With Additional, Spatially Distinct Nonmetal Component Patents (Class 428/621)
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Patent number: 6255001Abstract: A thermal barrier coating system and a method for forming the coating system on an article. The coating system employs a bond coat of a nickel aluminide alloy over which a thermal-insulating ceramic layer is deposited. The nickel aluminide bond coat contains zirconium, but is otherwise predominantly of the beta (&bgr;) NiAl phase. The bond coat is preferably deposited by a physical vapor deposition process to have a fine-grain microstructure and a limited diffusion zone in the article surface.Type: GrantFiled: January 19, 1999Date of Patent: July 3, 2001Assignee: General Electric CompanyInventor: Ramgopal Darolia
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Patent number: 6251526Abstract: The cast part (1) comprises a basic body (2) of a first material and a coating of at least one second material. The second material is applied to a co-cast skeleton structure (3) on the surface (20) of the basic body, with it forming a covering (4) or a covering layer (42).Type: GrantFiled: February 2, 1999Date of Patent: June 26, 2001Assignee: Sulzer Innotec AGInventor: Fritz Staub
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Patent number: 6230429Abstract: A composite tube for a gun barrel consists of: an inner tubular metal liner defining a longitudinal bore axis; a resin matrix material surrounding the liner, the resin matrix material containing a plurality of elongate carbon fibers, the carbon fibers being aligned parallel with the longitudinal bore axis of the liner and under compression along the longitudinal bore axis; a muzzle piece attached to the muzzle end of the barrel; and a breech piece attached to the breech end of the barrel, so that any vibrations transmitted along the longitudinal bore axis of the liner are absorbed by the resin matrix material and so that any vibrations reaching the muzzle piece and breech piece are reflected back into the resin matrix material and thus absorbed.Type: GrantFiled: June 30, 1999Date of Patent: May 15, 2001Assignee: Magnum Research, Inc.Inventor: David B. Smith
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Patent number: 6231999Abstract: A heat-resistant transparent glass article is formed with a film stack deposited on a glass substrate, the film stack comprising one or more infrared reflective films each bearing on its surface facing away from the substrate a protective film of niobium metal having a thickness of up to 25 Å and preferably in the range of about 7 Å to 20 Å. A protective film of niobium metal or metal oxide may be formed on the other surface (facing the substrate) of each infrared reflective film. Metal nitride films such as silicon nitride may be employed between neighboring infrared reflective films, and as an outer protective film.Type: GrantFiled: February 13, 1997Date of Patent: May 15, 2001Assignee: Cardinal IG CompanyInventor: Annette J. Krisko
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Patent number: 6228510Abstract: An improved coating and method for applying the coating to minimize the consumption of substrate material during high temperature service by formation of an intermediate metal aluminide layer. A layer of Ni or Co or combinations of Ni and Co are added to the substrate material as an overlay by a process such as electroplating or electroless plating. A diffusion aluminide is then formed at the surface by exposing the plated substrate to a source of aluminum at an elevated temperature.Type: GrantFiled: December 22, 1998Date of Patent: May 8, 2001Assignee: General Electric CompanyInventors: Keng N. Chen, Shih T. Ngiam, Genfa Hu
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Patent number: 6221511Abstract: In the present invention, a metal-ceramic composite substitute is produced by joining a metal plate to a ceramic substrate by using a brazing material in a paste form prepared by adding 10-14 parts by weight of a vehicle to 100 parts by weight of a powder of which the solid centent comprises 90.0˜99.5% of an Ag powder, 0˜9.5% of a Cu powder and 0.5˜4.0% of an active metal powder, and 0.0˜0.9% of a titanium oxide powder if necessary.Type: GrantFiled: March 9, 1998Date of Patent: April 24, 2001Assignee: Dowa Mining Co. Ltd.Inventors: Masami Sakuraba, Masami Kimura, Masaya Takahara, Junji Nakamura
