomers, such as aromatic compounds. These derivatized hematins can also be used as catalysts in polymerizing aromatic monomers, and can exhibit significantly greater catalytic activity than underivatized hematin in acidic solutions. In one embodiment, polymerization is in the presence of a template, along which aromatic monomers align. An assembled hematin includes alternating layers of hematin and a polyelectrolyte, which are deposited on an electrically charged substrate. Assembled hematin can also be used to polymerize aromatic monomers.
    Type: Grant
    Filed: September 26, 2007
    Date of Patent: January 20, 2009
    Assignees: University of Massachusetts/Lowell, The United States of America as represented by the Secretary of the Army
    Inventors: Susan Tripathy, legal representative, Lynne A. Samuelson, Ferdinando F. Bruno, Sucharita Roy, Ramaswamy Nagarajan, Jayant Kumar, Bon-Cheol Ku, Soo-Hyoung Lee, Sukant Tripathy
  • Publication number: 20080318082
    Abstract: Disclosed are amorphous, ductile brazing foils with a composition consisting essentially of FeRestNiaCrbSicBdPe, wherein 0 atomic %?a<25 atomic %; 0 atomic %?b?15 atomic %; 1 atomic %?c?10 atomic %; 4 atomic %?d?15 atomic %; 1 atomic %?e?9 atomic %; any impurities?0.5 atomic %; rest Fe, wherein 2 atomic %?c+e?10 atomic % and 15 atomic %?c+d+e?22 atomic %, or consisting essentially of FeRestNiaCrbMofCugSicBdPe, wherein 0 atomic %?a<25 atomic %; 0 atomic %?b?15 atomic %; 1 atomic %<c?10 atomic %; 4 atomic %?d?15 atomic %; 1 atomic %?e?9 atomic %; 0 atomic %<f?3 atomic %; 0 atomic %?g?3 atomic %; any impurities?0.5 atomic %; rest Fe, wherein 2 atomic %?c+e?10 atomic % and 15 atomic %?c+d+e?22 atomic %. Also disclosed are brazed objects formed using these foils, particularly exhaust gas recirculation coolers and oil coolers, and methods for making the brazing foils and for making the brazed parts.
    Type: Application
    Filed: June 3, 2008
    Publication date: December 25, 2008
    Applicant: Vacuumschmelze GmbH & Co. KG
    Inventors: Thomas Hartmann, Dieter Nuetzel
  • Patent number: 7459219
    Abstract: An item made of wear resistant material, the item, in certain aspects, made by a method including forming a mass of wear resistant material, the wear resistant material comprising at least one element from the group consisting of arsenic, antimony, cerium and bismuth, wherein the at least one element is present by weight as between 0.01% to 0.0001% of a total weight of the wear resistant material, wherein the wear resistant material includes by weight percent chromium 29.10-30.00%; nickel 5.00-6.00%; titanium 1.00-2.10%; boron 3.00-3.90%; silicon 1.00-2.10%; manganese 1.10-2.00%; iron-balance.
    Type: Grant
    Filed: April 1, 2005
    Date of Patent: December 2, 2008
    Inventors: Jimmie Brooks Bolton, Billi Marie Rogers
  • Patent number: 7442445
    Abstract: A brazing clad material is a composite material that comprises a base material and a brazing material layer formed integrally on the base material. The brazing material layer has a Ni or Ni alloy layer, a Ti or Ti alloy layer and a Fe—Ni alloy layer that are sequentially stacked in this order on the base material. The brazing material layer has a Fe concentration of 25 to 40 wt % in the entire brazing material layer. The brazing material layer satisfies a ratio of W1/W2 to be 0.56 to 0.66, where W1 is a weight of Ni contained in the entire brazing material layer and W2 is a total weight of Ni and Ti contained in the entire brazing material layer.
    Type: Grant
    Filed: December 23, 2005
    Date of Patent: October 28, 2008
    Assignee: Hitachi Cable, Ltd.
    Inventors: Hideyuki Sagawa, Hiromitsu Kuroda, Kazuma Kuroki, Humio Horii, Tetsuya Tokumitu, Nobuhito Sakuyama, Shigeru Okamoto
  • Patent number: 7432815
    Abstract: Disclosed are a marker for a magnetic theft protection system, comprising: (a) at least one oblong alarm strip comprising an amorphous ferromagnetic alloy; and (b) at least one oblong activation strip comprising an alloy consisting essentially of formula NiaMobXcFeRest, wherein X is one or more of the elements from the group including Cr, W and V, and wherein a, b, and c are weight percentages, such that 15% by weight?a?25% by weight, 0% by weight?b?2.8% by weight, 0% by weight?c?8% by weight; and, wherein said activation strip has a coercitive force Hc of 10 A/cm to 25 A/cm and a remanence Br of at least 1.0 T; the activation strip itself, a tag containing the activation strip and/or marker, articles containing the marker or tag, methods for making the activation strip, and methods for making the marker.
    Type: Grant
    Filed: October 1, 2007
    Date of Patent: October 7, 2008
    Assignee: VACUUMSCHMELZE GmbH & Co. KG
    Inventors: Ottmar Roth, Hartwin Weber
  • Publication number: 20080233428
    Abstract: The present invention relates to wear-resistant mechanical parts.
