Abstract: A method of synthesizing of a biocompatible and biodegradable polyurethane foam includes the steps of: mixing at least one biocompatible polyol, water, at least one stabilizer, and at least one cell opener, to form a resin mix; contacting the resin mix with at least one polyisocyanate to form a reactive liquid mixture; and reacting the reactive liquid mixture form a polyurethane foam. The polyurethane foam is preferably biodegradable within a living organism to biocompatible degradation products. At least one biologically active molecule having at least one active hydrogen can be added to form the resin mix.

Abstract: The invention relates to a cellular elastomer which is anisotropic, with anisotropy being defined by the compressive modulus in one of three orthogonal directions being greater than that in the other two directions by a factor of at least 1.5. The invention also relates to a cellular elastomer containing magnetizable particles which have a chain-like alignment along one spatial direction. The invention also relates to a process for producing a cellular elastomer containing magnetiable particles and the use of such elastomers in articles of manufacture.

Abstract: A process for the preparation of thermoplastic auxetic foams comprising the steps of: a) taking conventional thermoplastic foam; b) subjecting said foam to at least one process cycle wherein the foam is biaxially compressed and heated; c) optionally subjecting the foam to at least one process cycle wherein the biaxial compression is removed and the foam mechanically agitated prior to reapplying biaxial compression and heating; d) cooling said foam to a temperature below the softening temperature of said foam; and e) removing said compression and heat.

Abstract: A polyurethane foam sponge that picks up at least 80% of water in a wipe dry performance test is made by variably felting (compressing under heat and pressure) a foam sheet to a compression ratio of about 1.05 to 2.9. The resulting foam sponge has from 5% to 25% of its top and bottom surface portions modified by the variable felting, while its core portion remains substantially unmodified.

Abstract: Halogen-free, flame-retardant polymer foams which comprise, as flame retardant, at least one cyclic or acyclic oligophosphorus compound, and processes for their production. Examples of suitable oligophosphorus compounds are those having the structure Ia, Ib, or Ic: Another group of suitable oligophosphorus compounds is that having one of the following structures IIa, IIb, or IIc: Cyclic oligophosphorus compounds of the following structure III are also suitable: The radicals R1-R5 have been selected independently of one another from the group of C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenyloxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, NR2R3, COR2, COOR2, and CONR2R3 , and the radicals X1 and X2, independently of one another, are O or S.

Abstract: A monolith separation medium comprising a skeletal phase and continuous pores forming a three-dimensional network structure, which has a functional group enabling the introduction of a new functional group on the surface of the skeletal phase. The skeletal phase has an average diameter of a submicron to micrometer size and is in a co-continuous structure of the non-particle-aggregation type. It is composed of an addition polymer of 1,3-bis(N,N?-diglycidylaminomethyl)cyclohexane as an epoxy compound with a bifunctional or higher amine compound, is rich in organic matters and is free from any aromatic-origin carbon atom. Thus, it is an organic polymer monolith separation medium of the non-particle-aggregation type.

Abstract: The present invention provides compounds produced by the reaction of glycidyl ethers and glycidyl esters with ether compounds including N,N,N?-trimethyl-bis-(aminoethyl)ether. N,N,N?-trimethyl-bis-(aminoethyl)ether and its derivatives can be used as polyurethane catalysts.

Abstract: The present invention relates to polyester polyols based on aromatic dicarboxylic acids and their use for producing rigid polyurethane foams.

Abstract: Polyether polyols are initiated with aminocyclohexanealkylamines such as isophoronediamine and 1,8-diaminop-menthane. The polyols are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times.

Abstract: Foamed polyurethane articles, such as a sponges, sheets, tapes or ribbons, blocks or other molded, extruded or cast article which foamed polyurethane articles exhibit an antimicrobial benefit and are particularly useful in the formation of cleaning articles. Processes for the manufacture of such cleaning articles based on hydrophilic polyurethane foams exhibit an antimicrobial benefit and their use are also described.

Abstract: Disclosed is a polyol composition containing an aromatic polyester polyol having a hydroxyl number of 300-500 mgKOH/g and an average number of functional groups of 2.0-2.5, a medium-chain polyether polyol having a hydroxyl number of 100-250 mgKOH/g and an average number of functional groups of 2.0-4.0 and composed of a polyoxypropylene unit, and a long-chain polyether polyol having a hydroxyl number of 15-40 mgKOH/g, an average number of functional groups of 2.0-4.0 and an oxyethylene content of not more than 14% by weight and mainly composed of a polyoxypropylene unit.

