Developer Patents (Class 430/464)
  • Patent number: 5480628
    Abstract: There is disclosed a color developer and a method for processing a silver halide color photographic material with said color developer. The color developer comprises a water-soluble silicone compound, preferably at least one water-soluble silicone compound represented by the following formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4, which may be the same or different, each represent a substituent or a linking group; at least one of R.sub.1, R.sub.2, R.sub.3, and R.sub.4 represents a water-soluble group; A represents a bivalent group; and n is an integer of 0 to 10.
    Type: Grant
    Filed: August 8, 1994
    Date of Patent: January 2, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Masakazu Yoneyama
  • Patent number: 5457011
    Abstract: An improved photographic developing composition, for use in development of a black-and-white silver halide photographic element, is comprised of at least one developing agent and, in an amount sufficient to inhibit sludge deposition, a polyoxyalkylated phosphate ester. The developing composition is broadly useful in black-and-white development but is most advantageously employed in a process for forming a high-contrast image utilizing a silver halide photographic element comprising a hydrazine compound which functions as a nucleating agent and an amino compound which functions as an incorporated booster.
    Type: Grant
    Filed: November 29, 1994
    Date of Patent: October 10, 1995
    Assignee: Eastman Kodak Company
    Inventors: Gordon R. Lehr, Ronald J. Nothnagle
  • Patent number: 5427897
    Abstract: A method for processing an imagewise exposed silver halide color photographic material comprising a support having thereon at least a silver halide emulsion layer containing a cyan dye-forming coupler, a silver halide emulsion layer containing a magenta dye-forming coupler, and a silver halide emulsion layer containing a yellow dye-forming coupler: wherein the silver halide color photographic material contains at least one cyan dye-forming coupler represented by the following general formula (I) or (II) in the silver halide emulsion layer containing the cyan dye-forming coupler: and wherein the processing comprises color developing the imagewise exposed silver halide color photographic material with a color developer containing a p-phenylenediamine derivative represented by the following general formula (III): ##STR1## wherein the substituents are defined herein the specification.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: June 27, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Nakamura, Masato Taniguchi
  • Patent number: 5409805
    Abstract: A solid processing agent for a silver halide photographic light-sensitive material is disclosed, which comprises a compound represented by the following Formula (I): ##STR1## wherein R.sub.1 represents a halogen atom, an alkyl group or an alkenyl group, provided that a plural of R.sub.1 's may be the same or different; R.sub.2 represents a halogen atom, an alkyl group, an alkenyl group or an alkoxy group; R.sub.3 represents a lower alkyl group, provided that R.sub.1, R.sub.2 and R.sub.3 may be the same or different, m and n each represent an integer of 0 to 5; and X represents an anion.
    Type: Grant
    Filed: July 14, 1994
    Date of Patent: April 25, 1995
    Assignee: Konica Corporation
    Inventors: Tsuyoshi Haraguchi, Hiroaki Kobayashi
  • Patent number: 5389502
    Abstract: An alkaline, aqueous black-and-white photographic developer and developing method. The developer includes hydroquinone developing agent, auxiliary developing agent, dialdehyde hardener, organic antifoggant, sulfite antioxidant, buffer, and sequestering agent selected from the group consisting of oligomeric carboxylic acid substituted hydrocarbons.
    Type: Grant
    Filed: February 8, 1994
    Date of Patent: February 14, 1995
    Assignee: Eastman Kodak Company
    Inventors: Alan S. Fitterman, Jean M. Buongiorne
  • Patent number: 5387496
    Abstract: A process of forming a single color, dye ablation image having an improved D-min comprising imagewise heating by means of a laser, a dye-ablative recording element comprising a support having thereon a dye layer comprising an image dye dispersed in a polymeric binder and an infrared-absorbing material, the laser exposure taking place through the dye side of the element, and removing the ablated image dye material to obtain an image in the dye-ablative recording element, and wherein the element contains an interlayer containing infrared-absorbing material and which is located between the support and the dye layer.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: February 7, 1995
    Assignee: Eastman Kodak Company
    Inventor: Charles D. DeBoer
  • Patent number: 5376510
    Abstract: There is described a concentrated photographic silver halide developing solution which comprises from 50 to 150 g/liter of an ascorbic acid type compound of the general formula I: ##STR1## or alkali metal salts thereof, in which the group R represents a hydroxylated alkyl group, and at least one basic compound the anion of which is carbonate, sulphite or hydroxide of which the cation is an alkali metal, especially sodium or potassium, the total sodium to total potassium ion ratio in the concentrated developing solution being from about 50:50 to 0:100 (mole: mole).Preferably the concentrated solution is entirely aqueous but it may comprise a proportion of water-miscible organic solvents such as ethyl alcohol, or glycol solvents.
