Including Solid, Extended Surface, Fluid Contact Reaction Means; E.g., Inert Raschig Rings, Particulate Absorbent, Particulate Or Monolithic Catalyst, Etc. Patents (Class 422/211)
  • Patent number: 8071819
    Abstract: The invention provides an apparatus and process for producing high-purity diol by taking cyclic carbonate and aliphatic monohydric alcohol as starting materials, continuously feeding the starting materials into column A, carrying out reactive distillation in column A, continuously withdrawing a low boiling point reaction mixture containing a produced dialkyl carbonate and the aliphatic monohydric alcohol from an upper portion of column A, continuously withdrawing a high boiling point reaction mixture containing a produced diol from a lower portion of column A, continuously feeding the high boiling point reaction mixture into distillation column C, distilling off material having a lower boiling point than that of the diol contained in the high boiling point reaction mixture AB as a column top component and/or a side cut component so as to obtain a column bottom component, continuously feeding the column bottom component into distillation column E, and obtaining the diol.
    Type: Grant
    Filed: December 28, 2006
    Date of Patent: December 6, 2011
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Shinsuke Fukuoka, Hironori Miyaji, Hiroshi Hachiya, Kazuhiko Matsuzaki
  • Patent number: 8071045
    Abstract: A reformer includes first and second reforming units which are stacked together. A first hole is formed at the center of a first receiver member of the first reforming unit, and a plurality of holes are formed in a peripheral portion of a second receiver member of the second reforming unit. In the structure, a reforming channel having a serpentine pattern going through the first and second holes is formed. In each of the first and second receiver members, a single layer of catalyst pellets is provided. Both end surfaces of the catalyst pellets substantially contact the first and second receiver members.
    Type: Grant
    Filed: May 23, 2006
    Date of Patent: December 6, 2011
    Assignee: Honda Motor Co., Ltd.
    Inventor: Tomio Miyazaki
  • Patent number: 8071044
    Abstract: In an isomerization process where the isomerization effluent (108) is fractionated in a deisohexanizer (116) to provide an overhead (118) containing dimethylbutanes and a higher boiling fraction (122) containing normal hexane, the higher boiling is contacted with a selectively permeable membrane (124) to provide a retentate containing methylcyclopentane (128). If desired, the normal hexane-containing permeate can be recycled for isomerization. The preferred membranes are sieving membranes having a C6 Permeate Flow Index of at least 0.01 and a C6 Permeate Flow Ratio of at least 1.25:1.
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: December 6, 2011
    Assignee: UOP LLC
    Inventors: Lynn H. Rice, David J. Shecterle
  • Publication number: 20110293495
    Abstract: A component part has a catalyst surface. This surface has metallic components and components of MnO2 (13) in contact with the former. The metallic components are preferably formed of Ag and/or Ni. These material pairs achieve a great improvement in catalyst action compared to the pure metals. Especially in the case of use of Ni, which is toxicologically safe, these surfaces, for example, may also find use in ambient air purification for reduction of the ozone content. The surface can be applied, for example, by a coating of the component part, in which case the metallic component and the component of MnO2 are applied in two layers.
    Type: Application
    Filed: November 9, 2009
    Publication date: December 1, 2011
    Inventors: Axel Arndt, Christian Doye, Jens Dahl Jensen, Ursus Krüger, Uwe Pyritz, Oliver Stier
  • Publication number: 20110291051
    Abstract: A reactor with minimal dead volume especially suited to reverse-flow applications comprises: a) a reactor body; b) a first head engaged with said reactor body; c) a first conduit extending from outside said head to at least partially through said head; and d) a first valve in flow communication with said first conduit controlling fluid flow along a flow path extending from the first valve and through the reactor body. The reactor is especially suited for use in a process for rapid stream-switching of at least two streams in a reverse-flow reactor.
    Type: Application
    Filed: May 6, 2011
    Publication date: December 1, 2011
    Inventors: Frank Hershkowitz, Richard John Basile, Jeffrey William Frederick, John William Fulton, Paul F. Keusenkothen, Bryan A. Patel, Andrew Richard Szafran
  • Patent number: 8066955
    Abstract: A processing apparatus that is formed from a plurality of metal layers that are stacked and aligned together and then connected together to form one or more portions of the processing apparatus.
    Type: Grant
    Filed: March 18, 2008
    Date of Patent: November 29, 2011
    Inventor: James M. Pinchot
  • Patent number: 8066946
    Abstract: Cassette based systems and methods of hydrogen storage, distribution, and recovery are taught. A cassette or other container may contain a hydrogen storage or storing material. Information may be stored in the material and subsequently read or accessed. A probe may be used to interrogate the material. The hydrogen content or other characteristics of the material may be determined based on the interrogation. A hydrogen dispensing unit may contain a depleted cassette acceptor to accept depleted cassettes and a charged cassette dispenser to dispense charged cassettes. The dispensing unit may be implemented in a hydrogen retail store or as a standalone unit. The retail store or the unit may connect to a hydrogen network and implement various business methods, as taught herein.
