Abstract: A method of producing biodiesel from a source of triglycerides. The source of triglycerides is reacted with a blended alcohol composition in the presence of a catalyst to form a mixture of at least one fatty acid alcohol ester and glycerin. The fatty acid alcohol ester is then separated from the glycerin and is purified to produce a biofuel. The blended alcohol composition comprises at least one lower alcohol, a ketone and ethyl acetate. The use of the blended alcohol composition allows the transesterification process to proceed under ambient temperature and pressure conditions within a relatively short reaction time.

Abstract: Methods for making a fuel composition comprising contacting one or more components of a hydroprocessing feedstock, for example both a fatty acid- or triglyceride-containing component and a paraffin-rich component, with hydrogen under catalytic hydroprocessing conditions are disclosed. The methods are effective to upgrade the component(s) and provide a hydroprocessed biofuel. A representative method utilizes a single-stage process in which hydrogen-containing recycle gas is circulated through both a hydrodeoxygenation zone and a hydrocracking zone in series.

Abstract: The present invention relates to a genetically modified Acinetobacter host for lipid production. The Acinetobacter host has been genetically modified to be deficient of one or more of genes A) a gene encoding fatty acyl-CoA reductase (EC1.2.1.n2), wherein said host is capable of increased production of TAGs and/or of total lipids compared to the parent host; and/or B) a gene encoding lipase (EC:3.1.1.3), a gene encoding pyruvate dehydrogenase (EC:1.2.2.2), and/or gene ACIAD 2177, or functional equivalents of any of said genes, wherein said host is capable of increased production of wax esters and/or total lipids compared to the parent host.

Abstract: A process for catalytic cracking of a lipid-containing feedstock is provided. The lipid-containing feedstock contains lipids derived from microalgae and a hydrocarbon feedstock. The lipid-containing feedstock is contacted with at least one cracking catalyst at a temperature of at least 450° C., to obtain a product stream; and separating at least one hydrocarbon fraction from the product stream.

Abstract: A process for catalytic cracking of a lipid-containing feedstock is provided. The lipid-containing feedstock contains lipids derived from a diatomic microalgae species. The lipid-containing feedstock is contacted with at least one cracking catalyst at a temperature of at least 450° C., to obtain a product stream; and separating at least one hydrocarbon fraction from the product stream.

Abstract: The use of mixtures of (A) aliphatic saturated or unsaturated monocarboxylic acids having 12 to 24 carbon atoms or the dimerization or trimerization products thereof, which may be present in the form of free carboxylic acids and/or in the form of ammonium salts, amides, esters and/or nitriles, and (B) polycyclic hydrocarbon compounds which are obtainable from distillation residues of natural oils, which have been extracted from tree resins, for increasing the cetane number of fuel oils which comprise at least one additive with detergent action and at least one cetane number improver, the mixtures of components (A) and (B) being used in a concentration of 10 to 500 ppm by weight, based on the total amount of the fuel oil.

Abstract: A system and process for continuous production of fatty acid methyl esters (FAME) from the fatty acid triglycerides of waste oil via transesterification in the presence of a reusable sugar-based catalyst. The system and process incorporates re-cycling and re-use of waste by-product streams to result in a near-zero emissions, with a 97% product yield mix consisting of almost pure biodiesel and a very small percentage of impurities including glycerol.

Abstract: A method of burning fuel in a combustion chamber whereby reducing overall carbon emissions, comprising: feeding an oxidizing component and a combustible component to a combustion chamber in a ratio based on zero oxygen balance principle, wherein the oxidizing component has an oxygen balance value of more than zero, and the combustible component has an oxygen balance value of less than zero. The method of burning fuel can reduce overall carbon emissions, even to zero.

Abstract: The invention relates to tall oil fatty acid compositions having low sulfur content, as well as methods of using and making the same.

