Abstract: The invention relates to transparent, biaxially oriented and heat-set films having one or more layers and compris, as main constituent, at least one crystallizable thermoplastic, in particular a polyester, and also comprise at least one hydrolysis stabilizer. The hydrolysis stabilizer is preferably a phenolic compound, an oxazoline, and/or a monomeric or polymeric carbodiimide, where appropriate combined with an organic phosphite. It is preferably added in the form of a masterbatch. The film exhibits low longitudinal and transverse shrinkage. On exposure to moisture and heat it shows practically no embrittlement and retains its ultimate tensile strength. The additional functionality is preferably that the film has been made UV-resistant, or flame-retardant, or on one side or on both sides has been coated, or is sealable, and/or has been corona- or flame-treated.
Type:
Application
Filed:
June 15, 2001
Publication date:
May 30, 2002
Inventors:
Ursula Murschall, Ulrich Kern, Thorsten Kiehne, Harald Hessberger
Abstract: An organohybrid-based damping material for controlling unwanted vibration and noise, an organic damping improver exhibiting piezoelectric, dielectric and electroconductive effects, and their producing methods, are provided. The damping material comprises a polymer matrix having a polar side chain and a damping improver composed of a compound containing basic nitrogen and a phenol-based compound. The damping material shows an excellent damping properties, alleviates the functional deterioration, and is applicable to different application temperature regions and wide areas.
Abstract: A temperature indicating material of the present invention including at least an electron donating compound, an electron accepting compound a reversible material causing reversible transformation between crystal and amorphous, or reversible transformation between phase separation and non-phase-separation, with respect to a part or all of the composition system; and a temperature characteristic controller having solid-state in roam temperature. At least a part of the temperature characteristic controller dissolves in the electron accepting compound, the reversible material, or the electron accepting compound and the reversible material so as to cage speed of the reversible transformation between crystal and amorphous, or speed of the reversible transformation between phase separation and non-phase-separation, with respect to the composition system, by its reversible transformation between crystal and amorphous, or speed of the reversible transformation between phase separation and non-phase separation.
Abstract: Disclosed are a propylene polymer having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain (continuous propylene units wherein directions of &agr;-methyl carbons are the same as each other), and a process for preparing said polymer. Also disclosed are a propylene block copolymer containing a crystalline polypropylene portion having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain, and a process for preparing said copolymer. Further disclosed is a propylene polymer composition comprising the above propylene polymer or propylene block copolymer and at least one stabilizer selected from a phenol type stabilizer, an organophosphite type stabilizer, a thioether type stabilizer, a hindered amine type stabilizer and a metallic salt of higher aliphatic acid.
Abstract: An adhesive composition comprising (A) a copolymer of (meth)acrylic esters, (B) a crosslinking agent and (C) a phenol derivative; an adhesive composition comprising (D) a copolymer of (meth)acrylic esters having a weight-average molecular weight (Mw) of 500,000 to 2,500,000 or (D′) a mixture of the copolymer (D) and an oligomer of (meth)acrylic esters having Mw of 1,000 to 10,000 (100:5 to 100:100 by weight), (E) a crosslinking agent and (F) a radical scavenger; and an adhesive optical component comprising a layer of the adhesive composition disposed at least on one face of an optical component.
Abstract: A thermoreversibly thickening binder composition, comprises a resin latex wherein the amount of an emulsifier in the aqueous phase is smaller than 0.01 mmol/g, and a vinyl polymer having reversibility of hydrophilicity and hydrophobicity at a certain transition temperature. The resin latex is preferably prepared by using an emulsifier having a radically polymerizable group, and preferable as said vinyl polymer is a polymer having a cation-forming group. The binder composition exhibits an excellent chemical stability to factors other than heat without causing migration of the latex resin particles onto the surface of the coated layer even during the time of heat-drying, and thermoreversible thickening effects caused by a sharp heat-sensitive gelling properties. When applied to preparation of coated paper and pressure-sensitive recording sheet, the binder composition provides products excellent in gloss, printability and color producing properties.
