Cellular Product Formation Prior To Or During Solid Polymer Formation In The Presence Of A Stated Ingredient Other Than Water Patents (Class 521/99)
  • Patent number: 5739221
    Abstract: Expandable styrene resin beads are described, which, when expanded to a bulk density of 20 g/l, give pre-expanded beads in which the number of cells present along those surface parts of radii which range from the bead surface to a depth of 0.2 mm from the surface is from 3 to 20 per mm and to the bead center is 10 or larger per mm, the number of the number of cells present along those inner parts of the radii which range from a depth of 1 mm from the bead surface to the bead center is 10 or larger per mm, the number of cells present along said surface parts being smaller than the number of cells present along said inner parts.
    Type: Grant
    Filed: May 3, 1996
    Date of Patent: April 14, 1998
    Assignee: Mitsubishi Chemical BASF Company Limited
    Inventors: Hiroki Shinozaki, Masayuki Tanaka, Yonezo Ueda
  • Patent number: 5739173
    Abstract: A process for the preparation of flame-resistant soft polyurethane foams which produce less smoke in the event of fire involves reactinga) an organic polyisocyanate and/or a modified organic polyisocyanate withb) a high-molecular-weight compound containing at least two reactive hydrogen atoms and, if desired,c) a chain extender and/or crosslinking agent, in the presence ofd) a mixture of flameproofing agents which contains:di) melaminedii) expandable graphite and, if desired,diii) at least one further flameproofing agent, preferably a modified or unmodified ammonium polyphosphate,e) a blowing agent,f) a catalyst and, if desired,g) assistants and/or additives, and melamine/expandable graphite/polyether-polyol dispersions which are suitable for this purpose.
    Type: Grant
    Filed: September 20, 1995
    Date of Patent: April 14, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinz-Dieter Lutter, Ruth Zschiesche, Hans-Jurgen Gabbert, Volker Hasse, Karl Fimmel
  • Patent number: 5725815
    Abstract: The process of controlling foam in a foam-generating system by adding to the system a foam-inhibiting effective amount of a block copolymer containing alkylene oxide units obtained by reacting a homopolymer or copolymer of alkylene oxides with a diisocyanate or a dicarboxylic acid derivative containing 2 to 44 carbon atoms.
    Type: Grant
    Filed: November 9, 1995
    Date of Patent: March 10, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Horst-Werner Wollenweber, Thomas Moeller, Hans-Juergen Sladek, Heinz-Guenther Schulte, Wolfgang Gress, Ulrich Eicken, Herbert Fischer, Christian De Haut
  • Patent number: 5719201
    Abstract: A foamed isocyanate-based polymer having a cellular structure and containing a superabsorbent material, the polymer being capable of: (i) absorbing at least about 20 times its weight of an aqueous fluid maintained at a temperature of from about 20.degree. to about 25.degree. C., and (ii) retaining at least about 20 times its weight of absorbed aqueous fluid which is bound to the superabsorbent material. A process for producing a foamed isocyanate-based polymer comprising the steps of: providing a substantially uniform mixture comprising an isocyanate, an active hydrogen-containing compound and a superabsorbent material, the superabsorbent material being capable of absorbing at least about 20 times its weight of an aqueous fluid maintained at a temperature in the range of from about 20.degree. to about 25.degree. C.
    Type: Grant
    Filed: November 9, 1995
    Date of Patent: February 17, 1998
    Assignee: Woodbridge Foam Corporation
    Inventor: Robert N. Wilson
  • Patent number: 5716548
    Abstract: The invention provides polyurethane components and compositions capable of providing internal mold release properties in SRIM applications. The polyol composition of the invention has an isocyanate reactive polyol (A) having a number average molecular weight from 100 to about 10,000 and an effective amount of internal mold release composition (B) having a silicon-containing polymer (a) and an epoxidized ester (b). The invention further provides an SRIM polyurethane composition useful in the preparation of molded polyurethane articles having internal mold release properties, the composition comprising an isocyanate component (I) and the isocyanate reactive polyol composition (Component (II)) disclosed above. In another aspect of the invention, the invention provides methods of using the claimed compositions as well as the rigid cellular polyurethane SRIM articles resulting from such processes.
    Type: Grant
    Filed: April 23, 1996
    Date of Patent: February 10, 1998
    Assignee: BASF Corporation
    Inventors: Richard P. Harrison, Bari W. Brown, Richard C. Rossio, Gladys M. Aviles, Edward M. Dexheimer, David Ho
  • Patent number: 5707696
    Abstract: A scented plastic material such as a mesh net or scented bathing implement and method for producing same is taught. Briefly stated, a scented additive is simultaneously extruded with a plastic raw material in order to form an intermediate or raw stock. The intermediate or raw stock thereby has a particular scent or fragrance associated therewith and is embedded therein. The intermediate product is thereafter formed into a suitable end product.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: January 13, 1998
    Assignee: NSW Corporation, Inc.