Abstract: This invention provides co-cultures of photosynthetic microorganisms and biofuel producing microorganisms. In certain embodiments, polysaccharide-producing, photosynthetic microorganisms are microalgae having frustules provide a substrate on which biofuel-producing microorganisms can grow. In other embodiments, the photosynthetic microorganisms produce a lipid and the non-photosynthetic microorganisms produce a solvent in which the lipid is soluble.

Abstract: A method of purifying an organic solution comprising contacting a flocculating and sequestering agent with the organic solution, which organic solution comprises fatty acid alkyl esters. Also provided is a process for purification of the organic solution. The process comprises adding a flocculating and sequestering agent to the organic solution to facilitate the purification, and removing a portion from the organic solution, which portion comprises the flocculating and sequestering agent and impurities.

Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, sequentially adding solvent sets to the algal biomass, and sequentially separating solid biomass fractions from liquid fractions to arrive at a liquid fraction comprising neutral lipids. The method also includes esterifying the neutral lipids, separating a water miscible fraction comprising glycerin from a water immiscible fraction comprising fuel esters, carotenoids, and omega-3 fatty acids. The method also includes obtaining a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.

Abstract: A high power diesel fuel composition and method for increasing immediate power output of a diesel engine using same, the high power diesel fuel composition comprising: about 50% v/v or more ultra low sulfur diesel fuel; and, from about 40 to about 60 ppmw of one or more metal carboxylate comprising one or more metal selected from the group consisting of alkali metals, manganese, iron, and combinations thereof; the diesel fuel composition having a cetane value of 48 or more.

Abstract: A method comprising the steps of providing a fatty acyl mixture comprising: (i) a C10-C16 acyl carbon atom chain content of at least 30 wt. % wherein at least 80% of the C10-C16 acyl carbon atom chains are saturated; and (ii) a C18-C22 acyl carbon atom chain content of at least 20 wt. % wherein at least 50% of the acyl C16-C22 carbon atom chains contain at least one double bond; hydrolyzing at least some of the mixture to yield a quantity of C10-C16 saturated fatty acids and C18-C22 unsaturated fatty acids; oligomerizing at least some of the C18-C22 unsaturated fatty acids to yield a quantity of C36+ fatty acid oligomers; separating at least some of the C10-C16 saturated fatty acids from the C36+ fatty acid oligomers.

Abstract: Palm-based biodiesel formulations with enhanced cold flow properties are provided including the following: (I) A biodiesel formulation comprising not more than 40 vol % palm-based biodiesel and not less than 60 vol % petroleum-based file 1 oil; (II) A biodiesel formulation comprising not more than 20 wt % palm-based biodiesel and not less than 80 wt % alkyl ester of C6-C18 saturated or unsaturated fatty acid, or a mixture thereof; (III) A biodiesel formulation comprising approximately 0.1-1.0% (wt/vol) of a polyalkyl methacrylate (PAMA) additive and a palm-based biodiesel blend comprising i) not more than 40 vol % palm-based biodiesel; and ii) not less than 60 vol % petroleum-based fuel oil; (IV) A biodiesel formulation comprising approximately 0.1-5.0% (wt/vol) of a polyalkyl methacrylate (PAMA) additive and a palm-based biodiesel having unsaturation level of not less than 60%.

Abstract: The invention relates to alkyl(meth)acrylates comprising a long linear chain bearing alkyl ramifications corresponding to general formula (I): in which R1 is a hydrogen atom or a methyl radical and R2 is a long alkyl chain of formula (II): R(CH2—CH2)n(CH2—CH(R3))m— in which R is a methyl or ethyl radical, R3 is an linear- or branched-chain alkyl radical containing from 1 to 6 carbon atoms, n=9 to 20, m=1 to 5, wherein it is possible for the —CH2—CH2— and —CH2—CH(R3)— units to be distributed in block or random form. These compounds can in particular be used for the production of additives intended to lower the settings point of paraffinic oils or fuels (diesel oils or fuel oils), and for the production of additives for lubricants.

Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, sequentially adding solvent sets to the algal biomass, and sequentially separating solid biomass fractions from liquid fractions to arrive at a liquid fraction comprising neutral lipids. The method also includes esterifying the neutral lipids, separating a water miscible fraction comprising glycerin from a water immiscible fraction comprising fuel esters, carotenoids, and omega-3 fatty acids. The method also includes obtaining a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.

Abstract: The present invention relates to methods and systems for processing biomass to selectively yield a variety of hydrocarbon molecules and hydrogen as products, wherein some or all of these products can be further utilized for other biomass processing sub-processes, particularly wherein they lead to the generation of biofuels and/or other high-value products.

Abstract: The present invention relates to fuel additives, fuel compositions and methods of manufacture in which the additives are provided to impart desired properties to fuels. These properties include, without limitation, reduction of nitrogen oxide and particulate emissions from the exhaust stream of internal combustion engines using the fuels. Preferred embodiments of an additive form of the composition include a nitrogen-containing compound selected from the group consisting of urea, cyanuric acid, triazine, ammonia and mixtures thereof, a carrier blend comprising an alkoxylated alcohol, a polyalkylene glycol ester and an alkanolamide and water. The additive may be provided in a concentrate form by addition of a solvent or may be provided as a final form fuel composition. A method of additive manufacture and is disclosed.

Abstract: A method of producing biodiesel comprising the steps of collecting a raw material comprising a fatty acid and an oil; contacting the raw material with glycerol and a Lewis acid catalyst in a first reaction chamber at a selected pressure and temperature; separating water from the mixture product in a gas phase; and contacting the mixture product with a second alcohol and an alkali catalyst in a second reaction chamber to form a product comprising a fatty acid ester.

Abstract: Provided herein are blends oils or fatty acids comprising more than 50% medium chain fatty acids, or the fatty acid alkyl esters thereof, and having low melting points. Such blends are useful as a fuel or as a starting material for the production of, for example, a biodiesel. Also provided genetically altered or modified plants, modified such that the amount of medium chain fatty acids generated by the plant are increased. Further provided is a method of predicting the melting point of a blend of fatty acid methyl esters and the use of such a method for identifying blends suitable for use as, for example, a biodiesel.

Abstract: A process for producing a fuel composition from vegetable and/or animal oil comprises hydrodeoxygenating and hydroisomerizing the oil in a single step. The fuel composition has acceptable lubricity and comprises a mixture of C14 to C18 paraffins having a ratio of iso to normal paraffins of 2 to 8 and less than 5 ppm sulfur.

Abstract: A method of producing an upgraded bio-oil from a wet biomass that includes heating the wet biomass at a first temperature and a first pressure for a time period ranging from 10 to 200 minutes to form a crude bio-oil. The first temperature ranges from 200 to 400° C. and the first pressure ranges from 0.1 to 25 MPa, with the proviso that at least a portion of the water present in the wet biomass remains in a liquid phase throughout the step of heating to form the crude bio-oil, and the first temperature and pressure are below super-critical conditions for water. The method also includes heating the crude bio-oil and the water at a second temperature and a second pressure to form the upgraded bio-oil. Some water remains in the liquid phase or in a super-critical fluid phase throughout the step of heating to form the upgraded bio-oil.

Abstract: Compositions containing phenolic antioxidant solutions are provided. The invention further provides methods of making and using such compositions as well as compositions that contain both biodiesel and at least one antioxidant concentrate solutions and blended fuel compositions containing biodiesel blended with other fuels.

Abstract: The presently described invention relates to systems for continuously culturing, harvesting, and oil extraction of algal cultures for the production of algae oils.

