With Polycarboxylic Acid Or Derivative As Reactant Patents (Class 528/176)
  • Patent number: 8158743
    Abstract: Rosin modified phenolic resins are prepared by reacting together rosin, fatty acid, phenol and aldehyde. The fatty acid may be Monomer (derived from the fatty acid dimerization process). The reaction mixture may optionally include ?,?-olefinically unsaturated carboxylic acid(s) or anhydride(s), and polyol(s). The resin may be dissolved in a solvent to form a varnish. The resin may be used as a component of inks for lithographic or gravure printing.
    Type: Grant
    Filed: April 27, 2007
    Date of Patent: April 17, 2012
    Assignee: Arizona Chemical Company, LLC
    Inventor: Thomas A. Fontana
  • Patent number: 8153753
    Abstract: A polyamide having at least an alicyclic or aromatic group exhibiting a light transmittance of 80% or more in the wavelength region of 450 to 700 nm is produced by using an aramide polymer comprising specific structural units at an amount of 50 mol % or more. Colorless transparent alicyclic or aromatic polyamide films having high rigidity and high thermal resistance are provided by using the polyamide. Further, the invention provides various optical members made by using the polyamide or the polyamide films, and polyamide copolymers.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: April 10, 2012
    Assignee: Toray Industries, Inc.
    Inventors: Hideki Moriyama, Akimitsu Tsukuda
  • Patent number: 8148047
    Abstract: A carboxyl resin according to the present invention is obtained by a process including following steps: epoxy groups on a resin (a) having two or more epoxy groups in one molecule is made to react with 0.3-0.85 mol of a monocarboxylic acid (b) per one epoxy-group equivalent weight to obtain a reaction product (c); the epoxy group or groups on the reaction product (c) are made to react with 0.15-0.95 mol of a polybasic acid (d) per one epoxy-group equivalent weight to obtain a reaction product (e); and the epoxy group or groups on the reaction product (e) are further made to react with 1.0-5.0 mol of a monocarboxylic acid (f) per one epoxy-group equivalent weight. The carboxyl resin thus obtained has an acid value within a range from 20 to 200 mgKOH/g and is soluble in an organic solvent.
    Type: Grant
    Filed: February 20, 2009
    Date of Patent: April 3, 2012
    Assignee: Goo Chemical Company, Ltd.
    Inventors: Koichi Ikegami, Noboru Kohiyama, Teppei Nishikawa, Michiya Higuchi, Nobuhito Hamada, Hiroko Daido, Chieko Inui, Tatsuya Kubo
  • Patent number: 8138116
    Abstract: The application discloses a Titanium oxide composition and the application thereof. The mentioned Titanium oxide composition comprises Titanium co-precipitate(s), organic acid, diol, and water. According to this application, a catalyzed poly-esterification with said Titanium oxide composition is also disclosed. The mentioned polyesterification comprises a step of adding said Titanium oxide composition into at least one stage selected from slurry stage, esterification stage, and polycondensation stage.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: March 20, 2012
    Assignee: Far Eastern New Century Corporation
    Inventors: Hsin-Chin Ho, Ching-Tsu Peng, Shih-Fong Lee, Yui-Chi Lin, Chun-Wei Chen
  • Patent number: 8133650
    Abstract: A polyester resin which includes acid components having aromatic dibasic acid component and trivalent or higher acid component; alcohol components including aliphatic, aromatic or cycloaliphatic diol component, and trihydric or higher alcohol component; polyolefin polyol having 1,800 to 2,500 number average molecular weight and hydroxyl value of 40 to 55 KOHmg/g; and wax having melting point of 80 to 110, wherein the amount of the polyolefin polyol is 0.1 to 2 weight % and the amount of the wax is 0.5 to 15 weight % with respect to the total polyester resin. Also disclosed is a method for preparing polyester resin by (a) carrying out an esterification reaction or an ester exchange reaction with the acid components, the alcohol components, and the polyolefin polyol; and (b) carrying out a polycondensation reaction for reaction product of the esterification or ester exchange reaction in the presence of the wax.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: March 13, 2012
    Assignee: SK Chemicals Co., Ltd.
    Inventors: Young-Man Yoo, Jae-Kyoung Roh, Kye-Yune Lee, Tae-Woong Lee
  • Patent number: 8124225
    Abstract: An aqueous floor care composition comprising water, polymer particles wherein the polymer particles include units derived from a conjugated diene monomer, units derived from an acidic monomer, and units derived from a hard, non-acidic monomer, an external crosslinking agent, and optionally one or more of a leveling agent, surfactant, polyurethane, alkali-soluble resin, coalescing agent, plasticizer, and wax.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: February 28, 2012
    Assignee: OMNOVA Solutions Inc.