    Type: Grant
    Filed: December 13, 1993
    Date of Patent: December 27, 1994
    Assignee: Ilford Limited
    Inventors: Michael J. Parker, Anthony M. Lannon, Terence C. Webb, William E. Long
  • Patent number: 5364746
    Abstract: A developer for developing a silver halide photographic material is disclosed. The developer comprises a compound represented by Formula 1 or Formula 2; ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are each a hydrogen atom or an alkyl group having 1 to 3 carbon atoms provided that both of R.sub.1 and R.sub.2 are not hydrogen atoms at the same time; R.sub.5 is a hydroxy group, an amino group or an alkyl group having 1 to 3 carbon atoms; R.sub.6 and R.sub.7 are each a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, an acyl group having 1 to 18 carbon atoms or a --COOM.sub.2 group, provided that both of R.sub.1 and R.sub.2 are not hydrogen atoms at the same time, in the above M.sub.1 is a hydrogen atom, an alkali metal atom or an ammonium group; m is an integer 0, 1 or 2; and M.sub.2 is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkali metal atom, an aryl group or an aralkyl group having not more than 15 carbon atoms.
    Type: Grant
    Filed: March 23, 1994
    Date of Patent: November 15, 1994
    Assignee: Konica Corporation
    Inventors: Kenichi Inoue, Tsuyoshi Mitsuhashi
  • Patent number: 5342741
    Abstract: A developer composition having improved stability to aerial oxidation, which contains at least one compound represented by formulae (A) and (B): ##STR1## where R.sub.1 and R.sub.2 each represent a hydroxyl group, an amino group, an acylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, an alkoxycarbonylamino group, a mercapto group or an alkylthio group; and X represents a group of atoms selected from carbon and nitrogen which forms a 5-membered or 6-membered ring together with the two vinyl carbons substituted by R.sub.1 and R.sub.2, respectively, and the carbonyl carbon of formula (A); ##STR2## where R.sub.3 and R.sub.
    Type: Grant
    Filed: July 9, 1993
    Date of Patent: August 30, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyoshi Morimoto, Shin-ichi Morishima, Hiroshi Hayakawa
  • Patent number: 5300394
    Abstract: A solid particle aqueous dispersion of a compound useful in imaging is prepared by milling an aqueous slurry of the compound in the presence of a fluorosurfactant. The resulting dispersion has improved stability to particle growth.
    Type: Grant
    Filed: December 16, 1992
    Date of Patent: April 5, 1994
    Assignee: Eastman Kodak Company
    Inventors: David D. Miller, Mary C. Brick
  • Patent number: 5296342
    Abstract: For the processing in a total processing time of 60 seconds or less of exposed X-ray materials containing silver bromide or silver bromoiodide emulsions use is made of an aqueous alkaline photographic developing solution, having a pH in the range of 9 to 12, comprising a dihydroxybenzene developing agent, 4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone as an auxiliary developing agent, at least one organic antifoggant and a compound providing iodide ions.
    Type: Grant
    Filed: November 12, 1992
    Date of Patent: March 22, 1994
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Andre Roefs, Francis Sels, Marc Van den Zegel
  • Patent number: 5278035
    Abstract: A non-hydroquinone and non-alkali metal hydroxide containing developer composition for radiographic materials and a method of use thereof are provided. The developer composition comprises a developer selected from the group consisting of ascorbic acid and sugar-type derivatives thereof, stereoisomers and diastereoisomers of ascorbic acid and its sugar-type derivatives, their salts and mixtures thereof, together with a sulfite, a 3-pyrazolidone compound, and an anti-swelling agent selected from the group consisting of sodium sulfate, glutaraldehyde or mixtures thereof, said composition having a pH of from 9.5 to 10.6, and said developer being present in an amount of at least about 15 grams, said sulfite being present in an amount of from 2 to 50 grams, said swelling control agent being present in an amount of from 35 to 90 grams, and water to 1.0 liter.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: January 11, 1994
    Inventor: Audenried W. Knapp
  • Patent number: 5275915
    Abstract: A developer for light-sensitive material capable of processing in common a negative-working light-sensitive lithographic printing plate and a positive-working light-sensitive printing plate as well as a developing agent-containing type silver halide photographic material, is disclosed. The developer comprises an alkali agent, an anionic surface active agent, an antifoggant for a silver halide photographic material, and an alkylene oxide addition product (molecular weight of from 130 to 1200) of an aromatic amine or an aralkyl amine, and has pH of the range of from 11.5 to 13.5.
