Silica Containing Patents (Class 501/53)
  • Patent number: 7709081
    Abstract: The invention relates to porous bioglass and to the preparation method thereof. More specifically, the invention relates to a solid, porous crystalline or partially-crystalline composition containing at least SiO2, Ca<SB>O</SB>, Na2O, and P2O5, comprising micropores and macropores. The invention is characterised in that: the pore ratio varies between 50% and 80%, preferably between 60 and 75%, and is measured using the geometric method; the average diameter of the macropores varies between 100 and 1250 micrometers, preferably between 150 and 300 micrometers; the average diameter of the micropores is less than or equal to 5 micrometers; and the compression strength varies between 7 MPa and 70 MPa. The invention also relates to the method of preparing one such composition and to such a composition treated with a physiological liquid having an ionic composition similar to that of human plasma. The invention also relates to an implant which is made from one such composition.
    Type: Grant
    Filed: July 25, 2005
    Date of Patent: May 4, 2010
    Assignee: Institut National des Sciences Appliques (INSA)
    Inventors: Rachid Zenati, Gilbert Fantozzi, Jerome Chevalier, Mourad Arioua
  • Patent number: 7700682
    Abstract: A glass filler for a polycarbonate resin, whereby the refractive index of the glass filler can be improved to the same level as a polycarbonate resin, and the transparency of a molded product after reinforced with such a filler can be maintained without coloration, and a polycarbonate resin composition employing such a filler, are provided.
    Type: Grant
    Filed: November 6, 2006
    Date of Patent: April 20, 2010
    Assignee: Asahi Fiber Glass Company, Limited
    Inventor: Keiji Sekine
  • Publication number: 20100056353
    Abstract: The present invention relates generally to production of a fluoride gas and equivalents thereof, and fluorine-doped sodium silicate glass, glass ceramics, vitro ceramics and equivalents thereof. In one embodiment, the method includes providing a salt and an oxide in a reactor, heating the reactor to produce a vapor and the vitro ceramic and removing the vapor.
    Type: Application
    Filed: August 27, 2009
    Publication date: March 4, 2010
    Inventors: Angel Sanjurjo, Kai-Hung Lau, Xiaobing Xie, Gopala Krishnan
  • Patent number: 7666511
    Abstract: An alkali aluminosilicate glass that is chemically strengthened and has a down-drawable composition. The glass has a melting temperature less than about 1650° C. and a liquidus viscosity of at least 130 kpoise and, in one embodiment, greater than 250 kpoise. The glass undergoes ion exchange at relatively low temperatures to a depth of at least 30 ?m.
    Type: Grant
    Filed: July 31, 2007
    Date of Patent: February 23, 2010
    Assignee: Corning Incorporated
    Inventors: Adam James Ellison, Sinue Gomez
  • Publication number: 20100041538
    Abstract: Fused silica glass having an internal transmittance of UV with 245 nm wavelength, being at least 95% at 10 mm thickness, a OH content of not larger than 5 ppm, and a content of Li, Na, K, Mg, Ca and Cu each being smaller than 0.1 ppm. Preferably the glass has a viscosity coefficient at 1215° C. of at least 1011.5 Pa·s; and a Cu ion diffusion coefficient of not larger than 1×10?10 cm2/sec in a depth range of greater than 20 ?m up to 100 ?m, from the surface, when leaving to stand at 1050° C. in air for 24 hours. The glass is made by crystobalitizing powdery silica raw material; then, fusing the crystobalitized silica material in a non-reducing atmosphere. The glass exhibits a high transmittance of ultraviolet, visible and infrared rays, has high purity and heat resistance, and exhibits a reduced diffusion rate of metal impurities, therefore, it is suitable for various optical goods, semiconductor-production apparatus members, and liquid crystal display production apparatus members.
    Type: Application
    Filed: September 11, 2007
    Publication date: February 18, 2010
    Inventors: Kazuyoshi Arai, Tsutomu Takahata, Shinkichi Hasimoto, Masahito Uchida, Nobusuke Yamada, Yoshinori Harada, Hideharu Horikoshi
  • Publication number: 20100029459
    Abstract: The present invention provides novel glasses, methods of formulating glasses having a reduced stress-optic coefficient at visible wavelengths under anisotropic stress, and novel optical systems comprising a such glass.
    Type: Application
    Filed: July 26, 2007
    Publication date: February 4, 2010
    Inventors: Josef Wilson Zwanziger, Marie Helene Guignard
  • Publication number: 20100009154
    Abstract: A strengthened glass that does not exhibit frangible behavior when subjected to impact or contact forces, and a method of strengthening a glass. The glass may be strengthened by subjecting it to multiple, successive, ion exchange treatments. The multiple ion exchange treatments provide a local compressive stress maximum at a depth of the strengthened layer and a second local maximum at or near (e.g., within 10 ?m) the surface of the glass.
