Solid Polymer Derived From Ethylenic Monomers Only Patents (Class 524/804)
  • Patent number: 7034074
    Abstract: Aqueous primary dispersions and coating materials comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core-shell particles having a diameter?500 nm, preparable by free-radical microemulsion or miniemulsion polymerization of at least one olefinically unsaturated monomer (A) in the presence of at least one hydrophobic crosslinking agent for the (co)polymer resulting from the monomer or monomers (A), wherein said monomer or monomers (A) is or are dispersed prior to (co)polymerization in an aqueous dispersion of said crosslinking agent or agents; processes for preparing them, and their use.
    Type: Grant
    Filed: March 10, 2001
    Date of Patent: April 25, 2006
    Assignee: BASF Coatings AG
    Inventors: Maximilian Bendix, Heinz-Peter Rink, Elisabeth Wessling, Reinhold Clauss, Ralf Nicholaus
  • Patent number: 7026369
    Abstract: To provide an aqueous emulsion composition which has high adhesion strength for a wide variety of materials including molded products and affords sufficient wettability even for the object to be adhesive bonded of low surface polarity so that it can develop sufficient adhesiveness and whose emulsion is stable so satisfactorily as to provide good mechanical stability and storage stability, and to provide an adherent composition comprising the aqueous emulsion composition, at least ethylene-vinyl acetate copolymer or modified resin thereof, photo polymerization initiator, and unsaturated ethylenic monomer are mixed and dissolved or dispersed, to prepare oil drop component, followed by emulsifying the oil drop component in water by using a surface-active agent, whereby an aqueous emulsion composition, in which micelles each encapsulating at least the ethylene-vinyl acetate copolymer or modified resin thereof, the photo polymerization initiator and unsaturated ethylenic monomer are dispersed in water, is prepared
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: April 11, 2006
    Assignee: Mitsui Takeda Chemicals, Inc.
    Inventors: Kenji Kuroda, Susumu Okatani, Hiroyuki Shiraki
  • Patent number: 7019072
    Abstract: The present invention relates to styrene-butadienie latex, specifically a method of preparing latex for coating paper which shows excellent adhesion while maintaining printing property and comprised in a composition for coating paper. To achieve the object of the present invention, it provides a method of preparing styrene-butadiene latex comprising the step of emulsion polymerization by adding 0.1 to 10 parts by weight of chain transfer agent comprising; i) monofunctional thiol compound, and ii) polyfunctional thiol compound having at least two thiol groups based on 100 parts by weight of styrene-butadiene monomer composition. The latex prepared by the present method can easily control molecular weight and gel content, so that polymerization stability and mechanical stability are improved and thus, it is possible to print paper with high speed and to improve adhesion.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: March 28, 2006
    Assignee: LG Chem, Ltd.
    Inventors: Ho-Yeul Choi, Seung-Uk Yeu, Chang-Sun Han, Wan-Sik Cha
  • Patent number: 7008998
    Abstract: The invention relates to a method for preparing aqueous dispersions, especially electrodepositable aqueous dispersions. The invention requires the use of a polymer (a) comprising one or more water dispersible groups per molecule and one or more functional groups (f), and at least one crosslinking agent (b) comprising one or more blocked functional groups (fb) reactive with polymer (a) after unblocking. Crosslinking agent (b) has a Tg of from 40 to 70° C./105 to 158° F. and is a solid at 23.9° C./75° F. when at 100% by weight solids. Crosslinking agent (b) is mixed into polymer (a) at a temperature at or above the melting temperatures of both polymer (a) and compound (b) but below the temperature at which blocked functional groups (fb) unblock. Sufficient water is added to the resulting melt-mixture (ii) to provide an aqueous dispersion.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: March 7, 2006
    Assignee: BASF Corporation
    Inventors: Charles L. Tazzia, William H. Alford, Grant E. Cooley
  • Patent number: 7005474
    Abstract: The invention discloses an acrylic acid-modified epoxy polyester resin and the preparation process thereof. The resin comprises 100 pbw of a copolymer (A) formed from an unsaturated fatty acid-modified polyester and a bisphenol A type epoxy resin, and 20-40 pbw of poly(meth)acrylic acid (ester) (B). The preparation process comprises the following steps: (1) alcoholyzing a drying oil with a polyol; (2) adding successively, to the product from step (1), a dibasic anhydride, a fatty acid containing a conjugated double bond and an epoxy resin, and esterifying to obtain an epoxy polyester; and (3) copolymerizing the epoxy polyester from step (2) and an acrylic monomer. This invention also provides a water-based emulsion containing said resin, and a water-based paint exhibiting excellent antirust property and having low production cost.
