Abstract: A curable composition including a monomer having at least one curable acrylic functionality, an accelerator and optionally a free radical initiator, wherein the accelerator is a compound of the formula ##STR1## wherein R' is H or alkyl; when R' is H, R is substituted or unsubstituted cyclohexyl, alkenylamino, or C.sub.3 -C.sub.10 branched alkyl; andwhen R' is alkyl, R is aralkyl.Such compositions are useful as fixturing (e.g., threadlocking) compositions, and overcome the problems of poor solubility in organic non-polar media and temperature constraints associated with the use of saccharin per se as an accelerator in such compositions.Also disclosed is a corresponding method of polymerizing compositions containing acrylic-functional compounds, and a method of making the substituted saccharin compounds from the corresponding substituted benzene sulfonamide.Alkenylamido-substituted saccharin compounds and alkyl, aralkyl-disubstituted saccharin compounds are specifically disclosed.

Abstract: A formaldehyde binder containing at least one organic hydroxy compound, at least one amide, and water. This binder is suitable for use in preparing boards from lignocellulosic materials using adhesive based on formaldehyde.

Abstract: Two solid substrates are bonded together by using a functionally effective amount of an arylcyclobutene monomeric composition as an adhesive.

Abstract: The invention relates to chemically bonded laminated structures and their production from oriented polymeric laminae. The bonds between the contacting lamina are formed by chemical reaction across their interface involving constituent molecular chains of each laminae. Three methods have been found for producing the bonds: (a) bringing the surfaces of the lamina in intimate contact to within 10.degree. C. and 100.degree. C. below the melting temperature of the surfaces; (b) interposing a coupling agent for the polymer molecules of the intimately contacting surfaces of each member into their interface and heating the laminate to a temperature effective to cause reaction of the coupling agent with the molecules of each; and (c) interposing a catalyst to promote chemical reaction of the molecules of each laminae with the molecules of intimately contacting lamina into their interface and heating to a temperature effective to cause reaction.

Abstract: Adhesive compositions affording strong bonds of high environmental resistance between elastomers and substrates such as metals are provided. The adhesive compositions comprise an admixture of (i) olefinic organosilane, (ii) water, and (iii) an alumino zirconium metallo-organic complex of chelated aluminum moiety, an organofunctional ligand and zirconium oxyhalide. The adhesive composition preferably includes a polymer resin selected from phenolic-formaldehyde resins, urea-formaldehyde resins, resorcinol-formaldehyde resins or melamine-formaldehyde resins.

Abstract: The present invention describes novel solvent cements which are a combination of a solvent which is a 5- or 6-membered ring lactam and a cosolvent which is one or more lower alkanols and/or one or more lower alkyl esters of lower alkanoic acids and, optionally, include a water-insoluble polymer such as PVC or ABS.

Abstract: This invention is concerned with a method for preparing transparent laminated polarizing glass articles consisting of a support of an inorganic or organic glass, a coating exhibiting polarizing properties disposed on one of the surfaces of the support, and an optically transparent layer adhered to the coating which protects the coating from humidity. The vital feature of the method comprises a first treatment by a gamma-aminopropyltrialkoxysilane and a second treatment by an epoxyalkyltrialkoxysilane which is designed to improve the adherence of the optically transparent layer to the polarizing coating.The invention is especially useful in the fabrication of eyeglass lenses.

Abstract: A polymer is bonded or welded together with a composition containing at least one hydroxyl-ether and/or keto-ether.

Abstract: This invention concerns an improved method for fabricating transparent laminated polarizing glasses consisting of a substrate of inorganic or organic glass, a coating of polarizing properties deposited upon one surface of the substrate, and an integral, optically transparent composite film consisting, on the one hand, of one lamina of thermoplastic polyurethane of adhesive properties, and, on the other hand, of one lamina of thermosetting polyurethane of anti-lacerative and self-regenerating properties; the thermoplastic polyurethane ply adhering to the polarizing coating. The method comprises applying the polarizing coating to the substrate, then treating at least the coated surface of the substrate with a aqueous solution containing .gamma.-aminopropyltrimethoxysilane or .gamma.-aminopropyltriethoxysilane, and thereafter applying said composite film.