    Type: Grant
    Filed: June 2, 1992
    Date of Patent: January 4, 1994
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Yasuhiko Kojima, Yasuo Shigemitsu
  • Patent number: 5264331
    Abstract: There are provided p-phenylenediamine color developing agent such as ##STR1## which makes it possible to form a yellow dye having a color image fastness to light while its ordinary photographic properties such as the developing activity and hue are kept. A processing liquid composition for a silver halide color photosensitive material comprises the p-phenylenediamine color developing agent and a pH buffering agent, and has a pH of 9 to 12. A process for forming a color image of claim comprises color-developing an image-wise exposed silver halide color photographic material with the processing liquid composition at a temperature of 30.degree. to 45.degree. C. for 20 seconds to 4 minutes.
    Type: Grant
    Filed: June 11, 1991
    Date of Patent: November 23, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masato Taniguchi, Nobutaka Ohki, Koichi Nakamura
  • Patent number: 5240823
    Abstract: A developer composition comprising a dihydroxybenzene developing agent, a sulfite ion, and an antisludging agent is diluted with water to prepare a developer for the development of photographic silver halide photosensitive material. The components of the composition are divided into a plurality of parts such that the antisludging agent and the dihydroxybenzene developing agent are added to separate parts which are kept apart during storage until they were combined to form the developer.
    Type: Grant
    Filed: May 23, 1991
    Date of Patent: August 31, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Yamada, Takashi Toyoda, Morio Yagihara, Hiroshi Kawamoto
  • Patent number: 5217854
    Abstract: A vacuum package of a color developing composition comprising an aromatic primary amine color developing agent and other components is obtained by vacuum packaging the components in a bag as a layered structure of at least three solid state layers each consisting of a distinct component. A bottom layer consists of the color developing agent. A layer containing a component selected from an organic acid, brightener, polymer, surface active agent, and neutral salt is disposed adjacent the color developing agent layer. Additional layers containing a preservative and an alkaline agent are stacked on the bottom layer through the adjacent layer. The packaged composition is taken out of the bag and diluted with water to prepare a color developer.
    Type: Grant
    Filed: May 8, 1991
    Date of Patent: June 8, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Akira Abe
  • Patent number: 5215873
    Abstract: Process for developing photographic silver halide recording elements containing nonionic fluorinated surfactants using a developer containing at least 15 g/L of dihydroxy benzene compound, 0.15 mole/L of alkali metal sulfate and a wetting agent as described in a concentration of at least 0.1 g/L at a pH of no greater than 11.5. Silver halide recording elements that can be developed are those particularly useful in medical diagnostics with X-rays and in reprography.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: June 1, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Gunter Kiesslich, Max E. G. Wadewitz
  • Patent number: 5204230
    Abstract: A vacuum package of a photographic processing composition consisting of a plurality of components is obtained by placing the components in a bag as separate solid state layers in a vacuum sealed manner. A normally liquid component is converted into a solid adduct in order to form a layer. A substantially water insoluble component or trace component is coated on the surface of particles of a water soluble inorganic compound, from which another layer is formed. The packaged composition is taken out of the bag and diluted with water to prepare a processing solution.
    Type: Grant
    Filed: May 29, 1991
    Date of Patent: April 20, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Katsumi Hayashi
  • Patent number: 5204229
    Abstract: A replenishing solution unit for color-developing a color photographic light-sensitive material is disclosed. The replenishing solution unit comprises at least (1) a replenishing solution containing a color developing agent and a sulfinic acid or a salt thereof and the pH of said replenishing solution is 2 to 6 and (2) a replenishing solution containing a replenishing solution component other than the color developing agent. The replenishing solution unit enables the preparation of a concentrated developing solution and has excellent storage stability over a long period of time without the decrease of photographic sensitivity and the increase of D.sub.min. A method for processing a color photographic light-sensitive material with the above replenishing solution unit is also disclosed.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: April 20, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Nakamura, Masato Taniguchi
  • Patent number: 5196298
    Abstract: A photographic developing solution for immersion development is disclosed showing a pH of at least 12.0 and containing more than 0.4 moles/liter of a sugar derivative, or an alkali metal salt thereof, corresponding to general formula (I): ##STR1## wherein X represents an oxygen atom or an imino group, and n represents a positive integer from 1 to 4, and R represents a hydroxy group when n is 1, and R represents a hydroxy group or a hydrogen atom when n is 2 to 4.Preferred sugar derivatives according to the present invention are l-ascorbic acid and iso-ascorbic acid. In a most preferred embodiment there are substantially no other developing agents and no sulphite ions present. When developing a graphic arts photographic material lith quality is obtained. The disposal of depleted solutions can be performed in an ecologically safe way.