    Type: Grant
    Filed: March 11, 2002
    Date of Patent: February 28, 2006
    Assignee: Marine Research Institute of Chemical Industry
    Inventors: Fuchang Liu, Wenlin Liu, Peimin Hou, Yuanhao Xu
  • Patent number: 6998426
    Abstract: These objects and others may be accomplished with the present invention, the first embodiment of which provides an oil-in-water nanoemulsion, which includes: an oily phase dispersed in an aqueous phase; (i) at least one amphiphilic lipid selected from the group including nonionic amphiphilic lipids, anionic amphiphilic lipids, and combinations thereof; and (ii) at least one water-soluble nonionic polymer selected from the group including homopolymers and copolymers of ethylene oxide; polyvinyl alcohols; homopolymers and copolymers of vinylpyrrolidone; homopolymers and copolymers of vinylcaprolactam; homopolymers and copolymers of polyvinyl methyl ether; neutral acrylic homopolymers and copolymers; C1–C2 alkyl celluloses and their derivatives; C1–C3 alkyl guar; C1–C3 hydroxyalkyl guar; and combinations thereof; wherein a ratio of the weight of the oily phase to the weight of the amphiphilic lipid (i) ranges from 1.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: February 14, 2006
    Assignee: L'Oreal
    Inventors: Florence L'Alloret, Odile Aubrun-Sonneville, Jean-Thierry Simonnet
  • Patent number: 6989410
    Abstract: A multimodal polymer particle composition containing two or more populations of polymer particles having a total rubbery weight fraction of less than 90 weight percent is provided. Also disclosed is a process for preparing multimodal polymer particle compositions that can be dried to a powder. Multimodal polymer particle dispersions are disclosed for preparing impact modifiers that can be dried to a powder. Also provided are polymeric compositions having a matrix resin component and impact modifiers prepared from multimodal polymer particles.
    Type: Grant
    Filed: December 2, 2002
    Date of Patent: January 24, 2006
    Assignee: Rohm and Haas Company
    Inventors: Raymond Gerard Hamilton, Morris Christopher Wills, Kirk Harold Moyer, Jennifer Lynn Petoff, Joseph Robert Adamo
  • Patent number: 6964994
    Abstract: The invention relates to a method of conducting polymerization in nonaqueous miniemulsions.
    Type: Grant
    Filed: July 20, 2000
    Date of Patent: November 15, 2005
    Assignee: Max-Planck-Gesellschaft zur Forderung der Wissenschaften E.V.
    Inventors: Markus Antonietti, Katharina Landfester, Mirjam Willert, Franca Tiarks, Nina Bechthold
  • Patent number: 6919402
    Abstract: The present invention provides a compound having anionic functional groups that is useful as a pigment dispersant in waterborne coating compositions, particularly in anodic electrocoat compositions. The compound comprises an acrylic backbone having a stabilizing substituent and a plurality of anionic groups. The anionic groups result from the incorporation of a plurality of acid groups into the acrylic backbone followed by reaction with organic amine.
    Type: Grant
    Filed: November 8, 2001
    Date of Patent: July 19, 2005
    Assignee: BASF Corporation
    Inventor: Timothy S. December
  • Patent number: 6893722
    Abstract: A cationically stabilizable amino-functional polymer having a number-average molecular weight of >3000, exists in the presence of water as a solution or stable emulsion only when the pH is ?8. Upon drying the polymer contains ethenically unsaturated moieties selected from the group consisting of acrylic, methacrylic, and enamine. The polymer is useful to promote adhesion of curable inks and other coatings for plastic film. The invention further relates to a plastic film comprising such polymer.
    Type: Grant
    Filed: April 29, 2002
    Date of Patent: May 17, 2005
    Assignee: ExxonMobil Oil Corporation
    Inventor: Dennis E. McGee
  • Patent number: 6884438
    Abstract: A process for the preparation of nanoparticles for the encapsulation of active constituents, the nanocapsules prepared being dispersible in aqueous phase in colloidal form, non-toxic, biocompatible, stable in colloidal suspension and economical. In the process, two non-oily solvents as used, together with a third, oily solvent.