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: November 29, 2011
    Inventor: Scott D. Redmond
  • Patent number: 8062712
    Abstract: The invention relates to an amalgam decomposer for mercury cathode chlor-alkali cells. The amalgam decomposer of the invention contains a filling of carbon steel rings whose external surface is provided with a catalytic coating for amalgam decomposition consisting of one or more electrically conductive metals carbides. The internal surface of the rings is free of catalytic coating and wettable by the amalgam, while the external carbide catalytic coating is not wettable by the amalgam thereby favoring hydrogen evolution.
    Type: Grant
    Filed: October 10, 2008
    Date of Patent: November 22, 2011
    Assignee: Industrie De Nora S.p.A.
    Inventors: Giovanni Meneghini, Raffaello Bertin
  • Publication number: 20110281188
    Abstract: A preferential oxidation reactor for removing carbon monoxide in a hydrogen mixture gas is disclosed. The preferential oxidation reactor may include a housing having a catalytic layer provided therein, a mixture gas supply portion inserted into the interior of the housing and penetrating the catalytic layer, a condensate receiving portion contained within the housing and in fluid communication with a gas outlet port of the mixture gas supply portion and condensate control tubes arranged in the catalytic layer of the housing and in fluid communication with the condensate receiving portion. The condensate control tubes may have a capillary structure. A fuel cell system including the preferential oxidation reactor is also disclosed.
    Type: Application
    Filed: December 1, 2010
    Publication date: November 17, 2011
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Jong-Rock Choi, In-Huyk Son, Jin-Gco Ahn, Woo-Cheol Shin, In-Seob Song
  • Patent number: 8057559
    Abstract: The efficiency of dehydrogenation and that of hydrogenation are improved. A hydrogen generator for generating hydrogen by dehydrogenation of organic hydrides in the presence of a catalyst is characterized by comprising a reactor vessel (10) of a multi-tubular structure having a region (12) for supplying fuel to generate heat necessary for dehydrogenation, the region containing a combustion catalyst for combusting fuel, and a region (11) containing a dehydrogenation catalyst necessary for dehydrogenation, the regions being arranged radially side by side with a wall separating them.
    Type: Grant
    Filed: January 9, 2007
    Date of Patent: November 15, 2011
    Assignees: Hrein Energy, Inc.
    Inventors: Masaru Ichikawa, Katsumori Tanabe, Masashi Sakuramoto, Satoru Kikuchi, Yukimitsu Mita
  • Patent number: 8057743
    Abstract: Means for overcoming the problems which the conventional glass microchannel chips have are disclosed. That is, a microchannel chip in which microchannels can be formed at a low cost, and which has a high chemical resistance is disclosed. The microchannel chip is constituted by a substrate made of carbon, which has a channel in its surface; and a cover composed of a glass plate bonded to the substrate. The cover is bonded to the substrate by heating at least a part of the contact surface at which the substrate is in contact with the cover.
    Type: Grant
    Filed: June 13, 2008
    Date of Patent: November 15, 2011
    Assignees: Hipep Laboratories, Nippon Light Metal Company, Ltd.
    Inventors: Kiyoshi Nokihara, Yasuo Oka
  • Patent number: 8057749
    Abstract: A device for carrying out exothermal chemical reactions wherein a gas phase is guided across a fixed bed and allowed to react, comprising a housing and an exchangeable unit wherein the reaction takes place.
    Type: Grant
    Filed: September 18, 2006
    Date of Patent: November 15, 2011
    Assignee: Evonik Degussa GmbH
    Inventors: Achim Fischer, Harald Heinzel, Christoph Weckbecker, Klaus Huthmacher
  • Patent number: 8057560
    Abstract: A fuel processor having a movable burner, a method of operating the fuel processor, and a fuel cell system having the fuel processor. The fuel processor includes a combustion chamber, a reformer burner, a portion of which is partially disposed inside the combustion chamber, a reformer which is heated by heat transfer from the combustion chamber, and a burner-moving apparatus that moves the reformer burner with respect to the combustion chamber. The method of operating the fuel processor includes determining the load on and a plurality of temperatures within the fuel processor and moving the reformer burner depending upon such information.
