Include Electrolyte Chemically Specified And Method Patents (Class 429/188)
  • Patent number: 8753532
    Abstract: The invention relates to a LiaNixCoyMny?M?zO2 composite oxide for use as a cathode material in a rechargeable battery, with a non-homogenous Ni/M? ratio in the particles, allowing excellent power and safety properties when used as positive electrode material in Li battery. More particularly, in the formula 0.9<a<1.1, 0.3?x?0.9, 0<y?0.4, 0<y??0.4, 0<z?0.35, e<0.02, 0?f?0.05 and 0.9<(x+y+y?+z+f)<1.1; M? consists of either one or more elements from the group Al, Mg, Ti, Cr, V, Fe, Mn and Ga; N consists of either one or more elements from the group F, Cl, S, Zr, Ba, Y, Ca, B, Sn, Sb, Na and Zn. The powder has a particle size distribution defining a D10, D50 and D90; and the x and z parameters varying with the particles size of the powder, and is characterized in that either one or both of: x1?x2?0.005 and z2?z1?0.
    Type: Grant
    Filed: August 15, 2011
    Date of Patent: June 17, 2014
    Assignee: Umicore
    Inventors: Stephane Levasseur, Philippe Carlach, Randy De Palma, Michèle Van Thournout
  • Publication number: 20140159668
    Abstract: An anode electrode for an energy storage device includes both an ion intercalation material and a pseudocapacitive material. The ion intercalation material may be a NASICON material, such as NaTi2(PO4)3 and the pseudocapacitive material may be an activated carbon material. The energy storage device also includes a cathode, an electrolyte and a separator.
    Type: Application
    Filed: August 21, 2013
    Publication date: June 12, 2014
    Applicant: Aquion Energy Inc.
    Inventors: Jay Whitacre, Alex Mohamed, Andrew Polonsky, Sneha Shanbhag, Kristen Carlisle
  • Publication number: 20140162143
    Abstract: It is an object of the present invention to provide an electrochemical device having an electrolytic solution having high current density and high oxidation resistance, as well as high safety, where dissolution and deposition of magnesium progress repeatedly and stably. The present invention relates to the electrolytic solution for an electrochemical device comprising (1) the supporting electrolyte composed of a magnesium salt and (2) at least one or more kinds of the compound represented by the following general formula [2], as well as the electrochemical device comprising said electrolytic solution, a positive electrode, a negative electrode and a separator.
    Type: Application
    Filed: July 26, 2012
    Publication date: June 12, 2014
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Tsutomu Watahiki, Takahiro Kiyosu, Kuniaki Okamoto
  • Publication number: 20140162117
    Abstract: According to the embodiment, there is provided a nonaqueous electrolyte secondary battery comprising a positive electrode; a negative electrode including a negative electrode active material layer; and a nonaqueous electrolyte. The negative electrode active material layer contains carbon dioxide and releases the carbon dioxide in the range of 0.01 ml to 3 ml per 1 g when heated at 400° C. for 1 minute. The nonaqueous electrolyte contains carbon dioxide of 50 ml/L to 1000 ml/L.
    Type: Application
    Filed: February 14, 2014
    Publication date: June 12, 2014
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Shinsuke Matsuno, Hidesato Saruwatari, Dai Yamamoto, Asato Kondo
  • Patent number: 8748046
    Abstract: An embodiment lithium-ion battery comprising a lithium-ion electrolyte of ethylene carbonate; ethyl methyl carbonate; and at least one solvent selected from the group consisting of trifluoroethyl butyrate, ethyl trifluoroacetate, trifluoroethyl acetate, methyl pentafluoropropionate, and 2,2,2-trifluoroethyl propionate. Other embodiments are described and claimed.
    Type: Grant
    Filed: January 25, 2008
    Date of Patent: June 10, 2014
    Assignees: California Institute of Technology, University of Southern California
    Inventors: Marshall C. Smart, Ratnakumar V. Bugga, G. K. Surya Prakash, Kiah Smith, Pooja Bhalla
  • Publication number: 20140152269
    Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.
    Type: Application
    Filed: February 9, 2014
    Publication date: June 5, 2014
    Applicant: ASAHI KASEI KABUSHIKI KAISHA
    Inventors: Vinay Bhat, Gang Cheng, Steven Kaye, Bin Li, Risa Olugbile, Jen-Hsien Yang
  • Publication number: 20140154588
    Abstract: A method for preparing an ionic liquid nanoscale ionic material, the ionic liquid nanoscale ionic material and a battery that includes a battery electrolyte that comprises the ionic liquid nanoscale ionic material each provide superior performance. The superior performance may be manifested within the context of inhibited lithium dendrite formation.