    Type: Application
    Filed: July 10, 2009
    Publication date: January 14, 2010
    Inventors: Douglas Clippinger Allan, Adam James Ellison, Sinue Gomez
  • Publication number: 20100004113
    Abstract: Disclosed are synthetic silica glass having a low polarization-induced birefringence, process for making the glass and lithography system comprising optical element made of the glass. The silica glass has a polarization-induced birefringence measured at 633 nm of less than about 0.1 nm/cm when subjected to excimer laser pulses at about 193 nm having a fluence of about 40 ?J·cm?2·pulse?1 and a pulse length of about 25 ns for 5×109 pulses.
    Type: Application
    Filed: September 10, 2009
    Publication date: January 7, 2010
    Inventors: Douglas Clippinger Allan, Dana Craig Bookbinder, Ulrich W. H. Neukirch, Charlene Marie Smith
  • Publication number: 20090325778
    Abstract: The subject of the invention is a glass composition of the silica-soda-lime type, intended for the manufacture of substrates or sheets, the said glass composition having a ? coefficient of between 0.50 and 0.85 N/(mm2·° C.) and a working point of less than 1200° C.
    Type: Application
    Filed: May 1, 2008
    Publication date: December 31, 2009
    Applicant: SAINT-GOBAIN GLASS FRANCE
    Inventors: Nathalie El Khiati, Rene Gy, Eric Le Bourhis
  • Publication number: 20090318279
    Abstract: A substantially white powder for use as a filler and/or extender derived from by-products of manufacturing vitreous low alkali, low iron glass fibers, and a method for producing the powder. The filler has very low alkalinity and by virtue of its being essentially free of crystalline silica is non-hazardous to health and therefore safe for consumer-based and industrial-based uses.
    Type: Application
    Filed: August 26, 2009
    Publication date: December 24, 2009
    Inventors: Raymond T. Hemmings, Robert D. Nelson, Philip L. Graves, Bruce J. Cornelius
  • Publication number: 20090311538
    Abstract: The various embodiments of the present invention are directed to wear resistant coatings, tiles having the wear resistant coatings disposed thereon, and to methods of making the coatings and tiles. A wear resistant coating generally includes a strontium aluminosilicate glass-ceramic composition that is formed from a glaze. The glaze can include a crystallizing component, which itself can include strontium, aluminum, and silicon, but also comprises less than about 2 weight percent each of lithium, boron, barium, sodium, iron, titanium, zirconium, and carbon, based on a total weight of the crystallizing component.
    Type: Application
    Filed: May 13, 2009
    Publication date: December 17, 2009
    Applicants: Mohawk Carpet Corporation, Intercolor S.p.A.
    Inventors: Thomas Long, Claudio Ansaloni, Massimo Sernesi, David A. Earl
  • Publication number: 20090311209
    Abstract: The present invention relates to pigments, comprising a plate-like substrate of glass having an average thickness of <1 ?m, especially of from 20 nm to 400 nm, and (a) a dielectric material, especially a metal oxide, having a high index of refraction; or (a) a metal layer, especially a thin semi-transparent metal layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.
    Type: Application
    Filed: June 12, 2006
    Publication date: December 17, 2009
    Inventor: Patrice Bujard
  • Patent number: 7615201
    Abstract: By using a halogen-free siloxane and an organometallic compound containing at least one metal other than silicon as feed stocks, and simultaneously atomizing and burning them in a flame, spherical particles of silica-containing compound oxide are prepared which are substantially halogen-free, consist of 0.5-99% by weight of metal oxides and the balance of silica, and have a particle size of 10 nm to 3 ?m. The particles are useful as a filler in epoxy resin base semiconductor sealants, a refractive index modifier or the like.
    Type: Grant
    Filed: July 23, 2002
    Date of Patent: November 10, 2009
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshiharu Konya, Koichiro Watanabe, Susumu Ueno
  • Publication number: 20090258777
    Abstract: A method and system for treating fly ash with a treating fluid by evenly dispersing a treating fluid into a flowing stream of fly ash. By dispersing the treating fluid into the fly ash as the fly ash is flowing, the method takes advantage of natural mixing and particle motion that occurs during flow of the bulk solid. The application of treating fluid is advantageously controlled by an automated controller that has inputs and outputs that allow the controller to adjust flow rate of the treating fluid in correspondence with a measured flow rate of the fly ash.
    Type: Application
    Filed: June 19, 2009
    Publication date: October 15, 2009
    Applicant: BORAL MATERIAL TECHNOLOGIES INC.