    Type: Grant
    Filed: July 21, 1998
    Date of Patent: April 26, 2005
    Assignee: Universite Claude Bernard Lyon I
    Inventors: David Quintanar, Hatem Fessi, Eric Doelker, Eric Allemann
  • Patent number: 6884839
    Abstract: Aqueous primary dispersions and coating materials comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core shell particles having a diameter?500 nm preparable by controlled free-radical microemulsion or miniemulsion polymerization of A) at least one olefinically unsaturated monomer and B) at least one olefinically unsaturated monomer which is different than the olefinically unsaturated monomer (A) and has the general formula I: R1R2C?CR3R4 (I), in which the radicals R1, R2, R3 and R4 independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; and in the presence of (C) at least one hydrophobic cross-linking agent for the
    Type: Grant
    Filed: November 8, 2000
    Date of Patent: April 26, 2005
    Assignee: BASF Coatings AG
    Inventors: Maximilian Bendix, Reinhold Clauss, Ralf Nickolaus, Wolfgang Bremser
  • Patent number: 6867251
    Abstract: This invention relates to a process for making polymer-dye particles comprising, in order: I) forming a colorant mixture comprising a water insoluble dye and an organic medium containing at least one ethylenically-unsaturated monomer; II) combining the colorant mixture with an aqueous mixture comprising a surfactant and a co-stabilizer to form a colorant mixture/aqueous mixture; III) causing the colorant mixture/aqueous mixture to form a stable aqueous droplet mixture via strong agitation; and IV) initiating polymerization to form composite polymer-dye particles comprising a colorant phase and a polymer phase; wherein an addition polymerization initiator is added prior to initiating polymerization. It further relates to composite polymer dye particles prepared by the above process and to composite polymer dye particles comprising a colorant phase containing a water insoluble dye, and a polymer phase, said particles being associated with a co-stabilizer.
    Type: Grant
    Filed: December 14, 2001
    Date of Patent: March 15, 2005
    Assignee: Eastman Kodak Company
    Inventors: Xiaoru Wang, Huijuan D. Chen
  • Patent number: 6866860
    Abstract: The present invention is directed to medical devices or pharmaceutical composition, each containing a synthetic, biodegradable, biocompatible polymer that is the reaction product of a polybasic acid or derivative thereof, a monoglyceride, and a cationic polyol.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: March 15, 2005
    Assignee: Ethicon, Inc.
    Inventor: Aruna Nathan
  • Publication number: 20040249064
    Abstract: The invention concerns an aqueous polymer dispersion, prepared from a monomer composition comprising: (A) 50 to 99.99 parts by weight of at least an acrylic or methacrylic ester derived from acrylic or methacrylic acid and an alcohol having 1 to 12 carbon atoms; (B) 0 to 40 parts by weight of at least a vinylaromatic monomer; (C) 0 to 5 parts by weight of at least a short-chain &agr;,&bgr;-unsaturated mono- or polycarboxylic acid; (D) 0.01 to 5 parts by weight of at least an ethylenically unsaturated alpha-beta monomer compound (D), comprising at least a carbonyl group having at least a hydrogen atom borne in position alpha of said carbonyl (diacetone acrylamide), for 100 parts by weight of monomers (A)+(B)+(C)+(D), 80 to 98 wt. % of monomer components having been added to a reaction medium already containing a totally or partly polymerized pre-emulsion representing 2 to 20 wt. % of the final global proportion of monomer components in the dispersion finally obtained.
    Type: Application
    Filed: March 5, 2004
    Publication date: December 9, 2004
    Inventors: Carme Font Panades, Jordi Albalat Perez, Werber Ullenboom
  • Publication number: 20040249097
    Abstract: A process for producing organic peroxide initiators useful in the polymerization of ethylenically unsaturated monomers. The process for making the organic peroxides includes forming an aqueous emulsion of the organic peroxide. The organic peroxide is dispersed as small droplets of from 1 to 10 microns in size in the aqueous emulsion. The organic peroxide may be added to a polymerization reactor containing an ethylenically unsaturated monomer. The organic peroxide functions as a free radical initiator to polymerize the monomer. The organic peroxide may be substantially free of organic solvents and plasticizers. The resulting polymers are of high quality.
    Type: Application
    Filed: May 6, 2003
    Publication date: December 9, 2004
    Inventors: Ross J. Cozens, Qi Wang, M. Frederick V. Glock, Daniel A. Zust
  • Publication number: 20040242767
    Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms, which is selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from &agr;-methylstyrene dimer comprises including at least 30% of the hydrocarbon HC in the initial charge to the polymerization vessel and supplying the remainder of the hydrocarbon HC to the polymerization reaction in the course of that reaction.
    Type: Application
    Filed: March 31, 2004
    Publication date: December 2, 2004
    Inventors: Wolfgang Gaschler, Volker Schadler, Lambertus Manders, Thomas Wirth, Hubertus Kroner
  • Publication number: 20040229997
    Abstract: The present invention relates to the use of aqueous copolymer poly(vinyl ester) dispersions which comprise cellulose ethers in an amount up to a maximum of 0.45% by weight in food-coating compositions, and also food-coating compositions which comprise these aqueous copolymer poly(vinyl ester) dispersions, and their use in the coating of food, especially in the production of hard cheese.
