Azo, Acridone, Or Quinone Dye Patents (Class 8/662)
  • Patent number: 5989299
    Abstract: Dyestuff compositions are provided which incorporate, as the grinding aid and/or dispersant therefor, amine modified lignin admixed with sulfonated lignin. The disclosed dyestuff compositions exhibit improved heat stability and, as a result of the higher activity of the dispersant mixture of amine modified lignin blended with sulfonated lignin, less dispersant is present in the exhaust liquor and waste treatment demands are thereby reduced. The improved package dyeing grinding aid/dispersant of the invention is prepared by mixing an amine modified lignin with a sulfonated lignin.
    Type: Grant
    Filed: May 26, 1998
    Date of Patent: November 23, 1999
    Assignee: Westvaco Corporation
    Inventors: Peter Dilling, Gamini S. Samaranayake
  • Patent number: 5972047
    Abstract: Dyestuff compositions are provided which incorporate amine modified sulfonated lignins. The disclosed dyestuff compositions exhibit improved heat stability and, as a result of the higher activity of the amine modified sulfonated lignin, less dispersant is present in the exhaust liquor and waste treatment demands are thereby reduced. The presence of tertiary amine groups in sulfonated kraft, sulfomethylated kraft, and sulfite lignins provide dispersants with package dyeing heat stabilities significantly better than those of the unmodified lignins. The improved package dyeing grinding aid/dispersant of the invention is prepared by reacting sulfonate lignin with a secondary amine using formaldehyde and alkaline conditions.
    Type: Grant
    Filed: March 10, 1998
    Date of Patent: October 26, 1999
    Assignee: Westvaco Corporation
    Inventors: Peter Dilling, Gamini S. Samaranayake, Staci L. Waldrop
  • Patent number: 5964899
    Abstract: Azo dyes containing sulphur dye entities as a constitutional component are dyes of valuable properties, in particular for the dyeing of leather.
    Type: Grant
    Filed: October 8, 1997
    Date of Patent: October 12, 1999
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Jordi Berenguer, Manuel Jose Domingo, Jose Rocas
  • Patent number: 5961669
    Abstract: A process for dying materials containing natural or synthetic polyamides is disclosed. The process includes immersing the materials to be dyed in a dye bath containing an acid dye. The pH of the dye bath is initially at a level that substantially inhibits the dye from being absorbed by the polymer. In accordance with the present invention, however, an acid producing composition is added to the bath which gradually reduces the pH of the bath and allows for uniform diffusion of the dye into the polymer. The acid producing composition of the present invention is a maleate ester, which, in one embodiment, is the reaction product of maleic acid or maleic anhydride and a glycol.
    Type: Grant
    Filed: March 12, 1998
    Date of Patent: October 5, 1999
    Assignee: Sybron Chemicals, Inc.
    Inventors: Robert B. Login, Calvin McIntosh Wicker, Jr., Otto Bella
  • Patent number: 5935274
    Abstract: Dye mixtures comprising:A) a dye of the formula ##STR1## in which R.sub.1 is C.sub.1 -C.sub.4 alkyl,R.sub.2 is the radical (CH.sub.2).sub.n O--R.sub.5,R.sub.5, independently of R.sub.1, is C.sub.1 -C.sub.4 alkyl andn is the number 1, 2 or 3 andB) a dye of the formula ##STR2## in which R.sub.3 and R.sub.4 independently of one another are C.sub.1 -C.sub.4 alkyl, which are suitable for dyeing or printing textile fiber materials and give dyeings with good allround properties, are described.
    Type: Grant
    Filed: March 18, 1998
    Date of Patent: August 10, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Jurgen Schaetzer
  • Patent number: 5928386
    Abstract: A process for dyeing or printing natural or synthetic polyamide fiber material by the trichromatic technique, which comprises using at least one blue-dyeing dye of formula ##STR1## together with at least one red-dyeing dye of formula ##STR2## together with at least one yellow- or orange-dyeing dye of formula ##STR3##
    Type: Grant
    Filed: May 21, 1997
    Date of Patent: July 27, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rudolf Hurter, Jean-Marie Adam, Francine Casi
  • Patent number: 5922089
    Abstract: A process for dyeing a polyester or polyester-containing textile material at pH 8 to pH 11, which is characterized by applying one or more monoazo dyes of the formula I ##STR1## in which X is (C.sub.1 -C.sub.3)-alkyl,R is (C.sub.1 -C.sub.6)-alkyl andR.sup.1 and R.sup.2, independently of one another, are linear (C.sub.2 -C.sub.4) -alkyl, R.sup.1 and R.sup.2, independently of one another, being (C.sub.3 -C.sub.4)-alkyl if R is methyl.