    Inventor: Charles R. Boxler
  • Patent number: 5700845
    Abstract: Disclosed are foamable EPDM compositions comprising EPDM, a carbon black having a CTAB of about 50 to 60 m2/g and DBP of 90 to 115 cc/100 g and a blowing agent which are advantageous for use in applications where UHF microwave curing is utilized and for replacing foamable EPDM compositions incorporating similar amounts of conventional blends of carbon blacks. Also disclosed are foamed, cured EPDM compositions comprising: EPDM and a carbon black having a CTAB of about 50 to 60 m2/g and DBP of 90 to 115 cc/100 g which have advantageously lower sponge density and lower sponge compression set than EPDM compositions incorporating similar amounts of conventional low reinforcing carbon blacks. Further disclosed is a process for producing the foamed, cured EPDM compositions of the present invention. Additionally disclosed is use of the foamed, cured EPDM compositions of the present invention as weatherstripping.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: December 23, 1997
    Assignee: Cabot Corporation
    Inventors: Bin Chung, Bruce E. Mackay, Ivan Zlatko Podobnik
  • Patent number: 5698606
    Abstract: A process for the preparation of a fine celled, closed celled rigid polyurethane or urethane-modified polyisocyanate foam is disclosed which comprises reacting a polyfunctional isocyanate-reactive composition with a polyisocyanate composition, characterized in that the foam-forming composition comprises carbon black.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: December 16, 1997
    Assignee: Imperial Chemical Industries PLC
    Inventors: Rik De Vos, Anthony Cunningham
  • Patent number: 5691391
    Abstract: A variable pitch fan for a helicopter equipped with a NOTAR.RTM. mechanical antitorque directional control system comprises a plurality of blade assemblies. Each blade assembly includes a blade portion, which is molded from a blended material which includes fiber reinforced polypropylene. A key to the invention is the use of long fibers, having a length of at least approximately one-half inch, for reinforcement, the long fibers providing for about twice the pull-out strength of short or chopped fibers. Another key aspect of the invention is the use of a blowing agent in the blended material, which serves to reduce weight and warpage by creating a foamed structure having a variable density, the structure retaining considerable strength because of the fiber reinforcement. The blade portion is molded about a spar which has holes therethrough, the holes providing a mechanical interlock between the blade and the spar.
    Type: Grant
    Filed: December 5, 1994
    Date of Patent: November 25, 1997
    Assignee: McDonnell Douglas Helicopter
    Inventors: Steve P. Chen, John E. Schibler, Ramesh J. Patel
  • Patent number: 5674917
    Abstract: A foamed isocyanate-based polymer having a cellular structure and containing a superabsorbent material, the polymer being capable of: (i) absorbing at least about 20 times its weight of an aqueous fluid maintained at a temperature of from about 20.degree. to about 25.degree. C., and (ii) retaining at least about 20 times its weight of absorbed aqueous fluid which is bound to the superabsorbent material. A process for producing a foamed isocyanate-based polymer comprising the steps of: providing a substantially uniform mixture comprising an isocyanate, an active hydrogen-containing compound and a superabsorbent material, the superabsorbent material being capable of absorbing at least about 20 times its weight of an aqueous fluid maintained at a temperature in the range of from about 20.degree. to about 25.degree. C.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: October 7, 1997
    Assignee: Woodbridge Foam Corporation
    Inventor: Robert N. Wilson
  • Patent number: 5668189
    Abstract: A foamed isocyanate-based polymer containing a filler material, the filler material being present at a level greater than 30% by weight of the polymer and having a specific gravity of less than about 2.0 with the provisio that the filler material is not melamine. A process for producing the a foamed isocyanate-based polymer is also disclosed. The process comprises the steps of: providing a first mixture comprising water, a catalyst and a substantially inert filler material, the filler material being wetted by the water and the catalyst; providing a second mixture comprising an isocyanate and an active hydrogen-containing compound; mixing the first mixture and the second mixture to provide a reaction mixture; allowing the reaction mixture to expand to produce the foamed isocyanate-based polymer.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: September 16, 1997
    Assignee: Woodbridge Foam Corporation
    Inventor: Paul V. Farkas
  • Patent number: 5656344