Abstract: There is provided a method of providing an improved biofuel, by the presence of an additive which is the reaction product of (i) a compound containing the segment —NR1R2 where R1 represents a group containing from 4 to 44 carbon atom R2 represents a hydrogen atom or a group R1 (for example di-hydrogenated tallow amine) and (ii) a carboxylic acid having from 1 to 4 carboxylic acid groups or an acid anhydride or acid chloride thereof (for example phthalic acid or phthalic anhydride). The additives described combat problems arising from precipitation at temperatures above the cloud point.

Abstract: Methods and electroporation devices for electrical treatment of algal cell cultures for release of lipids and proteins are described herein. The method of the present invention exploits the differences in electrical time constants for the media inside the cell and outside the cell to produce a net force to cause cellular lysis and extract cellular components. The method of the present invention can be used in the treatment of flocculated as well as unflocculated algal cell cultures. The device of the present invention provides efficient cell lysing in a low-energy cost set-up.

Abstract: A subject of the present invention is an anti-corrosive and antistatic lubricating composition for a hydrocarbonated mixture comprising: a) at least a compound A of Formula (I) below: in which R1 and R2 are hydrogen or a linear or branched alkyl group of 1-40 carbon atoms, comprising possibly one to five double bond(s), R1 and R2 together being able to form an aromatic or aliphatic ring of 5-6 carbon atoms, said ring being capable of substitution by one to three linear or branched alkyl group(s) of 1-40 carbon atoms, in which R1 and R2 cannot be hydrogen at the same time, and in which R3 and R4, identical or different, are chosen from the OH groups, in which R3 and R4 cannot be the OH group at the same time, or deriving from a linear or branched monol or polyol group containing 1-20 carbon atoms having a functionality of 2 to 5 inclusive; b) and at least one B compound corresponding to a fatty acid of 16-24 carbon atoms, unsaturated or not, optionally in a mixture with a carboxylic acid comprisin

Abstract: A quick, economical and environmentally friendly, “green”, process for the continuous purification of biodiesel (fatty acid alkyl esters (FAAE)) is described using a powdered, granulated or extruded adsorbent. The adsorbent is contained in a column system and is regenerated for reuse multiple times. The process employs an adsorbent such as, but not limited to, carbon, silica, clay, zeolite or a metal silicate contained in a column to remove the impurities from fatty acid alkyl esters (FAAE) or crude biodiesel in a continuous process. The process utilizes the adsorbent column system for the purification of biodiesel, rather than water or filtration, to remove soaps and other impurities entrained in a crude biodiesel.

Abstract: This invention relates to a hydroprocessing process for the improvement of catalyst life. Such inventive process is carried out with intermittent or discontinuous addition of a co-feed stream when hydroprocessing petroleum based feedstock or an oxygen containing feedstock. More specifically, it has been found that intermittent or discontinuous addition of the co-feed stream such as carbon monoxide, carbon dioxide, or their precursors to the hydrogen stream can reduce the long term deactivation, extend the life and increase run length of a cobalt/molybdenum hydrotreating catalyst.

Abstract: A simple method is disclosed to produce oil soluble nano particle size additives with significantly higher flash points to improve the safety aspects of these products especially when used in, around, and near high temperature combustion equipment.

Abstract: The invention relates to a method for processing mixtures of carboxylic acids obtained as hydrolysis products of suberin and cutin, particularly suberin and cutin isolated from birch bark, to give mono-, oligo- and polyesters, or corresponding ester-ethers, as well as the use of the products thus obtained as lubricants, fuel components, plasticizers, surface active agents, environmentally friendly agents for modifying wood, binders in coatings, adhesives, printing inks and composites, further in various cosmetic applications.

Abstract: The present invention relates to a fatty acid composition which contains an effective amount of fatty acids providing improved low temperature stability of the composition. The present invention also relates to a process for producing a fatty acid composition wherein the process comprises the steps of selecting a crude tall oil having a fatty acid concentration and type capable of providing low temperature stability, distilling said crude tall oil to provide a fatty acid composition containing an effective amount of tall oil fatty acids providing low temperature stability.