    Inventors: Marc-Andre Tardif, Russ K. Majors, Russell L. Hill
  • Publication number: 20090237787
    Abstract: To Provide a polarizing glass with better weatherability than conventional polarizing glasses, affording high long-term reliability without the above-described surface deterioration. To provide an optical isolator employing polarizing glass of improved weatherability, affording good weatherability and high reliability for extended periods. [Means for Solving] A polarizing glass comprising geometrically anisotropic particles dispersed in an oriented manner in at least one surface layer of a glass base body. The glass base body does not comprise an oxide of alkali earth metal and PbO, and consists of borosilicate glass comprising at least one additive component selected from the group consisting of Y2O3, ZrO2, La2O3, CeO2, Ce2O3, TiO2, V2O5, Ta2O5, WO3, and Nb2O5, and the geometrically anisotropic metal particles are metallic cupper particles. An optical isolator employing the polarizing glass.
    Type: Application
    Filed: April 12, 2007
    Publication date: September 24, 2009
    Applicant: Hoya Candeo Optronics Corporation
    Inventors: Yoshitaka Yoneda, Sei-ichi Yokoyama
  • Publication number: 20090239733
    Abstract: A soda-lime glass substrate formed through a heat-treatment method has an absorption coefficient ranging from about 0.15 ?,W/m·K to about 0.54 ?,W/m·K, and a free path length ranging from about 0.12 cm to about 0.24 cm. The heat-treated soda-lime glass substrate is formed by heating for a selected time at a pre-specified maximum temperature of about 270° C. to about 330° C. so as to remove thermally induced residual deformations from the substrate and then the substrate is slowly cooled so as to substantially avoid reintroducing thermally induced residual deformations into the cooling substrate. Thus, the soda-lime glass substrate is transformed to one at or close to its contraction saturation point. This allows the heat-treated soda-lime glass substrate to serve in a practical way as a substrate of a flat display panel.
    Type: Application
    Filed: March 9, 2009
    Publication date: September 24, 2009
    Inventors: Se-Ah Kwon, Min Kang, Byoung-Joo kim, Jin-Ho Ju, Chul Huh, Sang-Woo Whangbo
  • Publication number: 20090208760
    Abstract: The present invention is to provide an optical fiber preform suitable for the production of an energy-transmitting or ultraviolet light-transmitting optical fiber, which has an excellent transmittance of a high-energy light of 50 KW/cm2 or more in terms of laser peak power or an ultraviolet light, to be transmitted through the optical fiber and which exhibits excellent durability that causes almost no deterioration by the irradiation with those two lights; and a production process thereof.
    Type: Application
    Filed: April 24, 2009
    Publication date: August 20, 2009
    Applicant: Asahi Glass Company, Limited
    Inventors: Madoka KUWAHARA, Akio KOIKE, Kaname OKADA, Tomonori OGAWA
  • Publication number: 20090202808
    Abstract: The invention is directed to a high strength, chemically toughened protective glass article, the glass article having a high damage tolerance threshold of at least 1500 g as measured by the lack of radial cracks when the load is applied to the glass using a Vickers indenter; preferably greater than 2000 g s measured by the lack of initiation of radial cracks when the load is applied to the glass using a Vickers indenter
    Type: Application
    Filed: February 6, 2009
    Publication date: August 13, 2009
    Inventors: Gregory Scott Glaesemann, James Joseph Price, Robert Sabia, Nagaraja Shashidhar
  • Publication number: 20090203511
    Abstract: Disclosed is a synthetic silica glass optical material having high resistance to optical damage by ultraviolet radiation in the ultraviolet wavelength range, particularly in the wavelength less than about 250 nm and particularly, exhibiting a low laser induced wavefront distortion; specifically a laser induced wavefront distortion, measured at 633 nm, of between about ?1.0 and 1.0 nm/cm when subjected to 10 billion pulses of a laser operating at approximately 193 nm and at a fluence of approximately 70 ?J/cm2. The synthetic silica glass optical material of the present invention comprises OH concentration levels of less than about 600 ppm, preferably less than 200 ppm, and H2 concentration levels less than about 5.0×1017 molecules/cm3? and preferably less than about 2.0×1017 molecules/cm3.