    Type: Application
    Filed: March 21, 2008
    Publication date: September 25, 2008
    Applicant: Skaff Corporation of America, Inc.
    Inventor: Habib Skaff
  • Patent number: 7410705
    Abstract: A phosphate bonded ceramic is used to provide a protective coating on a rare earth-transition metal (RE-TM) alloy substrate, conferring degradation resistance to the alloy by being oxidation resistant and acting as a diffusion barrier, thereby minimising/preventing oxygen diffusion and elemental depletion. The alloy substrate may, for example, be a permanent magnetic alloy component and may be used in aerospace applications.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: August 12, 2008
    Assignee: Rolls-Royce PLC
    Inventors: J. M. Shipton, legal representative, Mark H. Shipton
  • Patent number: 7405010
    Abstract: A metallic body of carbon steel covered with an adhesive layer capable of adhering to a rubber matrix based on diene elastomer. The carbon content of the steel is between 0.35 and 1.2% by weight. The adhesive layer is formed of a metallic layer bearing aluminum oxides or hydroxides, which itself is covered with an organosilane film which is at least bifunctional, capable of ensuring, as coupling agent, the bond between the aluminum oxides or hydroxides on one hand, and the rubber matrix on the other hand.
    Type: Grant
    Filed: March 1, 2006
    Date of Patent: July 29, 2008
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Bruno Grimberg, Yves Ravoire, Jean-Claude Tardivat, Le Tu Anh Vo
  • Patent number: 7399535
    Abstract: A hot press-formed article having improved corrosion resistance and coating adhesion when coated is obtained by hot press forming of a zinc-based plated steel material. It has a zinc-based plating layer comprising an iron-zinc solid solution phase and atop it a zinc oxide layer. The average thickness of the zinc oxide layer which is the outermost layer is at most 2 ?m. A hot press-formed article having a good appearance and excellent corrosion resistance, coating adhesion, post-coating corrosion resistance, and weldability has a layer (2) consisting essentially of an iron-zinc solid solution phase atop a base material steel sheet (1). It also has a zinc oxide layer (3) with an average thickness of at most 5 ?m as an uppermost layer, but it does not have a substantial amount of an iron-zinc intermetallic compound phase. The total amount of Al contained in the iron-zinc solid solution layer (2) and the zinc oxide layer (3) is at most 0.
    Type: Grant
    Filed: October 21, 2005
    Date of Patent: July 15, 2008
    Assignees: Sumitomo Metal Industries, Ltd., Toyota Jodosha Kabushiki Kaisha, Toyoda Iron Works Co., Ltd.
    Inventors: Yukihiro Yoshikawa, Kazuhito Imai, Kunihiro Fukui, Tamotsu Toki, Shuntaro Sudo, Akira Obayashi, Masanobu Ichikawa
  • Patent number: 7399532
    Abstract: A corrosive resistant metal material covered with a conductive substance suitable for use in a component material requiring conductivity and corrosion resistance like electrical conductive material, electrical contact, electromagnetic wave shield, electrochemical electrode or antistatic material, specifically for component material requiring conductivity in sever condition of corrosive environment is provided. A corrosive resistant metal material covered with a conductive substance is formed by cladding a corrosive resistant metal selected from the group consisting of titanium, zirconium, tantalum, niobium and alloy thereof on a conductive metal selected from the group consisting of iron, aluminum, copper, titanium, magnesium, zirconium, tantalum, niobium, tungsten, nickel, chrome and alloy thereof, and covering a conductive surface finishing layer over surface of a corrosive resistant metal layer with a mixture of conductive substance and resinous binder.
    Type: Grant
    Filed: March 14, 2003
    Date of Patent: July 15, 2008
    Assignees: Hitachi Cable, Ltd., Hitachi Powdered Metals Co., Ltd.
    Inventors: Masahiro Seido, Tatsuya Tonogi, Kazuhiko Nakagawa, Minoru Shirahige, Masahiro Okahara
  • Patent number: 7393597
    Abstract: A weld joint having a base material and a weld metal both of an austenitic steel, wherein the weld metal has a chemical composition, in mass %, that C: 0.04% or less, Si: 1.0% or less, Mn: 3% or less, P: 0.02% or less, S: 0.005% or less, Cr: 15 to 25%, Ni: 30% or more, Mo: 10% or less, Nb: 2.5 to 5%, Al: 3.0% or less, Ti: 0.5% or less, and the balance: Fe and inevitable impurities, the contents of Al and Ti satisfying the following: (Ti+Al)>Nb/8. The weld joint is a high strength austenitic steel weld joint which exhibits excellent toughness at a low temperature and excellent resistance to hydrogen embrittlement, which are required for a piping and a vessel for high pressure hydrogen, particularly also in a welded zone.