Abstract: A diesel fuel additive composition, a fuel containing the fuel additive, a method for improving diesel engine performance using the additive and a method for making the additive for diesel engines having a high pressure fuel injection system. The fuel additive has a number average molecular weight (Mn) of from about 500 to about 10,000 and is selected from a hydrocarbyl-substituted succinic acid or anhydride or derivative thereof and a hydrocarbyl-substituted Mannich base. The additive has a molecular weight distribution such that less than about 25 wt. % of the additive has a molecular weight of 400 or less as measured by gel permeation chromatography (GPC) based on a polystyrene calibration curve.

Abstract: Compositions containing phenolic antioxidant solutions are provided. The invention further provides methods of making and using such compositions as well as compositions that contain both biodiesel and at least one antioxidant concentrate solutions and blended fuel compositions containing biodiesel blended with other fuels.

Abstract: Biofuel compositions and methods. Biofuel compositions comprised of glycerine, water and one or more alcohols can be prepared and utilized as an alternative or renewable fuel or mixed with other fuels and fuel products. The methods of preparation require simple mixing as the biofuel composition is a solution. The components can be mixed in any sequence. By varying the amount of water and/or alcohol mixed with the glycerine allows for preparation of biofuel compositions having consistent or uniform properties, such as pour point and/or flashpoint even using glycerine from different sources and having different specifications.

Abstract: Disclosed are processes for producing glycerol related products. One process comprises introducing a biomass and an alkylation reagent to a substantially oxygen free environment, hydrolyzing at a temperature at or above 200° C. one or more lipid glycerides in the biomass, methylating one or more fatty acids in the biomass with methyl groups from the alkylation reagent, wherein the hydrolyzing and methylating occur contemporaneously and separating resulting biodiesel and methylated glycerol-related products from a residue of the biomass by condensation.

Abstract: Provided is a method for purifying a biodiesel fuel while completely preventing or greatly reducing generation of waste water. The present invention relates to a method for purifying a biodiesel fuel characterized by applying an electric field to or heating a crude biodiesel fuel and a method for purifying a biodiesel fuel characterized by adding water (preferably containing a demulsifier such as an inorganic calcium salt or a magnesium salt) to a crude biodiesel fuel to form W/O emulsion, and breaking the emulsion by application of an electric field or heating, etc.

Abstract: Disclosed is an environmentally conscious, odor-free lighter fluid mixture comprising a 50-70% ethanol and 30-50% biodiesel combination. Methyl-ester, ethyl-ester and propyl-ester fatty acids, commonly referred to as biodiesel, are clean burning fuels derived from new or waste vegetable oil such as soybean, canola or sunflower. Combined with an ethanol accelerant, the mixture provides a lighter fluid that is easily ignitable without risk of detonation or explosion, and one that brings charcoal briquettes up to temperature quicker than traditional methods. The mixture is petroleum free, which eliminates the associated unpleasant odors and potential health risks of traditional lighter fluid, including a reduction in the emission of volatile organic compounds (VOCs) into the environment. The mixture offers a renewable, sustainable, and efficient ignition source for charcoal that does not sacrifice utility compared to traditional lighter fluid, and does not impart undesirable flavors onto grilled food.

Abstract: Methods and apparatus for growing and sequentially processing algae to produce a variety of products including but not limited to biofuels, algal meal, oil, unsaturated fatty acids and recombinant proteins and peptides in a cost-effective and energy efficient manner. Also provided are methods of use for the products.

Abstract: The present invention relates to a process for the production of alkyl esters of carboxylic acids for use as biodiesel starting from the reaction of transesterification of triglycerides originating from oils and fats of vegetable or animal origin, which can be used individually or in mixtures with one another in any proportions, employing heterogeneous catalysis by means of protonated lamellar titanate catalysts in nanostructured form, and said forms can comprise, among in other forms, nanotubes, nanofibres or nanosheets.

