Abstract: Methods of forming a graphene material on a surface are presented. A metal material is disposed on a material substrate or material layer and is infused with carbon, for example, by exposing the metal to a carbon-containing vapor. The carbon-containing metal material is annealed to cause graphene to precipitate onto the bottom of the metal material to form a graphene layer between the metal material and the material substrate/material layer and also onto the top and/or sides of the metal material. Graphene material is removed from the top and sides of the metal material and then the metal material is removed, leaving only the graphene layer that was formed on the bottom of the metal material. In some cases graphene material that formed on one or more side of the sides of the metal material is not removed so that a vertical graphene material layer is formed.

Abstract: The invention presents a simple, non-destructive and non-abrasive method of diamond nucleation using polyethene. It particularly describes the nucleation of diamond on an electrically viable substrate surface using polyethene via chemical vapor deposition (CVD) technique in a gaseous environment.

Abstract: A method for growing an array of carbon nanotubes includes the steps of: (a) providing a substrate having a first substrate surface and a second substrate surface opposite to the first substrate surface; (b) forming a catalyst film on the first substrate surface; (c) flowing a mixture of a carrier gas and a first carbon source gas over the catalyst film on the first substrate surface; (d) focusing a laser beam on the second substrate surface to locally heat the substrate to a predetermined reaction temperature; and (e) growing an array of the carbon nanotubes on the first substrate surface via the catalyst film.

Abstract: A conductive paste composition is provided. The conductive paste composition includes 20 to 70 weight % of silver nanoparticles having an average particle size of 1 nm to 250 nm based on a total weight of the conductive paste composition, and 0.01 to 2 weight % of silver-decorated carbon nanotubes based on the total weight of the conductive paste composition.

Abstract: A method for producing a metamaterial including an electromagnetic wave resonator resonating with an electromagnetic wave. The method includes the steps of: (a) forming a support by a nanoimprint method or a photolithography method, the support including a portion on which an electromagnetic wave resonator is to be formed; and (b) vapor-depositing a material which can form the electromagnetic wave resonator on the portion of the support to thereby arrange the electromagnetic wave resonator on the support.

Abstract: Processes for synthesizing graphene films. Graphene films may be synthesized by heating a metal or a dielectric on a substrate to a temperature between 400° C. and 1,400° C. The metal or dielectric is exposed to an organic compound thereby growing graphene from the organic compound on the metal or dielectric. The metal or dielectric is later cooled to room temperature. As a result of the above process, standalone graphene films may be synthesized with properties equivalent to exfoliated graphene from natural graphite that is scalable to size far greater than that available on silicon carbide, single crystal silicon substrates or from natural graphite.

Abstract: A method of growing carbonaceous particles comprises depositing carbon from a carbon source, onto a particle nucleus, the particle nucleus being a carbon-containing material, an inorganic material, or a combination comprising at least one of the foregoing, and the carbon source comprising a saturated or unsaturated compound of C20 or less, the carbonaceous particles having a uniform particle size and particle size distribution. The method is useful for preparing polycrystalline diamond compacts (PDCs) by a high-pressure, high temperature (HPHT) process.

Abstract: The present disclosure relates to a method for the synthesis of at least one metallic nanotube (10). The method includes the steps of: growing at least one nanowhisker (6) on a substrate (2), the nanowhisker (6; 12) consisting of or having a coating of a first metal (12); coating said first metal (12) with a second metal (14) to form a coated nanowhiskers (8); and heat treating the at least one coated nanowhisker (8), to produce a metallic nanotube (10). Moreover, the present teaching relates to metallic nanotubes (10) grown by the method of the present teaching.

Abstract: A metal plate or wire coated with a graphene layer and a method for manufacturing the graphene coated metal plate or wire are provided. The graphene coated metal plate or wire can include a nickel layer or a copper layer coated on an outer surface of the metal plate or wire, and a graphene layer coated on an outer surface of the nickel layer or the copper layer. The graphene coated metal plate or wire can be manufactured by using a chemical vapor deposition equipment or spraying a reduced graphene oxide (RGO) solution or a graphene oxide (GO) solution on the surface.