    Type: Application
    Filed: July 10, 2012
    Publication date: June 5, 2014
    Applicant: CORNELL UNIVERSITY
    Inventors: Lynden A. Archer, Surya S. Moganty, Yingying Lu
  • Publication number: 20140154592
    Abstract: An electrolyte for a magnesium battery includes a magnesium salt having the formula MgBxHy where x=11?12 and y=11?12. The electrolyte also includes a solvent, the magnesium salt being dissolved in the solvent. Various solvents including aprotic solvents and molten salts such as ionic liquids may be utilized.
    Type: Application
    Filed: March 15, 2013
    Publication date: June 5, 2014
    Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventor: Toyota Motor Engineering & Manufacturing North America, Inc
  • Publication number: 20140154587
    Abstract: The present invention provides a nonaqueous electrolytic solution capable of improving electrochemical characteristics in a broad temperature range, such as low-temperature cycle properties and low-temperature discharge properties after high-temperature storage, and provides an energy storage device using the nonaqueous electrolytic solution. The invention includes (1) a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which comprises from 0.001 to 10% by mass of a compound represented by the following general formula (I), and (2) an energy storage device comprising a positive electrode, a negative electrode, and a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, wherein the nonaqueous electrolytic solution is the nonaqueous electrolytic solution of (1).
    Type: Application
    Filed: August 7, 2012
    Publication date: June 5, 2014
    Applicant: UBE INDUSTRIES, LTD
    Inventors: Koji Abe, Kei Shimamoto
  • Patent number: 8741479
    Abstract: An electrolyte for a lithium secondary battery including a lithium salt, a nonaqueous organic solvent, and an additive, in which the additive is composed of one or more compounds including a purinone or a purinone derivative. The lithium secondary battery with improved life and high-temperature storage may be provided by using the electrolyte for a lithium secondary battery according to an embodiment of the present invention.
    Type: Grant
    Filed: March 28, 2012
    Date of Patent: June 3, 2014
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Yoon-sok Kang, Jun-young Mun, Min-sik Park, Jin-hwan Park, Mi-jeong Song
  • Publication number: 20140147738
    Abstract: An electrode composite material is disclosed in the invention. The electrode composite material comprises ABxCyDz, wherein A is selected from at least one of polypyrrole, polyacrylonitrile, and polyacrylonitrile copolymer; B comprises sulfur; C is selected from carbon material; D is selected from metal oxides, l?x?20, 0?y<l, and 0?z<1. Comparing to the prior art, the conductivity of the electrode composite material is obviously increased, the material is dispersed uniformly and the size of the material is small. The electrochemical performance of the electrode composite material is improved. It has a good cycle life and high discharging capacity efficiency. A method for manufacturing the electrode composite material, a positive electrode using the electrode composite material and a battery including the same are also disclosed in the invention.
    Type: Application
    Filed: December 11, 2013
    Publication date: May 29, 2014
    Applicant: POSITEC POWER TOOLS (SUZHOU) CO., LTD
    Inventors: Pu Chen, Yongguang Zhang, Zhumabay Bakenov, Aishuak Konarov, The Nam Long Doan
  • Publication number: 20140147740
    Abstract: Provided is a positive electrode active material for a nonaqueous electrolyte secondary battery in which generation of gas resulting from a reaction between a lithium transition metal complex oxide and an electrolyte is suppressed even when the battery is stored at high temperature, thereby improving the reliability of the battery, suppressing deterioration of the lithium transition metal complex oxide, and suppressing the decrease in battery capacity. In the positive electrode active material, a compound containing zirconium and fluorine is attached to a surface of lithium cobaltate. This positive electrode active material can be produced by spraying a solution containing zirconium and fluorine onto lithium cobaltate while stirring lithium cobaltate.
    Type: Application
    Filed: July 27, 2012
    Publication date: May 29, 2014
    Applicant: SANYO ELECTRIC CO., LTD.