    Type: Application
    Filed: April 14, 2004
    Publication date: November 18, 2004
    Inventors: Bernd Papenfuhs, Holger Schimanke
  • Patent number: 6818303
    Abstract: Powder clearcoat dispersions (powder slurry clearcoats) preparable by dispersing a powder clearcoat in an aqueous medium and wet milling the resulting powder slurry, at least one adduct of ethylene oxide and/or propylene oxide with at least one glycol being added to the powder slurry prior to wet milling; and the use of the powder slurry clearcoats for producing clearcoat finishes, especially as part of multicoat color and/or effect finishes.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: November 16, 2004
    Assignee: BASF Coatings AG
    Inventors: Walter Lassmann, Horst Hintze-Brüning, Wolfgang Bremser, Ulrike Röckrath
  • Publication number: 20040220328
    Abstract: The present invention relates to a process for producing polymers comprising repeating units derived from at least one isoolefin monomer, at least one multiolefin monomer and optionally further copolymerizable monomers in the presence of at least one organic nitro compound and AlCl3/water wherein the process is conducted in the absence of compounds selected from the group consisting of vanadium compounds, zirconium halogenid, hafnium halogenides.
    Type: Application
    Filed: December 3, 2003
    Publication date: November 4, 2004
    Inventors: R. Resendes, Rotraud Casper, Rudolf Casper, William E. App, Gerhard Langstein, Martin Bohnenpoll, Gabor Kaszas, Stephan Glander
  • Publication number: 20040220329
    Abstract: An aqueous polymer composition including a plurality of comb copolymer particles is disclosed. The comb copolymer particles contain comb copolymer having a polymer backbone with at least one attached graft segment. The polymer backbone and the at least one graft segment have select compositional ranges and select glass transition temperature ranges. Further, the comb copolymer contains as a polymerized unit at least one select monomer such as, aldehyde reactive group-containing monomer or certain styrenic monomers. The aqueous polymer composition of the present invention is useful for preparing coatings having one or more improved properties such as dirt pickup resistance, gloss, gloss retention, alkyd adhesion, and tint retention. A method for forming a coated substrate from the aqueous polymer composition of this invention is also provided.
    Type: Application
    Filed: March 24, 2004
    Publication date: November 4, 2004
    Inventors: Robert David Solomon, Ralph Craig Even, Willie Lau, David Michael Fasano, Karl Allen Bromm
  • Publication number: 20040209997
    Abstract: A cross-linked acrylic polymer that is highly biocompatible is prepared from a water-soluble acrylamide monomer by preparing an aqueous polymerization solution containing an acrylamide monomer and a catalyzing agent; polymerizing the monomer present in the polymerization solution by agitating and heating the polymerization solution. The polymerization is conducted in the presence of gaseous oxygen.
    Type: Application
    Filed: May 11, 2004
    Publication date: October 21, 2004
    Applicant: Polymekon S. R. L.
    Inventors: Gerardo Balestrieri, Carmelo Protopapa
  • Publication number: 20040209996
    Abstract: The present invention relates to an emulsion type adhesive applicable for over-laminating films, the preparation and the use thereof. The emulsion type adhesive comprises: (a) 60 to 99.5 parts per hundred of monomers of one or more alkyl acrylates containing 4-12 carbon atoms on the alkyl group; (b) 0.5 to 40 parts per hundred of monomers of an alkyl acrylate containing 1-3 carbon atoms in the alkyl group or an alkyl methacrylate containing 1-6 carbon atoms in the alkyl group; (c) 0.1 to 5 parts per hundred of monomers of dicarboxylic acids; (d) 1 to 5 parts per hundred of a reactive surfactant; (e) 0.1 to 15 parts per hundred of an organic acid vinyl ester; and (f) 100 parts per hundred of soft water, (a) and (b) are 100 parts by hundred, while (c), (d), (e) and (f) are calculated based on the total weight of (a)+(b). The products of this invention have excellent properties.
    Type: Application
    Filed: December 12, 2003
    Publication date: October 21, 2004
    Inventors: Bin-Yen Yang, Chi-Lin Kao, Chih-Kuo Wan, Shu-Hei Lin, Shih-Shang Lo
  • Patent number: 6803020
    Abstract: The invention concerns a novel method for preparing latex by emulsion (co)polymerization of ethylenically unsaturated monomers, wherein the direct inline monitoring is carried out by Raman spectroscopy. The invention also concerns latex compositions obtainable by the emulsion (co) ploymerization method whereof the direct inline monitoring is performed by Raman spectroscopy. The invention further concerns a device for implementing said method, said device comprising a reactor, at least an optical probe, a Raman spectrometer, optical fibers, a computer and a regulating automaton.