Abstract: The object of the present invention is to provide a method for aggregating and separating algae dispersed in a liquid efficiently. According to the present invention, a method for aggregating and separating algae dispersed in a liquid, which comprises adding an alkaline inorganic aggregating agent to the liquid at pH of 2.0 to 4.0 in which algae are dispersed, followed by adding a cationic polymer aggregating agent, is provided. Further, according to the present invention, a method for producing biofuel utilizing algae is provided.

Abstract: The invention relates to a hydrocarbon composition, which can be used as a fuel and/or fuel oil, containing a petroleum component (A) and a component of a biological origin (B), wherein the component of a biological origin is present in a quantity of up to 75% by volume with respect to the total composition.

Abstract: A pyrolysis oil derived from a lignocellulosic biomass material is converted into precursors for liquid hydrocarbon transportation fuels by contacting the oil with water and carbon monoxide at elevated temperature, typically from 280 to 350° C., an elevated pressure, typically a total system pressure of 12 to 30 MPa and a CO partial pressure from 5 to 10 MPa and a weight ratio of water:biomass oil from 0.5:1 to 5.0:1, to dissolve the oil into the reaction mixture and depolymerize, deoxygenate and hydrogenate the oil, so converting it into liquid transportation fuel precursors.

Abstract: The present invention provides a gas oil composition that can achieve environment load reduction, low temperature properties and low fuel consumption all together and is suitably used in a winter season. The gas oil composition comprises an Ft synthetic base oil in an amount of 60 percent by mass or more on the basis of the total mass of the composition and has a sulfur content of 5 ppm by mass or less, an aromatic content of 10 percent by volume or less, an oxygen content of 100 ppm or less, an end point of 360° C. or lower, an insoluble content after an oxidation stability test of 0.5 mg/100 mL or less, an HFRR wear scar diameter (WS1.4) of 400 ?m or smaller and a specific relation in normal paraffin contents and the total content thereof.

Abstract: The invention provides methods for producing biofuel from algae, that use fish which have a high capacity of producing and/or accumulating lipids to harvest algae from an algal culture. The invention also provides methods for growing fish that result in a high lipid content. The invention also provides methods for creating fish that have a high capacity of producing and accumulating lipids by breeding and/or recombinant DNA techniques. Also included are transgenic fish that have a higher lipid content than wild-type fish.

Abstract: The present invention provides a gas oil composition that can achieve environment load reduction, low temperature properties and low fuel consumption all together and is suitably used in a winter season. The gas oil composition comprises an Ft synthetic base oil in an amount of 60 percent by mass or more on the basis of the total mass of the composition and has a sulfur content of 5 ppm by mass or less, an aromatic content of 10 percent by volume or less, an oxygen content of 100 ppm or less, an end point of 360° C. or lower, an insoluble content after an oxidation stability test of 0.5 mg/100 mL or less, an HFRR wear scar diameter (WS1.4) of 400 ?m or smaller and a specific relation in normal paraffin contents and the total content thereof.

Abstract: A method for producing diesel fuel from biocomponent feeds includes hydrotreating the feed followed by catalytic dewaxing with a ZSM-48 containing catalyst. The hydrotreated feed may be cascaded directly to the dewaxing step, or the hydrotreated feed can undergo intermediate separation. The diesel fuel resulting from processing of the biocomponent feed exhibits superior cetane values.

Abstract: Non-hydrotreated biocomponent feeds can be mixed with mineral feeds and processed under catalytic isomerization/dewaxing conditions. The catalytic isomerization/dewaxing conditions can be selected to advantageously also substantially deoxygenate the mixed feed. Diesel fuel products with improved cold flow properties can be produced.

Abstract: Feeds containing a hydrotreated biocomponent portion, and optionally a mineral portion, can be processed under catalytic conditions for isomerization and/or dewaxing. The sulfur content of the feed for dewaxing can be selected based on the hydrogenation metal used for the catalyst. Diesel fuel products with improved cold flow properties can be produced.