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Patent number: 6214471Abstract: A family of aluminoborate glasses that are compatible with aluminum at elevated temperatures, and an article comprising such a glass with either an aluminum coating, or with aluminum particles dispersed within the glass, whereby the glass may be rendered polarizing. The base glass consists essentially of, 15-85% B2O3, 5-45% Al2O3 and 10-75% Li2O+RO, where RO represents the alkaline earth metal oxides MgO, CaO, SrO and BaO, and is free of oxides reacting with aluminum at elevated temperatures.Type: GrantFiled: November 3, 1999Date of Patent: April 10, 2001Assignee: Corning IncorporatedInventors: Douglas M. Beall, George H. Beall
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Patent number: 6210812Abstract: An article includes a substrate and an adhesion layer overlying the substrate. The adhesion layer includes a first phase including particles, and a second phase including braze alloy that bonds the particles to the substrate. The article further includes a ceramic layer overlying the adhesion layer. In one embodiment, the ceramic layer is a thermal barrier coating (TBC), formed of stabilized zirconia (ZrO2).Type: GrantFiled: May 3, 1999Date of Patent: April 3, 2001Assignee: General Electric CompanyInventors: Wayne Charles Hasz, Jeffrey Allen Conner
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Patent number: 6207297Abstract: A turbine component contains a substrate (22) such as a superalloy, a basecoat (24) of the type MCrAlY, and a continuous barrier layer (28) between the substrate and basecoat, where the barrier layer (28) is made of an alloy of (Re, Ta, Ru, Os)X, where X can be Ni, Co or their mixture, where the barrier layer is at least 2 micrometers thick and substantially prevents materials from both the basecoat and substrate from migrating through it.Type: GrantFiled: September 29, 1999Date of Patent: March 27, 2001Assignee: Siemens Westinghouse Power CorporationInventors: Stephen M. Sabol, John G. Goedjen, Steven J. Vance
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Patent number: 6200672Abstract: A surface treated metal sheet which is coated with a layer comprising, as main components, a complex and/or salt between a rare earth metal element and an organic compound having in the molecule one or more functional groups selected from among —O—, ═O, —OH, —COOH, —NH2, ═NH, ═N—, —SH, —SO3H and phosphoric groups, and a matrix which physically holds the above and has adhesive power for metal sheets, as well as a metal surface treatment solution used therefor.Type: GrantFiled: October 13, 1999Date of Patent: March 13, 2001Assignee: Nippon Steel CorporationInventors: Kenichiro Tadokoro, Hiromasa Shoji, Masao Sakashita
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Patent number: 6198220Abstract: A sealing structure for an organic light emitting device display. The sealing structure comprises a metal film overlying a dielectric film. The sealing structure has low moisture and oxygen permeability. At least one of the metal layers may react with moisture or oxygen to seal off pin holes. A net low stress sealing structure may be formed by combining tensile and compressive films. The sealing structure may be etched to create openings for connection to outside circuitry. The innovative sealing structure minimizes moisture leakage and vertical shorts between diode cathode and anode.Type: GrantFiled: May 8, 1998Date of Patent: March 6, 2001Assignee: eMagin CorporationInventors: Gary W. Jones, Webster E. Howard, Steven M. Zimmerman
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Patent number: 6197435Abstract: An article comprising a metal circuit and/or a heat-radiating metal plate formed on a ceramic substrate, wherein the metal circuit and/or the heat-radiating metal plate comprise either (1) the following first metal-second metal bonded product, wherein the first metal and the second metal are different, or (2) the following first metal-third metal-second metal bonded product, and wherein in (1) and (2), the first metal is bonded to the ceramic substrate; first metal: a metal selected from the group consisting of aluminum (Al), lead (Pb), platinum (Pt) and an alloy containing at least one of these metal components; second metal: a metal selected from the group consisting of copper (Cu), silver (Ag), gold (Au), aluminum (Al) and an alloy containing at least one of these metal components; and third metal: a metal selected from the group consisting of titanium (Ti), nickel (Ni), zirconium (Zr), molybdenum (Mo), tungsten (W) and an alloy containing at least one of these metal components.Type: GrantFiled: October 20, 1998Date of Patent: March 6, 2001Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Yoshihiko Tsujimura, Miyuki Nakamura, Yasuhito Fushii