    Type: Grant
    Filed: January 7, 2002
    Date of Patent: October 12, 2004
    Assignee: Raisio Chemicals OY
    Inventors: Mathias Agnely, Bruno Amram, Phil D. Armitage, Dominique Charmot, Bruno Drochon, Eve Pere
  • Patent number: 6800699
    Abstract: Process for the production of aqueous polymer dispersions by reaction of one or more olefinically unsaturated compounds in aqueous medium in the presence of a complex compound which possesses the structural element Y—M—E, E standing for nitrogen, M for a transition metal of groups 7 to 10 of the periodic system of the elements and Y for oxygen, sulfur, nitrogen or phosphorus, and which possesses no hydrophilic groups in its ligand system.
    Type: Grant
    Filed: December 17, 2001
    Date of Patent: October 5, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Markus Schmid, Mubarik Mahmood Chowdhry, Marc Oliver Kristen, Stefan Mecking, Florian M. Bauers
  • Patent number: 6800675
    Abstract: The invention relates to starch, derived from amylopectin potatoes, which is preferably in a modified and/or derivatised form. Said starch is an especially advantages protective colloid for use in conducting emulsion polymerization reactions. The invention also relates to emulsion [co]polymerization methods and polymer dispersions produced thereby.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: October 5, 2004
    Assignee: Südzucker Aktiengesellschaft Mannheim/Ochsenfurt
    Inventors: Monika Pfalz, Michel Wastyn Marnik, Dietmar Grüll
  • Publication number: 20040192839
    Abstract: A process for the production of a vulcanized elastomer composition, said process consisting in producing an aqueous dispersion containing at least latex with a small particle size and a filler having undergone a mechanical working stage and conventional vulcanization ingredients, in drying said dispersion and then vulcanizing it in a mould under pressure without subjecting said dried aqueous dispersion to mechanical working.
    Type: Application
    Filed: February 2, 2004
    Publication date: September 30, 2004
    Applicant: Conception et Developpement Michelin S.A.
    Inventors: Herve Mousty, Marcel Tornare
  • Patent number: 6797761
    Abstract: Aqueous primary dispersions comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core-shell particles having a diameter≦500 nm, preparable by free-radical microemulsion or miniemulsion polymerization of at least one olefinically unsaturated monomer (A) in the presence of at least one polyhydroxy-functionalized cyclic and/or acyclic alkare having from 9 to 16 carbon atoms in the molecule, and their use in automotive OEM finishing and refinishing, in furniture coating and in industrial coating, including coil coating, container coating and the coating of electrical components.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: September 28, 2004
    Assignee: BASF Coatings AG
    Inventors: Maximilian Bendix, Heinz-Peter Rink
  • Publication number: 20040167259
    Abstract: The invention relates to a method for producing aqueous copolymer dispersions of copolymers consisting of carbon monoxide and olefinically unsaturated compounds, by means of copolymerisation of carbon monoxide and olefinically unsaturated compounds in an aqueous medium in the presence of metallic complexes.
    Type: Application
    Filed: January 9, 2004
    Publication date: August 26, 2004
    Inventors: Markus Schmid, Mubarik Mahmood Chowdhry, Marc Oliver Kristen, Stefan Mecking, Anke Held, Ekkehard Lindner, Mahmoud Sunjuk, Peter Wegner
  • Patent number: 6780472
    Abstract: A monomer useful in the formulation of a radiation curable coatable composition comprises (a) polyfunctional isocyanurate having at least three terminal reactive groups reacted with (b) hydroxyalkyl acrylate and (c) tertiary amine alcohol in a molar ratio of a:b:c of about 1:1-2.5:0.5-2, wherein b+c is at least 3 and no greater than the total number of terminal reactive groups of (a). The monomer is included in a radiation curable coatable composition suitable for use as a floor finish and in a floor finishing system comprising the foregoing coatable composition with a primer. A method for the treatment of a substrate using the floor finish and the floor finishing system is also described.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: August 24, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Steven J. Hamrock, Fidelis C. Onwumere, Bradford B. Wright, Michael A. Yandrasits
  • Publication number: 20040162386
    Abstract: Water-continuous emulsion of elastomeric polymers are disclosed having a solids content of greater than 75%, an average particle size less than 5 &mgr;m, and having sufficient stability to produce a stable lower solids emulsion upon dilution with water comprising; an elastomeric polymer, surfactant, water, optional plasticizer, optional low molecular weight acid, and is essentially free of organic solvents. The water-continuous emulsions of elastomeric polymers can be prepared by; (I) forming a premix that is essentially free of organic solvents comprising an elastomeric polymer and surfactant, and optionally a plasticizer and low molecular weight acid, and (II) adding water to the premix with mixing to form a water continuous emulsion of the elastomeric polymer having a solids content of greater than 75%, an average particle size less than 5 &mgr;m, and having sufficient stability to produce a stable lower solids emulsion upon dilution with water.