    Abstract: The electroconductive polyurethane foam according to the present invention is obtained by adding and dispersing, in the composition constituting polyurethane foam, a substance with electron conduction mechanism, and a substance with ionic conduction mechanism and mechanically agitating the resultant mixture in the presence of inert gas. The substance with ionic conduction mechanism is an antistatic agent selected from cationic surfactant, anionic surfactant, ampholytic surfactant, and non-ionic surfactant.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: August 12, 1997
    Assignee: Bridgestone Corporation
    Inventors: Eiji Sawa, Hiroya Fukuda, Shohei Morikawa, Hitoshi Yaguchi, Yuichiro Mori
  • Patent number: 5627219
    Abstract: A foamed plastic manufactured by foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in the foams of the foamed plastic is less than atmospheric pressure, is disclosed. Further, a foamed plastic manufactured by hermetically sealing with an airtight film and foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in a gap region between the airtight film and the foamed plastic and the pressure in the foams of the foamed plastic are less than atmospheric pressure is disclosed. Further, a method of manufacturing foamed plastic comprising foaming a mixture of a volatile polymerizable foaming agent and a resin, and irradiating the foamed plastic with an energy beam.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 6, 1997
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Kazufumi Ogawa
  • Patent number: 5605762
    Abstract: The invention provides polyurethane components and compositions capable of providing internal mold release properties in SRIM applications. The polyol composition of the invention has an isocyanate reactive polyol (A) having a number average molecular weight from 100 to about 10,000 and an effective amount of internal mold release composition (B) having a silicon-containing polymer (a) and an epoxidized ester (b). The invention further provides an SRIM polyurethane composition useful in the preparation of molded polyurethane articles having internal mold release properties, the composition comprising an isocyanate component (I) and the isocyanate reactive polyol composition (component (II)) disclosed above. In another aspect of the invention, the invention provides methods of using the claimed compositions as well as the rigid cellular polyurethane SRIM articles resulting from such processes.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: February 25, 1997
    Assignee: BASF Corporation
    Inventors: Richard P. Harrison, Bari W. Brown, Richard C. Rossio, Gladys M. Aviles, Edward M. Dexheimer, David Ho
  • Patent number: 5604265
    Abstract: A process for the preparation of a fine celled, closed celled rigid polyurethane or urethane-modified polyisocyanate foam is disclosed which comprises reacting a polyfunctional isocyanate-reactive composition with a polyisocyanate composition, characterized in that the foam-forming composition comprises carbon black.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: February 18, 1997
    Assignee: Imperial Chemical Industries PLC
    Inventors: Rik De Vos, Anthony Cunningham
  • Patent number: 5602188
    Abstract: Foam forming techniques capable of permitting foaming of biodegradable resin to be positively and uniformly accomplished to provide a biodegradable resin foam with satisfactory quality. The biodegradable resin foam is made of biodegradable resin consisting of a main biodegradable resin ingredient of 100.degree. C. or more in melting point and a low-melting biodegradable resin ingredient of 100.degree. C. or less in melting point. The biodegradable resin foam is produced by placing a starting material consisting of at least biodegradable resin and a substantial amount of moisture in a heated and pressurized environment, releasing the starting material from the environment to foam the biodegradable resin, and subjecting the foamed resin to forming by means of a forming mold. An apparatus for producing the foamed biodegradable resin foam includes a pressure adjusting chamber, an air-permeable forming mold, a pressure reducing tank and an injection machine.
    Type: Grant
    Filed: July 12, 1994
    Date of Patent: February 11, 1997
    Assignee: Suzuki Sogyo Co., Ltd.
    Inventor: Motoyasu Nakanishi
  • Patent number: 5596021
    Abstract: The present invention relates to a crosslinkable polyester/isocyanate composition suitable for preparing composite manufactured articles endowed with high structural mechanical properties, by means of injection processes, comprising:A--a polyfunctional isocyanate;B--an unsaturated polyester resin, or a vinyl ester resin, or a mixture of both said resins, wherein said resin can contain free hydroxy groups;C--a free-radical polymerization initiator;D--a promoter of decomposition of (C) initiator;E--a catalyst of (A) isocyanate trimerization.
    Type: Grant
    Filed: September 15, 1994
    Date of Patent: January 21, 1997
    Assignee: Sir Industriale S.p.A.