    Type: Application
    Filed: April 8, 2009
    Publication date: August 13, 2009
    Inventors: Dana Craig Bookbinder, Richard Michael Fiacco, Kenneth Edward Hrdina, Lisa Anne Moore, Susan Lee Schiefelbein
  • Publication number: 20090195960
    Abstract: Electronic device 1 comprises an element body 10, comprising a dielectric layer 2 constituted by a dielectric ceramic composition, and a terminal electrode 4, formed outside of the element body 10. The dielectric ceramic composition comprised a main component including barium titanate; a first subcomponent including at least one oxide of Mg and Ca; a second subcomponent including SiO2; a third subcomponent including at least one oxide of Mn and Cr; and a fourth subcomponent including an oxide of rare earth elements, wherein the net valence of Mn and/or Cr in the third subcomponent is 2.2 to 2.4. According to the electronic device 1, both high temperature accelerated lifetime characteristics and capacity stress aging characteristics can be improved in a balanced manner.
    Type: Application
    Filed: June 23, 2006
    Publication date: August 6, 2009
    Applicant: TDK CORPORATION
    Inventors: Shigeki Sato, Keiichi Fukuda
  • Publication number: 20090197755
    Abstract: An optical glass having optical constants of a refractive index (nd) of 1.78 or over, an Abbe number (v d) of 30 or below, and a partial dispersion ratio (? g, F) of 0.620 or below comprises SiO2 and Nb2O5 as essential components, wherein an amount of Nb2O5 in mass % is more than 40%. The optical glass further comprising, in mass % on oxide basis, less than 2% of K2O and one or more oxides selected from the group consisting of B2O3, TiO2, ZrO2, WO3, ZnO, SrO, Li2O and Na2O wherein a total amount of SiO2, B2O3, TiO2, ZrO2, Nb2O5, WO3, ZnO, SrO, Li2O and Na2O is more than 90% and TiO2/(ZrO2+Nb2O5) is less than 0.32.
    Type: Application
    Filed: January 9, 2009
    Publication date: August 6, 2009
    Applicant: OHARA INC.
    Inventor: Susumu UEHARA
  • Publication number: 20090165499
    Abstract: The invention discloses a glass-ceramic composition, a slurry, and a method for manufacturing a dielectric ceramic component with high frequency. The glass-ceramic composition comprises 5-30 wt % of aluminum oxide and 70-95 wt % of BiZnBSiAl glass. The invention mixes the glass-ceramic composition with an organic carrier to make a slurry, processes the slurry into green body, and then densities the green body to obtain dielectric ceramic component with high frequency, which can be sintered and densified under low temperature. Accordingly, the product of quality factor and resonance frequency of the component can meet the requirements of high quality factor and dielectric constant for industries.
    Type: Application
    Filed: July 28, 2008
    Publication date: July 2, 2009
    Inventors: Chin-Hung Wei, Yu-Ping Hsieh
  • Publication number: 20090163344
    Abstract: The invention starts from a known component of quartz glass for use in semiconductor manufacture, which component at least in a near-surface region shows a co-doping of a first dopant and of a second oxidic dopant, said second dopant containing one or more rare-earth metals in a concentration of 0.1-3% by wt. each (based on the total mass of SiO2 and dopant). Starting from this, to provide a quartz glass component for use in semiconductor manufacture in an environment with etching action, which component is distinguished by both high purity and high resistance to dry etching and avoids known drawbacks caused by co-doping with aluminum oxide, it is suggested according to the invention that the first dopant should be nitrogen and that the mean content of metastable hydroxyl groups of the quartz glass is less than 30 wtppm.
    Type: Application
    Filed: September 4, 2007
    Publication date: June 25, 2009
    Applicants: Heraeus Quarzglas GmbH & Co., KG, Shin-Etsu Quartz Products Co., Ltd.
    Inventors: Juergen Weber, Tatsuhiro Sato, Ralf Schneider, Achim Hofmann, Christian Gebauer
  • Publication number: 20090155533
    Abstract: In order to obtain glass or glass ceramic materials having increased strength, the invention provides a method for producing glass or glass ceramic articles, which comprises the steps: producing an initial glass body (11), mounting the initial glass body (11) on a gas cushion (13) between a levitation support (1) and the initial glass body (11), and at least partially ceramizing the initial glass body (11) on the levitation support (1). The levitation support comprises at least one continuous surface region (3) having at least one gas feed region (151, 152, 153) where levitation gas for the gas cushion (13) is fed out from the levitation support, and at least one gas discharge region (171 172, 173) where gas from the gas cushion (13) is at least partially discharged into the levitation support.