    Type: Grant
    Filed: December 9, 2005
    Date of Patent: July 1, 2008
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Kazuhiko Ogawa, Masaaki Igarashi, Hiroyuki Semba, Tomohiko Omura, Mitsuo Miyahara
  • Publication number: 20080141826
    Abstract: Novel carbon-plus-nitrogen corrosion-resistant ferrous and austenitic alloys, apparatus incorporating an inventive alloy, and methods of making and using the apparatus are described. The corrosion-resistant ferrous and austenitic alloys comprise no greater than about 4 wt. % nickel, are characterized by a strength greater than about 700 MPa (100 ksi), and, when being essentially free of molybdenum (<0.3 wt. %), have minimum Pitting Resistance Equivalence (PRE) numbers of 20 and minimum Measure of Alloying for Corrosion Resistance numbers (MARC) of 30 because of the use of both carbon and nitrogen. The ferrous and austenitic alloys are particularly formulated for use in oilfield operations, especially sour oil and gas wells and reservoirs. This abstract allows a searcher or other reader to quickly ascertain the subject matter of the disclosure. It will not be used to interpret or limit the scope or meaning of the claims.
    Type: Application
    Filed: December 18, 2006
    Publication date: June 19, 2008
    Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Manuel Marya, Rashmi Bhavsar
  • Patent number: 7381477
    Abstract: This invention provides a rare earth-transition metal (RE-TM) alloy structure comprising a RE-TM alloy substrate and a noble metal diffusion barrier disposed thereon. The noble metal diffusion barrier may be provided on the surface of the alloy substrate by an electroplating technique.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: June 3, 2008
    Assignee: Rolls-Royce, PLC
    Inventors: J. M. Shipton, legal representative, Mark H. Shipton
  • Patent number: 7381478
    Abstract: An exemplary hot rolled steel sheet for processing can include, in terms of percent by mass, C of 0.01 to 0.2%; Si of 0.01 to 0.3%; Mn of 0.1 to 1.5%; P of ?0.1%; S of ?0.03%; Al of 0.001 to 0.1%; N of ?0.006%; and as a remainder, Fe and unavoidable impurities. The microstructure may include a main phase in the form of polygonal ferrite and a hard second phase, a volume fraction of the hard second phase is 3 to 20%, a hardness ratio (hardness of the hard second phase/hardness of the polygonal ferrite) is 1.5 to 6, and a grain size ratio (e.g., grain size of the polygonal ferrite/grain size of the hard second phase) is 1.5 or more.
    Type: Grant
    Filed: September 22, 2004
    Date of Patent: June 3, 2008
    Assignee: Nippon Steel Corporation
    Inventors: Tatsuo Yokoi, Tetsuya Yamada, Osamu Kawano
  • Patent number: 7364801
    Abstract: An environmental coating suitable for use on turbine components, such as turbine disks and turbine seal elements, formed of alloys susceptible to oxidation and hot corrosion. The environmental coating is predominantly a solid solution phase of nickel, iron, and/or cobalt. The coating contains about 18 weight percent to about 60 weight percent chromium, which ensures the formation of a protective chromia (Cr2O3) scale while also exhibiting high ductility. The coating may further contain up to about 8 weight percent aluminum, as well as other optional additives. The environmental coating is preferably sufficiently thin and ductile to enable compressive stresses to be induced in the underlying substrate through shot peening without cracking the coating.
    Type: Grant
    Filed: December 6, 2006
    Date of Patent: April 29, 2008
    Assignee: General Electric Company
    Inventors: Brian Thomas Hazel, Michael James Weimer
  • Patent number: 7358327
    Abstract: An assembled hematin is formed by depositing hematin on an electrically charged substrate in one or more layers alternating with one or more layers of polyelectrolyte, preferably a cationic polymer. In a method for polymerizing an aromatic monomer, the assembled hematin is contacted with the monomer and a template, preferably an anionic polymer. In a method for polymerizing aniline, the aniline, sulfonated multi walled carbon nano tubes, PEG hematin and a reaction initiator are dispersed in water.
    Type: Grant
    Filed: April 21, 2005
    Date of Patent: April 15, 2008
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Ferdinando Bruno, Lynne A. Samuelson, Ramaswamy Nagarajan, Jayant Kumar, Michael Sennett
  • Patent number: 7354660
    Abstract: Alloy compositions which are resistant to metal dusting corrosion are provided by the present invention. Also provided are methods for preventing metal dusting on metal surfaces exposed to carbon supersaturated environments. The alloy compositions include an alloy (PQR), and a multi-layer oxide film on the surface of the alloy (PQR). The alloy (PQR) includes a metal (P) selected from the group consisting of Fe, Ni, Co, and mixtures thereof, an alloying metal (Q) comprising Cr, Mn, and either Al, Si, or Al/Si, and an alloying element (R). When the alloying metal (Q) includes Al, the multi-layer oxide film on the surface of the alloy includes at least three oxide layers. When the alloying metal (Q) includes Si, the multi-layer oxide film on the surface of the alloy (PQR) includes at least four oxide layers. When the alloying metal (Q) includes Al and Si, the multi-layer oxide film on the surface of the alloy (PQR) includes at least three oxide layers.
    Type: Grant
    Filed: May 10, 2005
    Date of Patent: April 8, 2008
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: ChangMin Chun, Trikur A. Ramanarayanan
  • Patent number: 7348068
    Abstract: A surface-treated steel sheet includes a steel sheet; a plating layer containing at least one metal selected from zinc and aluminum; a first layer film containing (?) 1 to 2000 mg/m2 of silica in terms of SiO2, (?) a total of 1 to 1000 mg/m2 of phosphoric acid groups in terms of P, (?) a total of 0.5 to 800 mg/m2 of at least one metal selected from Mg, Mn, and Al, and (?) 0.1 to 50 mg/m2 of a tetravalent vanadium compound; and a second layer film formed to a thickness of 0.1 to 5 ?m on the first layer film and containing a resin (A) having at least one type of functional group selected from OH and COOH groups, and at least one rust-proofing additive (B) selected from (a) a phosphate, (b) Ca ion-exchanged silica, (c) a molybdate, (d) silicon oxide, and (e) at least one organic compound selected from triazoles, thiols, thiadiazoles, thiazoles, and thiurams.