Abstract: A high damping material composition useful as a vibration damper and an acoustic insulating material such as a sound insulating wall for an acoustic room, a sound insulating partition for a construction structure and a soundproofing wall for a vehicle. The high damping material composition of the present invention containing the following components (A) and (B);
(A) a polymer having in the molecular chain thereof a chemical structural unit derived from the following (a);
(a) at least one selected from the group consisting of an acrylic monomer, a methacrylic monomer, an ethylene-acrylic copolymer, an ethylene-methacrylic copolymer and vinyl acetate;
(B) at least one damping property imparting agent selected from the group consisting of a hindered phenol compound, a phosphite ester compound, a phosphate ester compound, a basic compound containing nitrogen and a hindered amine compound.
Abstract: A process for the preparation of polymers containing double bonds by ruthenium carbene catalysis is carried out, where a ring-opening polymerization of monomers of the Formula (I) occurs 1
Type:
Application
Filed:
December 22, 2000
Publication date:
July 5, 2001
Applicant:
CREAVIS Gesellschaft fuer Technologie und Innovation mbH
Abstract: This invention relates to a rubber composition composed of high Tg diene-based elastomers and which contains a high Tg liquid polymer of high vinyl polybutadiene and to such a composition being sulfur cured. The invention also relates to a tire having a tread of such rubber composition.
Type:
Grant
Filed:
March 8, 1999
Date of Patent:
June 5, 2001
Assignee:
The Goodyear Tire & Rubber Company
Inventors:
Edward John Blok, Mark Leslie Kralevich, Jr., Paul Harry Sandstrom, Shingo Futamura
Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyether amine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functonalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts. A polyether monoamine that contains from about 36 to about 44 ethylene units and from about 1 to about 6 propylene units, and processes and blends using same.
Type:
Grant
Filed:
August 3, 1999
Date of Patent:
April 10, 2001
Assignee:
Huntsman Petrochemical Corporation
Inventors:
Randall Keith Evans, Richard J. G. Dominguez, Richard J. Clark
Abstract: Acrylic light pipe has adequate thermal and photo-thermal stability for many purposes, but is deficient in maintaining clarity, color, and good optical properties under conditions of exposure to high temperatures, especially in combination with exposure for lengthy periods to passage of light. Improved thermal stability, as reflected in reduced color formation, can be imparted by adjusting the polymerization conditions to produce the uncured core polymer of the core/clad construction with a much reduced terminal vinyl content, preferably below 0.5 vinyl groups/1000 monomer units. This process improvement, in combination with selected addition of a combination of certain hindered phenols and hydrolytically stable organic phosphites, together produce a substantial improvement in the resistance to discoloration under photo-thermal conditions, while maintaining the resistance to discoloration under thermal conditions.
Type:
Grant
Filed:
December 11, 1997
Date of Patent:
March 27, 2001
Assignee:
Fiberstors Incorporated
Inventors:
Casmir Stanislaus Ilenda, Phelps Brian Johnson, Michael Paul Hallden-Abberton
Abstract: The invention provides a polymer which is a polymerization product obtained by polymerizing at least ethylene, 1-pentene and 1-hexene; and a process for producing a polymer by reacting at least ethylene, 1-pentene and 1-hexene in a reaction zone at a pressure between atmospheric and 60 kg/cm3 and at a temperature between 30° C. and 120° C., in the presence of a catalyst system. The invention also provides a polymer composition which comprises a terpolymer of ethylene, 1-pentene and 1-hexene, a phenolic stabilizer component, a metal salt of a higher aliphatic acid, and, optionally, at least one organic phosphite stabilizer.