    Type: Grant
    Filed: December 18, 1997
    Date of Patent: July 13, 1999
    Assignee: Dystar Japan Ltd.
    Inventor: Ulrich Buhler
  • Patent number: 5922085
    Abstract: A process of preparing a dye composition and a resultant dye composition. The process includes preparing a mixture comprising a triphenylmethane dye and oxidation products by reacting methylenedianiline, aniline, an oxidation catalyst, and an oxidant; separating the oxidation products from the triphenylmethane dye to produce an aqueous solution of oxidation products; treating the solution of oxidation products with a basic compound; separating unreacted aniline from the solution of oxidation products and forming a mixture of oxidation products; and sulfonating the mixture of oxidation products to form a dye composition.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: July 13, 1999
    Assignee: BASF Corporation
    Inventors: Gray D. Ellis, Belinda J. DiMarcello, Debra J. Bradshaw
  • Patent number: 5917121
    Abstract: The present invention relates to the .beta. and .gamma. modifications of the dye of the formula (I) ##STR1## as well as to a process for their preparation and their use for dyeing and printing textile materials of polyester and/or cellulose esters or blended fabrics of these materials and wool or cellulose.
    Type: Grant
    Filed: September 5, 1997
    Date of Patent: June 29, 1999
    Assignees: Dystar Textilfarben GmbH & Co. Deutschland KG, Dystar Japan Ltd.
    Inventors: Ulrich Buhler, Hubert Kruse, Heinz G. Zorn, Klaus-Wilfried Wanken
  • Patent number: 5891227
    Abstract: Aqueous dye preparations useful for producing inks for the inkjet process or writing inks or for producing aqueous alcoholic coating or printing colors comprise, based on the weight of the preparation, from 0.1 to 15% by weight of a dye quantity comprising from 90 to 100% by weight of the dye of the formula I ##STR1## where Kat.sup..sym. is the equivalent of a metal or ammonium ion, from 1 to 40% by weight of carbon black and from 0.1 to 15% by weight of polyethylene glycol.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: April 6, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Dietrich Hoffmann, Ulrike Schlosser, Erwin Czech, Walter Kurtz, Karin Heidrun Beck, Doug R. Campbell, Helmut Bellaire, Horst Belde
  • Patent number: 5888253
    Abstract: A textile-printing method imparts ink containing a cyan disperse dye and ink containing blue disperse dye on a cloth such that the cyan ink and the blue ink are at least partially overlapped, thereby forming a color mixture portion on the cloth, wherein a weight ratio of the cyan dye to the blue dye at the overlapped portion is specified in the range of from 10:1 to 100:1.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: March 30, 1999
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tomoya Yamamoto, Masahiro Haruta, Shoji Koike, Koromo Shirota, Aya Yoshihira, Mariko Suzuki
  • Patent number: 5879413
    Abstract: Diazo dyes of the general formula (I) ##STR1## are described where X.sup.+ is a quaternary ammonium group and Y.sup.- is a counterbalancing anion. The dyes are useful for coloring hair.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: March 9, 1999
    Assignee: Warner-Jenkinson Europe Limited
    Inventors: Roger W. Pengilly, Francis C. P. McLoughlin, Roger G. J. C. Twigg
  • Patent number: 5879411
    Abstract: A non-oxidative dye composition for keratin fibers contains an o-benzoquinone compound of formula (I): ##STR1## wherein R1, R2, R3 and R4 are each, independently of each other, hydrogen, chlorine, an alkyl group with from 1 to 5 carbon atoms, an alkoxy group with from 1 to 5 carbon atoms, an alkylenedioxy group with from 1 to 2 carbon atoms or an amino group --NR.sup.5 R.sup.6, wherein R.sup.5 and R.sup.6 are each, independently of each other, hydrogen, an alkyl group having from 1 to 6 carbon atoms or an aryl group; and at least one amino- or hydroxy-compound of formula (II), X--A--Y, wherein X represents a nitro group, a cyano group or a sulfonate group; Y represents a hydroxy group or an amino group --NR.sup.a R.sup.b, wherein R.sup.a and R.sup.