    Inventors: Andrea Adembri, Lino Credali, Giovanni Di Drusco
  • Patent number: 5594037
    Abstract: The invention provides polyurethane components and compositions capable of providing internal mold release properties in SRIM applications. The polyol composition of the invention has an isocyanate reactive polyol (A) having a number average molecular weight from 100 to about 10,000 and an effective amount of internal mold release composition (B) having a silicon-containing polymer (a) and an epoxidized ester (b). The invention further provides an SRIM polyurethane composition useful in the preparation of molded polyurethane articles having internal mold release properties, the composition comprising an isocyanate component (I) and the isocyanate reactive polyol composition (component (II)) disclosed above. In another aspect of the invention, the invention provides methods of using the claimed compositions as well as the rigid cellular polyurethane SRIM articles resulting from such processes.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: January 14, 1997
    Assignee: BASF Corporation
    Inventors: Richard P. Harrison, Bari W. Brown, Richard C. Rossio, Gladys M. Aviles, Edward M. Dexheimer, David Ho
  • Patent number: 5587220
    Abstract: A foamed plastic manufactured by foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in the foams of the foamed plastic is less than atmospheric pressure, is disclosed. Further, a foamed plastic manufactured by hermetically sealing with an airtight film and foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in a gap region between the airtight film and the foamed plastic and the pressure in the foams of the foamed plastic are less than atmospheric pressure is disclosed. Further, a method of manufacturing foamed plastic comprising foaming a mixture of a volatile polymerizable foaming agent and a resin, and irradiating the foamed plastic with an energy beam.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 24, 1996
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Kazufumi Ogawa
  • Patent number: 5583197
    Abstract: The invention provides polyurethane components and compositions capable of providing internal mold release properties in SRIM applications. The polyol composition of the invention has an isocyanate reactive polyol (A) having a number average molecular weight from 100 to about 10,000 and an effective amount of internal mold release composition (B) having a silicon-containing polymer (a) and an epoxidized ester (b). The invention further provides an SRIM polyurethane composition useful in the preparation of molded polyurethane articles having internal mold release properties, the composition comprising an isocyanate component (I) and the isocyanate reactive polyol composition (component (II)) disclosed above. In another aspect of the invention, the invention provides methods of using the claimed compositions as well as the rigid cellular polyurethane SRIM articles resulting from such processes.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: December 10, 1996
    Assignee: BASF Corporation
    Inventors: Richard P. Harrison, Bari W. Brown, Richard C. Rossio, Gladys M. Aviles, Edward M. Dexheimer, David Ho
  • Patent number: 5571847
    Abstract: Disclosed is a compatibilized carbon black useful in melt processing of plastic material. The carbon black is coated with a compatibilizing agent which enhances the dispersibility of the carbon black in a melt of the plastic material. Further disclosed are processes for making plastic foam structures with the compatibilized carbon black.
    Type: Grant
    Filed: June 9, 1995
    Date of Patent: November 5, 1996
    Assignee: The Dow Chemical Company
    Inventors: Martin K. Hitchcock, Kyung W. Suh, Arnold M. Bartz, Andrew N. Paquet, William G. Stobby
  • Patent number: 5556891
    Abstract: The invention relates to prepolymers containing isocyanate groups which can be prepared by reactinga) organic isocyanates withb) polyetherols containing at least 2 hydroxyl groups per molecule and having molecular weights of greater than 400 and/or polyesterols containing at least 2 hydroxyl groups per molecule and having molecular weights of greater than 400,c) isocyanate-reactive compounds which are at least difunctional and have molecular weights of from 18 to 399, and, if desired,d) Lewis and/or Bronsted acidic compounds ande) conventional auxiliaries and additives, such as antioxidants, light stabilizers or fillers,wherein at least one aromatic aminopolyether alcohol of the formula ##STR1## where R is aryl, alkylaryl containing one or more C.sub.1 - to C.sub.4 -alkyl groups, haloaryl, nitroaryl or cyanoaryl,R' and R" are identical or different and are, independently of one another, hydrogen, alkyl, aryl, aralkyl, alkoxyalkyl, alkoxyaryl or aroxyaryl,x and y are independent of one another andx+y.gtoreq.
    Type: Grant
    Filed: November 1, 1995
    Date of Patent: September 17, 1996
    Assignee: BASF Schwarzheide GmbH
    Inventors: Holger Seifert, Juergen Winkler, Regina Pretzsch, Robert O'Meara
  • Patent number: 5547996
    Abstract: Reacting carbonyls, such as aldehydes and ketones, with amines produces a ketimine or aldimine and a water byproduct. When the ketimine or aldimine reaction occurs in a polymer composition, the polymer becomes foamed due to the evolution of water. Hence, carbonyl and amine containing compounds may be introduced into a polymeric composition to serve as an in-situ blowing agent. The carbonyl and amine containing compounds may be different polymers which will be combined through a ketimine or aldimine linkage to form a graft co-polymer, they may be small molecular weight additives that are placed in the composition with a polymer that is to be foamed as a byproduct of a ketimine or aldimine reaction of the additives, or they may be a polymer containing a carbonyl or amine moiety and a small molecular weight additive compound that will react with the moiety on the polymer to form a ketimine or aldimine.
    Type: Grant
    Filed: July 29, 1994
    Date of Patent: August 20, 1996
    Assignee: The Center for Innovative Technology
    Inventors: Donald K. Brandom, Jose P. DeSouza, Donald G. Baird, Garth L. Wilkes
  • Patent number: 5547608
    Abstract: The invention provides polyurethane components and compositions capable of providing internal mold release properties in SRIM applications. The polyol composition of the invention has an isocyanate reactive polyol (A) having a number average molecular weight from 100 to about 10,000 and an effective amount of internal mold release composition (B) having a silicon-containing polymer (a) and an epoxidized ester (b). The invention further provides an SRIM polyurethane composition useful in the preparation of molded polyurethane articles having internal mold release properties, the composition comprising an isocyanate component (I) and the isocyanate reactive polyol composition (component (II)) disclosed above. In another aspect of the invention, the invention provides methods of using the claimed compositions as well as the rigid cellular polyurethane SRIM articles resulting from such processes.