Type:
Grant
Filed:
January 12, 1998
Date of Patent:
February 20, 2001
Assignee:
Sasol Technology (Proprietary) Limited
Inventors:
Dawid Johannes Joubert, Ignatius Hendrik Potgieter, Ioan Tincul, Peter Loggenberg
Abstract: Materials not releasing gaseous organic materials during use are used as a dry-type sealing material such as a gasket disposed upon mounting an air filter to an opening of a ceiling or the like, a wet-type sealing material filled and used in a gap for connecting wall materials or partitionings, a vinyl chloride sheet or a vinyl chloride cloth as a facing material for walls and floors. Specifically, a carboxylic acid ester having a molecular weight of not less than 400 is used as a plasticizer, a phenolic compound having a molecular weight of not less 300 is used as an antioxidant, an aliphatic hydrocarbon having not less than 19 carbon atoms (for example, microcrystalline wax) is used as a lubricant, and an alkylamine ethylene oxide adduct having a molecular weight of not less than 350 is used as an antistatic agent.
Abstract: A solution of phenolic and polyamide polymers is used as a dipping resin to coat composite honeycomb structures. The phenolic/polyamide dipping resin increases the heat formability and strength of composite honeycomb structures. The coating formed by the resin includes from 30 to 95 weight percent phenolic resin and 5 to 30 weight percent polyamide resin.
Abstract: A process for preparing a styrenic resin is herein disclosed which comprises the step of volatilizing extrudinga styrenic polymer (SPS) powder having a syndiotactic configuration in the presence of water, an alcohol or an antioxidant by the use of an extruder to obtain pellets. According to this process, the operation of volatilization extrusion is done in the presence of water, the alcohol or the antioxidant to stably and efficiently prepare the SPS pellets in which yellowing is inhibited, and the operation of the volatilization extrusion is carried out in the presence of water to stably and efficiently prepare the SPS pellets containing a less amount of a remaining volatile component such as an unreacted monomer.
Abstract: To offer thermosetting paint compositions resistant to yellowing to brass, which give paint films of excellent resistance to yellowing due to brass, low-temperature curability, weather resistance, resistance to yellowing after stoving, acid resistance, scratch resistance, solvent resistance, adhesion and appearance. Thermosetting paint compositions, which are thermosetting paint compositions which are resistant to yellowing due to brass, characterized in that the paint-film-forming components include (A) a compound which has per molecule at least 2 functional groups which can react with an isocyanate group, at 49.6-90 wt %, (B) a blocked isocyanate which has par molecule at least 2 isocyanate groups blocked by an azole blocking agent, at 9.6-50 wt %, (C) an ultraviolet absorber and/or free radical scavenger, at 0.2-5 wt %, (D) an organotin compound at 0.1-3 wt %, and (E) an amino resin at 0.1-30 wt %.
Abstract: Viscosity-stabilized aqueous polyester dispersions comprising an acid-functional polyester resin a, neutralizing agent b for the polyester resin a, the amount of neutralizing agent being sufficient to convert from 10 to 200% of the amount of substance of acid groups in the polyester resin a into salt groups by means of the amount of neutralizing agents added, the neutralizing agents being selected from ammonia and organic amines and also alkali metal hydroxides and alkaline earth metal hydroxides; if desired, an organic auxiliary solvent, silica in an amount such that the mass of SiO.sub.2 is from 0.1 to 50% of the mass of the polyester resin, and water. The dispersions are useful in coating compositions.
Abstract: Novel dibenzoylresorcinol-based compounds are disclosed wherein the dibenzoylresorcinol is bonded to the residue of either an alcohol or a carboxylic acid group, via a methylene carboxylate linking group; and wherein the dibenzoylresorcinol is bonded directly to a substituted or unsubstituted aryl group which does not include a pendent hydroxyl group. The groups attached to the dibenzoylresorcinol may contain a wide variety of functional sites which permit further reaction, e.g., copolymerization. The described compounds are very useful as UV light absorbers and may be used to form improved coating compositions which usually include a transparent, polymeric matrix material. The coating compositions may be applied to various substrates, e.g., thermoplastics, to afford a selection of enhanced properties, such as UV light resistance and abrasion resistance.