    Inventors: Kyung Don Kim, James Gaston, II
  • Patent number: 8084569
    Abstract: A liquid-phase process is provided for the synthesis from glutarimidines of diaminopyridines and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
    Type: Grant
    Filed: December 18, 2007
    Date of Patent: December 27, 2011
    Assignee: E.I. DuPont de Nemours and Company
    Inventors: Aaron Minter, Berlin Stokes
  • Patent number: 8076446
    Abstract: An optical layered body having an excellent antistatic property and adhesion is provided. An optical layered body is provided that comprises an antistatic layer and a hard coat layer formed in sequence on a light transmitting substrate, wherein in the cross-sectional appearance of the layered body, the cross-section phase of the hard coat layer exists in the region of the light transmitting substrate via the antistatic layer from the hard coat layer.
    Type: Grant
    Filed: March 30, 2007
    Date of Patent: December 13, 2011
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Masataka Nakashima, Yoko Kinoshita, Kiyoshi Itoh
  • Publication number: 20110281482
    Abstract: Exemplary embodiments provide compositions for erasable media and methods of forming polymers for erasable media. The method can include providing a first monomer, the first monomer including one or more alkoxylated bisphenols and adding at least one second monomer and a catalyst to the first monomer to form a mixture at a first temperature, the second monomer selected from the group consisting of an organic diacid, a dialkyl ester of the organic diacid, and combinations thereof. The method can also include melt condensing the mixture by increasing the temperature from the first temperature to a second temperature over a first amount of time to form one or more polymers, wherein the one or more polymers has an acid value in the range of about 0.1 mg-KOH to about 12 mg-KOH.
    Type: Application
    Filed: May 13, 2010
    Publication date: November 17, 2011
    Applicant: XEROX CORPORATION
    Inventors: Adela Goredema, Guerino Sacripante, Gabriel Iftime, Kentaro Morimitsu, Roger Gaynor, Peter M. Kazmaier
  • Patent number: 8044151
    Abstract: The present invention provides a wholly aromatic liquid-crystalline polyester consisting of the repeating units represented by formulae (I), (II), (III) and (IV): wherein: the molar proportion of the repeating unit represented by formula (I) based on the total repeating units constituting the wholly aromatic liquid-crystalline polyester is 40-80 mol %; the molar ratio of the total amount of the repeating units represented by formulae (II) and (III) to the repeating unit represented by formula (IV) is from 90/100 to 100/90; the molar proportion of the repeating unit represented by formula (II) based on the total amount of the repeating units represented by formulae (II) and (III) is 80-99.9 mol%; and the two “—O—” attached to the benzene ring in formula (III) are positioned meta or para to each other and “Ar” in formula (IV) represents a bivalent aromatic group.
    Type: Grant
    Filed: October 29, 2008
    Date of Patent: October 25, 2011
    Assignee: Ueno Fine Chemicals Industry, Ltd.
    Inventors: Motoki Asahara, Hiroaki Terada, Hiroyuki Kato
  • Patent number: 8034892
    Abstract: A biocidal polymer including at least one repeating unit of formula (A): wherein: R1 in each occurrence independently represents a divalent aromatic group containing 6 to 30 carbon atoms, a C2-C16 alkylene group or an alkylene biscyclohexyl; Y in each occurrence independently represents an oxygen atom or a sulfur atom; and Z1, Z2, Z3 and Z4 in each occurrence independently represent a hydrogen atom or a halogen atom; wherein at least one of Z1, Z2, Z3 and Z4 in the at least one repeating unit of formula (A) is a halogen atom.
    Type: Grant
    Filed: June 15, 2009
    Date of Patent: October 11, 2011
    Assignee: Far Eastern New Century Corporation
    Inventors: Ken-Yuan Chang, Cheng-Tar Wu, Fa-Chen Chi, Kuo-Cheng Lu, Lin-Chien Yu
  • Patent number: 8030441
    Abstract: A loose mixture formed of one or more solid inert materials and a hardenable resin dissolved in an organic solvent, in particular the remainder of the initial mix used for the manufacture of conglomerate stone sheets, is rendered inert by means of dielectric heating at a frequency of less than 300 MHz. A plant for implements a method where a loose mixture is formed of one or more solid inert materials and a hardenable resin dissolved in an organic solvent, in particular the remainder of the initial mix used for the manufacture of conglomerate stone sheets, is rendered inert by means of dielectric heating at a frequency of less than 300 MHz.