    Type: Grant
    Filed: February 5, 1992
    Date of Patent: March 23, 1993
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Pascal F. Meeus, Peter M. Willems, Gino L. De Rycke
  • Patent number: 5155014
    Abstract: Method for the production of direct-positive images by image-wise exposing a light-sensitive silver halide material comprising a support and an internal latent image-type silver halide emulsion layer and developing said exposed material in the presence of at least one development nucleator and density-increasing amounts of a compound chosen from the class consisting of formic acid, oxalic acid, glyoxylic acid, or salts of these and/or of a compound chosen from the class consisting of polyethylene glycols, with a hydroquinone-type developing solution having a pH not higher than 12.0 and comprising less than 25 g per liter of a hydroquinone and 5 to 100 g per liter of at least one alkanolamine.
    Type: Grant
    Filed: August 14, 1991
    Date of Patent: October 13, 1992
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Jozef P. De Prijcker, Fernand I. Ketels, Jean-Marie O. Dewanckele, Piet Kok
  • Patent number: 5147767
    Abstract: An environmentally-safe, non-toxic non-hydroquinone and non-alkali metal hydroxide containing photographic developer composition is provided comprising a developer selected from the group consisting of 2-keto gluconic acid and derivatives thereof, together with a sulfite, an alkali metal carbonate, and a 3-pyrzaolidone developer compound.
    Type: Grant
    Filed: April 10, 1991
    Date of Patent: September 15, 1992
    Inventor: Audenried W. Knapp
  • Patent number: 5141843
    Abstract: A developer liquid suited for use in development of photographic silver halide emulsion layer materials which liquid contains:1) hydroquinone or a substituted hydroquinone as sole developing agent or said hydroquinone as main developing agent in combination with an auxiliary developing agent in an amount less than 10 mole % with respect to the main developing agent,2) an inorganic compound yielding free sulphite ions in an amount of at least 5 grams per liter,3) an organic anti-fogging agent corresponding to the following general formula (Z): ##STR1## wherein: X.sup.2 represents an alkyl group or an aryl group including said groups in substituted form or an amino group including said group in substituted form;the amount of anti-fogging agent being in the range of 50 mg to 1 g per liter,4) a polymer containing a plurality of alkylene oxide units, and5) the necessary alkaline material to have in said liquid a pH of at least 10.5. Optional additives can also be present in the developing liquid.
    Type: Grant
    Filed: March 27, 1991
    Date of Patent: August 25, 1992
    Assignee: AGFA-Gevaert N. V.
    Inventors: Richard A. Ooms, Piet Kok, Jean-Marie O. Dewanckele
  • Patent number: 5139921
    Abstract: A process of forming super high contrast negative photographic materials in a developer having a pH of from 9.6 to 11.0 wherein the photographic material contains a hydrazine compound and a nucleation accelerator. The nucleation accelerator is represented by formula (Ia):Y[(A.sub.1).sub.p A.sub.2 --B].sub.m (Ia)wherein Y represents a group adsorbing onto silver halide; A.sub.1 represents a divalent linkage group composed of an atom or an atomic group selected from hydrogen, carbon, nitrogen, oxygen, and sulfur and selected from ##STR1## with a straight chain or branched alkylene group wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.10 each represents hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aralkyl group; A.sub.
    Type: Grant
    Filed: February 12, 1991
    Date of Patent: August 18, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Takagi, Hisashi Okada, Morio Yagihara
  • Patent number: 5118595
    Abstract: A method of processing a silver halide color photographic material while regenerating the color development solution by ion exchange membrane electrodialysis comprisingdeveloping an image-wise exposed silver halide photographic material comprising a support having thereon at least one layer of a silver halide emulsion wherein silver halide grains which occupy 50% or more of the projected area of the total of the silver halide grains in the emulsion and which are selected in the order of decreasing aspect ratio from the largest aspect ratio, have an average aspect ratio of 5 or more with a developing solution, andsubjecting the development solution to a regeneration using ion-exchange membrane electrodialysis where the equilibrium concentration of bromine ions in the development solution is controlled at a level within the range of 6.0.times.10.sup.-3 to 1.3.times.10.sup.-2 mol/l.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: June 2, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takatoshi Ishikawa
  • Patent number: 5102779
    Abstract: A method for processing silver halide photographic materials comprising the step of: processing imagewise exposed silver halide photographic material using a developer containing at least one compound represented by general formula (X): ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group containing from 2 to 8 carbon atoms, an alkenyl group containing from 3 to 8 carbon atoms, or an aralkyl group containing from 7 to 12 carbon atoms; or R.sub.1 and R.sub.2 are combined to form a ring; R.sub.3, R.sub.4, R.sub.5, and R.sub.6 each represents a hydrogen atom, or an alkyl group containing from 1 to 4 carbon atoms: and n represents an integer from 3 to 20. A developer for processing silver halide photographic materials comprising at least one compound represented by general formula (X), described above. A silver halide photographic material comprising: at least one compound represented by general formula (X'): ##STR2## wherein R'.sub.1 and R'.sub.