Abstract: A thin foil or film is laminated to a substrate with an adhesive layer therebetween thicker than the surface roughness of the substrate, the laminating and drying of the adhesive being effected with the foil contacting a smooth contact surface under a contact pressure, the rate of heat input to dry the adhesive and the pressure on the back of the substrate being controlled to maintain the vapor pressure at the interface between the film and the adhesive above atmospheric and below the contact pressure so that the foil surface of the finished laminate is as smooth as the contact surface.

Abstract: A method for producing a hybrid integrated circuit includes steps of: applying an adhesive to an electronic part mounting conductor on an insulating substrate; adhering an electronic part to the applied adhesive and hardening the adhesive to temporarily fix the electronic part; fixing the temporarily fixed electronic part on the conductor with solder; and dissolving the hardened adhesive in a solvent and removing it. Upon being hardened, the adhesive can withstand the heat of molten solder and can be dissolved in a solvent and removed therewith.

Abstract: A process for bonding heat curable silicone rubber to a variety of substrates using an aqueous primer composition containing an alkenyltrihydrocarbonoxysilane and an aqueous miscible solvent selected from the group consisting of aliphatic alcohols, glycol ethers, ketones and esters.

Abstract: A fire protection and/or extinguishing article comprises a sheet which has, uniformly dispersed therein, a material which undergoes an endothermic reaction to release a non-flammable gas and simultaneously absorb heat when subjected to an elevated temperature. This sheet is sandwiched between a gas permeable thermal barrier and a layer of gas permeable thermal insulation in a preferred embodiment which may function as a foldable and storable blanket.

Abstract: A method as disclosed for preventing the formation of Newton ring light patterns between a transparency or photographic negative and a transparent mounting surface such as a sheet of glass. The method comprises the application of a thin film of a substantially transparent resin to form a matte surface finish on the surface of the transparency to be applied against the mounting surface and then mounting the transparency or equivalent to the mounting surface with the resin film interposed therebetween, such that the matte resin film serves as a spacer and also reduces reflection of light between the transparency surface and the mounting surface.

Abstract: A process for making stained glass Tiffany-type lamp shades which comprises providing a kit containing an inscribed fiberglass form, a pressure-sensitive wax adhesive for attaching shaped pieces of different sized stained glass to the form in correspondingly shaped and sized circumscribed areas on the surface of the form, and a print on which a particular design is imprinted corresponding to the circumscribed areas on the form, and which may be cut out into patterns to be used to cut stained glass of different colors into pieces to conform to the various shapes and sizes to be incorporated into the design. A transparency is also provided on which the entire design is reproduced to slightly expanded size as opaque lines on a transparent medium. The transparency is placed over a light box, and each cut stained glass piece is placed in its corresponding position on the transparency as a preview to aid in the color selection of the stained glass pieces.

Abstract: A process and composition for applying and bonding an amine curable polymer or prepolymer at ambient temperatures to the surface of a cured elastomer substrate. The elastomer article or substrate is treated with an organic oxidant such as an N-halohydantoin, N-haloamide, or an N-haloimide, for example, the various isomers of mono- , di- , and trichloroisocyanuric acid. A polyisocyanate is applied thereto. A composition of the amine curable polymer or prepolymer is prepared with an amine curing agent. To the curing agent and curable polymer or prepolymer composition is added a polar solvent which is mixed with the resulting blend or mixture and added to the treated elastomer surface; said polymer or prepolymer cures at ambient temperature and becomes bonded to said elastomer. The application is relatively easy, since the entire mixture is a liquid and can be applied in situ.

Abstract: A mixture of an organosilicon compound having at least one alkoxy or alkoxyalkoxy radical per molecule, vinyltris(tertiary-butylperoxy)silane, and organic solvent is an adhesive primer composition useful for bonding thermosetting silicone rubber to a substrate, especially for bonding fluorosilicone rubber to a substrate. The adhesive primer composition can be used in a method of bonding thermosetting silicone rubber to a substrate.