    Inventors: Takao Kokubu, Hiroyuki Matsumoto, Takeshi Ogasawara
  • Publication number: 20140147739
    Abstract: According to an embodiment, a nonaqueous electrolyte secondary battery including a positive electrode, a negative electrode containing a lithium titanium composite oxide having a spinel structure as a negative electrode active material, and a nonaqueous electrolyte, wherein the lithium titanium composite oxide that is the negative electrode active material has an average particle size based on a mass basis of 0.3 ?m or more but 0.9 ?m or less, and a lithium carbonate content rate of the negative electrode is 0.1% by mass or less per mass of the negative electrode active material, is provided.
    Type: Application
    Filed: January 31, 2014
    Publication date: May 29, 2014
    Applicant: Kabushiki Kaisha Toshiba
    Inventors: Hiroshi NAKAGAWA, Hidesato SARUWATARI, Masataka SHIKOTA, Kazuko NEWTON, Kazuya KURIYAMA
  • Publication number: 20140147754
    Abstract: A magnesium battery electrolyte with a wide electrochemical window was developed. The electrolyte includes an organic boron magnesium salt and an aprotic polar solvent. The organic boron magnesium salt is an organic boron magnesium salt complex formed by compounding a Lewis acid with a boron center and a magnesium-containing Lewis base R?2-nMgXn, wherein n is 0 or 1, R and R? respectively represent a fluoroaryl group, an alkylated aryl group, an aryl group, an alkyl group, or a pyrrolidinyl group, and X represents a halogen. The solvent is an aprotic polar solvent such as ether or a mixed solvent thereof. The concentration of the electrolyte is 0.25 to 1 mol/L, and the electric conductivity is 0.5 to 10 mS/cm. The electrolyte allows reversible deposition/dissolution of magnesium, features good cycling stability, and has a wide electrochemical window (>3.0V vs.Mg/Mg2+).
    Type: Application
    Filed: July 30, 2012
    Publication date: May 29, 2014
    Applicants: SHANGHAI JIAO TONG UNIVERSITY, TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Jun Yang, Yongsheng Guo, Fan Zhang, Feifei Wang
  • Patent number: 8734984
    Abstract: When a bipolar battery is manufactured, a bipolar electrode and a separator are prepared first. Then, one electrode (for example, a positive electrode) out of positive and negative electrodes is applied with such an amount of electrolyte as being exposed on a surface of the one electrode. Then, the separator is arranged on the surface of the one electrode applied with the electrolyte, thus forming a sub-assembly unit. Then, a plurality of the sub-assembly units are layered, and the electrolyte applied to the one electrode is made to permeate through the separator to the other electrode, thus forming an assembly unit.
    Type: Grant
    Filed: October 20, 2008
    Date of Patent: May 27, 2014
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Gen Takayama, Kenji Hosaka, Teruo Segawa, Hajime Satou, Hideaki Horie, Takahiro Iwasaki, Yoshio Shimoida
  • Patent number: 8735002
    Abstract: An electrochemical cell including at least one nitrogen-containing compound is disclosed. The at least one nitrogen-containing compound may form part of or be included in: an anode structure, a cathode structure, an electrolyte and/or a separator of the electrochemical cell. Also disclosed is a battery including the electrochemical cell.
    Type: Grant
    Filed: September 7, 2011
    Date of Patent: May 27, 2014
    Assignee: Sion Power Corporation
    Inventors: Chariclea Scordilis-Kelley, Joseph Kubicki, Shuguang Cao, Yuriy V. Mikhaylik
  • Patent number: 8734668
    Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.
    Type: Grant
    Filed: October 5, 2012
    Date of Patent: May 27, 2014
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Vinay Bhat, Gang Cheng, Steven Kaye, Bin Li, Risa Olugbile, Jen-Hsien Yang
  • Publication number: 20140141323
    Abstract: According to one embodiment, there is provided an electrode. The nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, a separator provided between the positive electrode and the negative electrode, and a nonaqueous electrolyte. The negative electrode contains as an active material a titanium composite oxide. A lithium absorption/release reaction potential of the titanium composite oxide is higher than 0.5 V vs. Li/Li+. The nonaqueous electrolyte contains at least one element selected from B and S.
    Type: Application
    Filed: January 27, 2014
    Publication date: May 22, 2014
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Hidesato SARUWATARI, Hiromichi Kuriyama, Shinsuke Matsuno, Dai Yamamoto
  • Publication number: 20140141322
    Abstract: Disclosed is a positive active material composition that includes a positive active material and an additive represented by the following Chemical Formula 1. L1-A1-L2-A2-L3-A3-(L5-A5)n-L4-A4??[Chemical Formula 1] In Chemical Formula 1, each substituent is the same as described in the detailed description.