    Type: Grant
    Filed: October 12, 1990
    Date of Patent: April 7, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Eiichi Okutsu, Kazunobu Katoh
  • Patent number: 5085978
    Abstract: Disclosed is a method for processing a light-sensitive silver halide photographic material having at least one silver halide emulsion layer on a reflective support, characterized in that at least one layer of the silver halide emulsion layer contains a compound represented by the formula (I) shown below, and the light-sensitive silver halide photographic material with a total amount of a hydrophilic binder contained of 7.5 g/m.sup.2 or less is processed with a color developer with an amount of the color developer replenished of 25 to 100 ml per 1 m.sup.2 of the light-sensitive silver halide photographic material: ##STR1## wherein A, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X.sub.1 and X.sub.2 are as described in the description.
    Type: Grant
    Filed: October 24, 1990
    Date of Patent: February 4, 1992
    Assignee: Konica Corporation
    Inventors: Makoto Kajiwara, Toyoki Nishijima, Shigeo Chino
  • Patent number: 5064751
    Abstract: A method for processing a silver halide color photographic material including the step of developing the silver halide color photographic material with a color developing solution containing at least one aromatic primary amine developing agent and at least one hydrazide represented by the following formula (I) or (II)R.sup.1 --X.sup.1 --NHNH--R.sup.2 (I)in whichX.sup.1 represents --CO--, --SO.sub.2 -- or ##STR1## R.sup.1 represents a hydroxyl group, a hydroxyamino group, carbamoyl group, a hydrazinocarbonyl group, an amino group, or a hydrazino group; and R.sup.2 represents a hydrogen atom, an alkyl group, or an aryl group; provided that the R.sup.1 or R.sup.2 groups of at least two of the hydrazide groups may be linked to form a dimer or higher polymer of the hydrazide.R.sup.3 --X.sup.2 --NHNH--R.sup.4 (II)in whichX.sup.2 represents --CO-- or --SO.sub.2 --; R.sup.3 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, or an aryloxy group; and R.sup.
    Type: Grant
    Filed: January 23, 1991
    Date of Patent: November 12, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobutaka Ohki, Kazuto Andoh, Hideaki Naruse, Hiroshi Fujimoto, Jiro Tsukahara, Morio Yagihara, Takatoshi Ishikawa
  • Patent number: 5064750
    Abstract: The invention discloses an improved method for processing a silver halide color photographic material wherein said material is imagewise exposed and then processed. The improvement comprises the use of a particular naphthol amido coupler together with a bleaching bath containing (diaminopropanetetraacetatoiron) (III) complex salt at a particular pH.
    Type: Grant
    Filed: August 4, 1989
    Date of Patent: November 12, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hideki Naito
  • Patent number: 5063141
    Abstract: In a method of processing a silver halide photosensitive material wherein the exposed silver halide photosensitive material is developed with a developer containing a developing agent in two or more developing tanks, the first developing replenisher mainly comprising the developing agent is fed into a prior tank and the second developing replenisher mainly comprising an alkali is fed into a posterior tank to make pH of the developer in the posterior tank higher than that in the prior tank.
    Type: Grant
    Filed: April 9, 1990
    Date of Patent: November 5, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takashi Nakamura
  • Patent number: 5063144
    Abstract: Development of a color photographic material in which the emulsion layers contain silver halide grains with a chloride content of at least 80 mol % can be completed within 40 seconds by using a substantially bromide free color photographic developer solution containing, in 1 liter of aqueous solution ready for use, from 4 to 15 g of the developer corresponding to the following formula ##STR1## or a corresponding quantity of its salts, from 8 to 35 g of PO.sub.4.sup.3- ions, at least 0.2 g of antioxidant, from 0.5 to 5.0 g of KCl and other conventional components and adjusted to a pH of from 10.4 to 12.9.
    Type: Grant
    Filed: February 20, 1991
    Date of Patent: November 5, 1991
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventor: Ubbo Wernicke
  • Patent number: 5053322
    Abstract: A method for processing a silver halide color photographic material is disclosed, comprising a support having a thin film of metal or metal oxide on a substrate; said thin film having mirror surface reflection properties or secondary diffuse reflection properties and having a surfaced reflectance of at least 0.5; said photographic material having thereon, in order outwardly from the support, an adhesive layer and at least one light-sensitive silver halide emulsion layer, by the steps which comprise developing the silver halide color photographic material with a developing bath containing a color developing agent and at least one compound represented by formulae (I), (II), (III) or (IV): ##STR1## wherein M each represents hydrogen, an alkali metal or an ammonium group; and R.sub.1 represents a lower alkyl group; ##STR2## wherein R.sub.2 R.sub.3 and R.sub.4 each represents --COOM, --PO.sub.3 M.sub.