Type:
Grant
Filed:
January 16, 1997
Date of Patent:
November 9, 1999
Assignee:
General Electric Company
Inventors:
James Edward Pickett, Wen P Liao, Amy Kathleen Simonian, Gregory Ronald Gillette
Abstract: Injection-moldable thermoplastic polyurethane compositions with reduced cycle time contain a cycle time reducing amount of a low molecular weight, high softening point, poly(hydroxyl group)-containing resin, preferably a phenolic modified terpene resin.
Abstract: Polymer compositions of the invention typically comprise a base polymer composition, a polymer cleavage agent, and a stabilizer composition. The preferred base polymer composition comprises an ethylene vinyl alcohol copolymer composition. Preferred cleavage agent is an alkaline earth or transition metal salt, preferably an acetate, or a salt of an acid having 8 to 20 carbon atoms. The stabilizer composition comprises an alkylated phenol or bisphenol. Preferred stabilizer composition comprises a tocopherol, preferably alpha tocopherol.
Abstract: Antioxidant-containing polyolefin compositions are provided including titanium dioxide-coated mica particles having an overcoating calcined thereon to prevent yellowing of the compositions. Reduced photo-darkening and improved densification of the pigment can also be achieved.
Abstract: A resin-molded product includes a phenol-based oxidation inhibitor, and a thiol-based compound. The thiol-based compound reacts chemically with a coloring substance (or a compound having a quinone-type structure) resulting from the phenol-based oxidation inhibitor to interrupt a long conjugated system arising in the coloring substance. As a result, the absorption due to the coloring substance is canceled in the visible light region. Thus, the resin-molded product is inhibited from yellowing.
Type:
Grant
Filed:
June 27, 1996
Date of Patent:
August 24, 1999
Assignees:
Toyota Jidosha Kabushiki Kaisha, Kabushiki Kaisha Toyota Chuo Kenkyusho
Abstract: The present invention relates to rubber stocks containing a metal salt of hydroxy-aryl substituted maleamic acid. The rubber stocks compounded with the cobalt salts of hydroxy-aryl substituted maleamic acid exhibit improved aged rubber/wire adhesion. The rubber stocks compounded with sodium salts of hydroxy-aryl substituted maleamic acid exhibit improved peel adhesion.
Type:
Grant
Filed:
October 16, 1991
Date of Patent:
February 16, 1999
Assignee:
The Goodyear Tire & Rubber Company
Inventors:
Lawson Gibson Wideman, George Frank Balogh, Denise Jeannette Keith
Abstract: A polycarbonate substrate coated with an acrylic coating containing at least one polybenzoylresorcinol, and optionally a silicone hardcoat on the acrylic coating, wherein said at least one polybenzoylresorcinol has the formula ##STR1## wherein each A is independently a substituted or unsubstituted monocyclic aromatic radical wherein any substituents are hydrogen, halogen, alkoxy, C.sub.1-8 alkyl, or hydroxy, and R is hydrogen or a linear or branched aliphatic radical having less that about 10 carbon atoms.
Type:
Grant
Filed:
June 21, 1996
Date of Patent:
February 9, 1999
Assignee:
General Electric Company
Inventors:
Steven Roger Bahr, James Edward Pickett, Karen Kueck Webb
Abstract: Instant invention provides thermoplastic polyurethane compositions comprising one or more thermoplastic polyurethanes A) one or more acrylate based rubbers B), and one or more UV and/or heat stabilizers C), wherein the thermoplastic polyurethane composition of A)+B)+C) has a greater UV stability as compared to a thermoplastic polyurethane composition of A)+C), wherein (a.) UV stability is measured as the difference between (1.) Delta E versus white tile after molded, and (2.) Delta E versus white tile after 1000 hours of QUV (b.) increasing stability is indicated by minimization of the difference between (1.) and (2.).The invention further provides a process of making molded thermoplastic polyurethane articles using the aforementioned thermoplastic polyurethane compositions.