    Type: Application
    Filed: February 17, 2004
    Publication date: August 19, 2004
    Inventors: Michael Gene Altes, Craig Steven Gross, Lee Bowen Jensen, Shaow Burn Lin, Anil Kumar Saxena, Todd Matthew Starke, Toshio Suzuki, Raymond Lee Tabler
  • Patent number: 6770719
    Abstract: A process for producing peroxydicarbonates comprising first reacting at least one inorganic peroxide with at least one alkali metal hydroxide to form at least one alkali metal peroxide. The at least one alkali metal peroxide is added to a mixture of at least one haloformate, at least one dispersant and water. The mixture is homogenized during the entire reaction to form a peroxydicarbonate. The peroxydicarbonate is dispersed as small droplets of from 1 to 10 microns in size in the aqueous mixture. The entire mixture is added to a polymerization reactor containing an ethylenically unsaturated monomer. The peroxydicarbonate functions as the free radical initiator to polymerize the monomer. The peroxydicarbonate is substantially free of organic solvents and plasticizers. The resulting polymers are of high quality.
    Type: Grant
    Filed: April 25, 2002
    Date of Patent: August 3, 2004
    Assignee: Oxy Vinyls, L.P.
    Inventor: Ross James Cozens
  • Publication number: 20040116598
    Abstract: Removable, water-whitening resistant pressure sensitive adhesive (PSA) comprising a crosslinked aqueous emulsion polymer comprising (a) at least one hydrophobic monomer; (b) at least about 2 wt. % of at least one hydrophilic monomer; and (c) at least about 5 wt. % of at least one partially hydrophilic monomer; wherein the crosslinked aqueous emulsion polymer is crosslinked with an effective amount of at least one polyfunctional aziridine crosslinker, and the wt. % of monomers (a), (b), and (c) are based on the total weight of monomers (a), (b), and (c).
    Type: Application
    Filed: September 25, 2003
    Publication date: June 17, 2004
    Inventors: Jong-Shing Guo, Augustin T. Chen, Sharon D. Trembley
  • Publication number: 20040116597
    Abstract: Polymer solids are maintained in an intermediate pressure zone for a desired polymer solids residence time and then transferred to a purge zone or other lower pressure zone. An increase in the polymer solids residence time in the intermediate pressure zone allows more diluent to flash or separate, thereby avoiding or reducing the need for a low pressure flash zone. A fluff chamber may be disposed between the intermediate pressure zone and a lower pressure zone transporter tank may be used to transport polymer solids after the intermediate pressure zone.
    Type: Application
    Filed: September 15, 2003
    Publication date: June 17, 2004
    Inventors: Thomas A. Reid, Scott E. Kufeld, John H. Tait, David H. Burns, Donald W. Verser
  • Patent number: 6737473
    Abstract: Water-continuous emulsion of elastomeric polymers are disclosed having a solids content of greater than 75%, an average particle size less than 5 &mgr;m, and having sufficient stability to produce a stable lower solids emulsion upon dilution with water comprising; an elastomeric polymer, surfactant, water, optional plasticizer, optional low molecular weight acid, and is essentially free of organic solvents. The water-continuous emulsions of elastomeric polymers can be prepared by; (I) forming a premix that is essentially free of organic solvents comprising an elastomeric polymer and surfactant, and optionally a plasticizer and low molecular weight acid, and (II) adding water to the premix with mixing to form a water continuous emulsion of the elastomeric polymer having a solids content of greater than 75%, an average particle size less than 5 &mgr;m, and having sufficient stability to produce a stable lower solids emulsion upon dilution with water.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: May 18, 2004
    Assignee: Dow Corning Corporation
    Inventors: Michael Gene Altes, Craig Steven Gross, Lee Bowen Jensen, Shaow Burn Lin, Anil Kumar Saxena, Todd Matthew Starke, Toshio Suzuki, Raymond Lee Tabler
  • Publication number: 20040092693
    Abstract: The invention is directed to amphipathic polymeric particles that serve as both the dispersant and the binder in water based inks, ink compositions containing these particles, and methods for making the particles. The polymeric particles contain both hydrophilic and hydrophobic moieties with a pre-determined structure, and have an average diameter of 50 to 500 nm. The amphipathic polymeric particles may be prepared by a side-chain conversion method or a polymerization process involving an ATRP step, with or without a cross-linking agent. This invention improves the stability of polymer and inks by both ionic and steric stabilization of the suspended polymer particles.