    Type: Application
    Filed: March 11, 2013
    Publication date: May 22, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventor: Dae-Sik Kim
  • Publication number: 20140141342
    Abstract: The present invention relates to an electrolyte for a lithium secondary battery and a lithium secondary battery including the same, wherein the electrolyte comprises an organic solvent and an electrolyte additive, represented by chemical formula 1 and mixed lithium salts in the organic solvent so that room and high temperature life-time properties of the battery can be improved. Said chemical 1 is defined in the specification.
    Type: Application
    Filed: July 12, 2012
    Publication date: May 22, 2014
    Inventors: Hyeong Kyu Lim, Hong Hie Lee, Eun Gi Shim, Jong Su Kim, Chang Sin Lee, Kyung Il Park, Hahn Mok Song
  • Patent number: 8728650
    Abstract: An apparatus for enhancing impregnation of the electrolyte in a secondary battery includes a tray in which at least one battery cell is received, and an oscillation and rotation unit capable of oscillating and rotating the tray simultaneously.
    Type: Grant
    Filed: November 6, 2012
    Date of Patent: May 20, 2014
    Assignee: LG Chem, Ltd.
    Inventors: In-Jung Kim, Jong-Hee Kim, Hyung-Kyu Lim, In-Seok Yang, Seok-Jung Park
  • Patent number: 8728669
    Abstract: A nonaqueous electrolyte battery includes a positive electrode, a negative electrode and a nonaqueous electrolyte. The positive electrode contains active material particles and a coating material. The active material particles are represented by any one of the following formulae (1) to (3): LixM1yO2??(1) LizM22wO4??(2) LisM3tPO4??(3) and have an average particle diameter of 0.1 to 10 ?m. The coating material comprises at least particles having an average particle diameter of 60 nm or less or layers having an average thickness of 60 nm or less. The particles or the layers contain at least one element selected from the group consisting of Mg, Ti, Zr, Ba, B and C.
    Type: Grant
    Filed: February 21, 2013
    Date of Patent: May 20, 2014
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Norio Takami, Hiroki Inagaki, Keigo Hoshina
  • Patent number: 8728657
    Abstract: An object of the present invention is to provide: a production method for commercially advantageously producing lithium difluorophosphate or an electrolyte solution containing the lithium difluorophosphate, the lithium difluorophosphate serving as an additive useful for improving performance of a nonaqueous electrolyte battery; and a nonaqueous electrolyte battery employing the electrolyte solution for the nonaqueous electrolyte battery which solution contains the lithium difluorophosphate produced by the production method. To provide an electrolyte solution for a nonaqueous electrolyte battery which solution contains lithium difluorophosphate, in such a manner as to produce lithium difluorophosphate in the electrolyte solution by reacting a halide other than a fluoride, LiPF6 and water in a nonaqueous solvent, the lithium difluorophosphate serving as an additive useful for improving performance of the nonaqueous electrolyte battery.
    Type: Grant
    Filed: February 19, 2008
    Date of Patent: May 20, 2014
    Assignee: Central Glass Company, Limited
    Inventors: Shoichi Tsujioka, Aiichiro Fujiwara, Toshinori Mitsui
  • Patent number: 8728670
    Abstract: The invention provides a nonaqueous-electrolyte battery which has a positive electrode 3 including a positive active material, a negative electrode 4 including a negative active material having a lithium insertion/release potential higher than 1.0 V (vs. Li/Li+), and a nonaqueous electrolyte, wherein an organic compound having one or more isocyanato groups has been added to the nonaqueous electrolyte.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: May 20, 2014
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hiroki Inagaki, Norio Takami
  • Publication number: 20140134500
    Abstract: An anode and a battery, which have a high capacity and can improve battery characteristics such as large current discharge characteristics and low temperature discharge characteristics are provided. An anode has an anode current collector and an anode active material layer provided on the anode current collector. The density of the anode active material layer is in the range from 1.5 g/cm3 to 1.8 g/cm3. Further, the anode active material layer contains a granulated graphite material which is obtained by granulating a flat graphite particle in nodular shape and mesocarbon microbeads. Thereby, the granulated graphite material is prevented from being destroyed, and diffusion path of lithium ions is secured.