Abstract: Cardanol derivative comprising one or more units of the formula and a method for obtaining such cardanol derivative.

Abstract: An azeotrope-like mixture consisting essentially of chlorotrifluoropropene and at least one component selected from the group consisting of a C1-C3 alcohol, a C5-C6 hydrocarbon, a halogenated hydrocarbon, methylal, methyl acetone, water, nitromethane, and combinations thereof.

Abstract: The present invention relates to a process for the production of an expandable thermoplastic polymer comprising water as blowing agent, comprising at least the step (A) of storage of the thermoplastic polymer in water, so that water is absorbed by the thermoplastic polymer, in order to obtain an expandable thermoplastic polymer, to expandable thermoplastic polymer, obtainable via the process, to a corresponding expanded thermoplastic polymer, to a process for the production of a foam via foaming and fusion of the expanded thermoplastic polymer, and also to a foam, obtainable via said process.

Abstract: A composition is disclosed that comprises an otherwise flammable flexible polyurethane foam and a multi-component flame retardant additive. The flame retardant additive includes an alkyl substituted aryl phosphate and an alkyl phosphate ester wherein the alkyl groups range from C4 to C20 and contain one to six oxygen atoms in the alkyl chain. Optionally, the flame retardant additive includes a halogenated flame retardant containing more than 30 wt. percent of bromine, chlorine, or a mixture thereof.

Abstract: The subject of the present invention is a foamed polymer-inorganic binder hybrid material having controlled density and morphology, in particular a foamed polyurethane-inorganic binder hybrid, a method for the preparation of the same and its uses. Said material has high characteristics of thermal and acoustic insulation, water vapor permeability, fire resistance, lightness, as well as a good adhesiveness to concretes, mortars and plasters and a good compression resistance.

Abstract: The invention relates to the surprising and unexpected discovery that a sub-group of phenolic resins (i.e., those which are substantially completely free of ether moieties) is particularly advantageous to confer load building properties to an isocyanate-based foam (e.g., a polyurethane foam). Indeed, its possible to utilize the sub-group of phenolic resins to partially or fully displace copolymer polyols conventionally used to confer load building characteristics to isocyanate-based polymer foams. Further, the invention relates to the surprising and unexpected discovery that a sub-group of phenolic resins (i.e., those which are substantially completely free of ether moieties) is particularly advantageous to confer energy absorption properties in an isocyanate-based foam.

Abstract: Derivatized solid epoxy resins of the formula (I), which are outstandingly suitable as impact modifiers; and compositions which include such derivatized solid epoxy resins and are outstandingly suitable as one-component heat-curable adhesives, and as structural foams which have a high impact resistance and high mechanical stability.

Abstract: The present invention relates to organic polymer porous materials, and in particular, to an organic polymer porous material that functions as a reusable insoluble solid catalyst and a method for producing the same. The organic polymer porous material of the present invention is characteristic in that the amount of immobilized bases is high and the specific surface area is large. The object has been achieved by an organic polymer porous material including a polymer (PA) obtained by polymerizing a polymerizable composition (A) containing a compound (a) obtained by reacting a dendrimer (a1) having at least an amino group as a reactive functional group or a polyethyleneimine (a2) having at least an amino group as a reactive functional group with a compound (a3) having a vinyl group and a group that can react with the reactive functional group.

Abstract: Rigid closed-cell polyurethane foams with low k-factors are produced by reacting an organic polyisocyanate with an amine-based polyether polyol and a polyester polyol in the presence of a catalyst and a hydrofluorocarbon blowing agent, preferably, HFC-245fa. It is preferred that no water be added to the reaction mixture.

Abstract: Disclosed are new compositions consisting of polyphosphonates and specific additive compositions that exhibit superior resistance to degradation due to exposure to air, high temperature and air, moisture or combinations thereof. Also disclosed are polymer mixtures or blends comprising these polyphosphonates/additive compositions and commodity and engineering plastics and articles produced therefrom. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, or any combination thereof.

Abstract: The present invention provides an article with at least one switching segment. The switching segment comprises a shape-memory compound and an isolating region surrounding the shape memory compound. The present invention also provides a method of producing such an article.