Abstract: An apparatus (CVD apparatus (1)) having a reaction chamber (3) for accommodating a substrate (2) formed with a metal catalyst film and means (gas supply pipes (5, 6)) for supplying a feedstock gas (9) and a catalyst activating material (10) into the reaction chamber (3) for manufacturing CNTs aligned in a direction perpendicular to the catalyst film surface (2a) of the substrate (2), wherein the means for supplying the feedstock gas (9) and the catalyst activating material (10) have a plurality of ejection holes placed at positions facing the catalyst film surface (2a) of the substrate (2), and the ejecting direction of the ejection holes is adjusted to the direction of alignment of CNTs grown from the metal catalyst film. This can provide a manufacturing technology for CNTs capable of mass-producing aligned CNTs at lower cost.

Abstract: A hybrid carbon nanotube and clay nanofiller is produced by a freeze-drying process performed on clay platelets, and carbon nanotubes grown on the clay platelets using a chemical vapor deposition process.

Abstract: A method for depositing a hydrogenated diamond-like carbon (H-DLC) film on a surface of a substrate. The method includes maintaining a reduced-pressure environment around a substrate holder for holding a substrate, holding the substrate securely within the reduced-pressure environment, and forming a gas cluster ion beam (GCIB) from a pressurized gas containing hydrocarbon gas and a carrier gas. The method further includes accelerating the GCIB to the reduced-pressure environment, irradiating the accelerated GCIB onto at least a portion of the surface of the substrate, and forming an H-DLC film on the surface.

Abstract: A method of fabricating carbon nanotube arrays (CNTA) on an oxide catalyst layer is disclosed. In one embodiment, the oxide catalyst is a metal oxide. The metal oxide may be deposited on a substrate used as a support. The CNTA is grown on the oxide catalyst layer under conditions promoting CNT growth. CNT growth is dependent on temperature, concentration of oxidizing molecules and carbon availability. One embodiment of the method comprises depositing an oxide catalyst layer on the substrate, heating the catalyst layer at certain rates to the target temperatures, adding oxidation molecules for the pretreatment of the oxide catalyst layer, and growing the array on the substrate. The oxide catalyst layer may comprise a group VIII element.

Abstract: THE PRESENT INVENTION PROVIDES A METHOD FOR PREPARING GRAPHENE BY PROVIDING A REACTION GAS INCLUDING A CARBON SOURCE AND HEAT ONTO A SUBSTRATE, AND REACTING THE SAME TO FORM A GRAPHENE ON THE SUBSTRATE, A GRAPHENE SHEET FORMED BY THE METHOD, AND A DEVICE USING THE SAME.

Abstract: A graphene manufacturing apparatus includes a gas supplying unit supplying a gas including carbon; a gas heating unit heating the gas supplied from the gas supplying unit; a deposition chamber in which a substrate having a catalyst layer is disposed; and an inlet pipe introducing the gas of the gas heating unit into the deposition chamber. A temperature of the deposition chamber is set at a temperature lower than a temperature of the gas heating unit so that a selection range with respect to a catalyst metal to be used in the catalyst layer may be expanded, and damage of the substrate due to a high temperature heat may be minimized.

Abstract: There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

Abstract: Disclosed is a method of forming carbon nanotubes on a conductor that covers a portion of a substrate, the method includes depositing a mesh-like conductive member made of Mo or the like on a substrate made of glass or the like, forming a catalyst support, such as Al2O3, and a catalyst such as Fe or Co on the conductive member, placing the substrate in a carbon-source gas atmosphere, and generating heat with the conductive member for a short period of time to grow nanotubes while avoiding damage to the substrate.

Abstract: A composite structure and methods of making and using are provided. The composite structure includes at least one nanofiber having silicon-based material and at least one carbon nanotube associated with the nanofiber. The silicon-based material includes one or more of silicon carbide, silicon oxycarbide, silicon nitride and silicon oxide.