Abstract: A solution which comprises: a non-polar organic solvent, such as an aliphatic hydrocarbon solvent, like hexane; polyaniline; and an effective amount of an amphiphilic phenol-containing reagent, which can be a monomeric compound or a phenol-containing polymer, for the solubilization of the polyaniline in the solvent. The alkyl substituent in the phenol-containing reagent, if monomeric, can contain from about six to about twelve carbon atoms, with a preferred solubilizer being dodecylphenol.
Abstract: Polyphenylene ethers are decolorized by contact in the melt or in solution with a hydroxy compound containing either another hydroxy group or a double or aromatic bond in a specific location in the molecule. Illustrative decolorizing compounds are benzopinacol, benzoin and acetoin.
Type:
Grant
Filed:
January 24, 1997
Date of Patent:
June 2, 1998
Assignee:
General Electric Company
Inventors:
Dwain Montgomery White, Gary William Yeager
Abstract: Curable and cured elastomer compositions, and methods for the preparation thereof, in which vulcanization is retarded by incorporating the acid salts of certain methyl substituted aminoalkyl phenols into the compositions to be vulcanized. The compositions include an elastomer, a scorch retarding effective amount of a phenolic scorch retarder acid salt, and a cure effective amount of a free radical generating compound.
Type:
Grant
Filed:
June 27, 1995
Date of Patent:
December 9, 1997
Assignee:
Sartomer Company
Inventors:
Lester A. Brooks, C. Richard Costin, Walter R. Nagel
Abstract: A process is disclosed for increasing the molecular weight of polyesters, polyester copolymers or polyester blends, which comprises heating a polyester blended with a tetracarboxylic acid dianhydride and a sterically hindered hydroxyphenylalkylphosphonic acid ester or half-ester to above the melting point (glass transition temperature) of the polyester.
Type:
Grant
Filed:
August 28, 1996
Date of Patent:
December 2, 1997
Assignee:
Ciba Specialty Chemicals Corporation
Inventors:
Rudolf Pfaendner, Heinz Herbst, Kurt Hoffmann
Abstract: A hydrophilic coating composition used to impart increased lubricity and wettability to the surface of a hydrophobic substrate which is comprised of three essential components:1) Hydrogel-forming polymer component A2) Water-soluble polymer component B3) Common solvent C for the components A and BThe water-insoluble, hydrogel-forming component A consists of a segmented copolymer with long, hydrophilic terminal blocks and the essentially hydrophobic central section. The two polymer components A and B have a limited miscibility in the absence of a common solvent C. Therefore, their blend tends to separate spontaneously into two polymer phases. The phase separation takes place during the solvent evaporation or extraction. A gradient of hydrophilicity and swelling within the coating layer is thus spontaneously created achieving a good adhesion to the substrate and high surface hydrophilicity at the same time.
Type:
Grant
Filed:
May 1, 1995
Date of Patent:
November 18, 1997
Assignee:
S.K.Y. Polymers, Inc.
Inventors:
Vladimir A. Stoy, Gerald A. Gontarz, Jr., Patrick Stoy
Abstract: A thermoplastic polyurethane urea prepared by reacting a reaction mixture ofa) one or more polyisocyanates, withb) one or more compounds having on average at least 1.8 Zerewitinoff-active hydrogen atoms and a molecular weight of between 400 and 10,000, andc) water,wherein the water is introduced into the reaction mixture with the aid of an effective quantity of one or more emulsifiers. The reaction mixture may additionally contain d) further conventional auxiliary substances and additives.