Abstract: A polyurethane foam composition includes a polyol, a polyisocyanate, a catalyst, a foam stabilizer, a blowing agent and a fluorinated carbonate wherein the fluorinated carbonate is a compound represented by Formula 1: a compound represented by Formula 2: or a mixture thereof. Also disclosed is a polyurethane foam derived from the composition.

Abstract: A porous polyimide obtained by removing a silica phase from an organic-inorganic polymer hybrid having a molecule structure in which a polyimide phase and the silica phase are held together by covalent bond.

Abstract: A polishing pad generates very few scratches on a surface of a polishing object, and is excellent in planarization property. The polishing pad has a high polishing rate and is excellent in planarization property. The polishing pad grooves become very little clogged with abrasive grains or polishing swarf during polishing and, even when continuously used for a long period of time, the polishing rate is scarcely reduced.

Abstract: A process for producing a polyurethane product comprises steps of (a) supplying at least one polyisocyanate (b) supplying at least one polyol composition comprising at least about 5 weight percent based on total weight of polyols of at least one natural oil based polyol (b1) having a hydroxyl number of at most about 300 and a viscosity below about 10000 mPa·os; and (c) exposing the polyisocyanate and the polyol composition to reaction conditions such that urethane bonds are formed, wherein reaction conditions include the presence of at least one bismuth catalyst. Use of bismuth catalysts is particularly applicable to preparation of open celled, flexible polyurethane foams using polyols made from renewable resources, optionally with other polyols. The invention includes foams made by the process, including viscoelastic foams, preferably having a velvet feel.

Abstract: Porous bodies which are soluble or dispersible in non-aqueous media comprising a three dimensional open-cell lattice containing (a) 10 to 70% by weight of a polymeric material which is soluble in water immiscible non-aqueous media and (b) 30 to 90% by weight of a surfactant, said porous bodies having an intrusion volume as measured by mercury porosimetry of at least 3 ml/g.

Abstract: The invention relates to a polyisocyanurate comprising isocyanurate rings linked by linker groups coupled to the nitrogen atoms of said rings. The polyisocyanurate may be microporous or mesoporous or both microporous and mesoporous.

Abstract: Process for making a slabstock, visco-elastic, flexible, polyurethane foam which process comprises reacting a polyisocyanate and a polyol at an index of 60-95 and using a blowing agent, wherein 5-50 and preferably 10-40% by weight of the polyol used is castor oil. The foams and a polyol composition are claimed as well.

Abstract: The invention presents a new method to prepare biomedical polyurethanes with high tensile and tear strengths. Such polyurethanes are especially interesting for making foams thereof, e.g. as meniscus implants. A new method, applicable to the biomedical polyurethanes, has been found to make such foams, that can be used as scaffolds. This method is based on salt leaching and phase separation.

Abstract: The present invention provides a polyurethane implant that is porous and degradable, and act as a scaffold for the repair of damaged tissue. Importantly, the implant of the present invention is biocompatible with the degradation products of the implant causing minimal immune or cytotoxic reaction. The present invention also provides for a method of making these biocompatible implants.

Abstract: A protective barrier sealant product and methods of applying the same, including a high density polyurethane material provided in an amount, volume, and density effective for providing a protective barrier for a surface, wherein the polyurethane material is combined with at least one active agent just prior to or at the time of application of the sealant product to an object surface.

Abstract: A composition is provided which is suitable for producing polyurethane systems appropriate for hot adhesive bonding. The composition includes from 0.1 to 20% by mass of an additive mixture comprising at least one organic phosphorus compound either alone or in combination with a crosslinker or extender.

Abstract: Thermoset polyurethanes comprising a cis, trans-1,3- and -1,4-cyclohexanedimethylether moiety. Adducts of epoxy resins comprising a cis, trans-1,3- and -1,4-cyclohexanedimethylether moiety are used to react with a polyisocyanate to produce the thermoset polyurethanes.

Abstract: Various uses of fluorinated olefin having an MRI value of less than ethane, in combination with one or more other components, including other fluoroalkenes, hydrocarbons; hydrofluorocarbons (HFCs), ethers, alcohols, aldehydes, ketones, methyl formate, formic acid, water, trans-1,2-dichloroethylene, carbon dioxide and combinations of any two or more of these, in a variety of applications, including as blowing agents, are disclosed.