    Type: Grant
    Filed: January 24, 2007
    Date of Patent: November 15, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Hyun-chul Lee, Soon-ho Kim, Doo-hwan Lee, Kang-hee Lee
  • Patent number: 8057575
    Abstract: Hydrogen-producing fuel processing systems, hydrogen purification membranes, hydrogen purification devices, fuel processing and fuel cell systems that include hydrogen purification devices, and methods for operating the same. In some embodiments, operation of the fuel processing system is initiated by heating at least the reforming region of the fuel processing system to at least a selected hydrogen-producing operating temperature. In some embodiments, an electric heater is utilized to perform this initial heating. In some embodiments, use of the electric heater is discontinued after startup, and a burner or other combustion-based heating assembly combusts a fuel to heat at least the hydrogen producing region, such as due to the reforming region utilizing an endothermic catalytic reaction to produce hydrogen gas.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: November 15, 2011
    Assignee: Idatech, LLC
    Inventors: David J. Edlund, William A. Pledger, R. Todd Studebaker
  • Patent number: 8057889
    Abstract: A method is disclosed for manufacturing an anisotropic material comprising providing a viscoplastic material having a yield stress, and a plurality of magnetic particles disposed therein, and then subjecting the viscoplastic material to a magnetic field for a time sufficient to at least partially align at least a portion of the magnetic particles to at least one of a predetermined position or orientation. Also disclosed is an article having anisotropic properties comprising a viscoplastic material, and a plurality of magnetic particles distributed therein and at least partially aligned to a predetermined orientation. An article having anisotropic properties, comprising a fixed viscoplastic material, and a plurality of magnetic particles distributed and at least partially anisotropically aligned in the fixed viscoplastic material is disclosed.
    Type: Grant
    Filed: May 21, 2007
    Date of Patent: November 15, 2011
    Assignee: Corning Incorporated
    Inventors: Andrey V Filippov, Charlotte Diane Milia
  • Patent number: 8052938
    Abstract: The present invention provides a reactor system having: (1) a first reactor receiving an oxygenate component and a hydrocarbon component and capable of converting the oxygenate component into a light olefin and the hydrocarbon component into alkyl aromatic compounds; (2) a separator system for providing a first product stream containing a C3 olefin, a second stream containing a C7 aromatic, and a third stream containing C8 aromatic compounds; (3) a first line connecting the separator to the inlet of the first reactor for conveying the second stream to the first reactor; (4) a second line in fluid communication with the separator system for conveying the C3 olefin to a propylene recovery unit, and (4) a third line in fluid communication with the separator system for conveying the C8 aromatic compounds to a xylene recovery unit.
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: November 8, 2011
    Assignee: UOP LLC
    Inventors: Andrea G. Bozzano, Timur V. Voskoboynikov, Tom N. Kalnes, Paul T. Barger, Gavin P. Towler, Bryan K. Glover
  • Patent number: 8052935
    Abstract: A system for removing sulfur from a gaseous stream includes (a) a reaction bed for receiving the gaseous stream and for reacting sulfur dioxide and at least some of the hydrogen sulfide of the gaseous stream into elemental sulfur to provide an elemental sulfur stream and a first product stream; and (b) a circulating fluidized bed comprising (i) a first region for receiving the first product stream and using a sulfur adsorption material to adsorb and remove any remaining hydrogen sulfide from the first product stream to generate saturated sulfur adsorption material and a second product stream substantially free of sulfur; and (ii) a second region for receiving a regeneration stream and for using the regeneration stream to regenerate the saturated sulfur adsorption material and to generate the sulfur dioxide.
    Type: Grant
    Filed: April 30, 2009
    Date of Patent: November 8, 2011
    Assignee: General Electric Company
    Inventors: Thomas Frederick Leininger, Ke Liu, Wei Wei, Rizeq George Rizeq
  • Patent number: 8052940
    Abstract: Provided are an apparatus for synthesizing carbon nanotubes, the apparatus including a reaction tube that provides a space for carbon nanotubes and is formed vertically long, a heating unit that is formed at the outer side of the reaction tube, and heats the reaction tube, a gas-supply unit that sprays reaction gas for synthesizing the carbon nanotubes by reacting with catalysts positioned inside the reaction tube, an exhaustion unit that is connected to the upper portion of the reaction tube, and discharges non-reacted reaction gas for synthesizing the carbon nanotubes, and a blocking unit that is formed inside the reaction tube, discharges only the non-reacted reaction gas for synthesizing the carbon nanotubes to the exhaustion unit, and blocks the discharge of the carbon nanotubes and catalysts, in which the cross-section of the blocking unit is divided in a plurality of polygon structures, and downward-slanted blocking wings are formed at each divided cell.
    Type: Grant
    Filed: September 29, 2009
    Date of Patent: November 8, 2011
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Chung-Heon Jeong, Jong-Kwan Jeon, Suk-Won Jang
  • Publication number: 20110268242
    Abstract: A recombination apparatus is provided to an off-gas system of a boiling water nuclear plant. An off-gas system pipe connected to a condenser is connected to the recombination apparatus. A catalyst layer filled with a catalyst for recombining hydrogen and oxygen is disposed in the recombination apparatus. The recombination catalyst has a percentage of the number of Pt particles whose diameters are in a range from more than 1 nm to not more than 3 nm to the numbers of Pt particles whose diameters are in a range from more than 0 nm to not more than 20 nm, falling within a range from 20 to 100%. The condenser discharges gas containing an organosilicon compound (ex. D5), hydrogen, and oxygen, which is introduced to the recombination apparatus. Use of the above recombination catalyst can improve the performance of recombining hydrogen and oxygen more than conventional catalysts and the initial performance of the catalyst can be maintained for a longer period of time.