    Type: Application
    Filed: December 9, 2005
    Publication date: June 18, 2009
    Applicant: SCHOTT AG
    Inventors: Sybill Nuettgens, Wolfgang Schmidbauer, Roland Dudek, Friedrich Georg Schroeder, Gerhard Hahn, Markus Borrmann, Helga Goetz
  • Publication number: 20090148627
    Abstract: What is disclosed includes OD-doped synthetic silica glass capable of being used in optical elements for use in lithography below about 300 nm. OD-doped synthetic silica glass was found to have significantly lower polarization-induced birefringence value than non-OD-doped silica glass with comparable concentration of OH. Also disclosed are processes for making OD-doped synthetic silica glasses, optical member comprising such glasses, and lithographic systems comprising such optical member. The glass is particularly suitable for immersion lithographic systems due to the exceptionally low polarization-induced birefringence values at about 193 nm.
    Type: Application
    Filed: February 13, 2009
    Publication date: June 11, 2009
    Inventors: Dana Craig Bookbinder, Richard Michael Fiacco, Ulrich Wilhelm Heinz Neukirch
  • Publication number: 20090148578
    Abstract: A production method of amorphous silicon oxide powder comprises a step of preparing a wood, agricultural crop or plant containing hexose and/or pentose and silicon oxide as a starting raw material, a step of hydrolyzing the starting raw material with nitric acid, hydrochloric acid, sulfuric acid, phosphoric acid or organic acid to reduce a content of the hexose to 10% by weight or less and/or a content of the pentose to 20% by weight or less, and a step of burning residue yielded in the hydrolyzing step at a temperature of 400° C. to 1200° C.
    Type: Application
    Filed: August 29, 2006
    Publication date: June 11, 2009
    Inventors: Katsuyoshi Kondoh, Yoshisada Michiura
  • Publication number: 20090149307
    Abstract: An optical glass comprising SiO2, B2O3 and La2O3 and one or more oxides selected from the group consisting of ZrO2, Nb2O5 and Ta2O5, having a refractive index of 1.83 or over and an Abbe number of 35 or over and being free of F.
    Type: Application
    Filed: December 16, 2008
    Publication date: June 11, 2009
    Applicant: KABUSHIKI KAISHA
    Inventor: Koji Shimizu
  • Publication number: 20090143213
    Abstract: A low expansion glass substrate includes titania and silica and has a thermal expansivity with an average gradient less than 1 ppb/° C./° C. in a temperature range of 19° C. to 25° C.
    Type: Application
    Filed: November 25, 2008
    Publication date: June 4, 2009
    Inventors: Kenneth Edward Hrdina, Robert Sabia
  • Publication number: 20090136740
    Abstract: A composite article includes a substrate and a layer attached to the substrate. The layer includes a metal phase, a first ceramic phase, and a second ceramic phase.
    Type: Application
    Filed: November 28, 2007
    Publication date: May 28, 2009
    Inventors: George H. Reynolds, Christopher W. Strock
  • Patent number: 7538052
    Abstract: A silica glass containing TiO2, which has a fictive temperature of at most 1,200° C., a F concentration of at least 100 ppm and a coefficient of thermal expansion of 0±200 ppb/° C. from 0 to 100° C. A process for producing a silica glass containing TiO2, which comprises a step of forming a porous glass body on a target quartz glass particles obtained by flame hydrolysis of glass-forming materials, a step of obtaining a fluorine-containing porous glass body, a step of obtaining a fluorine-containing vitrified glass body, a step of obtaining a fluorine-containing formed glass body and a step of carrying out annealing treatment.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: May 26, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Yasutomi Iwahashi, Akio Koike
  • Patent number: 7538068
    Abstract: A carbon dioxide gas absorbent includes a porous body containing a lithium complex oxide. The porous body includes pores having a pore diameter distribution such that main pores which consist of first pores with a diameter of 10 to 100 ?m and second pores with a diameter larger than 100 ?m and 500 ?m or smaller occupy 80 to 100%, third pores with a diameter smaller than 10 ?m occupy 0 to 10% and fourth pores with a diameter larger than 500 ?m occupy 0 to 10%, the main pores have a pore diameter distribution such that the first pores occupy 15 to 85% and second pores occupy 15 to 85%.
    Type: Grant
    Filed: March 16, 2006
    Date of Patent: May 26, 2009
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masahiro Kato, Toshihiro Imada, Kenji Essaki
  • Publication number: 20090131240
    Abstract: A glass composition that simultaneously has a low temperature coefficient of refractive index and a good light transmittance, being suitable for use in environments of intense temperature change. There is provided an optical glass containing SiO2, B2O3 and La2O3, which has a temperature coefficient (20° to 40° C.) of relative refractive index (546.07 nm) of 10.0×10?6 (° C.?1) or below. Further, there is provided an optical glass mentioned above having a temperature coefficient (20° to 40° C.) of relative refractive index (546.07 nm) of 4.6×10?6 (° C.?1) or below.