Abstract: Disclosed is a primer composition which contains an isocyanate compound having one or more 1,3,5-oxadiazine-2,4,6-trione rings as an adhesion promoter, which is useful as a primer for bonding polyester plastics to the same or different substrates using an adhesive such as polyurethane, epoxy and polyolefin adhesives. When the surface of polyester plastics is treated with said primer prior to application of the adhesive, the bonding achieved is excellent in adhesion.

Abstract: The repair of a reinforced elastomer article having a deformity such as a cut, cavity, or an aperture therein relates to utilizing an amine curable polymer or prepolymer and a cured elastomer patch. The deformity in the elastomer as well as the areas juxtaposition to the patch are coated with a treating agent. The amine curable polymer or prepolymer applied to the patch area has no rubber filler therein and is cured at ambient temperature. The amine curable polymer or prepolymer applied to the cut, cavity or to the aperture does have a rubber filler therein and is also cured at ambient temperature. One area of use is in the repair of tires.

Abstract: The repair of a reinforced elastomer article having a hollow therein relates to utilizing an amine curable polymer or prepolymer and a cured elastomer patch. The hollow in the elastomer as well as the areas juxtaposition to the patch is coated with a treating agent. The amine curable polymer or prepolymer is then applied to the hollow as well as to the area between the patch and the elastomer and cured at ambient temperature. One area of use is in the repair of tires.

Abstract: A process affixes a honeycomb structure to a plate in a manner whereby the structure and the plate may be chucked and the exposed surface of the honeycomb may be machined. The steps of the process include applying to the surface of the plate a viscous coating of honey; embedding one surface of the honeycomb in the viscous honey coating to leave the opposite honeycomb surface exposed for machining, and curing the coating to more tightly secure the honeycomb to the surface.

Abstract: In repairing articles of natural rubber or elastomer predominantly of natural rubber with cured polymer or prepolymer (polyurethane/polyurea), adhering advantages are obtained especially at elevated temperatures when the damaged area is treated with halogen-containing oxidant dissolved in 1,2-dichloroethane instead of other solvents.

Abstract: A process and composition for applying and bonding an amine curable polymer or prepolymer at ambient temperatures to the surface of a cured elastomer substrate. The elastomer article or substrate is treated with an organic oxidant such as an N-halohydantoin, N-haloamide, or an N-haloimide, for example, the various isomers of mono-, di-, and tri-chloroisocyanuric acid. A polyisocyanate is applied thereto. A composition of the amine curable polymer or prepolymer is prepared with an amine curing agent. To the curing agent and curable polymer or prepolymer composition is added a polar solvent which is mixed with the resulting blend or mixture and added to the treated elastomer surface; said polymer or prepolymer cures at ambient temperature and becomes bonded to said elastomer. The application is relatively easy, since the entire mixture is a liquid and can be applied in situ.

Abstract: A method for improving the adhesion of organopolysiloxane elastomers to solid substrates which comprises (1) coating the substrate with a primer composition containing (a) a mixture consisting of a silane having an SiC-bonded aliphatic multiple bond and a silane having an SiC-bonded epoxy group; or (b) a stratum consisting of (i) at least a partially crosslinked organopolysiloxane containing SiO.sub.

Abstract: An improved adhesive binder composition is provided for the preparation of lignocellulosic composite molded articles such as flake or particleboard, made from moldable compositions which comprises an organic di- or polyisocyanate and a cyclic alkylene ester of carbonic acid and optionally lignin, for application to the lignocellulosic material prior to the molding process to form the composite product.

Abstract: A mixture of an alkoxy containing silicon compound, a hydroperoxide, and organic solvent is a primer composition useful for bonding heat curing silicone rubber, especially fluorosilicone rubber, to a substrate.