    Type: Grant
    Filed: November 18, 2004
    Date of Patent: March 25, 2008
    Assignee: JFE Steel Corporation
    Inventors: Takeshi Matsuda, Akira Matsuzaki, Kazuhisa Okai
  • Patent number: 7344751
    Abstract: An assembled hematin is formed by depositing hematin on an electrically charged substrate in one or more layers alternating with one or more layers of polyelectrolyte, preferably a cationic polymer. In a method for polymerizing an aromatic monomer, the assembled hematin is contacted with the monomer and a template, preferably an anionic polymer. In a method for polymerizing aniline, the aniline, sulfonated multi walled carbon nano tubes, PEG hematin and a reaction initiator are dispersed in water.
    Type: Grant
    Filed: April 21, 2005
    Date of Patent: March 18, 2008
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Ferdinando Bruno, Lynne A. Samuelson, Ramaswamy Nagarajan, Jayant Kumar, Michael Sennett
  • Patent number: 7341795
    Abstract: The invention provides a Fe—Cr alloy structure containing Cr of about 6% or more by mass but about 25% or less by mass, having a corrosion-resistant paint film containing metal powder having ionization tendencies greater than iron, with a content of the metal powder of about 20% or more by volume but about 60% or less by volume in a dry paint film, with a dry film thickness of about 5 ?m or more but about 100 ?m or less; and a manufacturing method thereof; whereby excellent corrosion resistance and excellent adhesion is provided.
    Type: Grant
    Filed: June 23, 2003
    Date of Patent: March 11, 2008
    Assignee: JFE Steel Corporation
    Inventors: Yoshihiro Yazawa, Osamu Furukimi, Yasushi Kato, Sadao Hasuno
  • Patent number: 7326472
    Abstract: A head body of a golf club head has a hollow portion defined by an outer wall. An opening portion is provided in a part of the head body. A small tungsten alloy piece having a shape fittable to the opening portion so as to cover the opening portion is fixedly attached to the opening portion by welding. The golf club head defines the opening portion in a part of the metal head body and has the small tungsten alloy piece fitted and joined to the opening portion by welding so that the golf club head can be reduced in weight because of provision of the hollow portion. Since the small tungsten alloy piece is joined to the opening portion by welding, difficult plastic forming is not required particularly, and the weight can be adjusted easily and accurately.
    Type: Grant
    Filed: November 16, 2004
    Date of Patent: February 5, 2008
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hideo Shimazaki, Yasunori Imamoto
  • Patent number: 7294412
    Abstract: The present invention stably provides a high-strength hot-dip galvanized steel sheet having a high tensile strength and no non-plated portions and being excellent in workability and surface properties even when the employed equipment has only a reduction annealing furnace and a steel sheet containing relatively large amounts of Si, Mn and Al that are regarded as likely to cause non-plated portions is used as the substrate.
    Type: Grant
    Filed: January 15, 2004
    Date of Patent: November 13, 2007
    Assignee: Nippon Steel Corporation
    Inventors: Yoshihisa Takada, Masayoshi Suehiro, Masao Kurosaki, Hidekuni Murakami, Hiroyasu Fujii, Haruhiko Eguchi, Hisaaki Sato
  • Patent number: 7291401
    Abstract: A steel material that has on its surface a non-hexavalent-chromium type corrosion-resistant coating film formed by a composite of a metal layer and a resin layer. The steel material having or not having a copper layer is formed with 1) a Zn and/or Zn-based alloy layer, 2) a Zn/Ni alloy layer which is on this Zn and/or Zn-based alloy layer, 3) a de-Zn layer which is on the Zn/Ni alloy layer and is obtained by chemically treating the surface of the Zn/Ni alloy layer, and 4) at least one resin covering layer which is on this de-Zn layer, which are successively formed to make a corrosion-resistant coating film, the corrosion-resistant coating film, which is superior in adhesion between the metal layer and resin layer, being obtained by way of taking into account the use of a trivalent chromium type chromate layer instead of a hexavalent chromium type chromate layer (which is a substance that places a burden on the environment).
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: November 6, 2007
    Assignee: USUI Kokusai Sangyo Kabushiki Kaisha, Ltd.
    Inventors: Kazuo Suzuki, Iyoshi Watanabe
  • Patent number: 7291402
    Abstract: The invention is to provide a surface-treated steel sheet of good white rust resistance with no chromium in its surface treatment film, and it has realized a surface-treated steel sheet of higher-level corrosion resistance by forming a reaction layer of plating metal with a barrier layer effective for anticorrosion not in a two-layered film but in a single-layered film.
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: November 6, 2007
    Assignees: JFE Steel Corporation, Kansai Paint Co., Ltd.