Abstract: In accordance with the present invention, there are provided methods for imparting abrasion wear resistant color to “gemstones” by providing an integrated coating consisting of the color imparting agent and the abrasion wear resistant agent. The color imparting agent may provide the perception of color via interference phenomena or via bulk absorption phenomena. Abrasion wear resistance may be provided by integrating any of the materials such as DLC (diamond-like carbon), CVD diamond (CVDD), alumina, polymer-based materials, nitrides and carbonitrides. Abrasion wear resistant properties of DLC or CVDD may be further improved, in addition to improvement of other mechanical properties and inducing hydrophobicity, by incorporating certain elements into the deposited film.

Abstract: An apparatus and method for graphene film synthesis. The apparatus includes a quasi enclosed substrate holder which includes one open side, a cap disposed over the one open side of the quasi enclosed substrate holder, and a substrate for graphene film synthesis located inside the quasi enclosed substrate holder. The method includes placing a substrate for graphene film synthesis inside of a quasi enclosed substrate holder and generating a graphene film on the substrate via chemical vapor deposition, wherein the quasi enclosed substrate holder includes one open side and a cap disposed over the open side of the quasi enclosed substrate holder.

Abstract: A method for synthesizing carbon nanotubes (CNT) comprises the steps of providing a growth chamber, the growth chamber being heated to a first temperature sufficiently high to facilitate a growth of carbon nanotubes; and passing a substrate through the growth chamber; and introducing a feed gas into the growth chamber pre-heated to a second temperature sufficient to dissociate at least some of the feed gas into at least free carbon radicals to thereby initiate formation of carbon nanotubes onto the substrate.

Abstract: A method of forming a cutting element that includes placing at least one cutting element in an inner surface of at least one hollow tubular member such that at least a portion of the at least one cutting element is exposed; generating plasma within the hollow portion of the tubular; and depositing at least one refractory metal or sp3 carbon-containing coating on an exposed surface of the at least one cutting element is disclosed.

Abstract: A method to grow a boule of silicon carbide is described. The method may include flowing a silicon-containing precursor and a carbon-containing precursor proximate to a heated filament array and forming the silicon carbide boule on a substrate from reactions of the heated silicon-containing and carbon-containing precursors. Also, an apparatus for growing a silicon carbide boule is described. The apparatus may include a deposition chamber to deposit silicon carbide on a substrate, and a precursor transport system for introducing silicon-containing and carbon-containing precursors into the deposition chamber. The apparatus may also include at least one filament or filament segment capable of being heated to a temperature that can activate the precursors, and a substrate pedestal to hold a deposition substrate upon which the silicon carbide boule is grown. The pedestal may be operable to change the distance between the substrate and the filament as the silicon carbide boule is grown.

Abstract: An apparatus for growing carbon nanostructures (CNSs) on a substrate can include at least two CNS growth zones with at least one intermediate zone disposed therebetween and a substrate inlet before the CNS growth zones sized to allow a spoolable length substrate to pass therethrough.

Abstract: Provided is a method for forming a diamond-like carbon (DLC) film capable of enhancing the adhesion strength of a diamond-like carbon (DLC) film by simple steps. A surface of a substrate 11 made of polytetrafluoroethylene (PTFE) is modified by plasma radiation, and a diamond-like carbon film 12 is formed on the modified PTFE substrate 11 surface by chemical vapor deposition.

Abstract: An apparatus and method for forming a carbon protective layer on a substrate using a plasma CVD method allows a more uniform in-plane distribution of the carbon protective layer thickness. The apparatus includes an annular anode that generates a plasma beam and a disk-shaped shield disposed between the anode and the substrate. The anode, the shield, and the substrate are concentrically arranged so that a straight line connecting the centers of the anode and the substrate is perpendicular to the deposition surface of the substrate where the carbon protective layer is to be formed. The center of the shield is also on the straight line.