    Type: Grant
    Filed: September 9, 1994
    Date of Patent: August 20, 1996
    Assignee: BASF Corporation
    Inventors: Richard P. Harrison, Bari W. Brown, Richard C. Rossio, Gladys M. Aviles, Edward M. Dexheimer, David Ho
  • Patent number: 5523330
    Abstract: A process for producing a foamed isocyanate-based polymer based on an amount of water and an amount of catalyst, the process comprising the steps of: providing a first stream comprising a particulate, non-cellular filler material surrounded by a mixture comprising less than 100% by weight of the amount of water and less than 100% by weight of the amount catalyst; providing a second stream comprising an active hydrogen-containing compound and the remainder of the amount of water and the amount of catalyst; providing a thin stream comprising an isocyanate; feeding each of the first stream, the second stream and the third stream-independently of one another to a mixing device; mixing the first stream, the second stream and the third stream in the mixing device to produce a reaction mixture; and allowing the reaction mixture to expand to produce the foamed isocyanate-based polymer. A system for alternating between production of filled or untilled isocyanate-base foam is also provided.
    Type: Grant
    Filed: July 21, 1994
    Date of Patent: June 4, 1996
    Assignee: Woodbridge Foam Corporation
    Inventor: Paul V. Farkas
  • Patent number: 5498409
    Abstract: An insoluble material for adsorbing a pyrogen comprising a polymer of an aziridine compound. According to the present invention, a large amount of the pyrogen can be easily removed from a solution containing pyrogen, and a large amount of the material for adsorbing the pyrogen can be prepared in easy steps. Therefore, the adsorbing material can greatly contribute to the preparation of medicines.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: March 12, 1996
    Assignees: Chuichi Hirayama, Kohjin Co., Ltd.
    Inventors: Chuichi Hirayama, Keijun Hiraoka, Sunao Morimoto
  • Patent number: 5482978
    Abstract: An expandable conductive-silicone rubber composition includes (A) an organopolysiloxane having at least two alkenyl groups, (B) conductive carbon black, (C) an organic peroxide of the formula: ##STR1## wherein R.sup.2 and R.sup.3 each are a monovalent C.sub.3 -C.sub.10 hydrocarbon group or a group of --SiR.sup.4.sub.3 wherein R.sup.4 is methyl, ethyl or phenyl, X is --(CH.sub.2).sub.n --, --CH.sub.2 --C(CH.sub.3).sub.2 --CH.sub.2 -- or --(C.sub.2 H.sub.4 O).sub.m --C.sub.2 H.sub.4 -- wherein n=2 to 8 and m=1 to 4, (D) an organohydrogenpolysiloxane, (E) a platinum catalyst, and (F) a blowing agent. It is fully stable during shelf storage, has a long pot life, and is rapidly expandable and curable through hot air vulcanization into conductive silicone rubber foam having high conductivity and improved fatigue endurance of sponge cells when the foam is used as a sponge roll.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: January 9, 1996
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masaharu Takahashi, Tomiyoshi Tsuchida
  • Patent number: 5474740
    Abstract: The present invention relates to apparatus for transferring constituents into and out of a fluid such as blood. The apparatus includes a biphasic foam body which functions as a blood oxygenator, blood dialyzer, or other blood mass transfer device.
    Type: Grant
    Filed: September 2, 1994
    Date of Patent: December 12, 1995
    Inventors: Leonard A. Trudell, Anthony D. Whittemore
  • Patent number: 5472639
    Abstract: A lightweight, electroconductive foam comprising an effective amount of a conductive ionic salt, a polymer capable of complexing said conductive ionic salt and an effective amount of particulate conductive material such as carbon black or metal is disclosed. Additionally, a method of preparing a lightweight electroconductive foam having a surface resistivity less than about 10.sup.10 ohms per square by an extrusion process is disclosed. Foams of the present invention exhibit relatively high conductivities yet require only relatively low amounts of particulate conductive material.
    Type: Grant
    Filed: August 13, 1993
    Date of Patent: December 5, 1995
    Assignee: The Dow Chemical Company
    Inventor: Peter C. Yao
  • Patent number: 5468783
    Abstract: Polyaromatic polyisocyanates are modified by reaction with 0.1 to 10 weight %, preferably 2 to 7 weight % (based on polyisocyanate) of a polyether alcohol of molecular weight 206 to 948, obtainable by the reaction of alkylene oxides with C.sub.6 -C.sub.30, preferably C.sub.8 -C.sub.20, hydrocarbons containing 1 to 3 active H atoms, and are used for the production of rigid polyurethane foamed materials.