    Type: Grant
    Filed: December 16, 1997
    Date of Patent: March 9, 1999
    Assignee: Wella AG
    Inventors: Hans-Juergen Braun, Gisela Umbricht
  • Patent number: 5824118
    Abstract: A dye which is durable for practical use in the field of coloring automobile seat materials for which a good light-fastness is required and a dyeing method making use of the dye is provided. In the method, a disazo dye is obtained by converting guanazole to a tetrazo compound and coupling the tetrazo with an indole derivative to form a compound which is then quaternized using e.g., an alkylating agent resulting in a red dye with superior light-fastness at high temperatures.
    Type: Grant
    Filed: September 8, 1995
    Date of Patent: October 20, 1998
    Assignee: Hodogaya Chemical Co., Ltd.
    Inventors: Minoru Akai, Itsuo Suda, Katsumi Nonomura, Kumiko Arai
  • Patent number: 5811040
    Abstract: The specification describes a process of making a fiber for a carpet face yarn, the yarn being made of polyolefin/polymer filaments which contain a plurality of longitudinally dispersed relatively small, short polymer fibrils inside the filaments generally concentrated toward the center thereof within the polyolefm matrix. The yarn has the stain resistant properties of polyolefm based yarns and the resiliency of polyamide based yarns at a substantially lower cost than nylon carpet yarns.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: September 22, 1998
    Inventor: William C. Mallonee
  • Patent number: 5782934
    Abstract: A process for colouring a synthetic textile material or fiber blend thereof which comprises applying to the synthetic textile material a compound of Formula (1):A--N.dbd.N--D--N.dbd.N--E Formula (1)wherein:A, D and E each independently is an optionally substituted heterocyclic or carbocyclic group and at least one of A, D or E carries directly at least one --SO.sub.2 F group or carries a substituent to which at least one --SO.sub.2 F group is attached.A process for the mass coloration of plastics which comprises incorporating into a plastics material a compound or mixture thereof which is free from water solubilising groups, of Formula (1).
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: July 21, 1998
    Assignee: Zeneca Limited
    Inventors: Nigel Hall, Mark Robert James
  • Patent number: 5777089
    Abstract: Phenol derivatives of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, X, Y and Z have the meanings stated in the description, are used in particular in nonlinear optics.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: July 7, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Beckmann, Karl-Heinz Etzbach, Rudiger Sens
  • Patent number: 5772696
    Abstract: An invention is disclosed which pertains to a method for purifying water soluble dyes, such as quinoline, fluoran, and xanthene dyes. The method comprises the steps of A) adding a metal salt to the water soluble dye to form a water insoluble dye salt of the metal; B) isolating the water insoluble dye salt of step A; C) converting the water insoluble dye salt of step B into a water soluble dye solution; and D) isolating the water soluble dye from the solution of step C. The present invention teaches a straight forward, economical, and environmentally sound method for purifying water soluble dyes of FDA certifiable purity and with an aesthetically improved shade.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: June 30, 1998
    Assignee: Warner-Jenkinson Company, Inc.