    Type: Grant
    Filed: July 10, 2007
    Date of Patent: October 4, 2011
    Inventor: Dario Toncelli
  • Patent number: 8030433
    Abstract: Tailorable polyimide resin systems suitable for processing by resin transfer molding (RTM) and resin infusion (RI) methods. An exemplary resin system includes first and second prepolymer components present in respective amounts to provide the desired processibility. The cured polyimide system exhibits high glass transition temperature and other properties required for gas turbine engine applications. The first and second prepolymer components independently comprise a monomeric mixture or a reaction product of a diamine component, a dianhydride component, and an end group component.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: October 4, 2011
    Assignee: General Electric Company
    Inventors: Stephen Mark Whiteker, Lisa Vinciguerra Shafer, Warren Rosal Ronk
  • Publication number: 20110237771
    Abstract: A method for producing polyester resin includes: esterifying an alcoholic component, and an acid component containing polyvalent carboxylic acid and/or an ester-forming derivative thereof in a reaction solution. A condition of reaction pressure is changed from a pressurized state to a normal pressure state, or to a depressurized state under a condition (I) that an acid-based extent of reaction of the esterification is 76-94%, and a condition (II) that an undissolved acid component is present in the reaction solution.
    Type: Application
    Filed: November 26, 2009
    Publication date: September 29, 2011
    Applicant: KAO CORPORATION
    Inventors: Yuichi Kono, Kazuma Yoshida, Hidekazu Yawata, Seiki Yoshioka, Shinpei Oota
  • Patent number: 8022167
    Abstract: A liquid-phase process is provided for the manufacture from glutaronitriles and related compounds of 2,6-diaminopyridine and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
    Type: Grant
    Filed: December 18, 2007
    Date of Patent: September 20, 2011
    Inventors: Aaron Minter, Berlin Stokes
  • Publication number: 20110223254
    Abstract: The present invention relates to dephenolic compounds, an example of which is shown below, which are functionalized, and polymers formed from the same. Polymers formed from the functionalized diphenolics are expected to have controllable degradation profiles, enabling them to release an active component over a desired time range. The polymers are also expected to be useful in a variety of medical applications.
    Type: Application
    Filed: March 25, 2011
    Publication date: September 15, 2011
    Applicant: BEZWADA BIOMEDICAL, LLC
    Inventor: Rao S. Bezwada
  • Patent number: 8017713
    Abstract: An apparatus of a polycarbonate resin having polymerization tanks is provided. In supplying a molten reactant to a liquid phase in a polymerization tank, or supplying the molten reactant to a gas phase in the polymerization tank by an insertion pipe, in at least one polymerization tank, and/or producing a polycarbonate resin by an ester exchange reaction between an aromatic dihydroxy compound and a carbonic diester by using three vertical polymerization tanks and one horizontal polymerization tank, a wall surface temperature T of a distillation pipe is set higher than a boiling point t1 of by-produced phenol such that the relationship of the boiling point t1 of the by-produced phenol under a pressure in at least a third vertical polymerization tank, the wall surface temperature T of the distillation pipe and an inner temperature t2 of the third vertical polymerization tank satisfies t1<T?t2.
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: September 13, 2011
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kazuyuki Takahashi, Ryuuji Uchimura, Toshiyuki Hamano, Masaaki Miyamoto, Kodama Miyamoto, legal representative, Taro Miyamoto, legal representative, Hideo Miyamoto, legal representative, Hanae Miyamoto, legal representative
  • Patent number: 8017715
    Abstract: An object of the present invention is to provide a polyester film having excellent dimensional stability to temperature and humidity. The present invention is a polyester containing a dicarboxylic acid component and a diol component, wherein (i) the dicarboxylic acid component contains not less than 5 mol % and less than 50 mol % of a recurring unit represented by the following formula (A) and more than 50 mol % and not more than 95 mol % of a recurring unit represented by the following formula (B): wherein RA is an alkylene group having 2 to 10 carbon atoms, wherein RB is a phenylene group or naphthalenediyl group; and (ii) the diol component contains 90 to 100 mol % of a recurring unit represented by the following formula (C): —O—RC—O—??(C) wherein RC is an alkylene group having 2 to 10 carbon atoms, and a film comprising the same.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: September 13, 2011
    Assignee: Teijin Limited
    Inventors: Eiji Kinoshita, Tomoyuki Kishino, Kazuteru Kohno, Tatsuya Ogawa
  • Patent number: 8017723
    Abstract: Processes for making polyesters in a polyester production facility are disclosed, that include the steps of forming a reaction medium comprising at least one monomer that includes terephthalic acid (TPA) and/or an ester derivative of TPA; subjecting at least a portion of the reaction medium to one or more chemical reactions in the polymer production facility to thereby produce the polyester; and heating the reaction medium at one or more locations in the polyester production facility, wherein at least 50 percent of the total energy input employed for the heating of the reaction medium is provided by indirect heat exchange between the reaction medium and steam.
    Type: Grant
    Filed: September 11, 2009
    Date of Patent: September 13, 2011
    Assignee: Grupo Petrotemex, S.A. de C.V.
