Abstract: In a fuel cell comprising an electrolyte-retaining matrix interposed between a pair of gas-diffusion electrodes, the matrix comprises particles or fibers of a substance unreactive with phosphoric acid and having electron-insulating properties and an inorganic binder.

Abstract: A copper plastic laminate is provided having a high bond strength. The copper is selected from the group consisting of copper and copper alloys and has on its surface a uniform glassy-like, substantially pore-free coating of copper phosphate. A plastic encapsulating material containing a mold release agent is adhesively bonded to the copper.

Abstract: A connection between a graphite or carbon block having a cavity therein and the end of an electrical conductor disposed therein is made with a tamping material comprising flowable graphite powder, a metal oxide, a resin binder, and a flow promoter such a silica or a resin. The finished connection is treated with an acid dopant which reacts with the metal oxide to form a bond between the conductor and the block.

Abstract: The present invention relates to laminated materials which are constructed using layers of reinforcing and/or non-reinforcing materials in combination with layers of a composition which is known in the art to provide water-resistant phosphate ceramic materials. In a preferred embodiment, the products are fire-resistant and intumescent when exposed to heat or direct flame, and they produce little or no smoke. Nevertheless, these products are tough, durable and suitable to provide a decorative and pleasing appearance.

Abstract: An inorganic composition adapted for use in bonding a high temperature resistant polymeric material to an aluminum base substrate is provided. The composition is obtained by reacting a first inorganic compound containing chromium and oxygen with a second inorganic compound containing at least one element selected from the group consisting essentially of calcium, barium and strontium to form a reaction product containing chromium, oxygen and at least one element selected from the group essentially consisting of calcium, barium and strontium. A method of bonding a high temperature resistant polymeric material to an aluminum base substrate using the above composition is also provided.

Abstract: A semiconductor die attach adhesive is provided which is formed of a plurality of spacers formed in a suspension of silver filled glass. In one embodiment of this invention, the spacers are spheres. The spacers utilized in one embodiment of this invention have a melting temperature below the temperature at which the solvents are evaporated from the die attach adhesive. In this manner, as the solvents are driven from the silver filled glass during the die attach operation, thus causing the volume of the silver filled glass to decrease, the spacers utilized in this invention partially melt, thus decreasing their thickness. This decreased thickness of the spacers decreases the separation between the die and the substrate, thus preventing the formation of voids within the die attach adhesive. In one embodiment, the spacers are formed of a lead/tin alloy.

Abstract: A ceramic bonded structure with a high bonding strength has a first member of a ceramic, a ceramic-modified bonding layer formed on at least a bonding surface of the first member by a thermal treatment, a metal layer formed on the ceramic-modified bonding layer, and a second member of a ceramic or metal bonded with the first member through the metal layer.

Abstract: An adhesive agent having, as its active components, copper sulfide and at least one member selected from the group consisting of alumina, silica, and kaoline enables the opposed surfaces of two oxide-type ceramic articles to be joined to each other with high adhesive strength, this fast union being accomplished by interposing the adhesive agent between the opposed surfaces of the ceramic articles and heating the adhesive agent to a temperature of not less than 1000.degree. C.

Abstract: A process for bonding a copper or copper-chromium alloy body and a ceramic body of components of an electrical or electronic device to each other includes a step of directly sandwiching a layer of chromium oxide between the ceramic and copper or copper-chromium bodies, a step of heating a temporary assembly of the ceramic and copper or copper-chromium alloy bodies and the layer of chromium oxide, under an atmosphere which can oxidize chromium without oxidizing copper, at a temperature of at least 900.degree. C. but below the melting point of copper or the alloy, and then a step of slowly cooling the resulting bonded assembly. In particular, in a process for bonding the alloy body to the ceramic body, the chromium oxide sandwiching step is performed concurrently with the temporary assembly heating step. The bonding process can produce a hermetic envelope, particularly a vacuum envelope of a vacuum interrupter.