    Inventor: Puthalath Koroth Sujeeth
  • Patent number: 5766268
    Abstract: A colorant composition which can be liquid in the neat form at 25.degree. C., having the structure ABXYZ, whereA is an organic chromophore;B is an electrophilic reactive group covalently bonded to A directly or through a linking group;X is a nucleophilic linking group covalently bonding B and Y;Y is a poly(oxyalkylene)-containing moiety comprising the formula (C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n where a and b are different and from 1 to 8, m is at least 3, n is 0 to 15; andZ is a terminal group for Y.The colorant composition can be prepared from a reactive dye AB which is reacted with XYZ, a poly(oxyalkylene)-containing moiety containing a nucleophilic group.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: June 16, 1998
    Assignee: Milliken Research Corporation
    Inventor: John D. Bruhnke
  • Patent number: 5759212
    Abstract: A process for coloring a synthetic textile material or fiber blend thereof which comprises applying to the synthetic textile material a dye, which is free from water solubilizing groups, carrying at least one --SO.sub.2 F group provided that the dye is not an azo, bisazo or anthraquinone dye.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: June 2, 1998
    Assignee: Zeneca Limited
    Inventor: Nigel Hall
  • Patent number: 5746778
    Abstract: A wood stain which is water-based, which is suitable for staining wood, and which is comprised of water; at least one dye selected from the group consisting of azo, diazo and triarylmethane dyes; and a stabilizing agent which is effective to reduce free iron ion concentration in the stain when in contact with an autoclave composed of non-rust resistant steel during the staining process. The stabilizing agent includes at least one buffer effective to maintain the pH of the wood stain at greater than 7.0. Alternatively or additionally, the stabilizing agent includes at least one complexing agent which forms a complex with iron ions.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: May 5, 1998
    Assignee: A.W. Faber-Castell Unternehmensverwaltung GmbH & Co.
    Inventors: Axel Jankewitz, Gerhard Lugert
  • Patent number: 5739299
    Abstract: A process for coloring a synthetic textile material or fibre blend thereof which comprises applying to the synthetic textile material a compound or mixture thereof, which is free from water solubilizing groups, of Formula (1):A--N.dbd.N--D Formula (1)whereinA and D each independently is an optionally substituted heterocyclic or carbocyclic group and at least one of A or D carries directly at least one --SO.sub.2 F group or carries a substituent to which at least one --SO.sub.2 F group is attached except for 4-(4-fluorosulphonylphenylazo)-N,N-dimethylaniline, provided that one of A or D is not 3,5-difluorosulphonylthien-2-yl, optionally substituted 1-phenyl-pyrazol-4-yl-5-one or ##STR1## or that one of A or D does not carry an --NCH.sub.2 CH(OH)CH.sub.2 Cl, --NCOCH.sub.2 Cl or --NCH.sub.2 CH.sub.2 SO.sub.2 F substituent.The presence of one or more --SO.sub.2 F groups in a dye molecule generally improves the properties of that dye and confers surprisingly good wet fastness and light fastness properties.
    Type: Grant
    Filed: July 15, 1996
    Date of Patent: April 14, 1998
    Assignee: Zeneca Limited
    Inventor: Nigel Hall
  • Patent number: 5698682
    Abstract: The present invention provides a polarizing film having high heat resistance and a high degree of polarization and excellent optical properties by dyeing a polymer film with a novel azo compound represented by the following formula (1) or (2): ##STR1##
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: December 16, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoriaki Matsuzaki, Ryu Oi, Rihoko Imai, Keisuke Takuma, Hisato Itoh
  • Patent number: 5688291
    Abstract: In accordance with the present invention, there is provided a single-step process and composition of a category-2 hair bleach which can simultaneously lighten the hair up to seven levels, and effectively neutralize any undesirable warmth that accompanies the lightening process. This is achieved by including in the bleach composition disperse dye molecules which the present invention has found to be both, stable in the bleach, and capable of depositing the desired amount of various permanent tones on the hair. These disperse dyes do not stain the scalp of the client or the hands of the hairdresser, but are substantive only to the hair fibers. The dyes fall into the classes of anthraquinones and azo compounds.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: November 18, 1997
    Assignee: L'Avante Garde, Inc.