Type:
Grant
Filed:
January 5, 1996
Date of Patent:
November 18, 1997
Assignee:
Bayer Aktiengesellschaft
Inventors:
Stephan Kirchmeyer, Hanns-Peter Muller, Hans-Georg Wussow, Bodo Rehbold
Abstract: High-temperature-resistant, flexible screen printing inks containing as binder a thermoplastic aromatic polycarbonate with a molecular weight M.sub.w (weight average) of at least 10,000 which contains bifunctional carbonate structural units corresponding to formula (I): ##STR1## in which R.sup.1 and R.sup.2 independently of one another represent hydrogen, halogen, C.sub.1-8 alkyl, C.sub.5-6 cycloalkyl, C.sub.6-10 aralkyl,m is an integer of 4 to 7R.sup.3 and R.sup.4 may be individually selected for each X and, independently of one another, represent hydrogen or C.sub.1-6 alkyl andX represents carbonwith the proviso that, at least one atom X, R.sup.3 and R.sup.4 are both alkyl, and halogen-free solvents or solvent mixtures.
Type:
Grant
Filed:
June 8, 1995
Date of Patent:
July 15, 1997
Assignee:
Bayer Aktiengesellschaft
Inventors:
Peter Bier, Joachim Wank, Peter Capellen
Abstract: A polyoxymethylene composition, polyoxymethylene parts, and a process for the production of polyoxymethylene. The polyoxymethylene composition contains one or more polyoxymethylene species, an aqueous anionic polyurethane dispersion, phenolic antioxidant(s), and optionally, colorant, filler, and conventional additives. The composition exhibits improved resistance to non-ferrous metal corrosion.
Type:
Grant
Filed:
September 21, 1995
Date of Patent:
June 24, 1997
Assignee:
DeGussa Aktiengesellschaft
Inventors:
Edwin Nun, Stephanie Schauhoff, Klaus Dorn
Abstract: Disclosed are certain aromatic polycarbodiimides. Also disclosed is the use of an aromatic polycarbodiimide containing only aromatic carbodiimide groups as a cross-linker for a coating binder polymer bearing carboxyl groups.
Abstract: A polyester film contains a polyester having an intrinsic viscosity (IV) in the range from 0.65 to 0.8 and an antioxidant. The polyester has an endothermic high temperature peak at a temperature of (A).degree.C. and an endothermic low temperature peak at a temperature of (B).degree.C., both peaks being measured by differential scanning calorimetry (DSC), and the value of (A-B) is in the range from 25.degree. C. to 50.degree. C. The polyester film is suitable for use an insulation film, exhibiting improved ageing properties.
Abstract: There is provided an aromatic polycarbonate copolymer obtained by reacting a dihydric phenol component comprising mainly 2,2-bis(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropane and 9,9-bis(4-hydroxyphenyl)fluorene or 1,1-bis(4-hydroxyphenyl)-1-phenylethane in a prescribed ratio with a carbonate precursor substance. This aromatic polycarbonate copolymer has a specific viscosity in a limited range. The aromatic polycarbonate copolymer is excellent in optical characteristics, transparency, hydrolysis resistance, heat resistance, oxidation resistance, and heat stability and good in moldability, and is suitable for a plastic optical waveguide that is small in transmission loss and excellent in heat resistance.
Type:
Grant
Filed:
January 17, 1995
Date of Patent:
September 17, 1996
Assignees:
The Furukawa Electric Co. Ltd, Teijin Chemicals Ltd.
Abstract: An antibacterial electret material which consists of a synthesized organic polymer having a volume resistivity of not less than 10.sup.13 .OMEGA..multidot.cm and containing 0.01 to 2% by weight of one kind of electret stabilizer selected from the group composed of a hindered amine compound, a nitrogen-containing hindered phenol compound, a metallic salt hindered phenol compound, a phenol compound, a sulfur compound and a phosphorus compound and 0.1 to 4% by weight of metal ion-containing inorganic compound, and which has a surface density of charge of not less than 1.times.10.sup.-10 coulomb/cm.sup.2.