Abstract: Disclosed is an extruded laminate and a method for making the laminate. Protective and decorative molding and trim strips for automotive vehicles and the like can be made from the laminate which comprises a body of an extruded thermoplastic material such as extruded polyvinylchloride and an extruded outer layer of a different and incompatible material with a tie sheet sandwiched therebetween. The tie sheet is a thin laminate of a layer compatible with the thermoplastic material of the body and a layer compatible with the material of the outer layer. Optionally, a decorative layer of metallized polyester and/or other material can be encapsulated between the tie sheet and the body or outer layer.

Abstract: This disclosure is directed to a heat-activated patch or repair composition for metal object or surface capable of maintaining its shape at the temperatures to which it is heated to activate and set the composition and ranging from about 250.degree. to about 500.degree. F. comprising a preponderant concentration of a fibrous adhesive containing silicate, soda and asbestos fibrous cement, and lesser concentrations of iron ore and an alumina-containing air set mortar having Pier test of about 600 to about 800 p.s.i. and comprised of alumina, clay and grog (ground-up fired clay). The aforementioned heat-activated patch or repair composition is utilized in a system for repairing such metal object or surface by intimately associating said composition with asbestos cloth, preferably woven asbestos cloth, by applying said composition to one surface of said asbestos cloth and then wrapping the adhesive composition surface of the woven asbestos cloth around the exterior of the metal object or surface to be repaired.

Abstract: A composition of at least one member selected from the group consisting of sodium fluoride and calcium fluoride and optionally containing kaolin is powerful adhesive for ceramic articles which is used by interposing the adhesive intimately between the opposed surfaces for union of the ceramic articles and heating the adhesive to a temperature equal to or higher than the decomposition temperature of the fluoride used.

Abstract: Adhesion of two silicon nitride parts is accomplished by interposing a layer of calcium fluoride or a mixture of calcium fluoride with kaoline between the two silicon nitride parts and heating the resultant interposed layer.

Abstract: A bonding method which uses two solutions, one being anionic and the other being cationic, to lay down alternating layers of particles of accurate dimension onto members which are to be bonded. Thereafter, the layers are placed in contact, and the members are bonded together by diffusion bonding techniques.

Abstract: A silver metallizing paste for attachment of silicon semi-conductive devices in lead-frame packages, specifically ceramic packages, which is less expensive than a gold preform but useable in hermetic packages, and provides better electrical and thermal conductivity, and higher bond strength, than silver polyimides. From 25 to 95% of silver is blended with a low-melting glass, preferably one having 95-96% PbO, and a paste or ink is formed with a suitable vehicle at 75-85% solids. Use of the paste follows conventional practice. Selection of Ag:glass ratio depends on the type of die bonding to be used. The paste is particularly useful in MOS technology, where low contact resistance is required, and also finds applications as a solder substitute and bonding chip capacitors. It is most advantageous in attachment of larger-area integrated circuits in that stress cracking associated with the gold-silicon eutectic is avoided.

Abstract: In a method for fixing a ferrite to a metal piece such as a pole-piece of a magnetic polarizing circuit of a microwave device, a first step consists in depositing a nonresistive metal on the ferrite face to be fixed. A second step consists in applying a very thin layer of heat-conducting adhesive on the metallized ferrite face and bonding the ferrite to the metal piece, thus ensuring low thermal resistance, very low insertion loss and high power capability.

Abstract: A copper-clad laminate having special utility in the production of high resolution printed circuit patterns by either subtractive or semi-additive processing is made by vapor depositing a film of zinc on a copper film on a silica-coated aluminum carrier sheet, vapor depositing a silica film on the resulting zinc-copper foil, bonding the resulting body to a substrate and then stripping the silica-coated aluminum carrier sheet from the copper-clad laminate.

Abstract: An adhesive having as its active component at least one fluoride selected from the group consisting of alkali metal fluorides except for sodium fluoride and alkaline earth metal fluorides except for calcium fluoride or a combination of the aforementioned at least one fluoride with kaolin and an adhesive having as its active component a combination of at least one member selected from the group consisting of yttria and alkaline earth metal compounds except for fluorides, an alkali metal fluoride, and at least one member selected from the group consisting of kaolin and alkaline earth metal fluorides both provide fast adhesion easily between two ceramic articles by a method which comprises the steps of interposing the adhesive between the ceramic articles and heating the ceramic articles with the adhesive therebetween to a temperature equal to or higher than the decomposition temperature of the fluoride in the adhesive.