    Type: Grant
    Filed: October 27, 1989
    Date of Patent: October 1, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Akira Abe
  • Patent number: 5043253
    Abstract: In a method for processing at least 2 kinds of silver halide color photographic light-sensitive materials comprising the steps of development, desilvering, water washing and/or stabilization, the method comprises processing, in a common desilvering bath, one silver halide color photographic light sensitive material having, applied to a substrate, a silver halide emulsion layer which contains, on average, not less than 3 mole % of silver iodide and another silver halide color photographic light sensitive material having, applied to a substrate, a silver halide emulsion layer which is substantially free of silver iodide, the desilvering bath containing a processing solution having bleaching ability which contains at least one stilbene type fluorescent brightener and a processing solution having fixing ability which contains iodide ions ranging from 1.times.10.sup.-4 to 1.times.10.sup.-1 mole/l.
    Type: Grant
    Filed: December 9, 1988
    Date of Patent: August 27, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takatoshi Ishikawa
  • Patent number: 5034302
    Abstract: A developer sheet useful in forming images having a high density comprising a support having front and back surfaces; anda developer layer coated from a solution on said front surface, said developer layer comprising a particulate reactive material being capable of reacting with a substantially colorless chromogenic material upon contact and generating an image, a binder material, and a viscosity increasing additive is provided. The developer sheet is particularly useful in photosensitive microencapsulated imaging systems for forming overhead transparencies.
    Type: Grant
    Filed: January 10, 1991
    Date of Patent: July 23, 1991
    Assignee: The Mead Corporation
    Inventors: Paul C. Adair, Cheryl L. Moore
  • Patent number: 5028515
    Abstract: In a color print containing cyan, magenta and yellow colored dyes, the color print where the spectral absorption peak wave lengths of the respective colored dyes lie in the range represented by the following formula:1/2(.lambda.y+.lambda.c).gtoreq..lambda.m.gtoreq.1/2(.lambda.y+.lambda.c)-1 0.lambda.c=Spectral absorption peak wave length (nm) of the colored cyan dye.lambda.m=Spectral absorption peak wave length (nm) of the colored magenta dye.lambda.y=Spectral absorption peak wave length (nm) of the colored yellow dyeIn the color print, improvement of the color reproduction and improvement of the observation light source dependency, which hitherto tend to conflict with each other, can be attained at the same time.
    Type: Grant
    Filed: October 15, 1990
    Date of Patent: July 2, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunori Hasebe, Koji Takahashi
  • Patent number: 5028517
    Abstract: A method for processing a silver halide color photographic light-sensitive material is disclosed. Fogging caused by the color developer contaminated by heavy metal ions is surpressed by the processing method. The processing method is excellent in the point that stable photographic propertied can be obtained for long while of running. The processing method comprises a step for developing with a color developer an imagewise exposed light-sensitive material which comprises a support and a photographic layer being provided on the support and including at least one silver halide emulsion layer, wherein the photographic layer has a swelling ratio within the range of from 1.5 to 3.5 and the silver halide emulsion layer comprises a silver halide emulsion having a silver chloride content of not less than 90 mole %, and the developing step is performed for a time of not less than 90 seconds with a color developer containing a compound represented by the following Formula (1): ##STR1## wherein R.sub.1 and R.sub.
    Type: Grant
    Filed: May 18, 1989
    Date of Patent: July 2, 1991
    Assignee: Konica Corporation
    Inventors: Satoru Kuse, Masao Ishikawa, Yoshimasa Komatsu, Shigeharu Koboshi
  • Patent number: 5021326
    Abstract: A process for processing a color photography silver halide recording material by development, bleach-fixing and stabilization or washing, wherein the silver halide emulsion layers of the photographic material have a chloride content of at least 80 mol %, the total processing time is not more than 60 seconds, the concentration of halide in the developing bath in the use state does not exceed 10.sup.-2 mol/l, the chloride content of the halide in the developing bath being at least 80 mol %, and the processing baths are replenished during continuous operation, provides results of good quality such as are otherwise obtained only by processing over a total period of at least 180 seconds.