    Inventors: Hayel Said, Hian Said
  • Patent number: 5688288
    Abstract: A disperse dye composition comprising one or more dyes represented by the formula: ##STR1## wherein X represents a chlorine or bromine atom; Y a hydrogen atom or an alkoxy or alkoxyalkoxy group; and each of R.sub.1 and R.sub.2 independently a hydrogen atom, a linear or branched unsubstituted or substituted alkyl group, an allyl group or a cycloalkyl group, provided that each of the alkyl and alkoxy groups has 1 to 4 carbon atoms, anda dye represented by the formula: ##STR2## wherein Y represents an alkoxy or alkoxyalkoxy group; each of R.sub.1 and R.sub.2 independently a hydrogen atom, a linear or branched unsubstituted or substituted alkyl group, an allyl group or a cycloalkyl group, and R.sub.3 an alkyl group, provided that each of the alkyl and alkoxy groups has 1 to 4 carbon atoms.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: November 18, 1997
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Yoshiki Akatani, Yasuo Murakami, Hiroyuki Matsumoto, Kiyoko Tanaka
  • Patent number: 5679115
    Abstract: Process for dyeing or printing organic material, in particular fibre material which comprises applying dyes containing no polymerizable double bond together with at least one colorless cationic compound containing at least one polymerizable double bond and, if desired, one or more colorless nonionic compounds containing at least one polymerizable double bond and, if desired, further auxiliaries to the fibre material and then fixing them by means of ionizing radiation, or applying dyes containing no polymerizable double bond together with at least one colorless cationic compound containing one polymerizable double bond, and if desired, one or more colorless nonionic compounds containing at least one polymerizable double bond and at least one photoinitiator and also, if desired, further auxiliaries to the fibre material and then fixing them by means of UV light.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: October 21, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Katharina Fritzsche, Peter Aeschlimann, Peter Scheibli
  • Patent number: 5639282
    Abstract: The present invention relates to a process for dyeing polyester or polyester-containing textile materials at pH 8 to pH 11, characterized in that one or more monoazo dyestuffs of the general formula I ##STR1## wherein D is a substituted phenyl radical of the general formula II ##STR2## or 5,6-dichlorobenzothiazol-2-yl6,7-dichlorobenzothiazol-2-yl6-chlorobenzothiazol-2-yl5-nitrobenzothiazol-2-yl6-nitrobenzothiazol-2-yl6-methylsulphonylbenzothiazol-2-yl or5-nitrobenzoisothiazol-3-ylandx.sup.1, x.sup.2, x.sup.3, x.sup.4, y.sup.1, y.sup.2, y.sup.3, r.sup.1, r.sup.2 and r.sup.3 are as defined in claim 1, are employed.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: June 17, 1997
    Assignee: Dystar Japan, Ltd.
    Inventor: Ulrich Buhler
  • Patent number: 5624466
    Abstract: Condensation products obtainable by condensation of a mixture comprising unsubstituted melamine, substituted melamine and hydroxyphenyl compounds with formaldehyde or formaldehyde donor compounds are dyed in the form of fibers, yarns, threads, wovens, knits or nonwovens in an aqueous liquor with one or more dyes of the class of the azo, anthraquinone, coumarin, methine, azamethine, quinophthalone or nitro dyes.
    Type: Grant
    Filed: September 7, 1995
    Date of Patent: April 29, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Schindler, Uwe Nahr
  • Patent number: 5603735
    Abstract: Water-immiscible solvent dyes are mixed with citrus solvents and non-ionic surfactants to form a water-reducible true dye solution containing at least 35 wt % of the water-immiscible dye. The dye solution is dispersible in water and infinitely reducible.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: February 18, 1997
    Assignee: Morton International, Inc.
    Inventors: Alejandro Zimin, Sr., Peter A. Caputo
  • Patent number: 5595575
    Abstract: A blue disperse dye mixture comprising a monoazo dye of the following formula (1) and at least one azo dye selected from the group consisting of dyes of the following formulas (2), (3), (4) and (5): ##STR1## wherein each of the variables is defined in the specification.
    Type: Grant
    Filed: November 8, 1995
    Date of Patent: January 21, 1997
    Assignee: DyStar Japan Ltd.