    Inventors: Okai Kazuhisa, Akira Matsuzaki, Naoto Yoshimi, Takahiro Kubota, Masaaki Yamashita, Hisato Noro, Haruo Nakamichi, Kaoru Sato, Hiroyasu Matsuki, Reijiro Nishida, Masahiro Murata, Shoichi Tanaka, Yoshikazu Morohoshi, Shingo Amaki
  • Patent number: 7250222
    Abstract: A system for bonding layers (1) of different chemical compositions, such as bonding a thermal barrier layer to a metal substrate on a surface of a gas turbine component. A substrate (4) made either of a ceramic material or particularly of a metal super-alloy may be bonded to an outer layer (16) such as a ceramic by means of a fine-grained intermediate layer (7) bonded to the substrate (4), and a coarse-grained layer (10) bonded to the intermediate layer (7) to create a studded surface (9). The fine and coarse layers (7, 10) provide a transition between the substrate (4) and the outer layer (16) for improved bonding between them. The studded surface (9) may provide at least a 20% increase in bonding surface area for the outer layer (16). Additionally, a medium-grained layer (13) may be applied to the studded surface (9) before applying the outer layer(16).
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: July 31, 2007
    Assignee: Siemens Aktiengesellschaft
    Inventors: Knut Halberstadt, Werner Stamm
  • Publication number: 20070172692
    Abstract: The present invention provides methods of forming multi-layered patterned coating films comprising the steps of (1) applying a first colored base coating composition to a substrate, (2) applying a second colored base coating composition over the uncured coating film of the first colored base coating composition in such a manner that the first colored base coating film is partially exposed, the second colored base coating composition being able to form a coating film of different color and/or visual texture from that of the first colored base coating composition, and having, 30 seconds after application, 30 to 60 mass % of the solids content of the base coating composition, and (3) applying a top clear coating composition over the cured or uncured first and second colored base coating compositions, and curing the uncured composition(s).
    Type: Application
    Filed: January 19, 2007
    Publication date: July 26, 2007
    Applicant: KANSAI PAINT CO., LTD.
    Inventors: Isao Kamimori, Ikumi Ono, Takashi Kawasaki
  • Patent number: 7223480
    Abstract: The present invention relates to a metal laminate which is broadly used for a flexible wiring board or the like and an etching method therefor. In particular, the present invention relates to a metal laminate which includes a layer obtained by laminating a metal layer and an insulating layer, where the insulating layer is subjected to an etching process, wherein, in a surface of the metal layer which is positioned so as to come in contact with the insulating layer, respective concentrations of main metal element and oxygen element constituting the metal layer are measured from the surface of the metal layer towards inside of the metal layer in a time-elapsing manner according to AES (Auger electron spectroscopy) and a value of the thickness of a metal oxide film of the surface of the metal layer measured at a time when atomic concentrations of the main metal element and the oxygen element constituting the metal layer become equal to each other is in a range of at least 0 ? to less than 50 ?.
    Type: Grant
    Filed: July 28, 2003
    Date of Patent: May 29, 2007
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Koji Hirota, Masanao Kobayashi, Minehiro Mori, Naoki Nakazawa
  • Patent number: 7211332
    Abstract: A laminate having a metal foil layer, and a polyimide resin layer provided on the metal foil layer, wherein the polyimide resin layer is obtained by curing a coating of a polyimide resin precursor solution directly applied onto a surface of the metal foil layer, wherein the polyimide resin layer has a linear expansion coefficient in the range from 10 to 30 ppm/K, wherein the metal foil layer and the polyimide resin layer have a bonding strength therebetween of at least 0.5 kN/m in terms of 180° peel strength, and wherein the polyimide resin obtained from the polyimide resin precursor solution contains at least 50% by weight of a moiety having a structure represented by the following formula (1) shown in the specification.
    Type: Grant
    Filed: March 9, 2006
    Date of Patent: May 1, 2007
    Assignee: AMT Laboratory Co., Ltd.
    Inventors: Hisashi Watanabe, Hiroshi Ito
  • Patent number: 7208232
    Abstract: A coating suitable for use as an environmentally-protective coating on surfaces of components used in hostile thermal environments, including the turbine, combustor and augmentor sections of a gas turbine engine. The coating is used in a coating system deposited on a substrate formed of a superalloy material. The coating contacts a surface of the superalloy substrate and is formed of a coating material having a tensile strength of more than 50% of the superalloy material. The coating material is predominantly at least one metal chosen from the group consisting of platinum, rhodium, palladium, and iridium, and has sufficient strength to significantly contribute to the strength of the component on which the coating is deposited.
    Type: Grant
    Filed: November 29, 2005
    Date of Patent: April 24, 2007
    Assignee: General Electric Company
    Inventors: Mark Daniel Gorman, Ramgopal Darolia
  • Patent number: 7169479
    Abstract: The invention relates to a grain-oriented magnetic steel sheet including an electrically insulating coating made of an amorphous carbon-hydrogen network, which is applied after final annealing in order to ensure electrical insulation of the individual layers of the sheet. The grain-oriented magnetic steel sheet including the electrically insulating coating made of an amorphous carbon-hydrogen network can be used in transformers.