    Type: Application
    Filed: January 17, 2014
    Publication date: May 15, 2014
    Applicant: SONY CORPORATION
    Inventor: Gentaro KANO
  • Publication number: 20140134501
    Abstract: This invention relates to electrolytic solutions and secondary batteries containing same. The electrolytic solutions contain (a) one or more ionic salts; (b) one or more non-aqueous solvents; (c) at least one solid electrolyte interphase former; (d) at least one fluorinated compound; and (e), optionally, at least one high temperature stability compound. Components (c), (d) and (e) are each different compounds and each are different from the ionic salts (a) and solvents (b).
    Type: Application
    Filed: November 12, 2012
    Publication date: May 15, 2014
    Applicant: NOVOLYTE TECHNOLOGIES, INC.
    Inventors: Jing Li, Martin W. Payne
  • Publication number: 20140134502
    Abstract: An electrolyte for a lithium secondary battery, the electrolyte including a lithium salt; a nonaqueous organic solvent; and an additive composition, wherein the additive composition comprises at least one of a first compound of Formula 1 and a second compound of Formula 2: wherein A1, A2, C1 to C4, R1 to R4, X1 to X4, Y1 to Y4, Z1 to Z4, L1, L2, p, and q are defined in the specification.
    Type: Application
    Filed: July 30, 2013
    Publication date: May 15, 2014
    Applicants: SAMSUNG FINE CHEMICALS CO., LTD., SAMSUNG SDI CO., LTD.
    Inventors: Yoon-sok KANG, Min-sik PARK, Jun-young MUN
  • Publication number: 20140134481
    Abstract: Disclosed is a nonaqueous electrolytic solution which forms a nonaqueous-electrolyte battery having high capacity and excellent storage characteristics at high temperatures, while sufficiently enhancing safety at the time of overcharge, and a nonaqueous-electrolyte battery using the same. The nonaqueous electrolytic solution has an electrolyte and a nonaqueous solvent with (A) a compound of formula (2): wherein R7 is an optionally halogenated and/or phenylated alkyl group comprising 1-12 carbon atoms, R8 to R12 are independently a hydrogen atom, a halogen atom, an optionally halogenated ether or alkyl group comprising 1-12 carbon atoms, and at least one of R8 to R12 is an optionally halogenated alkyl group comprising 2-12 carbon atoms; and/or (B) a carboxylic acid ester with a phenyl group substituted by at least one alkyl group (having 4 or more carbon atoms) that is optionally substituted.
    Type: Application
    Filed: January 17, 2014
    Publication date: May 15, 2014
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Yumiko NAKAGAWA, Minoru Kotato, Daisuke Noda, Shinichi Kinoshita
  • Publication number: 20140134480
    Abstract: Disclosed are an additive for a rechargeable lithium battery electrolyte including an aromatic compound having an isothiocyanate group (—NCS), and an electrolyte and rechargeable lithium battery including the same.
    Type: Application
    Filed: March 14, 2013
    Publication date: May 15, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Makhmut Khasanov, Woo-Cheol Shin, Denis Chernyshov, Alexey Tereshchenko, Vladimir Egorov, Pavel Shatunov
  • Publication number: 20140134477
    Abstract: A nonaqueous electrolyte secondary battery according to an embodiment includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The negative electrode contains a negative electrode active material. A lithium insertion-extraction reaction potential of a negative electrode active material is higher than the oxidation-reduction potential of lithium by a value of 1 V or more. The nonaqueous electrolyte contains an electrolytic salt, a nonaqueous solvent, at least one hydroxyalkylsulfonic acid, and at least one sulfonate.
    Type: Application
    Filed: January 29, 2014
    Publication date: May 15, 2014
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Hiromichi KURIYAMA, Hidesato SARUWATARI, Kazuya KURIYAMA, Shinsuke MATSUNO
  • Publication number: 20140134499
    Abstract: Disclosed are functionalized Group IVA particles, methods of preparing the Group IVA particles, and methods of using the Group IVA particles. The Group IVA particles may be passivated with at least one layer of material covering at least a portion of the particle. The layer of material may be a covalently bonded non-dielectric layer of material. The Group IVA particles may be used in various technologies, including lithium ion batteries and photovoltaic cells.