    Type: Application
    Filed: April 27, 2011
    Publication date: November 3, 2011
    Applicants: Nikki-Universal Co., Ltd., Hitachi-GE Nuclear Energy, Ltd.
    Inventors: Hidehiro IIZUKA, Motohiro AIZAWA, Toru KAWASAKI, Hirofumi MATSUBARA, Takashi NISHI, Shuichi KANNO, Yasuo YOSHII, Yoshinori EBINA, Takanobu SAKURAI, Tsukasa TAMAI, Michihito ARIOKA
  • Publication number: 20110268612
    Abstract: A microchannel is disclosed. The present invention relates to a microchannel having a porous polymer inserted therein, more particularly, to a microchannel including a channel body and a porous polymer inserted in a surface of the channel body to be employed as a valve which can locally maximize a surface area of reaction between samples and reagents and which can control flow of a fluid in the microchannel.
    Type: Application
    Filed: December 21, 2009
    Publication date: November 3, 2011
    Inventor: Dae-Sung Hur
  • Publication number: 20110262309
    Abstract: In accordance with the present invention, there are provided simplified systems and methods for deactivating, removing, or reducing the levels of reactive component(s) from vapor phase fluids prior to introduction thereof into fuel storage tanks. The simple apparatus described herein can be utilized to replace complex systems on the market. Simply stated, in one embodiment of the invention, the vapor phase fluid contemplated for introduction into the fuel storage tank is passed through a reaction zone (e.g., a catalytic bed) operated at appropriate temperatures to allow the reaction between free reactive components therein (e.g., oxygen and hydrogen or other fuel vapor), thereby deactivating reactive component(s) in the gas phase.
    Type: Application
    Filed: August 20, 2008
    Publication date: October 27, 2011
    Inventors: Santosh Y. Limaye, Stuart Robertson, Donald Koenig, Wesley Jung
  • Patent number: 8043576
    Abstract: A reformer module (10) comprises a hollow support member (12) having at least one passage (14) extending longitudinally therethrough. The hollow support member (14) has an external surface (20), a barrier layer (22) arranged on at least a portion of the external surface (20) of the hollow support member (12), a catalyst layer (24) arranged on the barrier layer (22) and a sealing layer (26) arranged on the catalyst layer (24) and the external surface (20) of the hollow support member (12) other than the at least a portion of the external surface of the hollow support member (12). By providing the barrier layer (22) and the catalyst layer (24) on the exterior surface (20) of the hollow support member (12), the distribution of the barrier layer (22) and/or the catalyst layer (24) may be more precisely controlled and thus a non-uniform distribution of barrier layer (22) and/or catalyst layer (24) may be achieved.
    Type: Grant
    Filed: January 19, 2010
    Date of Patent: October 25, 2011
    Assignee: Rolls-Royce plc
    Inventors: Gerard D Agnew, Robert H Cunningham, Philip D Butler, Robert D Collins
  • Patent number: 8043577
    Abstract: With the help of a method and device for nozzle-jetting oxygen into a synthesis reactor, e.g. for oxy-dehydration, with largely axial flow of the gas mixture through a catalyst bed, it is intended to vastly improve the mixing-in and mixing-through of oxygen above the catalyst especially for oxy-dehydration process. This is achieved by feeding the oxygen to a ring distributor system arranged above the catalyst bed in pure form, as air or mixed with inert gas or water vapor and jetting the oxygen onto the catalyst surface through several exit openings in the ring distributor at an inclined angle deviating from the vertical.
    Type: Grant
    Filed: December 10, 2004
    Date of Patent: October 25, 2011
    Assignee: Uhde GmbH
    Inventors: Johannes Kowoll, Max Heinritz-Adrian, Lothar Semrau
  • Patent number: 8043575
    Abstract: A reactor system for the oxidation of ethylene to ethylene oxide. The reactor system includes a reactor tube that contains a packed bed of shaped support material that can include a catalytic component. The shaped support material has a hollow cylinder geometric configuration. The reactor system has specific combinations of reactor tube and catalyst system geometries.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: October 25, 2011
    Assignee: Shell Oil Company
    Inventors: Paul Michael McAllister, Alouisius Nicolaas Renee Bos, Michael Alan Richard, Dominicus Maria Rekers
  • Publication number: 20110257453
    Abstract: A method for the oxidative coupling of hydrocarbons includes providing an oxidative catalyst inside a reactor and carrying out the oxidative coupling reaction under a set of reaction conditions. The reactor surfaces that contact the reactants and products do not provide a significant detrimental catalyzing effect. In an embodiment the reactor contains an inert lining or a portion of the reactor inner surface is treated to reduce the detrimental catalytic effects. In an embodiment the reactor contains a lining that includes an oxidative catalyst.
    Type: Application
    Filed: April 20, 2010
    Publication date: October 20, 2011
    Applicant: Fina Technology, Inc.