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: January 30, 2007
    Assignee: ThyssenKrupp Electrical Steel EBG GmbH
    Inventors: Bernd Schuhmacher, Klaus Guenther, Hermann Hingmann, Klaus Bewilogua, Claus-Peter Klages, Heinz Dimigen, Thomas Jung
  • Patent number: 7169480
    Abstract: A clad pipe includes an external layer and a coating layer made of Ni base anticorrosion alloy. Both end portion areas of the coating layer are formed by a build-up welded layer (Ni base alloy of composition 1) on the inner surface of the external layer. Other areas are formed by a Ni base alloy layer (Ni base alloy of composition 2) fusion-bonded to the build-up welded layers and the inner surface of the pipe, a solidus-curve temperature of the Ni base alloy layer being 1300° C. or below and lower than a solidus-curve temperature of the Ni base alloy formed by build-up welding by 150° C. or more. Composition 1 and composition 2 are adjusted so that, in the same environment, corrosion resistance of the Ni base alloy of composition 1 is equivalent to or superior to that of the Ni base alloy of composition 2.
    Type: Grant
    Filed: February 1, 2005
    Date of Patent: January 30, 2007
    Assignee: Dai-Ichi High Frequency Co., Ltd.
    Inventors: Yoichi Matsubara, Akihiro Takeya, Seiichiro Miyata
  • Patent number: 7166364
    Abstract: I provide an aqueous coating composition to provide an outer protective coating for a metal selected from the group consisting of an aluminum, aluminum alloy, iron, iron alloy, zinc, zinc alloy, zinc coated iron, zinc coated iron alloy, and these metals and magnesium and magnesium alloys having a conversion coating thereon. The aqueous coating composition consists essentially of 60 to 90 parts by weight water, 0.5 to 10 parts by weight of a polyvinyl alcohol having a weight average molecular weight of at least 100,000 and being at least 95% hydrolyzed, 0.5 to 20 parts by weight of a polybasic acid or anhydride, and 0.0 to 3 parts by weight of a cross-linking agent or plasticizer to form a in-situ polyester conversion coating on the metal. The composition is applied directly to the metal or to the metal article which has a non-chromium conversion coating thereon and forms a thin film thereon. Then the metal with the film thereon is heated to between 300° to 550° F.
    Type: Grant
    Filed: April 19, 2005
    Date of Patent: January 23, 2007
    Assignee: Sanchem, Inc.
    Inventor: John W. Bibber
  • Patent number: 7160630
    Abstract: The disclosure relates to a corrosion resistant article comprising a metal body and a protective coating applied on at least one surface of said metal body, said protective coating comprising: (a) a zinc layer comprising metallic zinc; (b) a silicate layer comprising at least one silicate; and (c) a lubricant layer comprising at least one lubricant such as, for example, polyethylene wax. In particular, the disclosure relates to a corrosion resistant bolt and/or nut having a protective coating for use in motor vehicles. The protective coating is substantially free of chromates and phosphates and, hence, environmentally acceptable. The article has an excellent coefficient of friction, temperature resistance and anti-corrosion properties.
    Type: Grant
    Filed: May 31, 2005
    Date of Patent: January 9, 2007
    Assignee: Elisha Holding LLC
    Inventor: Klaus-Peter Klos
  • Patent number: 7156743
    Abstract: An inexpensive mechanical fuse having a high fatigue limit ratio and high rupture reliability, and superior in forming performance, and a method of manufacturing the same are presented. The mechanical fuse is composed of Fe-based sintered alloy, and comprises an inner rim 2 fixed to one power transmission shaft, an outer rim 3 fixed to the other power transmission shaft, and plural arms 4 for linking the inner rim 2 and outer rim 3, which are formed integrally. The arms 4 include rupture portions 6 which are ruptured when exposed to an overload torque. By treating in steam, an iron oxide phase is formed in the surface layer and pore inner wall. The iron oxide phase is effective to form round pores and lower the notch sensitivity. As a result, the fatigue strength and fatigue limit ratio are enhanced.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: January 2, 2007
    Assignees: Hitachi Powdered Metals Co., Ltd., Denso Corporation
    Inventors: Tadayuki Tsutsui, Kei Ishii, Yoshihiro Tanimura, Kouji Yamada, Yuuichi Aoki
  • Patent number: 7147934
    Abstract: A chemically processed steel sheet comprises a steel base coated with an Al—Si alloy plating layer, whose Si content is preferably adjusted to 5–13 mass % as a whole and to 7–80 mass % at a surface, and a converted layer generated on the surface of the plating layer. The converted layer contains both soluble and scarcely-soluble compounds. The soluble compound, such as a manganese oxide or hydroxide, or a valve metal fluoride, is once dissolved into water in an atmosphere and then re-precipitated as scarcely-soluble compounds at defective parts of the converted layer. The scarcely-soluble compounds act as a barrier for corrosion prevention of a base steel. Due to the re-precipitation, i.e., self-repairing faculty, excellent corrosion resistance of the converted layer is still maintained even after defects are introduced therein during plastic deformation of the steel sheet.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: December 12, 2006
    Assignee: Nisshin Steel Co., Ltd.