    Type: Application
    Filed: August 21, 2013
    Publication date: May 15, 2014
    Inventors: Timothy D. Newbound, Leslie Matthews, Jeff A. Norris
  • Patent number: 8722243
    Abstract: An inventive electrolyte material contains a lithium salt comprising the following components (A1) and (B), or contains the following components (A1), (A2) and (B): (A1) a lithium cation; (A2) an organic cation; and (B) a cyanofluorophosphate anion represented by the following general formula (1): ?P(CN)nF6-n??(1) wherein n is an integer of 1 to 5. The inventive electrolyte material is excellent in electrochemical properties, i.e., has a higher electrical conductivity and a higher oxidation potential, and is capable of forming an electrode protection film, so that a highly safe lithium secondary battery can be provided.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: May 13, 2014
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventors: Ryouta Tatsumi, Yasuhiro Aoki, Seiji Maeda, Mio Miyano, Seiichirou Hayakawa
  • Patent number: 8722242
    Abstract: A magnesium battery, having an anode containing magnesium; a cathode stable to a voltage of at least 2.6 V relative to a magnesium reference; and an electrolyte containing an electrochemically active magnesium salt obtained by reaction of a Grignard reagent or Hauser base with a boron compound of formula BR3 is provided. The electrolyte is stable to 2.6 E.V. vs. Mg in the presence of stainless steel.
    Type: Grant
    Filed: August 4, 2011
    Date of Patent: May 13, 2014
    Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventors: John Muldoon, Claudiu Bogdan Bucur
  • Publication number: 20140127556
    Abstract: A lithium salt is disclosed. The lithium salt includes a lithium ion and an anion represented by formula (I), wherein R1 to R5 are independently selected from hydrogen atom, cyano group, fluorine atom, and C1-C5 alkyl group, in which the C1-C5 alkyl group is substituted with at least one fluorine atom. The present invention further provides an electrolyte solution and a lithium battery containing the lithium salt to enable a high conductivity of the battery at a high temperature.
    Type: Application
    Filed: October 30, 2013
    Publication date: May 8, 2014
    Applicant: China Petrochemical Development Corporation, Taipei (Taiwan)
    Inventor: Fu-Ming Wang
  • Publication number: 20140125292
    Abstract: The present invention generally relates to lithium based energy storage devices. According to the present invention there is provided a lithium energy storage device comprising: at least one positive electrode; at least one negative electrode; and an ionic liquid electrolyte comprising an anion, a cation counterion and lithium mobile ions, wherein the anion comprises a nitrogen, boron, phosphorous, arsenic or carbon anionic group having at least one nitrile group coordinated to the nitrogen, boron, phosphorous, arsenic or carbon atom of the anionic group.
    Type: Application
    Filed: October 28, 2013
    Publication date: May 8, 2014
    Applicants: MONASH UNIVERSITY, COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
    Inventors: Adam Samuel Best, George Hamilton Lane
  • Publication number: 20140127590
    Abstract: A nonaqueous electrolytic solution effective in improving cycle characteristics and used for a nonaqueous electrolyte secondary battery including a positive electrode having a positive-electrode active material capable of storing and releasing metal ions and a negative electrode having a negative-electrode active material containing at least one atom selected from the group consisting of Si, Sn, and Pb includes an electrolyte, a nonaqueous solvent, and an isocyanate compound having at least one aromatic ring in its molecule.
    Type: Application
    Filed: January 13, 2014
    Publication date: May 8, 2014
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Youichi OHASHI, Takashi Fujii, Shinichi Kinoshita, Martin Winter, Michael Sternad
  • Publication number: 20140127560
    Abstract: An electrochemical apparatus (e.g. a battery (cell)) including an aqueous electrolyte and one or two electrodes (e.g., an anode and/or a cathode), one or both of which includes a Prussian Blue analogue (PBA) material of the general chemical formula AxP[R(CN)6-jLj]z.nH2O, where: A is a cation; P is a metal cation; R is a transition metal cation; L is a ligand that may be substituted in the place of a CN? ligand; 0?x?2; 0?z?1; and 0?n?5, one or both electrodes including a PBA coating to decrease capacity loss.
    Type: Application
    Filed: May 13, 2013
    Publication date: May 8, 2014
    Applicant: ALVEO ENERGY, INC.
    Inventors: Colin Deane Wessells, Robert Alan Huggins
  • Publication number: 20140127592
    Abstract: An electrochemical device (e.g., a battery (cell)) including: an aqueous electrolyte and one or two electrodes (e.g., an anode and/or a cathode), one or both of which is a Prussian Blue analogue material of the general chemical formula AxP[R(CN)6-jLj]z.nH2O, where: A is a cation; P is a metal cation; R is a transition metal cation; L is a ligand that may be substituted in the place of a CN? ligand; 0?x?2; 0?z?1; and 0?n?5, the electrode including a polymer coating to reduce capacity loss.