Abstract: A process and composition for applying and bonding an indicia which is curable at ambient temperatures to a cured elastomer substrate. The substrate is treated generally at ambient temperatures with organic oxidants selected from the group consisting of N-halosulfonamides, N-halohydantoins, N-haloamides, N-haloimides, and the various isomers of mono-, di-, and trichloroisocyanuric acid. The indicia which is generally a urethane polymer or prepolymer is blended with an amine curing agent. A polar solvent is added to the amine curing agent and the amine curable polymer or prepolymer composition and mixed with the resulting blend or mixture applied to the treated elastomer surface in the form of an indicia so that said polymer or prepolymer cures at ambient temperature and is bonded to said elastomer. The invention is particularly suitable for applying indicia to various elastomer articles such as tires, conveyor belts, hoses, floor mats, sporting goods, and the like.

Abstract: The invention herein disclosed provides a method for preparing improved fluoroelastomer film compositions including the steps of dissolving a fluoroelastomer gum selected from the group consisting of copolymers of vinylidene fluoride and hexafluoropropylene, and terpolymers of vinylidene fluoride, hexafluoropropylene and tetrafluoroethylene in a solvent, adding a silane compound to the gum solution and curing the fluoroelastomer gum with a silane in the absence of metallic oxides. A method is also provided for adhering fluoroelastomer film compositions, devoid of metallic oxides, to substrates which includes the steps of dissolving the fluoroelastomer gum in a solvent, adding a silane compound to the gum solution, coating the substrate with the fluoroelastomer gum-silane solution, evaporating the solvent and leaving a film firmly adhered to the substrate.

Abstract: A process and composition for applying and bonding a curable polymer or prepolymer, for example, an amine curable polymer or prepolymer, at ambient temperatures to the surface of a cured elastomer substrate. The elastomer article or substrate is treated with an organic oxidant such as one selected, for example, from the group consisting of N-halosulfonamides, N-halohydantoins, N-haloamides, N-haloimides, and the various isomers of mono-, di-, and trichloroisocyanuric acid. A composition of a curable polymer or prepolymer is prepared with a curing agent. To the curing agent and curable polymer or prepolymer composition is added a polar solvent which is mixed with the resulting blend or mixture and added to the treated elastomer surface; said polymer or prepolymer cures at ambient temperature and becomes bonded to said elastomer. The application is relatively easy, since the entire mixture is a liquid and can be applied in situ.

Abstract: A laminating and coating adhesive based on an aqueous dispersion of(1) a copolymer of a vinyl ester, and/or an acrylic acid ester, and/or a further monomer and an ethylenically-unsaturated functional group-containing monomer having from 3 to 18 carbon atoms and hydroxy and carbonyl groups as functional groups, such as a monocarboxylic acid or dicarboxylic acid and/or N-methylol-(meth)-acrylamide,(2) an epoxy compound, and(3) an amine hardener.The adhesive gives a laminate bond with especially high resistance to peeling even in the case of thermal stress and/or in the presence of water.

Abstract: There are disclosed radiation curable compositions containing (a) about 5-95% by weight of at least one cyanoalkoxyalkyl or cyanothiaalkylalkyl acrylate, (b) about 1-90% by weight of a photopolymerizable acrylated polymer or oil, and (c) from 0 to about 5% by weight of a photoinitiator. The compositions are useful as 100% solids coatings and adhesives compositions which are curable upon exposure to radiation, and which are useful in a variety of applications such as for coating textiles and fabrics, for producing pressure sensitive adhesives, and for producing laminating adhesives.

Abstract: An adhesive binder composition is provided for the preparation of lignocellulosic composite molded articles such as flake or particle board, made from moldable compositions which comprises an organic di- or polyisocyanate and a liquid mixture of ethylene carbonate and propylene carbonate and optionally lignin, for application to the lignocellulosic material prior to the molding process to form the composite product.

Abstract: An adhesive binder composition is provided for the preparation of lignocellulosic composite molded articles such as flake or particle board, made from moldable compositions which comprises an organic di- or polyisocyanate and a liquid dialkyl ester of carbonic acid and optionally lignin, for application to the lignocellulosic material prior to the molding process to form the composite product.