    Inventors: Masaya Yamamoto, Mitsuo Asabuki, Shigeyasu Morikawa, Shinya Furukawa, Hirofumi Taketsu
  • Patent number: 7135240
    Abstract: A thermal spray composition and method of deposition for abradable seals for use in gas turbine engines, turbochargers and steam turbines. The thermal spray composition includes a solid lubricant and a ceramic preferably comprising 5 to 60 wt % total of the composition in a ratio of 1:7 to 20:1 of solid lubricant to ceramic, the balance a matrix-forming metal alloy selected from Ni, Co, Cu, Fe and Al and combinations and alloys thereof. The solid lubricant is at least one of hexagonal boron nitride, graphite, calcium fluoride, lithium fluoride, magnesium fluoride, barium fluoride, tungsten disulfide and molybdenum disulfide particles. The ceramic includes at least one of albite, illite, quartz and alumina-silica.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: November 14, 2006
    Assignee: Sulzer Metco (Canada) Inc.
    Inventors: Petr Fiala, Anthony Peter Chilkowich, Karel Hajmrle
  • Patent number: 7125613
    Abstract: A coated metal article includes a ferrous metal substrate, and an abraded metallic coating on the substrate, wherein the abraded metallic coating has a substantially uniform patterned appearance which simulates the surface appearance of polished stainless steel. A top coating, which may be a relatively thick PVC coating or a thin coating of polyester, epoxy, or acrylic, may overlie the abraded metallic coating on an obverse side of the substrate. The metallic coating may be a Zinc-Nickel alloy and a pre-treatment coating may be applied beneath the top coating. A primer coating may be applied beneath the PVC top coating.
    Type: Grant
    Filed: March 7, 2005
    Date of Patent: October 24, 2006
    Assignee: Material Sciences Corporation, Engineered Materials and Solutions Group, Inc.
    Inventors: Bryan Tullis, Rebecca A. Jones, Kevin R. Sanchez, James E. Blanton, Joseph M. Ilk, Santos Ares, David M. Christopher
  • Patent number: 7087315
    Abstract: A method for forming a plating film, comprising the steps of: applying a plating film onto an object to be plated at a first current density for a predetermined period in a plating bath having a cathode capable of varying current and an anode and; and maintaining the object to be plated at a second current density lower than the first current density. According to the present invention, it is possible to improve solderability of a plating film for conventional lead-free solder by a simple method, which allows the productivity to further enhanced, resulting in a plating film with reduced production costs.
    Type: Grant
    Filed: September 21, 2004
    Date of Patent: August 8, 2006
    Assignees: Sharp Kabushiki Kaisha, Kobe Leadmikk Co., Ltd.
    Inventors: Yoshihiko Matsuo, Ryukichi Ikeda, Kimihiko Yoshida, Fumio Okuda
  • Patent number: 7087316
    Abstract: A low-expansion unit includes a plate member and an iron-nickel layer. Upper and lower surface layers of the plate member each have the iron-nickel layer thereon and/or therein. While the plate member has a relatively large thermal expansion coefficient, the iron-nickel layers, which are formed on and/or in the upper and lower surface layers of the plate member, have a relatively small thermal expansion coefficient. Therefore, thermal expansion coefficient of the low-expansion unit is as a whole restrained to a relatively small value. Also, the plate member includes pure iron whose thermal conductivity is relatively high. Meanwhile, the iron-nickel layers, which are formed on the plate member, are relatively thin. Therefore, the low-expansion unit has a relatively large thermal conductivity in a direction of thickness thereof.
    Type: Grant
    Filed: September 3, 2003
    Date of Patent: August 8, 2006
    Assignee: Kabushiki Kaisha Toyota Jidoshokki
    Inventors: Takashi Yoshida, Kyoichi Kinoshita, Katsufumi Tanaka, Tomohei Sugiyama, Hidehiro Kudo, Eiji Kono
  • Patent number: 7078107
    Abstract: A contact material which provides improved wear resistance as well as reduced adhesion utilizing the features of an intermetallic compound having an ordered phase, with the intention of (i) improving the seizure resistance and/or wear resistance of an implement bearing which slides under low-speed, high-surface-pressure conditions and is susceptible to lubricant starvation; (ii) preventing abnormal noises; and (iii) achieving prolonged greasing intervals. The contact material contains 10% by volume or more a metallic alloy phase having such a composition range that causes an order-disorder transition. The metallic alloy phase is a Fe base alloy phase containing one or more elements selected from the group consisting of Al, Si, Co and Ni.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: July 18, 2006
    Assignee: Komatsu Ltd.
    Inventors: Takemori Takayama, Yoshikiyo Tanaka, Tetsuo Onishi
  • Patent number: 7078112
    Abstract: A mechanical fuse has further improved and stabilized fatigue limit ratio, and can obtain high reliability under a using condition in which cyclic loading is applied. The mechanical fuse includes a Fe-based sintered alloy that has at least one element of P at 0.15 to 1.5 mass %, Si at 0.4 to 2.0 mass %, and Mn at 1.0 to 4.0 mass %, and the remainder consisting of Fe and inevitable impurities. An iron oxide layer is formed on a pore inner wall and the pores have roundness of 0.004 or more. A method of production therefore is also provided.