    Inventors: Sivadinarayana Chinta, Joseph Thorman
  • Publication number: 20110256029
    Abstract: The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.
    Type: Application
    Filed: June 30, 2011
    Publication date: October 20, 2011
    Applicant: C-QUEST TECHNOLOGY, L.L.C.
    Inventor: Douglas C. Comrie
  • Patent number: 8038960
    Abstract: A reformer that produces reformed gas from a hydrocarbon material includes a reforming chamber having an inner cylinder and an outer cylinder; a reforming catalyst filled in the reforming chamber; a burner that heats the reforming catalyst and fuel of reformed gas; a combustion gas outer flow channel through which combustion gas of the burner flows along an outer side surface of the reforming chamber; a combustion gas inner flow channel through which the combustion gas of the burner flows along an inner side surface of the reforming chamber; and a plurality of return pipes as a reformed gas flow channel.
    Type: Grant
    Filed: January 24, 2005
    Date of Patent: October 18, 2011
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Kazuyuki Higashino
  • Patent number: 8038743
    Abstract: A supercritical water reformer (SCWR) and methods for using supercritical water to convert hydrocarbons, particularly hydrocarbon fuels such as diesel fuel or gasoline, into carbonaceous gases and hydrogen. The synthesis gas stream generated by the fuel reforming reaction can then be further refined to increase hydrogen content, and the resultant hydrogen can be utilized to power fuel cells.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: October 18, 2011
    Assignee: DRS Sustainment Systems, Inc.
    Inventors: John R. Wootton, Sunggyu Lee, Asdrubal Garcia-Ortiz
  • Patent number: 8038778
    Abstract: An apparatus (10) for purifying polluted air consisting of particle phase pollutants and gaseous phase pollutants, the apparatus (10) comprising: a dust level sensor (23) to measure the amount of particle phase pollutants in the polluted air; a dust removal component (14) to remove the particle phase pollutants from the polluted air; a catalyst filtering core (17) to decompose the gaseous phase pollutants by chemical reaction; a valve (22) for selectively controlling a path of air flow within the apparatus (10) and is movable between an open position and closed position, the valve (22) being positioned downstream from the dust removal component (14); wherein if the amount of particle phase pollutants measured by the dust level sensor (23) is above a predetermined value, the valve (22) is moved to the open position to enable the air to bypass the catalyst filtering core (17); and if the amount of particle phase pollutants measured by the dust level sensor (23) is less than a predetermined value, the valve (22)
    Type: Grant
    Filed: February 3, 2009
    Date of Patent: October 18, 2011
    Assignee: Akos Advanced Technology Ltd.
    Inventors: Yiu Wai Chan, Sui Chun Law
  • Patent number: 8039651
    Abstract: In the method of the present invention for producing fatty acid alkyl ester and/or glycerin, as a heat source for an alcohol refining step of refining alcohol from unreacted alcohol that remains without reacting in a first reaction step, at least a part of heat of the unreacted alcohol is used. This allows reducing costs in production of fatty acid alkyl ester and/or glycerin over a solid catalyst.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: October 18, 2011
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Masanori Nonoguchi, Hiroko Izumi, Atsushi Tachibana, Tomoharu Oku, Toshimitsu Moriguchi, Takeo Akatsuka, Izuho Okada, Hideaki Tsuneki, Hironori Horie
  • Patent number: 8038968
    Abstract: Embodiments are disclosed that relate to increasing a temperature in a low temperature zone in a steam reforming reactor via a radiative heating shunt. For example, one disclosed embodiment provides a steam reforming reactor comprising a reaction chamber having an interior surface, a packing material located within the reaction chamber, and a radiative heating shunt extending from the interior surface into the reaction chamber. The radiative heating shunt comprises a porous partition enclosing a sub-volume of the reaction chamber bounded by the porous partition and a portion of the interior surface, the sub-volume being at least partly free of packing material such that radiative heat has a path from the interior surface to a distal portion of the porous partition that is unobstructed by packing material.
    Type: Grant
    Filed: October 28, 2010
    Date of Patent: October 18, 2011
    Assignee: ClearEdge Power, Inc.
    Inventors: Bob Sorensen, Craig E. Evans, Brian Sonnichsen
  • Patent number: 8038961
    Abstract: Provided is an apparatus for preparing silanes of the general formula HnSiCU n where n=1, 2, 3 and/or 4 by dismutation of a chlorinated silane in the presence of a catalyst, wherein the apparatus includes: a distillation column having a column bottom, a column top, at least one feed inlet, a plurality of product offtakes, and a chimney tray; and a side reactor containing a catalyst bed having an upper edge, the side reactor being connected to the distillation column via at least three pipes including a first pipe, a second pipe, and a third pipe.