    Type: Application
    Filed: October 30, 2003
    Publication date: May 13, 2004
    Inventor: Sivapa Kia Ganapathiappan
  • Publication number: 20040092692
    Abstract: The invention is directed to amphipathic polymeric particles that serve as both the dispersant and the binder in water based inks, ink compositions containing these particles, and methods for making the particles. The polymeric particles contain both hydrophilic and hydrophobic moieties with a pre-determined structure, and have an average diameter of 50 to 500 nm. The amphipathic polymeric particles may be prepared by a side-chain conversion method or a polymerization process involving an ATRP step, with or without a cross-linking agent. This invention improves the stability of polymer and inks by both ionic and steric stabilization of the suspended polymer particles.
    Type: Application
    Filed: October 30, 2003
    Publication date: May 13, 2004
    Inventor: Sivapackia Ganapathiappan
  • Publication number: 20040092659
    Abstract: The invention is directed to amphipathic polymeric particles that serve as both the dispersant and the binder in water based inks, ink compositions containing these particles, and methods for making the particles. The polymeric particles contain both hydrophilic and hydrophobic moieties with a pre-determined structure, and have an average diameter of 50 to 500 nm. The amphipathic polymeric particles may be prepared by a side-chain conversion method or a polymerization process involving an ATRP step, with or without a cross-linking agent. This invention improves the stability of polymer and inks by both ionic and steric stabilization of the suspended polymer particles.
    Type: Application
    Filed: October 30, 2003
    Publication date: May 13, 2004
    Inventor: Sivapackia Ganapathiappan
  • Patent number: 6730715
    Abstract: A curable dental restorative composition comprising about 1 to about 90 wt %, based on the total weight of the composition, of a filler component, the filler component comprising about 10 to 100 wt %, based on the total weight of the filler component, of a surface reactive glass component; about 1 to about 50 wt %, based on the total weight of the composition, of water; and about 10 to about 97 wt %, based on the total weight of the composition, of a curable organic component, comprising about 50 to about 99 wt %, based on the total weight of the curable organic component, of an ethylenically unsaturated resin component, about 1 to about 50 wt %, based on the total weight of the curable organic component, of an ethylenically unsaturated phosphoric acid ester; and about 0.01 to about 5 wt % of a curing system.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: May 4, 2004
    Assignee: Pentron Clinical Technologies, LLC
    Inventor: Weitao Jia
  • Publication number: 20040077782
    Abstract: Aqueous plastic material dispersions, method for producing the same and use thereof The present invention relates to aqueous plastic material dispersions based on vinyl ester copolymers, having a solids content of up to 80% by weight and a minimum film formation temperature below 20° C., which is substantially stabilized by ionic components, the vinyl ester copolymers containing at least one homo- or copolymer A and at least one homo- or copolymer B, methods for producing the same and the use thereof.
    Type: Application
    Filed: October 6, 2003
    Publication date: April 22, 2004
    Inventors: Carsten Heldmann, Harald Petri, Thomas Wirth
  • Patent number: 6723773
    Abstract: A coated transfer sheet comprising a substrate having a first and second surface; optionally at least one barrier layer overlaying said first surface, at least one release layer overlaying said at least one barrier layer or, when the barrier layer is not present, said first surface of the substrate; and an optional image receiving layer comprising an ethylene acrylic acid co-polymer dispersion; wherein the coated transfer sheet exhibits cold peel and hot peel properties when transferred, and may be used in electrostatic printers and copiers or other devices in which toner particles are imagewise applied to a substrate. The addition of elastomeric polymers and polyurethanes help provide enhanced wash stability and chemical stability.
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: April 20, 2004
    Assignee: Foto-Wear, Inc.
    Inventors: Scott Williams, Heather Penk, Heather Reid
  • Publication number: 20040072946
    Abstract: There is described a method of preparing a first polymeric compound which comprises a providing a compound of general formula (I) or a salt thereof where A and B are the same or different and at least one comprises a relatively polar atom or group and R1 and R2 independently comprise relatively non-polar atoms or groups, in a solvent of a type in which ethene itself is generally insoluble and causing the groups C═C in said compound to react with one another to form a polymeric structure. The first polymeric compound may be reacted with a second compound, for example polyvinylalcohol, collagen or the like to produce a colloid or gel which may have applications in the treatment or bums or recovery of oils.