    Type: Application
    Filed: May 13, 2013
    Publication date: May 8, 2014
    Applicant: ALVEO ENERGY, INC.
    Inventors: Colin Deane Wessells, Robert Alan Huggins
  • Publication number: 20140127591
    Abstract: An electrochemical apparatus (e.g., a battery (cell)) including an aqueous electrolyte with electrode stabilizing additives and one or two electrodes (e.g., an anode and/or a cathode), one or both of which is a Prussian Blue analogue material of the general chemical formula AxP[R(CN)6-jLj]z.nH2O, where: A is a cation; P is a metal cation; R is a transition metal cation, L is a ligand that may be substituted in the place of a CN? ligand; 0?x?2; 0?z?1; and 0?n?5 with the electrolyte including an additive to reduce capacity loss of the electrode(s).
    Type: Application
    Filed: May 13, 2013
    Publication date: May 8, 2014
    Applicant: Alveo Energy, Inc.
    Inventors: Colin Deane Wessells, Robert Alan Huggins
  • Publication number: 20140127561
    Abstract: To provide a high-capacity non-aqueous electrolyte secondary battery with superior output characteristics and durability. The present invention is a non-aqueous electrolyte secondary battery including a negative electrode and a non-aqueous electrolyte, the non-aqueous electrolyte secondary battery characterized in that the non-aqueous electrolyte includes lithium bis(oxalato)borate, the negative electrode has a negative electrode core and a negative electrode active material layer formed on the negative electrode core, and the negative electrode active material is graphite particles having a D90/D10 ratio of three or more, D10 being the 10% particle size and D90 being the 90% particle size in a cumulative particle size distribution of the volume standard of the graphite particles.
    Type: Application
    Filed: July 16, 2013
    Publication date: May 8, 2014
    Inventors: Shinichi Yamami, Toshikazu Yoshida, Toyoki Fujihara, Toshiyuki Nohma
  • Patent number: 8715859
    Abstract: According to one embodiment, a non-aqueous electrolyte battery includes an outer case, a negative electrode, a positive electrode including a current collector and a positive electrode layer formed on surface of the current collector and opposed to the negative electrode layer, and a non-aqueous electrolyte, wherein the positive electrode layer includes a layered lithium nickel cobalt manganese composite oxide and a lithium cobalt composite oxide, the positive electrode layer has a pore volume with a pore diameter of 0.01 to 1.0 ?m, the pore volume being 0.06 to 0.25 mL per 1 g of a weight of the positive electrode layer, and a pore surface area within the pore volume range is 2.4 to 8 m2/g.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: May 6, 2014
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yoshiyuki Isozaki, Hidesato Saruwatari, Yoshinao Tatebayashi, Takashi Kuboki, Norio Takami
  • Publication number: 20140120415
    Abstract: An object of the present invention is to provide a high-capacity, long-life lithium secondary cell suppressing a reduction in capacity particularly with respect to use under a high-temperature environment, and having improved cycle properties. The lithium secondary cell comprises a positive electrode active material layer containing a positive electrode active material, a negative electrode active material layer containing a silicon-based material as a negative electrode active material, and an electrolytic solution in which the positive electrode active material layer and the negative electrode active material layer are immersed, the electrolytic solution contains one or more of specific cyclic acid anhydrides.
    Type: Application
    Filed: June 22, 2012
    Publication date: May 1, 2014
    Inventors: Masahiro Suguro, Midori Shimura
  • Publication number: 20140120414
    Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.
    Type: Application
    Filed: January 3, 2014
    Publication date: May 1, 2014
    Applicant: ASAHI KASEI KABUSHIKI KAISHA
    Inventors: Vinay V. Bhat, Gang Cheng, Steven S. Kaye, Bin Li, Risa Olugbile, Jen-Hsien Yang
  • Patent number: 8709273
    Abstract: An amorphous carbon having sulfonate group introduced therein is provided which is characterized in that chemical shifts of a condensed aromatic carbon 6-membered ring and a condensed aromatic carbon 6-membered ring having sulfonate group bonded thereto are detected in a 13C nuclear magnetic resonance spectrum and that at least a diffraction peak of carbon (002) face whose half-value width (2?) is in the range of 5 to 30° is detected in powder X-ray diffractometry, and which exhibits proton conductivity. This sulfonated amorphous carbon is very useful as a proton conductor material or solid acid catalyst because it excels in proton conductivity, acid catalytic activity, thermal stability and chemical stability and can be produced at low cost.