    Type: Grant
    Filed: July 21, 2005
    Date of Patent: October 18, 2011
    Assignee: Evonik Degussa GmbH
    Inventors: Raymund Sonnenschein, Peter Adler, Tim Pöpken, John Kahsnitz
  • Publication number: 20110245356
    Abstract: A bubble column reactor includes a reactor body which contains a slurry having solid catalyst particles suspended in a liquid, an inflow port which is provided at the bottom of the reactor body and allows a synthesis gas including a carbon monoxide gas and a hydrogen gas as the main components to flow into the slurry therethrough, and an outflow port which is provided at the top of the reactor body and allows gaseous hydrocarbons synthesized by a chemical reaction between the synthesis gas and the slurry, an unreacted synthesis gas, and the like to flow out therethrough. The distance in a vertical direction between the liquid surface of the slurry and the outflow port is 1.4 m or more and 10 m or less.
    Type: Application
    Filed: September 25, 2009
    Publication date: October 6, 2011
    Inventors: Yasuhiro Onishi, Yuzuru Kato, Eiichi Yamada, Atsushi Murata, Osamu Wakamura
  • Publication number: 20110243806
    Abstract: The present invention provides a Mo—Bi—Nb based composite metal oxide (with the proviso that Te is not included); a method for producing (meth)acrylic acid from at least one reactant selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, in which a Mo—Bi—Nb based composite metal oxide (with the proviso that Te is not included) is used as a catalyst; and a reactor used for producing (meth)acrylic acid from at least one reactant selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, in which a Mo—Bi—Nb based composite metal oxide (with the proviso that Te is not included) is used as a catalyst. Further, the present invention provides a method for producing the (meth)acrylic acid without any additional process of converting (meth)acrolein into (meth)acrylic acid.
    Type: Application
    Filed: April 7, 2011
    Publication date: October 6, 2011
    Inventors: Hyun-Jong Shin, Byung-Yul Choi, Yeon-Shick Yoo, Young-Jin Cho
  • Publication number: 20110243836
    Abstract: The present invention concerns a hydrogen gas-generating apparatus (10) comprising (1) a reservoir (100) comprising an aqueous component (110), (2) a fuel compartment (200) comprising a solid metal borohydride fuel component (210), and (3) a reaction chamber (300) comprising an aerogel catalyst (310). A first fluid path introduces the aqueous component into the fuel compartment where the solid metal borohydride fuel component is dissolved into a liquid metal borohydride fuel component (210?). A second fluid path introduces the liquid metal borohydride fuel component into the reaction chamber to produce a hydrogen gas by means of a hydride-water oxidation reaction that is accelerated by the aerogel catalyst. The temperature and/or pressure of the reaction chamber are predetermined to maintain the water in the borate byproduct to be substantially in the liquid phase to minimize the precipitation of the borate byproduct.
    Type: Application
    Filed: December 22, 2009
    Publication date: October 6, 2011
    Applicant: SOCIETE BIC
    Inventors: Michael Curello, Stepan Constance
  • Patent number: 8029748
    Abstract: The invention provides methods, apparatus and chemical systems for making vinyl acetate from ethylene, oxygen, and acetic acid.
    Type: Grant
    Filed: November 18, 2008
    Date of Patent: October 4, 2011
    Assignees: Velocys, Inc, Celanese International Corporation
    Inventors: Terry Mazanec, Victor J. Johnston, Michael Huckman, Sean P. Fitzgerald, James A. Foster, Daniel Lindley, Anna Lee Tonkovich, Francis P. Daly, Leslie Wade, Tony Hammock, Thomas Yuschak, Bin Yang, Kai Jarosch
  • Patent number: 8029737
    Abstract: A honeycomb filter for purifying exhaust gases includes columnar porous ceramic members and an adhesive layer combing the ceramic members with one another. Each porous ceramic member has a partition wall and through holes. The through holes are extending in parallel in length direction of the ceramic members. The partition wall is separating the through holes and filters particulates in exhaust gas. The through holes include ones sealed at inlet side of the ceramic members and ones sealed at outlet side of the ceramic members such that the exhaust gas enters from the inlet side, passes through the partition wall and flows out from the outlet side. The adhesive layer has thermal expansion coefficient ?L. The ceramic members have thermal expansion coefficient ?F. The thermal expansion coefficient ?L of the adhesive layer and the thermal expansion coefficient ?F of the ceramic members satisfy relationship, 0.01<|?L??F|/?F<1.0.
    Type: Grant
    Filed: February 5, 2003
    Date of Patent: October 4, 2011
    Assignee: Ibiden Co., Ltd.
    Inventors: Atsushi Kudo, Masafumi Kunieda
  • Patent number: 8029738
    Abstract: Methods and devices for removing inflammable gases produced by radiolysis in a closed chamber containing radioactive matters comprising organic compounds and possibly water, or radioactive matters in the presence of organic compounds and possibly water. Inside the chamber there may be placed a catalyst of at least one reaction for oxidizing the inflammable gases by oxygen contained in the chamber atmosphere, supported by an inert solid support; a catalyst of at least the reaction for oxidizing CO to CO2; possibly an oxygen source; and possibly a hygroscopic microporous inert solid support. Also, chambers for radioactive matters containing such devices.