    Type: Application
    Filed: August 21, 2003
    Publication date: April 15, 2004
    Applicant: Advanced Gel Technology Limited
    Inventors: Donald Eagland, Nicholas J. Crowther
  • Patent number: 6713552
    Abstract: An aqueous composition suitable for use when dry as a pressure sensitive adhesive including an aqueous emulsion polymer formed by the free radical polymerization of at least one ethylenically unsaturated monomer at a reaction temperature lower than 100° C. in the presence of 20-1500 ppm, based on the total weight of the monomer, of an N-oxyl radical, the polymer having a glass transition temperature (Tg) from −80° C. to 0° C. is provided. Also provided is a method for preparing the emulsion polymer and a method for coating a substrate with an aqueous composition to provide a pressure sensitive adhesive layer on a substrate.
    Type: Grant
    Filed: July 20, 2000
    Date of Patent: March 30, 2004
    Assignee: Rohm and Haas Company
    Inventors: Patricia Marie Lesko, Robert M. Blankenship
  • Patent number: 6713557
    Abstract: A process for preparing an aqueous emulsion polymer including providing at least one ethylenically unsaturated monomer and a free radical redox initiator system under emulsion polymerization conditions, the redox initiator system including an oxidant; a reductant and a metal promoter complex, and effecting the polymerization of at least some of the ethylenically unsaturated monomer is provided. Also provided is a process for reducing the residual ethylenically unsaturated monomer content of an aqueous emulsion polymer.
    Type: Grant
    Filed: November 20, 2001
    Date of Patent: March 30, 2004
    Assignee: Rohm and Haas Company
    Inventors: Steven Michael Baxter, Patrick Albert Clark
  • Patent number: 6710122
    Abstract: A process for preparing aqueous polymer dispersions by means of a polymerization, conducted in an aqueous system, of at least one free-radically polymerisable ethylenically unsaturated monomer in the presence of a polymerisation initiator, wherein the pH of the aqueous dispersion is adjusted during the preparation process by adding at least two different, basic reagents, at least one of said basic reagents being added in a plurality of stages.
    Type: Grant
    Filed: February 25, 2002
    Date of Patent: March 23, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Maximilian Angel, Karl Kolter, Axel Sanner
  • Patent number: 6696533
    Abstract: A process of free-radically initiated aqueous emulsion polymerization, in which monomers are polymerized in the presence of a N-oxyl radical and by means of special free-radical polymerization initiators at more than 100° C. and at pressures above the vapor pressure of the polymerization mixture.
    Type: Grant
    Filed: December 27, 1999
    Date of Patent: February 24, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Fischer, Bradley Ronald Morrison, Heinz Friedrich Sutoris, Yvon Durant
  • Patent number: 6696519
    Abstract: A process for preparing an aqueous emulsion polymer including providing at least one ethylenically unsaturated monomer and a free radical redox initiator system under emulsion polymerization conditions, the redox initiator system including a water-soluble oxidizing agent, a water-insoluble oxidizing agent, and a sulfinic acid, or salts thereof, reducing agent; and effecting the polymerization of at least some of the ethylenically unsaturated monomer is provided. Also provided is a process for reducing the residual ethylenically unsaturated monomer content of an aqueous emulsion polymer.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: February 24, 2004
    Assignee: Rohm and Haas Company
    Inventors: Steven Charles Brown, Ralph Craig Even
  • Publication number: 20040010077
    Abstract: A composition for a damp hand donnable glove using a novel coating. The novel coating results in the formulation of domains of variable size and height. The coating has a polyurethane polymer, and aqueous dispersion and a surfactant.
    Type: Application
    Filed: July 1, 2003
    Publication date: January 15, 2004
    Inventors: Jeffrey G Nile, Stanley J Gromelski, Paul Cacioli, Richard L Cox, E Anthony Yu
  • Patent number: 6677409
    Abstract: A method of producing a vinyl-based polymer is provided in which the blocking of piping resulting from solidification of a reaction inhibitor does not occur even if the operation of supplying the reaction inhibitor is conducted at a low temperature. This method involves the polymerization of a vinyl monomer via a radical reaction, wherein a reaction inhibitor formed from a compound represented by a general formula (1), shown below, is added to the polymerization system in the form of an aqueous dispersion, either prior to commencement of the polymerization, during the polymerization, or following completion of the polymerization, depending on the effect desired. R represents an alkyl group of 3 to 6 carbon atoms.
    Type: Grant
    Filed: April 16, 2002
    Date of Patent: January 13, 2004
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Ryuichi Saito, Tadashi Amano
  • Publication number: 20030236348
    Abstract: The present invention relates to a process for preparing emulsion polymers with very high purity.
    Type: Application
    Filed: May 29, 2003
    Publication date: December 25, 2003
    Inventors: Peter Wendling, Hartmut Gobel, Rolf Josten, Paul Krieger, Hans-Rafael Winkelbach, Hans Christian Strauch, Werner Obrecht, Jean-Pierre Lambert