    Inventors: Alan George Wonders, James Donald Simpson, Bruce Roger DeBruin
  • Patent number: 8003749
    Abstract: Disclosed is a fluorine-containing dicarboxylic acid represented by formula (1), wherein n represents an integer of 1-4, and the two carboxylic groups are not adjacent to each other on the aromatic ring. It is possible to obtain a linear polymer compound by reacting the fluorine-containing dicarboxylic acid with a comonomer (e.g., diaminodiol). By thermal cyclization, this linear polymer compound can be converted into another polymer compound having superior characteristics.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: August 23, 2011
    Assignee: Central Glass Company, Limited
    Inventors: Satoru Narizuka, Yuji Hagiwara, Masashi Nagamori, Kazuhiro Yamanaka
  • Patent number: 7999057
    Abstract: A gas-phase, continuous process is provided for the manufacture of 2,6-diaminopyridine and related compounds from glutaronitriles, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: August 16, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Keith W. Hutchenson, Aaron Minter, Gregg Sunshine
  • Patent number: 7999058
    Abstract: A method for producing an aromatic polymer includes polycondensing an aromatic compound represented by formula (I) in the presence of a nickel complex containing a phosphine compound represented by formula (II), wherein, Ar denotes an aromatic ring containing organic group, which aromatic ring may contain an oxygen atom and/or a nitrogen atom; R denotes a monovalent group containing a hydrocarbon group; k is an integer of 1 or more; X denotes an halogen atom, a nitro group or a group represented by —SO3Q, wherein Q denotes a monovalent hydrocarbon group; Y denotes O, S, an imino group, an ethenylene group, or an ethynylene group; n denotes 0 or 1; and M denotes H, —B(OQ1)2, —Si(Q2)3, —Sn(Q3)3 or —Z1(Z2)m, wherein Q1 denotes H or a monovalent hydrocarbon group; Q2 and Q3 denote a monovalent hydrocarbon group; Z1 denotes a metal atom or a metal ion; Z2 denotes a counter ion; and m is an integer of 0 or higher; wherein, R1 denotes a monovalent hydrocarbon group, and R2 denotes a divalent hydrocarbon gro
    Type: Grant
    Filed: February 13, 2007
    Date of Patent: August 16, 2011
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tsutomu Yokozawa, Hideyuki Higashimura
  • Patent number: 7999059
    Abstract: The invention relates to an optical film containing aromatic polymer which shows high solubility to solvents, and methods for production thereof. Further, the invention also relates to an optical laminate, a polarizing plate, and an image display device each using the optical film. The optical film may be attained by using polyester with a specific structure. The polyester with a specific structure may be obtained by condensation polymerization of bisphenol compound(s) and dicarboxylic acid compound(s) with biphenyl structure, and preferably has no halogen atom in its chemical structure. The optical film of the invention advantageously has not only high solubility in solvents but also a high level of heat resistance and birefringence producing capability. When the content of the biphenyl structure is high, the optical film of the invention can also have large wavelength dispersion of birefringence.
    Type: Grant
    Filed: November 6, 2008
    Date of Patent: August 16, 2011
    Assignee: Nitto Denko Corporation
    Inventors: Tomoyuki Hirayama, Toshiyuki Iida, Yutaka Ohmori, Miyuki Kurogi, Hisae Shimizu
  • Patent number: 7985825
    Abstract: Ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a halogenated aromatic acid such as is described by the structure of Formula II wherein each X is independently Cl, Br or I; the reaction mixture further comprising; (i) a polar protic solvent, a polar aprotic solvent or an alcoholic solvent containing the alcoholate RO-M+ (wherein M is Na or K), wherein the polar protic solvent, polar aprotic solvent or alcoholic solvent is either ROH or is a solvent that is less acidic than ROH; (ii) a copper (I) or copper (II) source; and (iii) an amino acid ligand that coordinates to copper, wherein the ligand comprises an amino acid in which the amine nitrogen and the carboxyl carbon are separated by no more than two carbon atoms.
    Type: Grant
    Filed: December 18, 2007
    Date of Patent: July 26, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Joachim C. Ritter
  • Patent number: 7964698
    Abstract: The benefits of liquid crystal polymers and polyetherimides are combined in an all-aromatic thermoplastic liquid crystalline polyetherimide. Because of the unique molecular structure, all-aromatic thermotropic liquid crystal polymers exhibit outstanding processing properties, excellent barrier properties, low solubilities and low coefficients of thermal expansion in the processing direction. These characteristics are combined with the strength, thermal, and radiation stability of polyetherimides.