    Type: Grant
    Filed: January 6, 2010
    Date of Patent: October 4, 2011
    Assignee: TN International
    Inventors: Pascale Abadie, Herve Issard
  • Patent number: 8025919
    Abstract: A catalyst filling method in a micro channel and a reformer manufactured by the method. The catalyst is filled in the micro channel using water, and unidirectional pressure is applied to the catalyst in the micro channel to fill the micro channel with high density. The catalyst in the micro channel is dried. The method according to the present invention allows uniformly filling the catalyst particles in the micro channel of the reformer with high density, increasing the reactive surface area of the catalyst particles with the fuel, thereby allowing highly efficient reforming effect.
    Type: Grant
    Filed: April 11, 2007
    Date of Patent: September 27, 2011
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Ji Won Ha, Young Soo Oh, Jae Hyuk Jang, Hong Ryul Lee, Jae Hyoung Gil, Sung Han Kim
  • Patent number: 8025858
    Abstract: The present invention relates to a process and apparatus for the production of light olefins comprising olefins having from 2 to 3 carbon atoms per molecule from a feedstock containing heavier olefins. An intermediate cut from a fractionation column is used as olefinic feed to an olefin cracking process preferably after undergoing selective hydrogenation of diolefins. In one embodiment, a liquid side draw from a fractionation column is selectively hydrogenated and then returned to the fractionation column from which a vapor side draw containing olefins is cracked in the olefin cracking reactor.
    Type: Grant
    Filed: July 26, 2007
    Date of Patent: September 27, 2011
    Assignee: UOP LLC
    Inventors: Douglas G. Stewart, Joseph E. Zimmermann, Angelo P. Furfaro, Bipin V. Vora
  • Publication number: 20110226664
    Abstract: A process for producing hydrocarbon products, comprising: a) operating a process unit in an alkylate mode wherein greater than 50 wt % of a C5+ hydrocarbon stream from the process unit boils at 137.8° C. or below, b) adjusting one or more process conditions in the process unit, and c) after the adjusting step, operating the process unit in a distillate mode wherein greater than 50 wt % of the C5+ hydrocarbon stream from the process unit boils above 137.8° C. Also, a process unit, comprising: a) an alkylation reactor; and b) a control system that enables the alkylation reactor to be operated in the alkylate mode and in the distillate mode; wherein the alkylation reactor can switch back and forth from operating in the alkylate mode to the distillate mode.
    Type: Application
    Filed: March 17, 2010
    Publication date: September 22, 2011
    Inventors: Hye-Kyung Timken, Shawn Winter, Howard S. Lacheen, Sven Ivar Hommeltoft
  • Publication number: 20110229379
    Abstract: The present invention provides a hydrogen separation membrane based on nanoporous, composite metal carbide or metal sulfide coated membranes capable of high flux and permselectivity for hydrogen without platinum group metals. The present invention is capable of being operated over a broad temperature range, including at elevated temperatures, while maintaining hydrogen selectivity.
    Type: Application
    Filed: March 22, 2011
    Publication date: September 22, 2011
    Inventors: J. Douglas Way, Colin A. Wolden
  • Publication number: 20110229383
    Abstract: In operating the carbon monoxide removal reactor or the fuel reforming system, there is provided a technique for removing carbon monoxide in a stable manner for an extended period of time. In a method of removing carbon monoxide including an introducing step of introducing a reactant gas including mixture gas and an oxidizer added thereto to a carbon monoxide removal reactor forming in its casing a catalyst layer comprising a carbon monoxide removal catalyst for removing carbon monoxide contained in the mixture gas and a removing step of removing the carbon monoxide by causing the oxidizer to react with the mixture gas on the carbon monoxide removal catalyst, in said introducing step, the reactant gas of 100° C. or lower is introduced to the carbon monoxide removal reactor.
    Type: Application
    Filed: May 31, 2011
    Publication date: September 22, 2011
    Applicant: OSAKA GAS CO., LTD.
    Inventors: Mitsuaki Echigo, Takeshi Tabata, Osamu Yamazaki
  • Publication number: 20110226669
    Abstract: A process comprising adjusting a level of conjunct polymers in an ionic liquid catalyst between a low level that favors production of C5+ products boiling at 137.8° C. or below and a higher level that favors production of both C5+ products boiling at 137.8° C. or below and C5+ products boiling above 137.8° C.; wherein the adjusting is done in response to market demand. A process unit, comprising a reactor that operates with an ionic liquid catalyst comprising a low level or a higher level of conjunct polymers, and the alkylation reactor is switched between operating with the low and the higher levels in response to market demand. A process unit, comprising a reactor that operates in an alkylate mode and a distillate mode, and a catalyst regenerator that operates with varying severity to adjust the level of conjunct polymers in response to demand for gasoline or distillate.