Abstract: A method of creating adherent surface coatings on carbide cutting tools or other workpiece substrates through the development of polycrystalline diamond coatings or composite coatings comprising a refractory metal carbide and polycrystalline diamond is described. The coating is deposited through a sequenced chemical vapor deposition process, first using a specified gas mixture of hydrogen and a refractory metal halide to deposit a base layer of a refractory metal carbide. This step is followed by a second step in which polycrystalline diamond is deposited from a gas mixture comprising a hydrocarbon and hydrogen. Co-deposition of refractory metal carbide and diamond in the second step to create a toughened diamond coating is also contemplated.

Abstract: A liquid immersion member holds liquid between the liquid immersion member and an object such that an optical path of exposure light applied to the object is filled with the liquid, thereby forming a liquid immersion space. In the liquid immersion member, an amorphous carbon film is formed on at least a part of a region coming into contact with the liquid.

Abstract: The invention relates to a hydrogenated amorphous carbon coating and to a method for the production thereof. It also relates to devices having such a coating. The method of the invention consists in producing a hydrogenated amorphous carbon coating comprising at least two layers of hydrogenated amorphous carbon, each of said layers having chemical compositions and physical and mechanical properties that are identical, and with thicknesses that are identical or different. The coating of the invention finds many applications, in particular in the mechanical field for parts subject to considerable wear and rubbing problems. It may also be applicable, in particular, in the field of surgical implants and in the MEMS (microelectromechanical systems) field.

Abstract: A thermal and electrical conducting apparatus includes a few-layer graphene film having a thickness D where D?1.5 nm and a plurality of carbon nanotubes crystallographically aligned with the few-layer graphene film.

Abstract: A method for growing a graphene nanoribbon on an insulating substrate having a cleavage plane with atomic level flatness is provided, and belongs to the field of low-dimensional materials and new materials. The method includes the following steps. Step 1: Cleave an insulating substrate to obtain a cleavage plane with atomic level flatness, and prepare a single atomic layer step. Step 2: Directly grow a graphene nanoribbon on the insulating substrate having regular single atomic steps. In the method, a characteristic that nucleation energy of graphene on the atomic step is different from that on the flat cleavage plane is used, and conditions, such as the temperature, intensity of pressure and supersaturation degree of activated carbon atoms, are adjusted, so that the graphene grows only along a step edge into a graphene nanoribbon of an adjustable size. The method is mainly applied to the field of new-type graphene optoelectronic devices.

Abstract: A method for forming an aperture includes stamping an aperture into the article using a pellet, and refining aperture shape(s) and/or aperture dimensions. Methods for forming articles having reduced residual compressive stress are also disclosed. Very generally, the methods include establishing a diamond coating on at least a portion of a substrate, and applying a stress-relief process to the diamond coating, the substrate, or combinations thereof.

Abstract: A method for depositing a conformal film on a substrate in a plasma processing chamber of a plasma processing system, the substrate being disposed on a chuck, the chuck being coupled to a cooling apparatus, is disclosed. The method includes flowing a first gas mixture into the plasma processing chamber at a first pressure, wherein the first gas mixture includes at least carbon, and wherein the first gas mixture has a condensation temperature. The method also includes cooling the chuck below the condensation temperature using the cooling apparatus thereby allowing at least some of the first gas mixture to condense on a surface of the substrate. The method further includes venting the first gas mixture from the processing chamber; flowing a second gas mixture into the plasma processing chamber, the second gas mixture being different in composition from the first gas mixture; and striking a plasma to form the conformal film.

Abstract: A method for directly growing carbon nanotubes, and in particular single-walled carbon nanotubes on a flat substrate, such as a silicon wafer, and subsequently transferring the nanotubes onto the surface of a polymer film, or separately harvesting the carbon nanotubes from the flat substrate.

Abstract: A first element (10) adapted to selectively engage a second element (20), wherein the first element comprises a coating (12) and at least an engaging portion (14) of the first element is coated in said coating, wherein the coating is formed by vapour deposition to provide a thermo-chemically stable layer for temperatures up to 800° C. The coating (12) may comprise one or more of a nitride, oxide or carbide of titanium, chromium or aluminium.