    Type: Grant
    Filed: April 4, 1990
    Date of Patent: June 4, 1991
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Heinz Meckl, Karl-Heinz Reuter, Rudolf Tromnau
  • Patent number: 5013633
    Abstract: A method of preparing a color proof from a silver halide color photographic light-sensitive material and a black-and-white halftone dot image is disclosed, wherein said light-sensitive material has on a support the photographic component layers including silver halide emulsion layers each having different spectral sensitivities, and one of said silver halide emulsion layers comprises a magenta coupler represented by Formula M-I; ##STR1## wherein Z represents a group of non-metal atoms necessary to form a nitrogen-containing heterocyclic ring including a substituted one; X represents one selected from the group consisting of a hydrogen atom and a group capable of splitting off upon a reaction with an oxidized product of a developer; and R represents one selected from the group consisting of a hydrogen atom and a substituent.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: May 7, 1991
    Assignee: Konica Corporation
    Inventors: Tomomi Yoshizawa, Keiji Ogi, Nariko Kimura
  • Patent number: 5006456
    Abstract: A method for processing a silver halide color photographic light-sensitive material comprises the steps of developing the light-sensitive material with a color developer containing an aromatic primary amine color developing agent, desilvering, washing with water and/or stabilizing the material in which at least one processing solution used in at least one step of the processing contains at least one compound selected from the group consisting of sulfinic acids and salts and precursors thereof. This method makes it possible to effectively prevent the formation of stains due to not only the components of the light-sensitive material per se but also those attributable to the processing solutions, during processing or storage with time, and to enhance the stability of processing solutions.
    Type: Grant
    Filed: June 6, 1988
    Date of Patent: April 9, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masakazu Morigaki, Takatoshi Ishikawa, Kazuto Andoh, Nobuo Seto, Toshio Koshimizu, Shinji Ueda
  • Patent number: 5006439
    Abstract: A photographic reversal process for the production of positive photographic images by imagewise exposure of the photosensitive material containing at least one silver halide emulsion layer, black-and-white first development of the material, chemical fogging, color development and bleaching, fixing, washing or stabilizing and drying, in which the material is transferred from the first development to the color development without any intermediate steps, such as intermediate washing or diffuse second exposure, the first development bath exclusively contains one or more N,N-dialkyl-p-phenylenediamine derivatives as developer and a tin(II) complex compound and is adjusted to a pH value of <8 and the color development bath likewise exclusively contains one or more N,N-dialkyl-p-phenylenediamine derivatives as developer and is adjusted to a pH value >10, requires considerably less time than the conventional process but produces equivalent results.
    Type: Grant
    Filed: November 13, 1989
    Date of Patent: April 9, 1991
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Ubbo Wernicke, Herbert Mitzinger
  • Patent number: 5004676
    Abstract: A new process for maintaining the properties of the developer in the preparation of colored images by development of exposed silver halide-containing material at an alkaline pH in a developer bath containing p-phenylenediamine derivative and at least 40 mol-% of the silver halide consisting of silver chloride and replenishing the color developer in the bath in such a limited quantity that no overflow occurs but it is sufficient to make up for the loss of bath constituents.This process preserves the sensitive results from development during use of the developer bath.
    Type: Grant
    Filed: February 14, 1990
    Date of Patent: April 2, 1991
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Heinz Meckl, Sieghart Klotzer, Erich Wolff, Helmut Haseler
  • Patent number: 5002862
    Abstract: A method for processing a silver halide color photographic material is described, comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein after imagewise exposure, said silver halide color photographic material is processed with a color developer containing at least one aromatic primary amine developing agent and at least one compound capable of releasing the aromatic primary amine developing agent which has substantially no developing agent ability prior to the release of the aromatic primary amine developing agent.
    Type: Grant
    Filed: September 28, 1988
    Date of Patent: March 26, 1991
    Assignee: Fuji Photo Film Co.
    Inventors: Morio Yagihara, Takatoshi Ishikawa, Hiroshi Fujimoto
  • Patent number: 5001041
    Abstract: A method for processing a silver halide color photographic material for prints comprising a color developing step, a bleach-fixing step, and either a stabilizing step or a water washing step is described, wherein the silver halide color photographic material comprises a reflective support having thereon at least one silver halide emulsion layer containing a silver halide having a silver chloride content of not less than 90 mol % and substantially not containing silver iodide, and the color developing step is conducted using a processing solution that does not substantially contain benzyl alcohol.According to the method of the present invention, the amount of water required in a water washing step or a stabilizing step can be greatly reduced without decreasing liquid stability of the water for washing or the stabilizing solution, and color prints having improved preservability are obtained.
    Type: Grant
    Filed: September 19, 1988
    Date of Patent: March 19, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinzo Kishimoto, Shinji Ueda, Kiyoshi Nakazyo
  • Patent number: 4997743
    Abstract: Silver halide photographic material and method of forming an image using the same are disclosed. The material comprises one or more silver halide emulsion layers on a support, with a hydrazine derivative and a developing agent being incorporated in at least one of said emulsion layers. The image forming method comprises performing imagewise exposure of the above-described photographic material and developing said material with a developing solution that contains sulfite ions in a concentration of not less than 0.15 mole per liter and which has a pH within the range of from 9.5 to 12.3, and provides a supercontrasty negative image that has a very contrasty photographic characteristic of a gamma (.gamma.) of 10 or more and which is not highly susceptible to the occurrence of "black spots".