    Type: Application
    Filed: September 8, 2006
    Publication date: May 21, 2009
    Inventor: Koji Shimizu
  • Publication number: 20090122281
    Abstract: A silica glass containing TiO2, which has a fictive temperature of at most 1,200° C., a F concentration of at least 100 ppm and a coefficient of thermal expansion of 0±200 ppb/° C. from 0 to 100° C. A process for producing a silica glass containing TiO2, which comprises a step of forming a porous glass body on a target quartz glass particles obtained by flame hydrolysis of glass-forming materials, a step of obtaining a fluorine-containing porous glass body, a step of obtaining a fluorine-containing vitrified glass body, a step of obtaining a fluorine-containing formed glass body and a step of carrying out annealing treatment.
    Type: Application
    Filed: January 12, 2009
    Publication date: May 14, 2009
    Applicant: ASAHI GLASS COMPANY LIMITED
    Inventors: Yasutomi IWAHASHI, Akio Koike
  • Publication number: 20090120132
    Abstract: A process for making a glass product with reduced greenhouse gas emission, comprising: providing a raw material composition comprising at least one silicon dioxide or silicon dioxide-containing compound and at least one pre-reacted compound, wherein the pre-reacted compound comprises an atom of an alkaline earth metal chemically bonded to an oxygen atom, and a silicon atom chemically bonded to the oxygen atom; melting the raw material composition to produce a molten material; and forming the molten material into a glass product.
    Type: Application
    Filed: November 13, 2007
    Publication date: May 14, 2009
    Inventors: Jon Frederick Bauer, Susan McMillin Gee
  • Publication number: 20090099000
    Abstract: To provide a vial with low alkali elution and a method for producing the same by removing a deteriorated region caused by processing on an internal surface of a vial. A vial with reduced alkali elution and a method for producing the same by forming vials from borosilicate glass tubes comprises a first step of forming a borosilicate glass tube into a cup-shaped body by formation of a bottom of a vial, and a second step of forming the cup-shaped body into the vial by formation of a mouth of the cup-shaped body.
    Type: Application
    Filed: May 15, 2006
    Publication date: April 16, 2009
    Inventors: Hideo Kuwabara, Hideki Yamauchi, Yoshitaka Ishimi, Shinichiro Senga
  • Patent number: 7514093
    Abstract: A vitreous antimicrobial agent that can exhibit excellent antimicrobial properties when added to various types of resins, that has excellent discoloration resistance and hot water resistance, and that can easily be produced at a commercial scale. The vitreous antimicrobial agent includes, relative to 100 mass % of total glass components, 0.1 to 2 mass % of Ag2O, 40.5 to 49 mass % of ZnO, 6 to 9.5 mass % of SiO2, 30.5 to 39.5 mass % of B2O3, 2 to 10 mass % of an alkaline earth metal oxide, and 6 to 7.5 mass % of Na2O; the vitreous antimicrobial agent comprising, in addition to these, 0.01 to 5 mass % of CeO2 as necessary. An antimicrobial resin composition and an antimicrobial product including the vitreous antimicrobial agent.
    Type: Grant
    Filed: January 26, 2004
    Date of Patent: April 7, 2009
    Assignee: Toagosei Co., Ltd.
    Inventor: Koji Sugiura
  • Patent number: 7514382
    Abstract: A synthetic quartz glass for an optical member which is free from compaction and rarefaction is obtained. A synthetic quartz glass for an optical member to be used for an optical device employing a light having a wavelength of at most 400 nm and at least 170 nm as a light source, which contains substantially no oxygen excess defects, dissolved oxygen molecules nor reduction type defects, which has a chlorine concentration of at most 50 ppm and a OH group concentration of at most 100 ppm, and which contains oxygen deficient defects within a concentration range of at most 5×1014 defects/cm3 and at least 1×1013 defects/cm3. The fluorine concentration is preferably at most 100 ppm.
    Type: Grant
    Filed: April 6, 2006
    Date of Patent: April 7, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Yoshiaki Ikuta, Noriyuki Agata
  • Publication number: 20090082190
    Abstract: A high-refractive index, low-dispersion optical glass which is small in a change of imaging properties due to a change in temperature of the use environment, specifically one capable of realizing an absolute value of multiplication (?×?) of an average coefficient of linear expansion (?) at from ?30 to +70° C. and a photoelastic constant (?) at a wavelength of 546.1 nm of not more than 130×10?12° C.?1×nm×cm?1×Pa?1, is manufactured without using large qualities of components which are high in an environmental load and scarce mineral resources. The optical glass of the invention has an absolute value of multiplication (?×?) of an average coefficient of linear expansion (?) at from ?30 to +70° C. and a photoelastic constant (?) at a wavelength of 546.1 nm of not more than 130×10?12° C.?1×nm×cm?1×Pa?1; and contains more than 0% of SiO2, B2O3 and La2O3, more than 13% and less than 20% of (ZrO2+Nb2O5) and less than 2.0% of ZnO in terms of % by mass on the oxide basis.