Abstract: A method for depositing a non-oxide ceramic-type coating based on chrome carbides, nitrides or carbonitrides, by DLI-CVD at low temperature and atmospheric pressure on a metallic substrate, includes: a) a solution is prepared, containing a molecular compound which is a precursor of the metal to be deposited, belongs to the bis(arene) family, and has a decomposition temperature of 300° C.-550° C., the compound being dissolved in an oxygen atom depleted solvent; b) the solution is introduced as aerosol into a heated evaporator at a temperature between the solvent boiling temperature and the precursor decomposition temperature; and c) the precursor and the vaporized solvent are driven from the evaporator towards a CVD reactor having cold walls, with a susceptor carrying the substrate to be covered and heated to a temperature higher than the decomposition temperature of the precursor, to a maximum of 550° C., the evaporator and the CVD reactor being at atmospheric pressure.

Abstract: An improved method of synthesizing nanotubes that avoids the slow process and the impurities or defects that are usually encountered with regard to as-grown carbon nanotubes. In a preferred embodiment, nanotubes are synthesized from nanotubes providing a novel catalyst-free growth method for direct growth of single- or multi-walled, metallic or semiconducting nanotubes.

Abstract: The present invention is in relation to a composition of electrode material in the form of a coating, said composition represented by formula Mn1-xO/C, wherein Mn1-xO is the monoxide of manganese with x is ?0 and ?0.1 and C is carbon. In addition, the invention also provides a process for deposition of aforementioned composition in the form of a nanocomposite coat on the electrode of an electrochemical capacitor in the fields of automobile, aerospace engineering and applications, very large scale integrated circuits (VLSI) technology, micro-electro-mechanical systems (MEMS) and combinations thereof.

Abstract: The present invention provides arrays of longitudinally aligned carbon nanotubes having specified positions, nanotube densities and orientations, and corresponding methods of making nanotube arrays using guided growth and guided deposition methods. Also provided are electronic devices and device arrays comprising one or more arrays of longitudinally aligned carbon nanotubes including multilayer nanotube array structures and devices.

Abstract: A method and apparatus are provided for formation of a composite material on a substrate. The composite material includes carbon nanotubes and/or nanofibers, and composite intrinsic and doped silicon structures. In one embodiment, the substrates are in the form of an elongated sheet or web of material, and the apparatus includes supply and take-up rolls to support the web prior to and after formation of the composite materials. The web is guided through various processing chambers to form the composite materials. In another embodiment, the large scale substrates comprise discrete substrates. The discrete substrates are supported on a conveyor system or, alternatively, are handled by robots that route the substrates through the processing chambers to form the composite materials on the substrates. The composite materials are useful in the formation of energy storage devices and/or photovoltaic devices.

Abstract: A method of growing carbon nanomaterials on a substrate wherein the substrate is exposed to an oxidizing gas; a seed material is deposited on the substrate to form a receptor for a catalyst on the surface of said substrate; a catalyst is deposited on the seed material by exposing the receptor on the surface of the substrate to a vapor of the catalyst; and substrate is subjected to chemical vapor deposition in a carbon containing gas to grow carbon nanomaterial on the substrate.

Abstract: Disclosed are a carbon nanotube composite and a method for making the same advantageous for achieving a higher density of a carbon nanotube assembly. The carbon nanotube composite includes a substrate and a carbon nanotube assembly mounted on the surface of the substrate. The carbon nanotube assembly is composed of multiple carbon nanotubes arranged densely in parallel oriented in the direction upward from the surface of the substrate. The carbon nanotube assembly has a density of 70 mg/cm3 or more in a grown state.

Abstract: Anchored nanostructure materials and methods for their fabrication are described. The anchored nanostructure materials may utilize nano-catalysts that include powder-based or solid-based support materials. The support material may comprise metal, such as NiAl, ceramic, a cermet, or silicon or other metalloid. Typically, nanoparticles are disposed adjacent a surface of the support material. Nanostructures may be formed as anchored to nanoparticles that are adjacent the surface of the support material by heating the nano-catalysts and then exposing the nano-catalysts to an organic vapor. The nanostructures are typically single wall or multi-wall carbon nanotubes.