    Type: Grant
    Filed: March 1, 1995
    Date of Patent: November 21, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Gebauer, Pramod Gupta, Christian Konig
  • Patent number: 5461083
    Abstract: A foamed plastic manufactured by foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in the foams of the foamed plastic is less than atmospheric pressure, is disclosed. Further, a foamed plastic manufactured by hermetically sealing with an airtight film and foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in a gap region between the airtight film and the foamed plastic and the pressure in the foams of the foamed plastic are less than atmospheric pressure is disclosed. Further, a method of manufacturing foamed plastic comprising foaming a mixture of a volatile polymerizable foaming agent and a resin, and irradiating the foamed plastic with an energy beam.
    Type: Grant
    Filed: July 16, 1992
    Date of Patent: October 24, 1995
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Kazufumi Ogawa
  • Patent number: 5461098
    Abstract: Disclosed is a compatibilized carbon black useful in melt processing of plastic material. The carbon black is coated with a compatibilizing agent which enhances the dispersibility of the carbon black in a melt of the plastic material. Further disclosed are processes for making plastic foam structures with the compatibilized carbon black.
    Type: Grant
    Filed: August 26, 1994
    Date of Patent: October 24, 1995
    Assignee: The Dow Chemical Company
    Inventors: Martin K. Hitchcock, Kyung W. Suh, Arnold M. Bartz, Andrew N. Paquet, William G. Stobby
  • Patent number: 5447921
    Abstract: A thermosetting unsaturated polyester-polyurethane hybrid foam resin composition is made without significant blistering by using a 2-component catalyst system--one which initiates at room temperature and one which initiates at a temperature of at least 75.degree. C. and has a one-hour half-life temperature of at least 90.degree. C.; the composition has a room temperature stability of at least thirty days.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: September 5, 1995
    Assignee: Aristech Chemical Corporation
    Inventors: Keith A. Borden, David S. Jensen, Robert E. Anderson
  • Patent number: 5432204
    Abstract: A foamed isocyanate-based polymer containing a filler material, the filler material being present at a level greater than 30% by weight of the polymer and having a specific gravity of less than about 2.0 with the provisio that the filler material is not melamine. A process for producing the a foamed isocyanate-based polymer is also disclosed. The process comprises the steps of: providing a first mixture comprising water, a catalyst and a substantially inert filler material, the filler material being wetted by the water and the catalyst; providing a second mixture comprising an isocyanate and an active hydrogen-containing compound; mixing the first mixture and the second mixture to provide a reaction mixture; allowing the reaction mixture to expand to produce the foamed isocyanate-based polymer.
    Type: Grant
    Filed: June 11, 1993
    Date of Patent: July 11, 1995
    Assignee: Woodbridge Foam Corporation
    Inventor: Paul V. Farkas
  • Patent number: 5420168
    Abstract: A process whereby Resorcinol/Formaldehyde (RF) aerogel having a density of about 0.4-1.2 g/cc can be manufactured using a simple air drying procedure. This process is inherently simpler, quicker, and less expensive than the more conventional supercritical or subcritical CO.sub.2 extraction procedures. RF aerogels can be used as produced, such as in insulation applications, or pyrolyzed to form carbon aerogels with a density of about 0.9 g/cc for use in applications such as batteries, supercapacitors, etc.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: May 30, 1995
    Assignee: The Regents of the University of California
    Inventors: Steven T. Mayer, James L. Kaschmitter, Richard W. Pekala
  • Patent number: 5415499
    Abstract: This invention relates to a method of repairing existing manholes and similar structures by applying a fast-curing elastomeric material using spray techniques whereby a homogeneous, non-porous, and monolithic coating or lining is formed. The fast-curing elastomeric material can be applied directly to existing substrates, which may comprise of concrete, brick, tile, mortar, and metal surfaces normally found in sewer manholes and catch basins, sewer and drainage pipes, parking decks, bridge piers and footings, holding ponds, bridge trusses, culverts, gratings, and the like and does not require any formwork. More preferably, the substrate surfaces are first cleaned and primed to improve the bond of elastomeric coating to the substrate. The most preferred primer is an aqueous solution of silane, preferably containing 10% to 30% silane.
    Type: Grant
    Filed: October 19, 1993
    Date of Patent: May 16, 1995
    Assignee: Foamseal, Inc.
    Inventors: Peter K. Hyde-Smith, Yeara Houvras
  • Patent number: 5397808
    Abstract: The present invention is directed to the discovery that a specific combination of HCFC-141b, certain perfluorinated compounds and carbon black significantly improve the insulating capacity of isocyanate-based foams when compared to foams made without all three ingredients.
    Type: Grant
    Filed: May 12, 1994
    Date of Patent: March 14, 1995
    Assignee: Miles Inc.