    Type: Application
    Filed: March 17, 2010
    Publication date: September 22, 2011
    Inventors: Hye-Kyung Timken, Shawn Winter, Howard S. Lacheen, Sven Ivar Hommeltoft
  • Patent number: 8021620
    Abstract: The process and apparatus converts ethylene in a dilute ethylene stream that may be derived from an FCC product to heavier hydrocarbons. The catalyst may be an amorphous silica-alumina base with a Group VIII and/or VIB metal. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, hydrogen and ammonia. At least 40 wt-% of the ethylene in the dilute ethylene stream can be converted to heavier hydrocarbons.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: September 20, 2011
    Assignee: UOP LLC
    Inventors: Christopher P. Nicholas, Alakananda Bhattacharyya, David E. Mackowiak
  • Patent number: 8021622
    Abstract: Disclosed is a heat insulating container, including a heat source, a housing that houses the heat source therein and a temperature detection unit that is formed on a surface of the housing and reflects radiation.
    Type: Grant
    Filed: August 28, 2007
    Date of Patent: September 20, 2011
    Assignee: Casio Computer Co., Ltd.
    Inventor: Masatoshi Nomura
  • Patent number: 8021447
    Abstract: Hydrogen-producing fuel processing assemblies for producing hydrogen gas. The assemblies include a catalyst chamber, a heat source adapted to heat the catalyst chamber, a hydrogen-producing region within the catalyst chamber adapted to produce hydrogen gas from a feed stream, and a conductive guide structure within the catalyst chamber adapted to conduct and distribute heat from the heat source within the hydrogen-producing region and to direct fluid through the hydrogen-producing region. In some embodiments, the conductive guide structure includes a helical member. In some embodiments, the assembly further includes a vaporization region within the catalyst chamber. In some embodiments, the fuel processing assembly is adapted to produce hydrogen gas via a steam reforming or other endothermic reaction.
    Type: Grant
    Filed: July 30, 2008
    Date of Patent: September 20, 2011
    Assignee: Idatech, LLC
    Inventors: Vernon Wade Popham, Robert A. Sorensen, Kyle Taylor
  • Publication number: 20110223412
    Abstract: The invention concerns a nanowire structural element which is suited for implementation in, for example, a microreactor system or microcatalyzer system. For the production of the nanowire structural element, a template based process is used wherein the electrochemical deposition of the nanowires in nanopores is ideally carried out at least until caps are formed and said caps ideally are at least partially merged together. After reinforcing the two cover layers the structured hollow chamber between the two cover layers is cleared by dissolving the template foil and removing the dissolved template material, wherein the two cover layers remain intact. In this manner, a stable sandwich-like nanostructure is constructed with a two-dimensional hollow chamber-like structure in the plane parallel to the cover layers contained on both sides by the cover layers and permeated in a column-like manner with nanowires.
    Type: Application
    Filed: March 12, 2009
    Publication date: September 15, 2011
    Inventors: Thomas Cornelius, Wolfgang Ensinger, Reinhard Neumann, Markus Rauber
  • Patent number: 8017088
    Abstract: A fuel reformer including a first pipe, a second pipe which is disposed in the first pipe, a main heat source, which includes an oxidation catalyst, filling the second pipe adapted to generate thermal energy with a predetermined temperature range through an oxidation reaction of a fuel using the oxidation catalyst; an auxiliary heat source which includes a torch connected to the second pipe to ignite and burn the gaseous fuel, thereby preheating the oxidation catalyst to within a reaction starting temperature range, and a reforming reaction unit which includes a reforming catalyst filling a space between the first and second pipes to generate a reforming gas containing hydrogen through the reforming reaction of the fuel using the reforming catalyst by using the thermal energy generated by the main heat source.
    Type: Grant
    Filed: September 27, 2006
    Date of Patent: September 13, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Sung-Chul Lee, Ju-Yong Kim, Chan-Ho Lee, Dong-Myung Suh, Jin-Kwang Kim, Jin-Goo Ahn, Man-Seok Han, Yong-Kul Lee, Dong-Uk Lee, Leonid Gorobinskiy
  • Patent number: 8017090
    Abstract: Phosphine gas is generated by agitating a reaction mixture of a metal phosphide and water with agitation air in a reaction pot of a phosphine gas generator. The resulting phosphine gas is then diluted with dilution air to produce a fumigant phosphine gas which is directly delivered to a commodity for fumigation. The reaction pot does not have any rotating means such as agitators, rotors, or stirrers. The generator provides on-site generation of phosphine gas in a rapid manner improving the fumigation efficiency for a commodity, such as grain, preferably contained within a storage structures, such as a grain silo. The generator has a built in deactivation system for the unused metal phosphide and phosphine gas.
    Type: Grant
    Filed: May 21, 2009
    Date of Patent: September 13, 2011
    Assignee: United Phosphorus Ltd.
    Inventors: Shroff Rajnikant Devidas, Pushpaksen P. Asher