    Type: Grant
    Filed: November 5, 2007
    Date of Patent: June 21, 2011
    Assignee: United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Erik S. Weiser, Theodorus J. Dingemans, Terry L. St. Clair, Jeffrey A. Hinkley
  • Patent number: 7956154
    Abstract: A polymer containing a polyester polymer unit having the formula -(I-III-II)-, wherein III is derived form a di-carboxylic acid, wherein I is derived from 1,3 cyclohexanedimethanol, wherein II is derived from 1,4 cyclohexanedimethanol and wherein the polymer is a solid at room temperature.
    Type: Grant
    Filed: September 26, 2006
    Date of Patent: June 7, 2011
    Inventors: John N. Argyropoulos, Marcos Pini Franca, Gary E. Spilman
  • Publication number: 20110092662
    Abstract: There is provided an aromatic polyester suitable for optical applications, which has not only high heat resistance and transparency, but also enhanced fluidity at a relatively low molding temperature of less than 300° C. despite its high molecular weight to be substantially colorless after the molding process. The aromatic polyester of the present invention comprises polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof; wherein the polyhydric phenol residues comprise polyhydric phenol residues represented by Formula (I): —O—Ar—W1x—Ar—O— and/or Formula (II): —O—Ar—O—, and bulky polyhydric phenol residues represented by Formula (III): —O—Ar—W2—Ar—O—; wherein the molar ratio of the polyhydric phenol residues represented by Formula (I) and/or Formula (II) to the polyhydric phenol residues represented by Formula (III) is in the range of 100:0 to 30:70 (exclusive of 100:0).
    Type: Application
    Filed: August 30, 2010
    Publication date: April 21, 2011
    Inventors: Masayoshi TABATA, Takayoshi Yamazaki
  • Patent number: 7928183
    Abstract: The invention relates to polyesters containing at least one partly acylated polyhydroxylated compound belonging the group consisting of glycerol polycarbonates, specific polyglycerols, [(a-hydroxymethyl) oxyethylene/(a-hydroxymethyl)ethylene carbonate] copolymers, [a -hydroxymethyl) oxyethylene/(a-hydroxymethyl)ethylene carbonate] copolymers, and [a -alkyl) oxyethylene/(a-hydroxyalkyl) oxyethylene] copolymers. The invention also relates to methods for acylating, at least partly, the polyhydroxylated compounds. The polyesters of this invention are applicable to the technical fields relating to engine and industrial lubricants, greases, hydraulic fluids, metal deformation and processing lubricants, stripping and mold dressing products, oil prospecting, mines, tunnel borers, cosmetics, detergency, inks, textile coatings and papers, to the field of food products, to the protection of wood as synthesis intermediates.
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: April 19, 2011
    Inventors: Nguyen Truong Dinh, Zephirin Mouloungui, Philippe Marechal
  • Patent number: 7923525
    Abstract: A polyester resin and a fabrication method thereof are provided. The fabrication method includes providing a diphenol monomer and a diacid monomer. The diphenol monomer is acetylated and then melt pre-polymerized with diacid monomer to form a pre-polymer. Then, the pre-polymer is polymerized by solid state polymerization to form a heat-resistant and transparent polyester resin.
    Type: Grant
    Filed: May 18, 2009
    Date of Patent: April 12, 2011
    Assignee: Industrial Technology Research Institute
    Inventors: Chih-Hsiang Lin, Hsin-Ching Kao
  • Patent number: 7915375
    Abstract: The disclosure relates to unsaturated metathesis interpolymers having at least one or more specified terminal functional groups. The interpolymers are prepared by metathesis polymerization, and are selected from 1,5-cyclooctadiene and cyclopentene, 1,5-cyclooctadiene and cyclooctene, and cyclooctene and cyclopentene interpolymers.
    Type: Grant
    Filed: March 1, 2007
    Date of Patent: March 29, 2011
    Inventors: James Pawlow, William Hergenrother
  • Patent number: 7906211
    Abstract: This invention relates to thermoplastic article having one or more decorative materials embedded therein which is obtained by applying heat and pressure to one or more laminates wherein at least one of said laminates comprises, in order, (1) an upper sheet material; (2) one or more decorative materials; and (3) a lower sheet material; wherein the upper and lower sheet materials are formed from a polyester/aromatic polycarbonate blend wherein the thermoplastic article comprises at least one polyester composition comprising at least one polyester which comprises terephthalic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol.
    Type: Grant
    Filed: March 16, 2010
    Date of Patent: March 15, 2011
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Patent number: 7906212
    Abstract: This invention relates to thermoplastic article having one or more decorative materials embedded therein which is obtained by applying heat and pressure to one or more laminates wherein at least one of said laminates comprises, in order, (1) an upper sheet material; (2) one or more decorative materials; and (3) a lower sheet material; wherein the upper and lower sheet materials are formed from a polyester/aromatic polycarbonate blend wherein the thermoplastic article comprises at least one polyester composition comprising at least one polyester which comprises terephthalic acid and 2,2,4,4-tetramethyl-1,3,-cyclobutanediol.