Abstract: Expanded products, more specifically, rigid or semi-flexible foams of low density from 1.5 to 12 lbs/ft3 or more, with closed cells can be manufactured. The products have a PVC backbone with branches with methacrylate crosslinked with isocyanate through a reaction activated by ultraviolet or microwave radiation. The use of polyfunctional monomers that are sensitive to irradiation yields a higher cross-link density, which improves the physical and mechanical properties such as hardness, resistance to abrasion, ductility, and resistance to friction. The selection of monomers and oligomers allows the manufacturer to determine of the final properties of the foam. The process yields foams with extreme hardness and better shear factors making the foam an ideal product for aerospace and windmill use. These physical properties emerge during the post-curing process, preferably by use of compounds based on methacrylates in dispersion with PVC and isocyanates.

Abstract: The present invention relates to an open-cell polyurethane foam comprising polyester and polyether structures and having a density of 70 to 300 g/L, 1 to 20 cells/cm, a rebound intensity greater than 30%, an elongation at break of greater than 200%, a tear propagation resistance of greater than 1.2 N/mm and a tensile strength of greater than 200 kPa. The present invention further relates to a process for producing inventive open-cell polyurethane sponges and to the use thereof as a pipe cleaning sponge.

Abstract: The present invention provides a process for the production of polyurethane foams from A1 compounds which contain hydrogen atoms which are reactive towards isocyanates and have a molecular weight of 400-15,000, A2 optionally compounds which contain hydrogen atoms which are reactive towards isocyanates and have a molecular weight of 62-399, A3 water and/or physical blowing agents, A4 optionally auxiliary substances and additives, such as a) catalysts which differ from component A5, b) surface-active additives, c) pigments or flameproofing agents, A5 at least one tin(II) salt of carboxylic acids, the carboxylic acid having from 10 to 16 carbon atoms, and B di- or polyisocyanates, wherein the resulting polyurethane foams have low emission values and a good resistance to ageing.

Abstract: It has been found that basalt particles, when combined with a resin binder and a reinforcing material, such as fiberglass, provide unexpected strength, fire-resistance, radiation impermeability, and projectile shielding for ballistic armor/shields, fire-resistant building panels, construction blocks and protective coatings on substrates. The armor panels can be worn, as in a bullet-proof vest, or can be used as a shield to protect a vehicle, aircraft or other structures as projectile penetration-resistant and fire and radiation resistant materials.

Abstract: A foam-forming composition is disclosed which includes both cis-1,1,1,4,4,4-hexafluoro-2-butene and a poorly compatible active hydrogen-containing compound having two or more active hydrogens. Also disclosed is a closed-cell polyurethane or polyisocyanurate polymer foam prepared from reaction of effective amounts of the foam-forming composition and a suitable polyisocyanate. Also disclosed is a process for producing a closed-cell polyurethane or polyisocyanurate polymer foam by reacting an effective amount of the foam-forming composition with a suitable polyisocyanate.

Abstract: A coalescing agent for facilitating the separation of a non-aqueous phase from an aqueous phase of an aqueous medium, said agent consisting of particles of a polymeric foam material having: an IFD no. of 40 or higher (i.e. at least 40); a BR no. of 35 or higher (at least 35); a SF no. of 1.8 or higher (i.e. at least 1.8) and a density of 42 kg/m3 or less.

Abstract: A polyurethane obtained by reaction between (i) at least one homopolymer obtained by homopolymerization of ?-caprolactone, and (ii) at least one dissocyanate, wherein said reaction between (i) and (ii) and said homopolymerization are performed in presence of a catalyst selected from (a) a catalyst containing bismuth ethylhexanoate and ethylhexanoic acid, (b) a catalyst containing bismuth ethylhexanoate and bismuth neodecanoate, and (c) a catalyst containing zinc neodecanoate and zinc oxide.

Abstract: The present invention relates to foamed polyurethane obtainable by mixing a) polyisocyanates, b) relatively high molecular weight compounds having groups reactive toward isocyanate groups, c) solid particles, d) blowing agents, e) if appropriate, chain extender, crosslinking agent or mixtures thereof, f) if appropriate, catalyst and g) if appropriate, other additives to give a reaction mixture and allowing the reaction mixture to react to completion, the proportion of chain extender being less than 6% by weight, based on the total weight of the components a) to f), the content of solid particles being greater than 15% by weight, based on the total weight of the components a) to f), and the average functionality of the relatively high molecular weight compounds having groups reactive toward isocyanate groups being less than 2.5.