    Inventors: Kiyoshi Himeno, Toshio Hihara, Ryouichi Sekioka
  • Patent number: 5587118
    Abstract: The specification describes a conjugate carpet face yarn including trilobal or delta cross-section polyolefin filaments and a plurality of generally co-linear smaller polyamide fibrils embedded within the polyolefin filaments. This yarn has the stain resistant properties of polyolefin based yarns and the resiliency of polyamide based yarns.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: December 24, 1996
    Inventor: William C. Mallonee
  • Patent number: 5575820
    Abstract: A process for the dyeing and printing of organic material, in particular fibre material, which comprises applying dyes containing at least one polymerisable double bond together with at lease one colourless cationic compound containing at least one polymerisable double bond and, if desired, one or more colourless nonionic compounds containing at least one polymerisable double bond and, if desired, further auxiliaries to the organic material, in particular fibre material, and then fixing them by means of ionizing radiation.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: November 19, 1996
    Assignee: Ciba-Geigy Corporation
    Inventor: Katharina Fritzsche
  • Patent number: 5567206
    Abstract: A wood stain which is water-based, which is suitable for staining wood, and which is comprised of water; at least one dye selected from the group, consisting of azo, diazo and triarylmethane dyes; and a stabilizing agent which is effective to reduce free iron ion concentration in the stain when in contact with an autioclave composed of non-rust resistant steel during the staining process. The stabilizing agent includes at least one buffer effective to maintain the pH of the wood stain at greater than 7.0. Alternatively or additionally, the stabilizing agent includes at least one complexing agent which forms a complex with iron ions. A method for staining wood includes placing the wood into an autoclave composed of non-rust-resistant steel; submerging the wood in the wood stain; and staining the wood under pressure and temperature conditions effective therefor.
    Type: Grant
    Filed: July 31, 1995
    Date of Patent: October 22, 1996
    Assignee: A.W. Faber-Castell Unternehmensverwaltung GmbH & Co.
    Inventors: Axel Jankewitz, Gerhard Lugert
  • Patent number: 5567624
    Abstract: A composition for determining pH of a solution comprises a fluorescent carbazine dye covalently bound to a solid support. A method of determining pH of a solution comprises placing the composition in the solution, contacting the composition with a selected wavelength of light to excite fluorescence by the carbazine dye, measuring intensities of the fluorescence at two selected wavelengths, calculating a ratio of fluorescence intensities at the two selected wavelengths, and correlating the ratio with a predetermined relationship of such ratios to pH. A fiber optic system for measuring pH of a solution with the carbazine-dye-containing composition is also disclosed.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: October 22, 1996
    Assignee: Utah Medical Products, Inc.
    Inventor: Roger E. Smith
  • Patent number: 5545725
    Abstract: Disazo dyes are disclosed which are particularly suitable for dyeing paper.Paper is dyed with these dyes in greenish-yellow or yellow to red shades of good fastness properties.
    Type: Grant
    Filed: November 10, 1994
    Date of Patent: August 13, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Adolf K aser, Willy Stingelin
  • Patent number: 5514782
    Abstract: Water-soluble monoazo compounds of the formula ##STR1## are described, suitable as fiber-reactive dyes for dyeing hydroxy- and/or carboxamido-containing material, in particular fiber material, such as wool and cellulose fiber materials, in which D is phenylene which can be substituted by 1 or 2 substituents customary in diazo components of fiber-reactive dyes and/or by a group of the formula Y--SO.sub.2 --(CH.sub.2).sub.m -- where Y has one of the meanings given below and m is the number 1 or 2, or is naphthylene which can be substituted by 1 or 2 substituents customary in diazo components of fiber-reactive dyes, or is benzothiazol-2-yl containing the group aforementioned Y--SO.sub.2 --(CH.sub.2).sub.n -- bonded to the carbocyclic ring thereof and can be substituted by a further substituent customary in fiber-reactive dyes, n is the number zero, 1 or 2, the group Y-SO.sub.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: May 7, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Jorg Dannheim
  • Patent number: 5505742
    Abstract: A method for dyeing hydrophobic fibers black, wherein a mixed black dye is used which comprises a blue color component containing at least 70 wt % of a disperse dye of the following formula (I): ##STR1## wherein X is a chlorine atom or a bromine atom, and R is a methyl group or an ethyl group.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: April 9, 1996
    Assignee: Dystar Japan Ltd.