Abstract: An improvement in barrier properties of films and molded articles containing an organic polymer is achieved by incorporation therein of fluorochemicals, fluoropolymers or mixtures thereof, wherein said fluorochemicals or fluoropolymers contain greater than 40% fluorine by weight and exhibit less than 20% weight loss at 165.degree. C., as measured by thermogravimetric analysis at 20.degree. C. per minute in air. The films and molded articles in accordance with the present invention exhibit improved vapor and chemical barrier properties.
Abstract: A polyimide precursor solution which comprises a polyimide precursor and a solvent wherein the polyimide precursor and the solvent are not solated strongly. A process for the production of the polyimide precursor solution, as well as moldings and coatings obtained from the solution.The polyimide precursor solution of the present invention has excellent storage stability, and the solvent can be removed easily at the time of the production of moldings or coatings. According to the process of the present invention, the polyimide precursor solution can be produced easily using simple apparatus and an inexpensive solvent(s) having low toxicity. The polyimide molding obtained from the polyimide precursor solution has excellent uniformity and no residual solvent. The polyimide coating obtained from the polyimide precursor solution has excellent uniformity, no residual solvent and excellent adhesiveness to a base material.
Abstract: A polyamide/aliphatic polyester block, copolymer (A) comprising a polyamide block and an aliphatic polyester block, (B) satisfying the expression T.sub.1 -T<100-C (in which T is the melting point (.degree.C.) of the above block copolymer, T.sub.1 is the melting point (.degree.C.) of a polyamide composed of the polyamide block and C is the content (wt. %) of the polyamide block), (C) exhibiting the extraction amount which satisfies the expression, when extracted in tetrahydrofuran, E<(100-C).times.0.4 (in which E is the extraction amount (wt. %) when the block copolymer is refluxed in tetrahydrofuran, and C is the content (wt. %) of the polyamide block) and (D) having an intrinsic viscosity, measured at 35.degree. C., in the range of from 0.5 to 5; a process for the production thereof; a fiber formed therefrom; and an intimate blend comprising a thermoplastic resin having no or poor compatibility with polyamide and the block copolymer.
Abstract: A resin composition for forming a core for web material comprising 70 to 30 wt. % of polypropylene resin having a melt index of 10 to 60 g/10 minutes, a bending elastic modulus of more than 8,000 kg/cm.sup.2, an Izod impact strength of more than 2 kg.cm/cm and a Rockwell hardness of more than 70 R, 30 to 70 wt. % of linear low density polyethylene resin having a melt index of 3 to 50 g/10 minutes, a density of 0.910 to 0.935 g/cm.sup.3, an Olsen rigidity of more than 1,500 kg/cm.sup.2 and a Shore hardness of more than 40 D, more than 0.01 wt. % of a lubricant and more than 0.01 wt. % of an antioxidant.The resin composition is a light weight and excellent in injection moldability, appearance, dropping strength, solvent resistance, transparency, processibility, wear resistance, dimensional accuracy, and little molding troubles such as sink marks, resin remaining at gate, stringiness, weld lines, twist and deformation, add nevertheless, it has a flexibility.
Abstract: There is provided an aromatic polycarbonate copolymer obtained by reacting a dihydric phenol component comprising mainly 2,2-bis(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropane and 9,9-bis(4-hydroxyphenyl)fluorene or 1,1-bis(4-hydroxyphenyl)-1-phenylethane in a prescribed ratio with a carbonate precursor substance. This aromatic polycarbonate copolymer has a specific viscosity in a limited range. The aromatic polycarbonate copolymer is excellent in optical characteristics, transparency, hydrolysis resistance, heat resistance, oxidation resistance, and heat stability and good in moldability, and is suitable for a plastic optical waveguide that is small in transmission loss and excellent in heat resistance.
Type:
Grant
Filed:
October 25, 1993
Date of Patent:
April 25, 1995
Assignees:
The Furukawa Electric Co., Ltd., Teijin Chemicals, Ltd.
Abstract: Antioxidant containing polyolefin compositions are provided including titanium dioxide-coated mica particles comprising a coating of silica and alumina calcined thereon to prevent yellowing of the compositions. Process for preventing the yellowing of antioxidant containing polyolefin compositions is also disclosed.