    Inventors: Herman P. Doerge, Joseph M. Sutej, Edward E. Ball, John F. Szabat
  • Patent number: 5397807
    Abstract: Disclosed is a compatibilized carbon black useful in melt processing of plastic material. The carbon black is coated with a compatibilizing agent which enhances the dispersibility of the carbon black in a melt of the plastic material. Further disclosed are processes for making plastic foam structures with the compatibilized carbon black.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: March 14, 1995
    Assignee: The Dow Chemical Company
    Inventors: Martin K. Hitchcock, Kyung W. Suh, Arnold M. Bartz, Andrew N. Paquet, William G. Stobby
  • Patent number: 5382603
    Abstract: The variations in the delivery rate of additive caused by fluctuations in a system for the preparation of a polyurethane reaction mixture from flowable reactants and an additive, in particular a blowing agent, are kept within negligible limits by subdividing the supply pipe (4) to the mixing head (6) into a main pipe (8) and a subpipe (9) and introducing the additive into the side stream, which is substantially smaller than the main stream.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: January 17, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Kurt Krippl, Wilfried Ebeling, Jurgen Fietz, Hans-Michael Sulzbach, Reiner Raffel, Ferdinand Althausen
  • Patent number: 5382602
    Abstract: Flexible, slabstock polyurethane foam compositions useful for a rapid-cool process are disclosed. The foams are produced in the presence of a tetravalent tin catalyst, preferably at a relatively low isocyanate index, and preferably with a polyol that contains a non-volatile inhibitor. The foams of the invention eliminate or greatly reduce the amount of visible smoke produced in a rapid-cool process.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: January 17, 1995
    Inventors: Robert D. Duffy, George Combs
  • Patent number: 5373028
    Abstract: In a method of preparing a poly-urethane and/or -urea foam from a formulation including (a) a polyisocyanate, (b) an isocyanate-reactive component, and (c) a visible emissions producing component, wherein (a), (b) and (e) are reacted under reaction conditions sufficient to form a poly-urethane and/or -urea foam and the foam is then cooled, whereby visible emissions are emitted during cooling, an improvement comprising including in the formulation a visible emissions reducing agent, such that the amount of the visible emissions is reduced as compared with the amount emitted by a foam prepared from a formulation which does not contain the visible emissions reducing agent but which is otherwise substantially similar. Foams prepared therefrom exhibit reduction in visible emissions during the cure period, which is particularly evident when the foams are mechanically cooled. They also exhibit generally good physical properties.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: December 13, 1994
    Assignee: The Dow Chemical Company
    Inventors: Carl D. McAfee, Richard G. Skorpenske, Don H. Ridgway, Stephen K. Lewis, Eugene P. Wiltz, Jr.
  • Patent number: 5373026
    Abstract: Disclosed is a method of insulating a surface or enclosure by applying to the surface or enclosure a polymeric foam structure of a polymer material and carbon black. The carbon black is generally uniformly dispersed in the polymer matrix in the form of discrete particles substantially free of agglomeration. A preferred carbon black is thermal black. The carbon black provides a number of advantages over those previously employed commercially. Further disclosed is a process for making the foam structure. Further disclosed is an extruded, insulative foam structure of the type described above.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: December 13, 1994
    Assignee: The Dow Chemical Company
    Inventors: Arnold M. Bartz, Martin K. Hitchcock
  • Patent number: 5369137
    Abstract: Disclosed is a flexibilized, insulative styrenic polymer foam structure comprising a foam of a polymeric composition of a styrenic polymer greater than 50 percent by weight styrenic monomeric units, the foam having relatively larger primary cells with an average cell size range of about 0.05 to about 1.2 millimeters and relatively smaller secondary cells ranging in cell size from about 5 percent to about 50 percent of the average cell size of the primary cells. The primary and secondary cells constitute at least about 90 percent of the total cell volume within the foam structure. Between 1 and 30 percent by number of the cells have microscopic "pinholes" between them. The presence of the pinholes enhances the flexure of the foam structure. Further disclosed is a method of insulating a surface comprising applying to the surface an insulating panel fashioned from the structure of claim 1.
    Type: Grant
    Filed: April 20, 1994
    Date of Patent: November 29, 1994
    Assignee: The Dow Chemical Company
    Inventors: Andrew N. Paquet, Kyung W. Suh
  • Patent number: 5360831
    Abstract: The present invention concerns a process for the preparation of foam-in-fabric articles useful in furniture and automotive applications such as car seats, arm seats and head rests. According to the present invention a flexible or semi-flexible foam formulation is frothed with a non-reactive gas when poured onto a foam hacking of a composite cover, and allowed to rise and cure.
    Type: Grant
    Filed: June 15, 1993
    Date of Patent: November 1, 1994
    Assignee: Polyol International B.V.