    Inventors: Kiyoshi Himeno, Kazuhisa Konishi, Ryouichi Sekioka
  • Patent number: 5496380
    Abstract: A dispersed dye composition which is (A) a combination of blue dye composition (1) and red dye composition (2); (B) a combination of blue dye composition (1) and yellow dye composition (3); or (C) a combination of blue dye composition (1), red dye composition (2) and yellow dye composition (3); wherein blue dye composition (1) consists of from 35 to 55 weight percent of a compound of Formula (I), from 35 to 55 weight percent of a compound of Formula (II) and from 2 to 20 weight percent of a compound of Formula (III); red dye composition (2) consists of at least one red dye selected from the group of compounds of Formulas (IV-1) and (IV-2); and yellow dye composition (3) consists of at least one dye within the scope of the compound of Formula (V).
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: March 5, 1996
    Assignee: Dystar Japan Ltd.
    Inventors: Hideaki Imafuku, Takashi Fujita, Toshikazu Tamiya, Kuniko Kira
  • Patent number: 5494492
    Abstract: A disperse dye composition comprising compounds of the formulae (I) and (II): ##STR1## wherein each of R.sup.1 and R.sup.5 is a methyl group or an ethyl group, and each of R.sup.2, R.sup.3 and R.sup.4 is a C.sub.1-5 alkyl group, wherein the weight ratio of the compound of the formula (I) to the compound of the formula (II) is within a range of from 95:5 to 5:95.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: February 27, 1996
    Assignee: Dystar Japan Ltd.
    Inventors: Kiyoshi Himeno, Kazuhisa Konishi, Ryouichi Sekioka
  • Patent number: 5494493
    Abstract: A disperse dye mixture comprising dye (I) and dye (II) blended at a ratio of from 0.1 to 10 times by weight of dye (II) to dye (I): ##STR1## wherein X is halogen, nitro, cyano, thiocyanate, methylsulfonyl, C.sub.1 or C.sub.2 alkylcarbonyl, C.sub.1 -C.sub.4 alkoxycarbonyl or vinylsulfonyl, Y is hydrogen, halogen, cyano, trifluoromethyl or methylsulfonyl, W is hydrogen, halogen, C.sub.1 or C.sub.2 alkyl or C.sub.1 or C.sub.2 alkoxy, and each of R.sup.1 and R.sup.2 which are independent of each other, is hydrogen, C.sub.1 --C.sub.8 alkyl, or C.sub.2 -C.sub.4 alkyl substituted by halogen, hydroxyl, cyano, alkoxy, alkoxyalkoxy, a hydroxyalkoxy, hydroxyalkoxyalkoxy, acyloxyalkoxy or acyloxyalkoxyalkoxy, provided that each alkoxy has from 1 to 4 carbon atoms.
    Type: Grant
    Filed: November 22, 1994
    Date of Patent: February 27, 1996
    Assignee: Dystar Japan Ltd.
    Inventors: Kiyoshi Himeno, Toshio Hihara
  • Patent number: 5484460
    Abstract: Dye mixtures comprising at least six isochromatic dyes of the formula ##STR1## where D is the radical of a diazo component of the aniline, aminothiophene, aminothiazole, aminoisothiazole or aminobenzisothiazole series andone of the radicals X.sup.1 and X.sup.2 is amino and the other is a radical of the formula ##STR2## where L is unsubstituted or substituted C.sub.2 -C.sub.8 -alkyleneR.sup.1 is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl andR.sup.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl, benzyl, phenyl, or C.sub.1 -C.sub.8 -alkanoyl,and the use thereof for dyeing or printing textile materials, and dye mixtures comprising thienylazopyridine dyes and anthraquinone dyes and the use thereof for dyeing or printing textile materials.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: January 16, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Hermann Loeffler, Gunther Lamm, Volker Bach, Arno Lange, Helmut Reichelt, Herbert Rothmaier
  • Patent number: 5476519
    Abstract: Water insoluble or sparingly soluble dyestuffs such as disperse dyes as concentrates for making up dyebaths or for use as printing pastes, and optical brightening agents for laundry detergents are formulated as stable suspensions in aqueous structured surfactants.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: December 19, 1995
    Assignee: Albright & Wilson, Limited
    Inventors: William P. Haslop, Jill E. Newton, Richard M. Clapperton
  • Patent number: 5462565
    Abstract: The new process for dyeing polyamide fibers with acid dyestuffs, in which small amounts of metal salts are added to the dyebath, gives dyeings having improved lightfastness.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: October 31, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jurgen Rohr, Martin Riegels, Sylvia Lohmann
  • Patent number: 5456727
    Abstract: The invention is a dye composition containing two or more dyes of the vinyl sulfone type which can be used in combination to dye polyamide substrates. Preferably the dye compositions of the invention contain at least three dyes of different primary colors.