Abstract: A process and composition for applying and bonding a curable polymer or prepolymer, for example, an amine curable polymer or prepolymer, at ambient temperatures to the surface of a cured elastomer substrate. The elastomer article or substrate is treated with an organic oxidant such as one selected, for example, from the group consisting of N-halosulfonamides, N-halohydantoins, N-haloamides, N-haloimides, and the various isomers of mono-, di-, and trichloroisocyanuric acid. A composition of a curable polymer or prepolymer is prepared with a curing agent. To the curing agent and curable polymer or prepolymer composition is added a polar solvent which is mixed with the resulting blend or mixture and added to the treated elastomer surface; said polymer or prepolymer cures at ambient temperature and becomes bonded to said elastomer. The application is relatively easy, since the entire mixture is a liquid and can be applied in situ.

Abstract: The invention herein disclosed provides a method for preparing improved fluoroelastomer film compositions including the steps of dissolving a fluoroelastomer gum selected from the group consisting of copolymers of vinylidene fluoride and hexafluoropropylene, and terpolymers of vinylidene fluoride, hexafluoropropylene and tetrafluoroethylene in a solvent, adding a silane compound to the gum solution and curing the fluoroelastomer gum with a silane in the absence of metallic oxides. A method is also provided for adhering fluoroelastomer film compositions, devoid of metallic oxides, to substrates which includes the steps of dissolving the fluoroelastomer gum in a solvent, adding a silane compound to the gum solution, coating the substrate with the fluoroelastomer gum-silane solution, evaporating the solvent and leaving a film firmly adhered to the substrate.

Abstract: A process and composition for applying and bonding an indicia which is curable at ambient temperatures to a cured elastomer substrate. The substrate is treated generally at ambient temperatures with organic oxidants selected from the group consisting of N-halosulfonamides, N-halohydantoins, N-haloamides, N-haloimides, and the various isomers of mono-, di-, and trichloroisocyanuric acid. The indicia which is generally a urethane polymer or prepolymer is blended with an amine curing agent. A polar solvent is added to the amine curing agent and the amine curable polymer or prepolymer composition and mixed with the resulting blend or mixture applied to the treated elastomer surface in the form of an indicia so that said polymer or prepolymer cures at ambient temperature and is bonded to said elastomer. The invention is particularly suitable for applying indicia to various elastomer articles such as tires, conveyor belts, hoses, floor mats, sporting goods, and the like.

Abstract: Process for the direct joining of rubber to metal surfaces by vulcanization using a rubber mixture containing the additives common for sulfur vulcanization wherein either the rubber mixture contains additionally tellurium, tellurium alloys and/or tellurium compounds as bonding aid, or that tellurium, tellurium alloy and/or tellurium compound is applied on the metal surface before vulcanizing.

Abstract: A process for the preparation of an oligomeric acrylic acid of the formulaCH.sub.2 .dbd.CH--COO[CH.sub.2 --CH.sub.2 --COO].sub.n Hwherein n represents a number from 1 to 6 is described wherein acrylic acid is heated in the presence of a polymerization inhibitor to a temperature of about 50.degree. to about 200.degree. C. The process can be carried out at sub-atmospheric pressure, atmospheric pressure or super-atmospheric pressure and in the presence or absence of a solvent.

Abstract: A method for bonding high acrylonitrile copolymers to themselves comprises using certain organic solvents, such as an epoxide, as bonding agents.

Abstract: The adhesion of acrylic pressure sensitive adhesives to plastic substrates is improved by the presence of the adhesive of an effective amount for such adhesion improvement, e.g., from about 0.3% to about 4.0%, by weight of the adhesive when in liquid form, of a monoalkyl acid phosphate.

Abstract: Artificial membrane for wound-dressings composed of two polypeptide layers, one of which at least, the inside layer which contacts the wound, is biologically resorbable and the outside layer has an asymmetric structure permeable to water and to drug solutions but pratically impervious to outside pathogenic agents. The inside layer, at least, is constituted from biodegradable copolymers of amino-acids and -diacids of which the --COOH functions are partially esterified with mono and/or di-ols.