    Type: Grant
    Filed: March 16, 2010
    Date of Patent: March 15, 2011
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Patent number: 7897720
    Abstract: Disclosed is a method for removing a metallic compound catalyst residue from a polymer solution which is prepared in the presence of a catalyst containing metal of Group 10 using a thiourea compound, a polymer from which the metallic compound catalyst residue is removed using the method, and a film produced using the method.
    Type: Grant
    Filed: November 7, 2007
    Date of Patent: March 1, 2011
    Assignee: LG Chem, Ltd.
    Inventors: Sung-Cheol Yoon, Hye-Young Jung, Sung-Ho Chun
  • Patent number: 7884173
    Abstract: To provide an aromatic polyester which is formed into a film having excellent heat resistance, color, mechanical properties, dimensional stability and gas barrier properties and a manufacturing process thereof; the aromatic polyester comprises a dicabroxylic acid component and a diol component, wherein (i) the dicarboxylic acid component contains 50 to 100 mol % of a recurring unit represented by the following formula (A): ?wherein R is an alkylene group having 2 to 10 carbon atoms, (ii) the aromatic polyester has an intrinsic viscosity measured at 35° C. by using a mixed solvent of P-chlorophenol and 1,1,2,2-tetrachloroethane (weight ratio of 40/60) of 0.4 to 3.0; (iii) the aromatic polyester has a content of a recurring unit represented by the following formula (D) of less than 10 mol %: —O—CH2CH2—O—CH2CH2—O—??(D) (iv) the aromatic polyester has a terminal carboxyl group concentration of 200 eq/ton or less; and (v) the aromatic polyester has an alkali metal content of 300 ppm or less.
    Type: Grant
    Filed: July 19, 2007
    Date of Patent: February 8, 2011
    Assignee: Teijin Limited
    Inventors: Kazuteru Kohno, Eiji Kinoshita, Tomoyuki Kishino
  • Publication number: 20110021739
    Abstract: The object of the present invention is to provide a polycarbonate resin having an extremely narrow molecular weight distribution, good flowability when melting, and particularly extremely good flowability when melting that does not depend on shear rate. The present invention relates to a polycarbonate resin, characterized in that a value obtained by dividing difference between a logarithmic value log MV9.12 of a melt viscosity (Pa·s) measured at shear rate of 9.12 sec?1 and a logarithmic value log MV1824 of a melt viscosity (Pa·s) measured at shear rate of 1824 sec?, with a capillary rheometer having a die diameter of 1 mm? and an effective length of 30 mmL, by a viscosity average molecular weight Mv calculated by the following equations, viscosity difference/molecular weight ratio, is 2.0×10?5 or less. ?sp/C=[?]×(1+0.28?sp) [?]=1.23×10?4×Mv0.83 (In the above equations, ?sp is a specific viscosity measured at 20° C.
    Type: Application
    Filed: April 18, 2007
    Publication date: January 27, 2011
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Masaaki Miyamoto, Kenji Tsuruhara, Yoshitaka Shiraishi, Ryuuji Uchimura
  • Patent number: 7872090
    Abstract: A reactor system operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The reactor system includes a heat exchanger for heating the reaction medium and a disengagement vessel for disengaging vapor from the heated reaction medium.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: January 18, 2011
    Assignee: Eastman Chemical Company
    Inventors: Bruce Roger DeBruin, Thomas Lloyd Yount, Larry Cates Windes, Wesley Thomas Moyer
  • Patent number: 7872089
    Abstract: The disclosure describes a reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The reactor can include a horizontally elongated reactor segment containing a horizontally elongated tubular member and a tray disposed within the tubular member. The reaction medium can flow through the reactor segment on the tray and on the bottom of the tubular member in generally opposite directions. The reactor also can include a header and multiple horizontally elongated reactor segments coupled to the header and spaced vertically apart from one another. The reactor can be used to produce polyesters.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: January 18, 2011
    Assignee: Eastman Chemical Company
    Inventors: Bruce Roger DeBruin, Michael Paul Ekart, Thomas Lloyd Yount, Larry Cates Windes, David Allen Sliger
  • Patent number: 7872091
    Abstract: An electrical insulation system and method are disclosed which are based on poly(butylene terephthalate), wherein the poly(butylene terephthalate) contains a polymerized cyclic low molecular weight oligomeric poly(butylene terephthalate) resin. At least one filler material or a mixture of filler materials can be included. At least one hydrophobic compound or a mixture of hydrophobic compounds can also be included.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: January 18, 2011
    Assignee: ABB Research Ltd
    Inventors: Kurt Kaltenegger, Xavier Kornmann, Jens Rocks, Reto Weder
  • Patent number: 7872092
    Abstract: An objective of the present invention is to provide an inexpensive and excellent polyester resin sheet for photovoltaic batteries which enhances the electrical transduction efficiency of photovoltaic battery by improving the hydrolysis resistance and heat resistance, and further enhancing the screening potency, as well as a photovoltaic battery using the same. The polyester resin sheet for photovoltaic batteries comprises a polyester resin layer formed by using one or more layers having a number average molecular weight of 18500 to 40000 in which at least one or more layers having 5 to 40% by weight of titanium dioxide is formed on the polyester resin layer, wherein a light transmittance at wavelengths of 300 to 350 nm is 0.005 to 10%, a relative reflectance is 80% or more and 105% or less, an apparent density is 1.37 to 1.65 g/cm3, an optical density is 0.55 to 3.50, and the variation in optical density has a fluctuation of within 20% from the center value.