Abstract: A foam-forming composition is disclosed which includes both trans-1,1,1,4,4,4-hexafluoro-2-butene and an active hydrogen-containing compound having two or more active hydrogens. Also disclosed is a closed-cell polyurethane or polyisocyanurate polymer foam prepared from reaction of effective amounts of the foam-forming composition and a suitable polyisocyanate. Also disclosed is a process for producing a closed-cell polyurethane or polyisocyanurate polymer foam comprising: reacting an effective amount of the foam-forming composition and a suitable polyisocyanate.

Abstract: A polyurethane-graphite oxide composite material or nano composite is described, containing graphite oxide in expanded form present optionally, together with a phyllosilicate in expanded form in a polyurethane matrix, a method for the preparation of this composite material as well as its use as a fire retardant or as a flame-retardant seal for openings and/or bushings in walls, floors and/or ceilings of buildings.

Abstract: A non-woven textile may be formed from a plurality of thermoplastic polymer filaments. The non-woven textile may have a first region and a second region, with the filaments of the first region being fused to a greater degree than the filaments of the second region. A variety of products, including apparel (e.g., shirts, pants, footwear), may incorporate the non-woven textile. In some of these products, the non-woven textile may be joined with another textile element to form a seam. More particularly, an edge area of the non-woven textile may be heatbonded with an edge area of the other textile element at the seam. In other products, the non-woven textile may be joined with another component, whether a textile or a non-textile.

Abstract: Macroporous monolithic silica aerogels having mesoporous walls are produced via an acid-catalyzed sol-gel process from tetramethoxysilane (TMOS) using a triblock co-polymer (Pluronic P123) as a structure-directing agent and 1,3,5-trimethylbenzene (TMB) as a micelle-swelling reagent. Pluronic P 123 was removed by solvent extraction, and monoliths were obtained by removing the pore-filling solvent with liquid CO2, which was removed under supercritical conditions. The resulting materials are more robust compared to base-catalyzed silica aerogels of similar density. Mechanical properties can be further improved by reacting a di-isocyanate with the silanol groups on the macro and mesoporous surfaces. The polymer forms a conformal coat on the macropores and blocks access to the mesopores of templated samples, so that BET surface areas decrease dramatically.

Abstract: Disclosed are new compositions consisting of polyphosphonates and specific additive compositions that exhibit superior resistance to degradation due to exposure to air, high temperature and air, moisture or combinations thereof. Also disclosed are polymer mixtures or blends comprising these polyphosphonates/additive compositions and commodity and engineering plastics and articles produced therefrom. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, or any combination thereof.

Abstract: Absorbable polyurethanes, polyamides and polyester urethanes prepared from at least one compound selected from: or the diamines and diisocyanates thereof, wherein each X represents a member independently selected from —CH2COO— (glycolic acid moiety), —CH(CH3)COO— (lactic acid moiety), —CH2CH2OCH2COO— (dioxanone), —CH2CH2CH2CH2CH2COO— (caprolactone moiety), —(CH2)yCOO— where y is one of the numbers 2, 3, 4 or 6-24 inclusive, and —(CH2CH2O)z?CH2COO— where z? is an integer between 2 and 24, inclusive; each Y represents a member independently selected from —COCH2O— (glycolic ester moiety), —COCH(CH3)O— (lactic ester moiety), —COCH2OCH2CH2O— (dioxanone ester), —COCH2CH2CH2CH2CH2O— (caprolactone ester), —CO(CH2)mO— where m is an integer between 2, 3, 4 or 6-24 inclusive, —COCH2O(CH2CH2O)n— where n is an integer between 2 and 24, inclusive; R? is hydrogen, benzyl or an alkyl group, the alkyl group being either straight-chained or branched; p is an integer between 1 and 4, inclusive; and Rn represents one or more

Abstract: A foam composite which comprises at least one layer of an open-celled amino resin foam MF and a polyurethane foam PU and in which at least one of the layers comprises a formaldehyde scavenger, in particular a foam composite comprising a core comprising an open-celled melamine-formaldehyde resin foam and sheathing comprising a polyurethane foam PU comprising the formaldehyde scavenger on all sides.