Abstract: A coupling agent for bonding an organic polymer to an inorganic coating on glass is prepared by the stoichiometric conversion of silicon-functional terminal groups in a multifunctional silane primer into tin-functional terminal groups which have a high affinity for inorganic surfaces such as tin oxide or indium oxide films on glass.

Abstract: There is disclosed a primer composition which is coated on the polyolefinic-containing foam prior to application of the vinyl film and is comprised of a chlorinated hydrocarbon solvent in which there are added a material selected from the group consisting of a chlorinated paraffin, an acrylic type ester, and a vinyl copolymer.

Abstract: Polyvinyl formal dissolved in a solvent comprising certain monoalkyl ethers of diethylene glycol and triethylene glycol or the monophenyl ether of ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol or propylene glycol. In some cases it is necessary to have a diluent such as an aromatic hydrocarbon present.

Abstract: A size composition is described which is capable of increasing the adherence, and particularly the adherence to rubber, of multifilament yarns having a base of polyester, a base of polymers of high modulus of elasticity, or a base of thermostable polymers, wherein said size composition contains tris(epoxypropoxy 2,3)3-propionyl 1,3,5-hexahydro-s-triazine as preadhering agent, preferably present in an amount between 1 and 30% based on the weight of the size composition. The treated yarn is thereafter bonded to a desired substrate, such as rubber.

Abstract: Alcohols preferably having a pka below that of propanol-1 are heated with certain heterocyclic phosphites to give phosphonates and certain heterocyclic phosphonites, to give phosphinates. If small amounts of alcohols are employed, the products are generally polymeric in nature whereas if larger amounts of the alcohol are employed, there is generally ring opening to the simpler monomer, or isomerization to the phosphonate or phosphinate. The products are useful as fire retardants and as adhesives for glass. Pentaerythritol phosphite can be self-polymerized by such heating to form the adhesive polymer.

Abstract: The primer compositions consist essentially of a mercapto-containing organosilane or organopolysiloxane as one component and a titanic acid ester as the other. They are suitable for adhesively bonding a room-temperature-curing silicone rubber elastomer irrespective of its crosslinking mechanism to various substrates. The bond obtained by use of the primer composition is very strong and highly resistant to water or sea water even on prolonged immersion at high temperatures.

Abstract: A correction sheet material for masking characters on a substrate is composed of a carrier sheet and a thin dry coating layer on the carrier sheet, the coating layer adapted, on the application of sufficient pressure, to be transferred from the carrier sheet onto the characters on the substrate, the coating layer comprising a pigment in an amount to provide sufficient opacity to cover the characters to be masked, and a high molecular weight organic ammonium salt as a binder for the pigment, and as an adhesive agent for the subsequently transferred coating, the salt insoluble in water and also in oils used in typewriter ink and carbon paper, the salt present in the coating layer in both continuous film and precipitated salt form and on the application of pressure, a strong opaque film of pigment and precipitated salt particles is transferred to mask the character on the substrate.

Abstract: An automated process of making reinforced roof and wall sheets for trucks and trailers employs step-by-step advancement of the sheet rock and lateral infeed of the structural reinforcing members. As the reinforcing members are sequentially fed into registry with the sheet stock, two kinds of adhesive are applied to them, one being a hot melt adhesive and the other being a catalyzed room temperature curing adhesive. The hot melt adhesive sets to provide an initial bonding which allows normal handling while the room temperature curing adhesive cures in the joint ultimately to augment the hot melt and provide a high strength joint.

Abstract: Crosslinkable ethylene-vinyl acetate copolymer resins are rendered amenable to forming adherent laminates with crosslinkable silicone rubber by coating the surface of the ethylene-vinyl acetate resin with a solution of a silane or a member of the class of compounds known as polyfunctional monomers prior to adhering the resin to the silicone rubber.