Abstract: The present invention is directed to a brazing material for joining graphite structures that can be used at temperatures up to about 2800.degree. C. The brazing material formed of a paste-like composition of hafnium carbide and uranium oxide with a thermosetting resin. The uranium oxide is converted to uranium dicarbide during the brazing operation and then the hafnium carbide and uranium dicarbide form a liquid phase at a temperature about 2600.degree. C. with the uranium diffusing and vaporizing from the joint area as the temperature is increased to about 2800.degree. C. so as to provide a brazed joint consisting essentially of hafnium carbide. This brazing temperature for hafnium carbide is considerably less than the eutectic temperature of hafnium carbide of about 3150.degree. C.

Abstract: A method of bonding a plurality of thermally stable high strength graphite fiber reinforced glass matrix composite pieces is described. The process comprises applying to the surfaces to be bonded at least one layer of a metal which is highly adherent to the composite and the solder and is oxidatively stable. A tie layer may be used between the composite bond surface and the metal layer to better bond the metal layer to the composite. Following application of the metal layer, the composite pieces are stacked with the metal layers facing each other and a solder layer in between. The temperature of the assembly is raised to melt the solder and form the bond. The melting temperature of the solder and the metal layers are chosen so as to be higher than the use temperature of the bonded composite. A bonded composite article thus formed is also described.

Abstract: An adhesive is provided which comprises a thixotropic binder (24) containing metallic particles (23) of discrete size and specific density concentration. When used to bond faying surfaces (13 and 21/10 and 21) this adhesive is capable of conducting electrical currents on the order of 200,000 amps while withstanding structural loads on the order of 5000 psi. It has particular application in a highly volatile environment such as the skin panel (10) of an aircraft component housing an integral fuel tank (12). Lightning strike currents are thereby conducted in a controlled path (P) adjacent the exterior surfaces (S) of the component as defined by the parts (10, 13, 17 and 21) and arcing inside the fuel tank (12) is avoided.

Abstract: A method for producing a fire-resistant, thermally insulating board, which comprises applying liquid hydrated sodium silicate (B) onto the inner surface of a facing material or sheet (A), spreading powdery hydrated sodium silicate (C) over the said applied surface, laying the said spread surface on(1) a facing material or sheet (D),(2) a facing material or sheet (D) applied in advance with liquid hydrated sodium silicate (B) or(3) a facing material or sheet having powdery hydrated sodium silicate (C) spread further over the applied surface of (2),implementing the heating and pressing procedure for gluing the assembly, and laminating the resulting fire-resistant board (E) with rigid isocyanurate foam (F).The fire-resistant, thermally insulating board shows reduced fusing and combustion of the rigid isocyanurate foam (F) even when exposed to flame and posseses superior mechanical properties.

Abstract: An adhesive composition based upon an aqueous solution of alkali metal silicate with a content of powdered inorganic filler, having good storage stability, which comprises an aqueous alkali metal silicate solution containing:(a) from 10% to 40% by weight of at least one powdered inorganic filler,(b) a suspension effective amount of at least one zinc soap of a fatty acid having from 12 to 22 carbon atoms and(c) from 0 to about 24% by weight of a 50% by weight stable, aqueous dispersion of an alkali-resistant organic polymer, based on the weight of the total composition.Preferably zinc stearate in amounts of from 1% to 5% by weight are added to the adhesives containing powdered inorganic fillers and optionally organic additives on a base of aqueous water glass solutions, to prevent separation phenomena. Sodium and/or potassium silicate solutions can be used, the sodium silicate solution being preferably present in the ratio by weight of 3.3 to 3.9:1 for SiO.sub.2 /Na.sub.