Type:
Grant
Filed:
September 21, 1993
Date of Patent:
December 27, 1994
Assignee:
The Mearl Corporation
Inventors:
Ioannis P. Sipsas, Brian Mullaney, Leigh A. Kelderhouse
Abstract: Disclosed are polyester adhesive compositions which exhibit increased melt viscosity and improved adhesion comprised of residues of terephthalic acid, ethylene glycol and diethylene glycol and having reacted therewith or copolymerized therein the residue of a phosphite ester compound and optionally containing a phenolic antioxidant. Also disclosed are articles coated with the polyester compositions and bonded laminate articles based on the compositions.
Type:
Grant
Filed:
July 12, 1993
Date of Patent:
August 16, 1994
Assignee:
Eastman Chemical Company
Inventors:
Alan W. White, Barry G. Pearcy, Marc A. Strand, Joey C. Carico
Abstract: The present invention relates to a novel ethylene/pentene-1 copolymer whose molded film has a good balance between impact resistance and tear properties and high transparency, also is prominently reduced in a variation of the transparency even after subjected to a heat treatment, and further shows high blocking resistance, provided that the copolymer fulfills specific requisites. The invention also relates to a process for the preparation of the above-mentioned ethylene/pentene-1 copolymer and a formulation of the ethylene/pentene-1 copolymer composition using a stabilizer. According to the invention, there can be obtained an ethylene/pentene-1 copolymer composition which is excellent in heat stability in the molding stage, long-term heat stability and weatherability.
Abstract: A method for stabilizing an isocyanate compound by adding 10-5000 ppm of phenol to the isocyanate compound, and also an isocyanate composition so stabilized. In the isocyanate composition stabilized by the above method, coloring due to time-dependent changes and the occurrence of turbidity through self-polymerization are both suppressed so that it shows outstanding storage stability compared with a corresponding isocyanate composition containing a conventional stabilizer.
Type:
Grant
Filed:
March 17, 1992
Date of Patent:
April 12, 1994
Assignee:
Mitsui Toatsu Chemicals, Incorporated
Inventors:
Teruyuki Nagata, Hiroyuki Yamashita, Masahiko Kusumoto, Koju Okazaki
Abstract: The present invention relates to a novel ethylene/pentene-1 copolymer whose molded film has a good balance between impact resistance and tear properties and high transparency, also is prominently reduced in a variation of the transparency even after subjected to a heat treatment, and further shows high blocking resistance, provided that the copolymer fulfills specific requisites. The invention also relates to a process for the preparation of the above-mentioned ethylene/pentene-1 copolymer and a formulation of the ethylene/pentene-1 copolymer composition using a stabilizer. According to the invention, there can be obtained an ethylene/pentene-1 copolymer composition which is excellent in heat stability in the molding stage, long-term heat stability and weatherability.
Abstract: A thermoplastic composition based on a polyolefin and a vinyl aromatic polymer, having an improved combination of physical, mechanical and thermal properties, comprising:from 40 to 80% by weight of a vinyl aromatic polymer (A) containing, as an elastomeric component, from 0.5 to 5% by weight of a vinyl aromatic monomer - conjugated diene linear block polymer and from 5 to 15% of a diene rubber, from 5 to 50% by weight of a polyolefin (B) and from 10 to 50% by weight of an olefinic elastomer (C) containing, grafted thereon, a vinyl aromatic polymer, wherein the molar ratio between the vinyl aromatic polymer and the olefinic elastomer in the grafted phrase is greater than 0.8, the sum of components (A), (B) and (C) being equal to 100%.
Type:
Grant
Filed:
November 12, 1991
Date of Patent:
March 1, 1994
Assignee:
ECP Enichem Polimeri S.r.L.
Inventors:
Dario Ghidoni, Gian C. Fasulo, Aldo Longo, Italo Borghi