Abstract: A method for fabricating a continuous vapor grown carbon fiber, comprising: (a) providing a substrate which has a catalyst on its surface; (b) placing said substrate in a furnace; (c) loading said furnace with hydrogen, ammonia, or combinations thereof; (d) adjusting a temperature of said furnace to 400° C. to 900° C. to proceed heat treatment for 10 minutes to 2 hours; (e) adding a carbon-containing compound into said furnace; (f) adjusting the ratio of said carbon-containing compound and said hydrogen, ammonia, or combinations thereof; (g) adjusting the temperature of said furnace to 500° C. to 1200° C. to crack said carbon-containing compound, and thereby form a carbon fiber.

Abstract: A method for fabricating a composite material includes providing a free-standing carbon nanotube structure having a plurality of carbon nanotubes, introducing at least two reacting materials into the carbon nanotube structure to form a reacting layer, activating the reacting materials to grow a plurality of nanoparticles, wherein the nanoparticles are spaced from each other and coated on a surface of each of the carbon nanotubes of the carbon nanotube structure.

Abstract: Exemplary embodiments provide methodologies for generating structures of filamentous carbon (or carbon filaments) with controlled geometries. In one exemplary embodiment of forming the carbon filament structure, a metal template can be exposed to a fuel rich gaseous mixture to form a carbon filament structure at an appropriate gas flow and/or at an appropriate temperature on the metal template. The metal template can have one or more metal surfaces with controlled geometries. Carbon filament structures can then be grown on the metal surfaces having corresponding geometries (or shapes) in the growth direction. The carbon filament structure can be two or three dimensional and can have high density. In various embodiments, the metal template can be removed to leave a self-supporting carbon filament structure.

Abstract: A method of depositing silicon on carbon nanomaterials such as vapor grown carbon nanofibers, nanomats, or nanofiber powder is provided. The method includes flowing a silicon-containing precursor gas in contact with the carbon nanomaterial such that silicon is deposited on the exterior surface and within the hollow core of the carbon nanomaterials. A protective carbon coating may be deposited on the silicon-coated nanomaterials. The resulting nanocomposite materials may be used as anodes in lithium ion batteries.

Abstract: Methods of forming a graphene material on a surface are presented. A metal material is disposed on a material substrate or material layer and is infused with carbon, for example, by exposing the metal to a carbon-containing vapor. The carbon-containing metal material is annealed to cause graphene to precipitate onto the bottom of the metal material to form a graphene layer between the metal material and the material substrate/material layer and also onto the top and/or sides of the metal material. Graphene material is removed from the top and sides of the metal material and then the metal material is removed, leaving only the graphene layer that was formed on the bottom of the metal material. In some cases graphene material that formed on one or more side of the sides of the metal material is not removed so that a vertical graphene material layer is formed.

Abstract: A graphene pattern is fabricated by forming a pattern of passivation material on a growth substrate. The pattern of passivation material defines an inverse pattern of exposed surface on the growth substrate. A carbon-containing gas is supplied to the inverse pattern of the exposed surface of the growth substrate, and patterned graphene is formed from the carbon. The passivation material does not facilitate graphene growth, and the inverse pattern of exposed surface of the growth substrate facilitates graphene growth on the exposed surface of the growth substrate.

Abstract: A method of producing a carbon nanostructure is provided which can increase evenness of a shape and a purity of the carbon nanostructure and can reduce a production cost. In a method of producing a carbon nanostructure, a carbon crystal is grown by vapor phase epitaxy from a crystal growth surface of a catalyst base including a catalyst material, and the catalyst base is formed by diameter-reduction processing. The catalyst base is preferably formed as an aggregate including an arrangement of a plurality of catalyst structures each formed with a non-catalyst material, a material not having a substantial catalytic function for growth of the carbon crystal, formed on at least a portion of a side surface of the catalyst material of a columnar shape having the crystal growth surface as a top surface.