Abstract: A silver metallizing paste for attachment of silicon semi-conductive devices in lead-frame packages, specifically ceramic packages, which is less expensive than a gold preform but useable in hermetic packages, and provides better electrical and thermal conductivity, and higher bond strength, than silver polyimides. From 25 to 95% of silver is blended with a low-melting glass, preferably one having 95-96% PbO, and a paste or ink is formed with a suitable vehicle at 75-85% solids. Use of the paste follows conventional practice. Selection of Ag:glass ratio depends on the type of die bonding to be used. The paste is particularly useful in MOS technology, where low contact resistance is required, and also finds applications as a solder substitute and bonding chip capacitors. It is most advantageous in attachment of larger-area integrated circuits in that stress cracking associated with the gold-silicon eutectic is avoided.

Abstract: A method of bonding a graphite fiber reinforced glass matrix composite to a metal structure comprising depositing a layer of eutectic alloy metal component to the bond surfaces of the metal and composite followed by placing the thus treated bond surfaces of the metal and composite together with a layer of eutectic alloy containing such metal therebetween. The metal-bond-composite is then heated to melt the alloy and bond the composite to the metal. Articles formed by such a process are also described. The method has particular utility in bonding cooling channel containing metal bases to graphite-glass composite laser mirrors.

Abstract: A bucket for an adjustable turbine guide baffle system for gas turbines is formed of an alloy material comprised of a dispersion-strengthened Fe-Cr-Al alloy containing 64.5-75.5% by weight of Fe, 15-25% by weight of Cr, 3-8% by weight of Al, 0.1-1% by weight of Ti, 0-3% by weight of Co, 0.1% by weight of Y or Ce, and 0.1-1.5% by weight of yttrium oxide or aluminum oxide. The bucket has a shank which is under friction stress in the guide baffle system and which is coated with a layer of slip-providing material that contains 90-100% by weight of nickel oxide and 0-10% by weight of one or more oxides of chromium, aluminum, zirconium, titanium, iron, manganese, or magnesium.

Abstract: Resins suitable for adhesives are based on .alpha.-methyl styrene, styrene and phenol in certain percentages, viz. 25 to 63, 35 to 73 and 2 to 15 percent by weight, respectively,Combinations of resin, ethylene vinyl acetate copolymer or thermoelastomer and optionally a wax or tackifying oil yield excellent adhesives, in particular hot-melt adhesives.

Abstract: A method for forming a homogeneous bond between silicon nitride ceramics is disclosed which comprises melting a bonding composition placed between the surfaces to be bonded. The bonding composition is specifically selected to provide in the bond or joint the same chemical constituents found intergranularly in the silicon nitride materials to be bonded. The resultant bond is as strong or stronger than the silicon nitride materials bonded.

Abstract: A range of borosilicate glass compositions which are capable of sealing effectively to nickel iron alloys containing up to approximately 52% nickel to form a hermetic seal resistant to thermal shock breakage. The glass is in the composition range percent by weight of:SiO.sub.2 : 55-66Al.sub.2 O.sub.3 : 4.5-10Na.sub.2 O: 0-4K.sub.2 O: 3.5-7B.sub.2 O.sub.3 : 19.0-26.0TiO.sub.

Abstract: Process for the direct joining of rubber to metal surfaces by vulcanization using a rubber mixture containing the additives common for sulfur vulcanization wherein either the rubber mixture contains additionally tellurium, tellurium alloys and/or tellurium compounds as bonding aid, or that tellurium, tellurium alloy and/or tellurium compound is applied on the metal surface before vulcanizing.

Abstract: The use of polysulfide rubbers cured with zinc oxide and tetramethylthiuram disulfide and other sulfur containing cure accelerators for polyisoprene rubbers in hot applied processes and articles formed thereby are disclosed. The compositions are useful as hot applied sealants and in the extrusion of hoses and similar rubber articles.

Abstract: An air cleaner element for an internal combustion engine capable of adsorbing fuel vapor and having an air cleaning filter medium and a fuel vapor adsorption filter medium containing activated carbon fibers, the filter media being partly bonded together with an adhesive into a unitary construction. Both the filter media have a large surface area so that the reduction in size of the air cleaning filter medium and the increase in size of an air cleaner case may not be needed. Furthermore the wear and abrasion of activated carbon fibers due to the vibrations may be avoided.