    Type: Grant
    Filed: January 8, 1990
    Date of Patent: March 5, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Senzo Sasaoka, Nobuaki Inoue, Eiichi Okutsu
  • Patent number: 4997749
    Abstract: True-to-type development without any overflow is achieved with a developer solution system of a refill solution and--replenished therewith--a ready-to-use developer solution which contains the following constituents in the quantities indicated per liter aqueous solution and, optionally, other typical consituents:3-15 g of the following color developer compound ##STR1## or a corresponding quantity of salts thereof, 8-35 g PO.sub.4.sup.3 ions,at least 0.2 g antioxidant and2.1-4.2 g KBrand which is adjusted to a pH value of 10.5 to 12.5, the regeneration quota amounting to between 50 and 120 ml/m.sup.2 developed material and the refill solution containing the individual constituents in a such a concentration that, for the above-mentioned regeneration quota, the in-use developer solution always contains the constituents shown above in the quantities indicated.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: March 5, 1991
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Ubbo Wernicke, Herbert Mitzinger
  • Patent number: 4994345
    Abstract: A method for making a color proof in a photo-mechanical process. The method comprises a step for exposing a silver halide color photographic light-sensitive material to light through a black-and-white halftone dot image, and a step for developing said silver halide color photographic light-sensitive material with a color developer. The photographic material is comprised of at least three silver halide emulsion layers which are different from each other in spectral sensitivity thereof, and at least one of these silver halide emulsion layers contains a specific yellow coupler and the color developer contains a specific color developing agent. A halftone color image having a color tone similar to that of image printed with printing inks can be obtained by the simplified process.
    Type: Grant
    Filed: June 5, 1989
    Date of Patent: February 19, 1991
    Assignee: Konica Corporation
    Inventors: Tomomi Yoshizawa, Keiji Ogi, Nariko Kimura
  • Patent number: 4988603
    Abstract: A processing method for silver halide photographic material is disclosed, which stably provides images having high contrast and high dot quality with little degradation in sensitivity by rapid processing.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: January 29, 1991
    Assignee: Konica Corporation
    Inventors: Yasuhiko Takamuki, Takeshi Habu, Junichi Fukawa
  • Patent number: 4987060
    Abstract: A concentrated alkaline photographic developer composition, packaged in a single part to be diluted with water to form a ready to use developing solution for silver halide photographic materials, which comprises dihydroxybenzene developing agents, inorganic alkali agnets, inorganic antioxidant agents, sequestering agents and antifoggants, wherein said inorganic antioxidant agents comprise Na.sub.2 SO.sub.3 (sodium sulfite) and K.sub.2 SO.sub.3 (potassium sulfite) in a molecular ratio of 1:1 to 1:3 in an amount of from 1.6 to 4 moles per liter, the molecular ratio between said inorganic antioxidant agents and the developing agents is from 1.50 and 4.00, and said concentrated developer composition has a specific gravity higher than 1.300 at 20.degree. C.
    Type: Grant
    Filed: March 23, 1990
    Date of Patent: January 22, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Carlo Marchesano
  • Patent number: 4985347
    Abstract: A method for processing silver halide color photographic material is disclosed which comprises processing a silver halide color photographic material with a color developer containing substantially no sulfite ion and then processing the color photographic material with a solution having bleaching capability containing an aminopolycarboxylic acid having a molecular weight of at least 300.
    Type: Grant
    Filed: July 25, 1990
    Date of Patent: January 15, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Fujimoto, Morio Yagihara, Takatoshi Ishikawa
  • Patent number: 4983504
    Abstract: A method for processing photographic silver halide color negative film and color negative paper each through its own color developing solutions wherein the paper color developing solution is replenished and the overflow from this replenished solution is used to replenish the film color developing solution and wherein (a) the color paper is based on substantially pure silver chloride emulsions and contains no more than 1% molar silver bromide based on total silver halide and (b) both color developing solutions and the replenisher are free from benzyl alcohol.Apparatus for carrying out the above-described method comprises a series of processing stations and means for advancing the photographic material being processed through the apparatus wherein there is provided means for collecting the overflow from the paper developer station and means for passing it directly or indirectly to the film processing station.
    Type: Grant
    Filed: February 21, 1989
    Date of Patent: January 8, 1991
    Assignee: Eastman Kodak Company
    Inventors: Peter D. Marsden, John R. Fyson, Peter J. Twist