    Type: Application
    Filed: September 25, 2008
    Publication date: March 26, 2009
    Applicant: OHARA INC.
    Inventor: Michiko Ogino
  • Publication number: 20090082189
    Abstract: An optical glass having a refractive index (nd) within a range from 1.825 to 1.870, an Abbe number (?d) within a range from 22 to less than 27, a transformation temperature (Tg) within a range from 530° C. to 585° C. and an mean coefficient of linear thermal expansion (?) within a range from 80×10?7° C.?1 to 103×10?7° C.?1, comprising SiO2, TiO2, Nb2O5 and Li2O and being substantially free of a Pb compound.
    Type: Application
    Filed: November 19, 2008
    Publication date: March 26, 2009
    Applicant: KABUSHIKI KAISHA OHARA
    Inventors: Koji Shimizu, Susumu Uehara
  • Patent number: 7506522
    Abstract: Disclosed are high purity synthetic silica glass material having a high OH concentration homogeneity in a plane perpendicular to the optical axis, and process of making the same. The glass has high refractive index homogeneity. The glass can have high internal transmission of at least 99.65%/cm at 193 nm. The process does not require a post-sintering homogenization step. The controlling factors for high compositional homogeneity, thus high refractive index homogeneity, include high initial local soot density uniformity in the soot preform and slow sintering, notably isothermal treatment during consolidation.
    Type: Grant
    Filed: June 8, 2005
    Date of Patent: March 24, 2009
    Assignee: Corning Incorporated
    Inventors: Daniel Joseph Bleaking, Dana C. Bookbinder, Richard M. Fiacco, Kenneth E. Hrdina, Pushkar Tandon, John E. Maxon, Kimberly Ann Wilbert
  • Patent number: 7506521
    Abstract: Disclosed are high purity synthetic silica material having an internal transmission at 193 nm of at least 99.65%/cm and method of preparing such material. The material is also featured by a high compositional homogeneity in a plane transverse to the intended optical axis. The soot-to-glass process for making the material includes a step of consolidating the soot preform in the presence of H2O and/or O2.
    Type: Grant
    Filed: June 8, 2005
    Date of Patent: March 24, 2009
    Assignee: Corning Incorporated
    Inventors: Dana Craig Bookbinder, Richard Michael Fiacco, Kenneth Edward Hrdina, Lisa Anne Moore, Susan Lee Schiefelbein
  • Publication number: 20090068474
    Abstract: A coating for reducing interaction between a surface and the environment around the surface includes an alkali silicate glass material configured to protect the surface from environmental corrosion due to water or moisture. The alkali silicate glass material is doped with a first element to affect various forms of radiation passing through the coating. The electromagnetic radiation is at least one of ultraviolet, x-ray, atomic (gamma, alpha, beta), and electromagnetic or radio wave radiation. The coating may also be used to protect a solar cell from the environment and UV rays while retransmitting received light as usable light for conversion into electrical energy. The coating may also be used to prevent whisker formation in metal finishes of tin, cadmium, zinc, etc.
    Type: Application
    Filed: September 29, 2008
    Publication date: March 12, 2009
    Inventors: Nathan P. Lower, Alan P. Boone, Ross K. Wilcoxon, David D. Hillman
  • Publication number: 20090061195
    Abstract: A glass ceramic self-supporting film that includes silica (SiO2) matrix glass and fine crystalline zirconia (ZrO2) particles dispersed in the matrix glass. A process for production of a glass ceramic self-supporting film wherein the process includes the steps of combining a colloidal silica sol having a pH of 4 or less, a zirconium-containing compound and an organic binder to produce a mixture, coating the mixture onto a base material, drying the mixture on the coated base material to form a precursor film on the base material, releasing the precursor film from the base material, and firing the released precursor film.
    Type: Application
    Filed: March 26, 2007
    Publication date: March 5, 2009
    Inventor: Toshihiro Kasai
  • Publication number: 20090062101
    Abstract: An optical glass of the present invention has optical constants of a refractive index (nd) within a range from 1.75 to 1.85 and an Abbe number (? d) within a range from 35 to 45, comprises SiO2 and B2O3 as essential components and one or more components selected from the group consisting of ZrO2, Nb2O5, Ta2O5 and WO3, has a glass transition temperature (Tg) of 580° C. or below and has weathering resistance (surface method) of Class 1 or Class 2.