    Inventors: Werner A. Lidy, Gerard Gatouillat, Francois M. Casati
  • Patent number: 5344852
    Abstract: Water blown, thermosetting unsaturated polyester-polyurethane hybrid foam compositions are formed by the reaction of an A side composition and a B side composition. The A side composition comprises a polyfunctional isocyanate compound and a free radical initiator. The B side composition comprises a mixture of: (i) an ethylenically unsaturated monomer solution having dissolved therein about 30-90 weight percent of a polyester polyol having at least one ethylenically unsaturated group per molecule which has predominantly hydroxyl end groups; (ii) an amine compound having two or more primary or secondary amine groups in an amount effective to react with the A side composition to form small urea domains finely dispersed within a continuous polyester-polyurethane hybrid phase; and (iii) about 25 to about 150 equivalents water based on 100 equivalents of active hydrogen in the B side.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: September 6, 1994
    Assignee: Aristech Chemical Corporation
    Inventors: Gary T. Brooks, Harold R. Edwards, Jr., Kathy J. Thrash, Donald E. Rubis, David P. Sinclair
  • Patent number: 5342855
    Abstract: This invention relates to a process for the preparation of stable dispersions of hydroxyl-containing polyhydrazodicarbonamides in a hydroxyl-containing compound. The dispersions are prepared by the reaction of organic isocyanates, isocyanate-reactive compounds having a molecular weight in the range from 400 to 10,000, relatively low molecular weight isocyanate-reactive compounds, and hydrazines or hydrazides. This invention further relates to the dispersions prepared by said process, the use of the dispersions to prepare polyurethane foams having exceptional hardness, and the foams prepared thereby.
    Type: Grant
    Filed: January 23, 1990
    Date of Patent: August 30, 1994
    Assignee: Miles Inc.
    Inventors: Michael A. Lucarelli, Richard E. Keegan, Mark A. Koshute, Hans-Albrecht Freitag, Geza Avar
  • Patent number: 5336695
    Abstract: Hydrophilic foams based on a polyurethane gel material which can be obtained fromone or more polyether-polyols selected from the group comprising substances formed by the addition of propylene oxide and optionally ethylene oxide on to conventional starter molecules,one or more diisocyanates,one or more superabsorbers,one or more accelerators selected from the group comprising conventional accelerators for polyurethanes,water, and optionallyconventional auxiliary substances and/or additives.
    Type: Grant
    Filed: October 4, 1993
    Date of Patent: August 9, 1994
    Assignee: Beiersdorf Aktiengesellschaft
    Inventors: Martina Nass, Heidi Sacker
  • Patent number: 5332762
    Abstract: Blowing agent compositions (a) comprising aqueous emulsions containing organopolysiloxanes (1), emulsifiers (2), water (3) and thickeners (4) which may be used in the preparation of elastomeric silicone foams.The blowing agent compositions are used in curable compositions to form elastomeric silicone foams which comprise the blowing agent compositions (a), diorganopolysiloxanes (b), crosslinking agents (c) and, if appropriate, crosslinking catalysts (d) and optionally fillers (e). Elastomeric silicone foams are prepared by mixing the blowing agent compositions (a), with curable organopolysiloxane compositions containing diorganopolysiloxanes (b), crosslinking agents (c) and, if appropriate, crosslinking catalysts (d) and optionally fillers (e) and also optionally additional substances and then the resultant mixture is cured at temperatures in the range of from 100.degree. to 250.degree. C. with simultaneous foaming to form the elastomeric silicone foams.
    Type: Grant
    Filed: April 9, 1993
    Date of Patent: July 26, 1994
    Assignee: Wacker-Chemie GmbH
    Inventors: Adolf Maschberger, Christian Freyer
  • Patent number: 5331016
    Abstract: To arrive at an economical method of producing water-expanded polymer resin moldings, it is proposed that a monomer component and a cross-linker on an acrylate basis and/or a PMMA prepolymer be used as resin-forming components of a curable mixture.
    Type: Grant
    Filed: October 18, 1993
    Date of Patent: July 19, 1994
    Assignee: Schock & Co., GmbH
    Inventors: Lothar Frank, deceased, Gunter Hieber
  • Patent number: 5312844
    Abstract: A method of producing injection molded in-line skate wheels is disclosed. The method includes heating an injection molding unit suitable for injecting molten polyurethane, placing a thermoplastic polyether type polyurethane into the unit and heating the polyurethane until it is molten or at about 380.degree. to about 460.degree. F. A polyurethane hub is placed in a mold whereby the mold and hub are of shapes and sizes suitable for producing in-line skate wheels. The hub-containing mold is heated to about 50.degree. to about 100.degree. F. in order to prevent the molten polyurethane from prematurely hardening. Once the mold is heated, about 46 to about 50 g of polyurethane is injected into the mold at about 75 to about 100 psi. The polyurethane is cooled to about 120.degree. to about 130.degree. F. to allow the polyurethane to harden and the resulting wheel is removed from the mold.
    Type: Grant
    Filed: May 14, 1993
    Date of Patent: May 17, 1994
    Assignee: S&W Plastics, Inc.
    Inventors: Stanley W. Gonsior, Dennis L. Hvam