    Type: Grant
    Filed: May 24, 1994
    Date of Patent: October 10, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: Walter Heimling, Mark Helle, Kerry Proulx, Leslie McIntosh, Philomen DeCroos
  • Patent number: 5447540
    Abstract: A high heat-resistant synthetic fiber material containing, for example, aramid, PEEK, or PEN fibers, that can be dyed uniformly at a high color density, with a dye dissolved or dispersed in a liquid medium, for example, water, and having a molecular weight of 330 to 400, at a dyeing temperature of 150.degree. C. or more within a closed system.
    Type: Grant
    Filed: March 7, 1994
    Date of Patent: September 5, 1995
    Assignee: Teijin Limited
    Inventors: Shigenobu Kobayashi, Tetsuo Okamoto
  • Patent number: 5443599
    Abstract: A process comprising the reduction of textile dyestuffs in an aqueous alkaline medium by means of a reducing compound which is a complex of an organic complexing agent and an iron (II)-salt. The iron (II)-salt is present in an amount sufficient to ensure the desired reduction of the dyestuff after a single oxidation.
    Type: Grant
    Filed: December 19, 1994
    Date of Patent: August 22, 1995
    Assignee: Verein zur Forderung der Forschung und Entwicklung in der Textilwirtschaft
    Inventors: Thomas Bechtold, Eduard Burtscher
  • Patent number: 5431699
    Abstract: Dye mixtures containa) one or more azo dyes of the formula I ##STR1## where Y.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxy or unsubstituted or substituted C.sub.1 -C.sub.8 -alkanoylamino or C.sub.3 - or C.sub.4 -alkenylamino orY.sup.2 and Y.sup.3 are each hydrogen or unsubstituted or substituted C.sub.1 -C.sub.6 -alkylb) the azo dye of the formula II ##STR2## where L is allyl which may be partially replaced by or may furthermore be hydrogen andc) optionally, an azo dye of the formula III and/or IV as described in the specification.
    Type: Grant
    Filed: January 28, 1994
    Date of Patent: July 11, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Arno Lange, Uwe Nahr, Walter Sieber, Volker Walther
  • Patent number: 5425785
    Abstract: The present invention relates to a process for dyeing polyester or polyester-containing textile materials at pH 8 to pH 11 with one or more monoazo dyestuffs of the general formula I ##STR1## in which A, R and X.sup.1 to X.sup.3 are as defined in claim 1.
    Type: Grant
    Filed: August 17, 1994
    Date of Patent: June 20, 1995
    Assignee: Hoechst Mitsubishi Kasei Co.
    Inventors: Ulrich Buhler, Ralf Zerrer
  • Patent number: 5409502
    Abstract: The compositions for dyeing hair contains at least one 4'- amino-2-halogen-4-[bis-(.beta.-hydroxyethyl)amino]azobenzene. The hair dye compositions according to the invention have a good resistance to acids and provide a wide assortment of natural and fashion shades.
    Type: Grant
    Filed: December 9, 1993
    Date of Patent: April 25, 1995
    Assignee: Wella Aktiengesellschaft
    Inventor: Hans J. Braun
  • Patent number: RE35768
    Abstract: To prepare storage-stable, low-dusting dyestuff granules which are readily soluble in plastics, a suspension of the dyestuff containing 0.1-5% by weight of a polyglycol are dried while being granulated.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: April 14, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Vaclav Kaspar, Horst Brandt, Gottfried Popp