    Type: Grant
    Filed: March 14, 2006
    Date of Patent: January 18, 2011
    Assignee: Toray Industries, Inc.
    Inventors: Hideki Fujii, Masahiro Kawaguchi
  • Patent number: 7868130
    Abstract: A multi-level tubular reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The tubular reactor can include a plurality of horizontally elongated and vertically spaced reactor segments coupled to and extending outwardly from a common header. One or more of the reactor segments can contain a tray that divides the internal volume of the reactor segment into upper and lower chambers. The reaction medium can flow away from the header in the upper chambers and back to the header in the lower chambers.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: January 11, 2011
    Assignee: Eastman Chemical Company
    Inventors: Thomas Lloyd Yount, Bruce Roger DeBruin, Michael Paul Ekart, Larry Cates Windes, David Allen Sliger
  • Patent number: 7868129
    Abstract: A sloped tubular reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The reactor can include a plurality of spaced apart internal trays disposed at different elevations in a downwardly sloping elongated tubular member.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: January 11, 2011
    Assignee: Eastman Chemical Company
    Inventors: Larry Cates Windes, Bruce Roger DeBruin, Michael Paul Ekart
  • Patent number: 7863347
    Abstract: A resin composition is provided comprising a compound having a structure represented by formula (1) and a crosslinking agent: wherein in formula (1), R0 is a single bond or has a structure represented by formula (2); R1 to R8 are respectively any of hydrogen, a group having an alicyclic structure, an organic group having 1 to 10 carbon atoms other than the group having an alicyclic structure, a hydroxyl group and a carboxyl group; and “X” is any of —O—, —NHCO—, —CONH—, —COO— and —OCO—; further, wherein in formula (2), “Ar” is an aromatic group; “Y” is any of a single bond, —O—, —S—, —OCO— and —COO—; “q” is an integer of 1 or more; R9 is hydrogen or an organic group having 1 or more carbon atoms and may be identical with or different from each other when “q” is an integer of 2 or more; at least one of R1 to R8 is the group having an alicyclic structure when R0 is a single bond; at least one of R1 to R9 is the group having an alicyclic structure when R0 has the structure represented by formula (2); and “*”
    Type: Grant
    Filed: March 16, 2007
    Date of Patent: January 4, 2011
    Assignee: Sumitomo Bakelite Company, Ltd.
    Inventors: Kazuyoshi Fujita, Atsushi Izumi, Yumiko Yamanoi, Takahiro Harada, Hiromi Oki, Yukiharu Ono
  • Patent number: 7858730
    Abstract: A multi-level tubular reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The tubular reactor can include a plurality of horizontally elongated and vertically spaced tubular members coupled to and extending between a pair of horizontally spaced and vertically elongated headers.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: December 28, 2010
    Assignee: Eastman Chemical Company
    Inventors: Thomas Lloyd Yount, Bruce Roger DeBruin, Michael Paul Ekart, Larry Cates Windes, David Allen Sliger
  • Patent number: 7858728
    Abstract: Disclosed herein is a polycarbonate comprising a terminal olefin group of the formula wherein R1 is a C1-C40 hydrocarbon that can be unsubstituted or substituted with a halogen, olefin, ether, ketone, or C4-C30 polyoxyalkylene functionality in which the alkylene groups contain 2 to 6 carbon atoms, R2 to R4 are each independently a hydrogen or a C1-C40 hydrocarbon that can be unsubstituted or substituted with a halogen, olefin, ether, ketone, or a C4-C30 polyoxyalkylene functionality in which the alkylene groups contain 2 to 6 carbon atoms, and optionally wherein any two of R1 to R4 together form a monocyclic, bicyclic, or tricyclic ring system optionally substituted with a heteroatom in each ring.