    Type: Application
    Filed: February 21, 2006
    Publication date: March 5, 2009
    Applicant: KABUSHIKI KAISHA OHARA
    Inventor: Susumu Uehara
  • Publication number: 20090039758
    Abstract: An adhesive agent for fluorescent dyes for adhering a fluorescent layer on a substrate, wherein the adhesive agent contains or consists of a glass composition.
    Type: Application
    Filed: April 10, 2008
    Publication date: February 12, 2009
    Applicant: SCHOTT AG
    Inventors: Jorg Hinrich Fechner, Franz Ott
  • Publication number: 20090042709
    Abstract: The invention relates to a process for manufacturing compounds based on one or more silicates of alkali metals and/or of alkaline-earth metals, optionally in the form of mixed silicates that combine at least two of these elements, said process involving: (i) preferably a conversion reaction (1) in which halides of said alkali metals and/or of said rare earths and/or of said alkaline-earth metals are converted into the corresponding sulfates; (iii) a conversion reaction (2) in which said sulfates together with silica are converted into the corresponding silicates, the heat supply needed for this conversion being provided, at least in part, by a combustion reaction (3) using a submerged burner or a plurality of submerged burners.
    Type: Application
    Filed: September 29, 2008
    Publication date: February 12, 2009
    Applicant: SAINT-GOBAIN GLASS FRANCE
    Inventors: Pierre JEANVOINE, Arnaud LE VERGE
  • Publication number: 20090036289
    Abstract: An optical composite material comprises an amorphous optical material (6) with a first refractive index (na), into which crystalline nanoparticles (7) having a second, higher refractive index (nn) are embedded, wherein the amorphous material (6) and the nanoparticles (7) are resistant to UV radiation. A microlithography projection exposure apparatus comprises a projection objective (2) with at least one optical element (3) which is, in particular, operated in transmission and consists of an optical composite material of this type. In a method for producing the optical composite material, crystalline nanoparticles are introduced into the amorphous optical material during flame deposition in a soot or direct process.
    Type: Application
    Filed: February 22, 2006
    Publication date: February 5, 2009
    Applicant: Carl Zeiss SMT AG
    Inventors: Eric Eva, Wilfried Clauss
  • Publication number: 20090025777
    Abstract: A low-index silica coating may be made by forming a silica precursor having a radiation curable composition including a radiation curable monomer and/or a photoinitiator, and also including a silica sol comprising a silane and/or a colloidal silica. The silica precursor may be deposited on a substrate (e.g., glass substrate or silicon wafer) to form a coating layer. The coating layer may then be cured via exposure to electromagnetic radiation, such as UV radiation. Then, the cured coating layer may be fired using temperature(s) of from about 550 to 700° C., in forming the low-index silica based coating. The low-index silica based coating may be used as an antireflective (AR) film on a front glass substrate of a photovoltaic device (e.g., solar cell) in certain example instances.
    Type: Application
    Filed: December 11, 2007
    Publication date: January 29, 2009
    Applicant: Guardian Industries Corp.
    Inventor: Desaraju V. Varaprasad
  • Publication number: 20090029842
    Abstract: A fused silica article having a combined concentration of hydroxyl (OH) and deuteroxyl (OD) concentration of less than 10 parts per million (ppm) and, in one embodiment, less than 1 ppm. The fused silica article is formed by drying a soot blank in a halogen-free atmosphere comprising carbon monoxide. The dried soot blank may optionally be doped to reach target levels of OH and OD concentrations and improve homogeneity within the fused silica article. The dried soot blank is then oxidized and, sintered to form the article. A method of reducing the combined concentration of OH and OD to less than 10 ppm is also described.
    Type: Application
    Filed: July 27, 2007
    Publication date: January 29, 2009
    Inventors: Rostislav Radievich Khrapko, Nicolas LeBlond, James Edward Tingley
  • Publication number: 20090018007
    Abstract: A lithium-aluminosilicate glass or a corresponding glass ceramic that has a content of 0-0.4 SnO2, 1.3-2.7% by weight of ?SnO2+TiO2, 1.3-2.5% by weight of ZrO2, 3.65-4.3% by weight of ?ZrO2+0.87 (TiO2+SnO2), ?0.04% by weight of Fe2O3, 50-4000 ppm of Nd2O3 and 0-50 ppm of CoO is described. The glass or the glass ceramic is color-neutral, has a turbidity of less than 1% HAZE and a high light transmission. The glazing time for conversion of the glass into glass ceramic is especially short with less than 2.5 hours.
    Type: Application
    Filed: March 19, 2007
    Publication date: January 15, 2009
    Inventors: Friedrich Siebers, Ulrich Schiffner, Wolfgang Schmidbauer, Klaus Schonberger