Abstract: The invention relates to thermally insulating materials. It refers to a thermally insulating slab consisting of entangled refractory fibres, the major portion of the fibres being substantially parallel with the main faces of the slab, characterized in that the back of the slab bears a plurality of furrows or grooves distributed over the back. The slab is used for the insulation of furnaces and the like.

Abstract: A sealing cement which is useful for bonding together mutually aligned glass plates of a liquid crystal display cell, the improvement which comprises incorporating into said cement a particulate filler of variably sized particles, wherein the shortest distance between parallel tangential planes of each particle is substantially the same for a substantial majority of said particles and the shortest distance between parallel tangential planes for the remainder of said particles is less than said shortest distance between parallel tangential planes of said substantial majority of particles, whereby the spacing between said glass plates being bonded is determined by said shortest distance of said substantial majority of particles.

Abstract: A mesh electrode for a c.r.t. display device consists of a number of coplanar portions of mesh insulated from each other, and secured to a support plate by means of two layers of refractory compound. The first layer is applied to the support plate and allowed to set before the second layer is applied so as to space the mesh portions from the support plate by at least the thickness of the first layer.

Abstract: An air filter unit of the pleated media, high efficiency type wherein the media pleat edges are sealed to the supporting frame to prevent bypass of air with a ceramic adhesive and fibrous ceramic mat which allows the unit to be exposed to high temperatures (e.g., up to 2000.degree. F.) without danger of seal breakdown. While in the form of a slurry the adhesive is applied, for example, with a trowel to the zig-zag pleated edges of the media which, together with corrugated spacers, forms the filter core. The latter is then surrounded on four sides by the compressible mat of fibrous ceramic material and inserted in a box-like support frame with the slurry filling the space between the pleated edges of the media and the fibrous mat.

Abstract: A magnetic head is manufactured by depositing a layer of spacer material onto the facing surfaces of the magnetic cores; the thickness of each layer being approximately one-half the length of the intended gap and the thicknesses of both layers together being approximately equal to the thickness (length) of the gap. A layer of bonding glass is deposited onto the surfaces of the spacer layers and the cores are pressed together at an elevated temperature to fuse the glass layers and extrude most of the glass.

Abstract: A method of manufacturing a laminated, light-transmitting fire-screening panel comprising at least one solid layer of intumescent material sandwiched between two structural plies without the use of a sheet of plastic material to effect the bonding, comprising the steps of forming a stratum from an intumescent material assembling the stratum and a first structural ply to an inorganic face of a pane comprising a second structural ply so that the stratum is in contact with the inorganic face and sandwiched between the structural plies, enveloping at least the edges of the sandwich assembly in such manner as to define a space around the edges in which sub-atmospheric pressure can be created for subjecting the inter-ply space to suction at the edges, and subjecting the sandwich assembly to a treatment in which at least one of the main external faces of the sandwich assembly is exposed to sub-atmospheric environmental pressure while the sandwich assembly is exposed to heat in a treatment chamber and the inter-ply s

Abstract: Compositions possessing a porous, high specific area, silica-rich surface, or capable of developing such a surface in vivo, form strong bonds with bone tissue. These compositions are thus excellent materials for dental and surgical implants, or the coatings thereof. Examples of such compositions include highly porous glasses and glass-ceramics comprising at least about 80 weight percent silicon dioxide, hardened inorganic cements such as Portland cement and known silicon dioxide-based biologically active glasses and glass-ceramics. Neither calcium, sodium nor phoshorus compounds are necessary ingredients. Cements which develop the above described surface characteristics in vivo form a strong bond with both bone and implant when used in the fixation of dental and surgical implants, especially those made or coated with a biologically active silicon dioxide-based glass or glass-ceramic.

Abstract: The forming of an adherent platinum coating on the surface of hard, highly dense refractories by plasma flame spraying thereon an intermediate layer of a refractory oxide selected from the group comprised of zirconia, zircon, alumina, cordierite, mullite, or zirconia-alumina-silica having a particle size between 140 and 200 mesh, and further plasma sraying thereon a substantially 20-100 micron size platinum powder which is densified by heating to temperatures of 1350.degree.-1600.degree. C.