    Type: Grant
    Filed: October 19, 2007
    Date of Patent: December 28, 2010
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Hans-Peter Brack, Bernard Jansen, Jan Henk Kamps, Hans Looij, Han Vermeulen, Dennis Willemse
  • Patent number: 7851514
    Abstract: The invention provides a process for producing a recycled resin, which includes: a first step of decomposing a resin composition containing a thermosetting resin in a supercritical or subcritical solvent having a monomer constituting the thermosetting resin or a derivative thereof as an essential component and a second step of adding a polyfunctional compound thereto to process; a recycled resin or a processed and recovered matter obtained according to the process for producing; a recycled resin composition formed from a recycled resin and/or a processed and recovered matter of the resin composition; and a method for recycling a resin composition, which reuses said recycled resin and/or said processed and recovered matter of a resin composition as a raw material of a recycled resin composition.
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: December 14, 2010
    Assignee: Sumitomo Bakelite Company, Ltd.
    Inventors: Junya Goto, Masaki Ishikawa, Kazunori Shimoyachi
  • Patent number: 7847053
    Abstract: A multi-level tubular reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The tubular reactor can include a plurality of horizontally elongated and vertically spaced reactor segments coupled to and extending outwardly from a common header. One or more of the reactor segments can contain a tray that divides the internal volume of the reactor segment into upper and lower chambers. The reaction medium can flow away from the header in the upper chambers and back to the header in the lower chambers.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: December 7, 2010
    Assignee: Eastman Chemical Company
    Inventors: Thomas Lloyd Yount, Bruce Roger DeBruin, Michael Paul Ekart, Larry Cates Windes, David Allen Sliger
  • Patent number: 7848025
    Abstract: Disclosed herein is a camera lens comprising a thermoplastic composition comprising a poly(aliphatic ester)-polycarbonate copolymer comprising soft block ester units derived from an alpha, omega C6-20 aliphatic dicarboxylic acid or derivative thereof, a dihydroxyaromatic compound, and a carbonate source, wherein the thermoplastic composition has a melt volume rate of 13 to 25 cc/10 min at 250° C. and under a load of 1.2 Kg and a dwell time of 6 minutes, according to ASTM D1238-04, and wherein the camera lens has an effective lens area of 0.5 to 100 mm2. A method of making the camera lens, and a camera lens comprising a thermoplastic composition comprising a redistribution product of a poly(aliphatic ester)-polycarbonate, are also disclosed.
    Type: Grant
    Filed: December 31, 2008
    Date of Patent: December 7, 2010
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Akira Hatano, Theodorus Lambertus Hoeks, Dennis Karlik, Ken Kuriki, Jon M. Malinoski, Sriramakrishna Maruvuda
  • Patent number: 7842777
    Abstract: A sloped tubular reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The reactor can include a downwardly sloped tubular member, a flow divider disposed in the tubular member, and one or more internal trays disposed in the tubular member. The flow divider divides flow of the reaction medium among the trays and the bottom of the tubular member.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: November 30, 2010
    Assignee: Eastman Chemical Company
    Inventors: Bruce Roger DeBruin, Michael Paul Ekart, Larry Cates Windes
  • Patent number: 7838602
    Abstract: A multilayer article comprises a substrate layer, and a coating layer in contiguous superposed contact with the substrate layer, the coating layer comprising a thermostable, weatherable polymer comprising structural units derived from at least one 1,3-dihydroxybenzene moiety, at least one aromatic dicarboxylic acid moiety, at least one bisphenol moiety, and at least one soft-block moiety derived from a siloxane oligomer, in which the multilayer article comprises the substrate layer and the coating layer, or the substrate layer with coating layers on each side of the substrate layer.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: November 23, 2010
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Gary C Davis, Brian D Mullen, Paul D Sybert
  • Patent number: 7833931
    Abstract: The present invention relates to a solid acid catalyst for the production of polyester which enables the production of a metal-free polyester resin containing no residual catalyst, exhibits favorable utility efficiency in the production, exhibits extremely high selectivity for the polyesterification reaction with the amount of by-products being below the limit of detection, and is able to be isolated, recovered and reused. In other words, the present invention relates to a solid acid catalyst for the production of polyester, obtained by supporting a metal oxide (B) on a support (A) formed from a metal oxide, wherein said support (A) formed from a metal oxide is a zirconia, said metal oxide (B) is a molybdenum oxide, and a Hammett acidity function (H0) for said catalyst is within a range from ?3 to ?9, and also relates to a process for producing the solid acid catalyst and a process for producing a polyester that uses the catalyst.
    Type: Grant
    Filed: March 24, 2008
    Date of Patent: November 16, 2010
    Assignee: DIC Corporation
    Inventors: Hironobu Oki, Kouji Shiraishi