    Type: Grant
    Filed: June 3, 2004
    Date of Patent: July 18, 2006
    Assignees: Hitachi Powdered Metals Co., Ltd., Denso Corporation
    Inventors: Takashi Suzuki, Tadayuki Tsutsui, Kei Ishii, Yoshihiro Tanimura
  • Patent number: 7029762
    Abstract: The present invention provides an inorganic-organic composite-treated zinc-plated steel sheet whose treated coatings do not contain any chromium and which is excellent in corrosion resistance after degreasing, coating adhesion and electrodeposition coating performance. The inorganic-organic composite-treated zinc-plated steel sheet, which is obtained by forming a zinc phosphate coating, in a coating weight of 0.3 to 5 g/m2, on the zinc-plated steel sheet surface and forming thereon a post-treatment coating, in a coating weight of 0.01 to 1 g/m2, by using a post-treatment composition containing at least one compound (A) selected from the group consisting of thiocarbonyl group-containing compounds, sulfide group-containing compounds and guanidyl group-containing compounds, an organic resin (B), a crosslinking agent (C) and an inorganic corrosion inhibitor (D).
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: April 18, 2006
    Assignees: Nippon Steel Corporation, Nippon Paint Co., Ltd.
    Inventors: Kiyokazu Ishizuka, Hidetoshi Shindo, Atsushi Morishita, Koichi Saito, Motohiro Sasaki, Atsuhiko Tounaka
  • Patent number: 7022420
    Abstract: An assembled hematin is formed by depositing hematin on an electrically charged substrate in one or more layers alternating with one or more layers of polyelectrolyte, preferably a cationic polymer. In a method for polymerizing an aromatic monomer, the assembled hematin is contacted with the monomer and a template, preferably an anionic polymer. In a method for polymerizing aniline, the aniline, sulfonated multi walled carbon nano tubes, PEG hematin and a reaction initiator are dispersed in water.
    Type: Grant
    Filed: February 9, 2004
    Date of Patent: April 4, 2006
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Ferdinando Bruno, Lynne A. Samuelson, Ramaswamy Nagarajan, Jayant Kumar, Michael Sennett
  • Patent number: 6994919
    Abstract: The invention relates to a brazing sheet product including a core sheet, on at least one side of the core sheet a clad layer of an aluminum alloy including silicon in an amount in the range of 4 to 14% by weight, and further including on at least one outersurface of the clad layer a plated layer of nickel-tin alloy, such that the clad layer and all layers exterior thereto form a metal filler for a brazing operation and have a composition with the proviso that the mol-ratio of Ni:Sn is in the range of 10:(0.5 to 9).
    Type: Grant
    Filed: July 18, 2003
    Date of Patent: February 7, 2006
    Assignees: Corus Aluminium Walzprodukte GmbH, Corus Technology BV
    Inventors: Jacques Hubert Olga Joseph Wijenberg, Adrianus Jacobus Wittebrood, Joop Nicolaas Mooij
  • Patent number: 6986950
    Abstract: The invention relates to a partition (1) or a method for producing a partition (1) for a multilayer pressed packet (3), wherein the partition (1) can be placed as a pressing sheet in the composite of a multilayer pressed packet (3) to be produced, especially between two multilayers (2). The unfavorable image transfer between the multilayers (2) that has occurred in the prior art up to now is cost-effectively prevented in that the partition (1) is implemented as a steel sheet, but not as a high-grade steel sheet, and that the steel sheet—at a temperature of essentially 180?C—possesses a tensile strength of at least Rm ? 500 Mpa and/or—at a temperature of essentially 180?C—a yield strength of at least Rp0.2 ? 470 MPa.
    Type: Grant
    Filed: December 31, 2003
    Date of Patent: January 17, 2006
    Assignee: Monika Backhaus
    Inventor: Dieter Backhaus
  • Patent number: 6924045
    Abstract: It is disclosed a bond or overlay MCrAlY-coating for the use within a high temperature environment for the protection of the base alloy of turbine blades and vanes. The MCrAlY-coating having a ? or ?/??-structure comprises a dispersion of ?-NiAl and/or ?/?-MCrAlY particles. This provides a reservoir of aluminum reservoir to coatings wherein the reservoir replenish the aluminum lost due to oxidation and interdiffusion during service. The ?-NiAl and/or ?/?-MCrAlY is the aluminum reservoir and is applied by mixing appropriate powders with ? or ?/?? powders.
    Type: Grant
    Filed: May 3, 2002
    Date of Patent: August 2, 2005
    Assignee: ALSTOM Technology LTD
    Inventors: Abdus S. Khan, Maxime Konter, Robert Schmees
  • Patent number: 6913836
    Abstract: A spin-valve type magnetoresistive sensor with a bias structure enabling a magnetization direction of a free magnetic layer to be uniformly arranged with certainty. The spin-valve type magnetoresistive sensor comprises an antiferromagnetic layer; a pinned magnetic layer having a magnetization direction made stationary; a nonmagnetic electrically conductive layer formed between the pinned magnetic layer and a free magnetic layer; soft magnetic layers that are arranged on the free magnetic layer while a spacing corresponding to a track width is left between the soft magnetic layers and that fill recesses in the free magnetic layer on both sides of an area corresponding to the track width; bias layers formed on the soft magnetic layers; and electrically conductive layers. The antiferromagnetic layer and the bias layers are each made of an alloy containing at least one or more elements selected from among Pt, Pd, Rh, Ru, Ir, Os, Au, Ag, Cr, Ni, Ne, Ar, Xe and Kr, as well as Mn.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: July 5, 2005
    Assignee: Alps Electric Co., Ltd.
    Inventor: Naoya Hasegawa