Abstract: The compound ##STR1## wherein each M is selected from the group consisting of Na, K, H and mixtures thereof; n is the degree of polymerization and ranges from about 2 to about 1,000; T is selected from the group consisting of Al, Ti, Zn, Zr, Sn, V, Mo, W, Se, Ge and mixtures thereof; and R is an acyl group containing from about 2 to about 30 carbon atoms and from about 0 to about 5 additional carboxylate groups; detergent compositions containing said compound and similar capped compounds; and processes for preparing said compound.

Abstract: A diffusion barrier and separation substance for metal parts which adjoin each other in an oxygen-free, inert and preferably a helium-containing atmosphere such as used in a closed-cycle high temperature reactor or gas turbine comprises first and second adjoining metal parts with a hexagonal boron nitride placed between said parts. The hexagonal boron nitride is applied to the boundary surface of the metal parts in an aqueous or organic suspension prepared as a pasty, putty-like or brushable liquid substance. The substance contains from 5 to 50% of boron nitride, from 0.5 to 30% of binders and from 2 to 6% of swelling agents and 50 to 90% liquid suspension medium. The suspension medium may advantageously contain an anti corrosive agent and in addition the formed protective film is burned from 0.25 to 3 hours at a temperature of from 100.degree. to 500.degree. C.

Abstract: A method for continuously forming a hot melt adhesive cartridge having a non-stick, thermoplastic outer coating. The hot melt adhesive cartridge is formed by extruding a sleeve of non-stick, thermoplastic material having a predetermined outside dimension, cooling the sleeve to cause setting of the thermoplastic and introducing a hot melt adhesive into the set sleeve.

Abstract: A method of producing fire resistant wood products wherein a plurality of thin wood strips, each having a multiplicity of uniformly close spaced surface indentations, are bonded together in a stack by a binder having fine particles of inert non-flammable material mixed therein to produce a laminated wood unit having a multiplicity of close spaced cavities throughout which are filled with a set binder containing non-flammable material.

Abstract: A method of manufacturing laminated panels or foils consisting of a lead sheet and a synthetic sheet by using lead alloyed with antimony and/or coating the lead sheet with an alloy of lead. Optionally a protective film serving as an adhesive may be applied onto the surface that is to be welded to the synthetic material. A novel compound material consisting of a lead sheet and a plastics sheet.

Abstract: A composition comprising plasticized sulfur wherein the composition is prepared by steps including heating the plasticized sulfur to a temperature between 160.degree. C and 220.degree. C and then cooling the hot plasticized sulfur in liquid form below its normal melting point (freeze point) to thereby obtain a liquid, tacky, plasticized sulfur. Preferably the plasticized sulfur is brought to a temperature between about 170.degree. C and 210.degree. C and then cooled. The composition is useful as an adhesive and is useful as a binder in preparing conduit or pipe from laminated layers of paper-like material. The composition is also useful in preparing structures or structural members.

Abstract: A method for preparing polymerized products by spraying unsaturated polyester resin syrup, aqueous sodium silicate and a polymerization initiator for the unsaturated polyester resin syrup. The ingredients preferably are formed into sprays which are mixed by impingement. Alternatively the ingredients may be combined into a single spray. These sprays may include inert fillers in spray form. Preferably the sprays are impinged upon inert fillers including chopped fibrous reinforcements such as glass fibers.

Abstract: A manufacture comprising a plurality of fibers partially embedded in a solidified plasticized sulfur matrix with one end of the fibers extending outward from the matrix to form a turf or carpet-like surface.

Abstract: A liquid crystal cell consisting of two planar supports and a spacer interposed between them only on the margin, said supports being fixed at intervals of a limit by the spacer to form an aperture, has at least one opening through which the liquid crystal material is poured into said aperture. The openings are sealed with use of cyanoacrylates or polybutadiene type resins so that the liquid crystal cell can be prevented from lowering of the characteristics caused by incorporating of impurities into the liquid crystal layer.

Abstract: A high temperature cement for carbon articles comprising aluminum, and tantalum or silicon, in a specific weight percent ratio such that when heated in an inert atmosphere, the tantalum or silicon will react with the carbon in the articles to be joined to form, in situ, tantalum carbide or silicon carbide, respectively, in the presence of aluminum.