    Type: Grant
    Filed: September 8, 2004
    Date of Patent: April 29, 2014
    Assignee: Tokyo Institute of Technology
    Inventors: Michikazu Hara, Kazunari Domen
  • Publication number: 20140113186
    Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.
    Type: Application
    Filed: June 7, 2012
    Publication date: April 24, 2014
    Inventors: Vinay Bhat, Gang Cheng, Steven Kaye, Bin Li, Risa Olugbile, Jen Hsien Yang
  • Publication number: 20140113205
    Abstract: A rechargeable lithium battery and a method of preparing the same are described. The rechargeable lithium battery includes a positive electrode including a positive active material; a negative electrode including a negative active material; and a liquid electrolyte including a lithium salt and a non-aqueous organic solvent. A separator is interposed between the negative electrode and positive electrode and includes a support. A fluoro-based polymer layer is positioned on both sides of the support. The positive electrode includes the positive active material in an amount from about 30 to about 70 mg/cm2.
    Type: Application
    Filed: July 24, 2013
    Publication date: April 24, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventor: Se-Ho Park
  • Patent number: 8703329
    Abstract: A redox shuttle is provided to prevent overcharge of batteries and/or shuttle current in batteries including high voltage batteries, such as high voltage lithium ion (Li-ion) batteries. An exemplary redox shuttle includes a methylated closo-monocarborate anion.
    Type: Grant
    Filed: March 26, 2012
    Date of Patent: April 22, 2014
    Assignee: Enerdel, Inc.
    Inventors: Thomas Barbarich, Mary Patterson
  • Patent number: 8703310
    Abstract: A polymer that combines high ionic conductivity with the structural properties required for Li electrode stability is useful as a solid phase electrolyte for high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. The polymer electrolyte includes a linear block copolymer having a conductive linear polymer block with a molecular weight of at least 5000 Daltons, a structural linear polymer block with an elastic modulus in excess of 1×107 Pa and an ionic conductivity of at least 1×10?5 Scm?1. The electrolyte is made under dry conditions to achieve the noted characteristics. In another aspect, the electrolyte exhibits a conductivity drop when the temperature of electrolyte increases over a threshold temperature, thereby providing a shutoff mechanism for preventing thermal runaway in lithium battery cells.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: April 22, 2014
    Assignee: The Regents of The University of California
    Inventors: Scott Mullin, Ashoutosh Panday, Nitash Pervez Balsara, Mohit Singh, Hany Basam Eitouni, Enrique Daniel Gomez
  • Publication number: 20140106239
    Abstract: The invention relates to a lithium/sulphur accumulator including at least one unit cell including: a negative electrode; an electrode separator comprising a material soaked with electrolyte, said material comprising at least one nonwoven and having a porosity in the range from 50 to 96%, and a thickness in the range from 50 to 200 micrometers; a positive electrode; and wherein said electrolyte is introduced by an excess quantity, and comprises at least one lithium salt, and the excess quantity of electrolyte amounting to from 20 to 200% of the quantity of electrolyte ensuring the wetting of the electrodes and of the separator.
    Type: Application
    Filed: December 13, 2013
    Publication date: April 17, 2014
    Applicant: Commissariat A L'Energie Atomique Et Aux Energies Alternatives
    Inventors: Céline Barchasz, Sébastien PATOUX, Grégory SI LARBI
  • Publication number: 20140106214
    Abstract: Electrochemical devices which incorporate cathode materials that include layered crystalline compounds for which a structural modification has been achieved which increases the diffusion rate of multi-valent ions into and out of the cathode materials. Examples in which the layer spacing of the layered electrode materials is modified to have a specific spacing range such that the spacing is optimal for diffusion of magnesium ions are presented. An electrochemical cell comprised of a positive intercalation electrode, a negative metal electrode, and a separator impregnated with a nonaqueous electrolyte solution containing multi-valent ions and arranged between the positive electrode and the negative electrode active material is described.
    Type: Application
    Filed: March 11, 2013
    Publication date: April 17, 2014
    Applicant: PELLION TECHNOLOGIES, INC.
    Inventors: Robert Ellis Doe, Craig Michael Downie, Christopher Fischer, George Hamilton Lane, Dane Morgan, Josh Nevin, Gerbrand Ceder, Kristin Aslaug Persson, David Eaglesham