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Patent number: 6194084Abstract: A powder of dicalcium silicate is made by spray drying calcia and silica with incorporation of sodium and phosphorus or stabilized zirconia. The spray dried powder is sintered to form a thermal spray powder. Sprayed coatings have a web of interconnected, randomly oriented microcracks substantially perpendicular to the coating surface. The coatings are stable in thermal cycling and a hot corrosive environment.Type: GrantFiled: June 23, 1999Date of Patent: February 27, 2001Assignee: Sulzer Metco Inc.Inventors: Xiaohan Wei, Mitchell R. Dorfman, Luis F. Correa, Franz Jansen, John Peters
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Patent number: 6194085Abstract: A coating material used in the fabrication of electronic components such as a metallized paste is provided comprising a material to be coated on the electronic component substrate and an identifying component which identifying component can be identified and which identifying component identifies the coating material. Optical dyes visible to the eye can be used as the identifying component with a preferred dye being a UV fluorescent dye which is colorless under visible light and visible under UV light. A process for making an electronic component using the coating materials of the invention and electronic components made using the coating material are also provided.Type: GrantFiled: September 27, 1997Date of Patent: February 27, 2001Assignee: International Business Machines CorporationInventors: Benjamin V. Fasano, James N. Humenik, David C. Long, Cynthia J. Calli
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Patent number: 6194086Abstract: A process is provided for producing an abrasive coating on a substrate surface by applying a bond coat by low pressure plasma spraying and anchoring to the bond coat abrasive particles by electroplating and embedding the particles into an oxidation resistant matrix by entrapment plating.Type: GrantFiled: April 16, 1999Date of Patent: February 27, 2001Assignee: Chromalloy Gas Turbine CorporationInventors: Krassimir P. Nenov, Richard Fenton, Joseph A. Fuggini, Peter Howard
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Patent number: 6183883Abstract: Brazing or soldering materials which effectively improve the wettability of the brazing alloy or solder without using flux and a method of manufacturing such materials are provided. A metallic base is placed on turntable inside a vacuum chamber. A copper target is affixed to a sputtering electrode above the metallic base. Air is removed from the vacuum chamber through a vacuum outlet to increase the vacuum therein to a specific pressure, and carbon tetrafluoride and argon are introduced from a gas inlet to control the sputter pressure. Thereafter, turntable is rotated while a high frequency voltage is applied between the target and the metallic base to form a halide layer, such as a layer of copper fluoride, on a surface of metallic base.Type: GrantFiled: June 16, 1998Date of Patent: February 6, 2001Assignee: Seiko Epson CorporationInventors: Yoshiaki Mori, Katsuhiro Takahashi, Takuya Miyakawa, Yasushi Karasawa
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Patent number: 6168873Abstract: An electrode substrate comprises a backing substrate carrying thereon a metal electrode layer and/or a recording layer, the layer or layers having a smooth surface area with a surface roughness of less than 1 nm by more than 1 &mgr;m2. The smooth surface of the metal electrode layer and/or the recording layer is formed by firstly forming the layer on another substrate having a corresponding smooth surface and then peeling another substrate off the layer after the layer is bonded to the surface of the backing substrate, whereby the smooth surface profile of another substrate is transferred to the surface of the layer formed on the backing substrate.Type: GrantFiled: May 29, 1998Date of Patent: January 2, 2001Assignee: Canon Kabushiki KaishaInventors: Tsutomu Ikeda, Takehiko Kawasaki
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Patent number: 6168875Abstract: An iridium-niobium alloy bond coat is used under a ceramic thermal barrier coating on turbine blades and vanes to improve the life of the thermal barrier coating. Between the bond coat and the substrate is an underlying protective coating which is either a low pressure plasma sprayed coating such as a NiCoCrAlY alloy or a vapor deposited coating such as tantalum, nickel-tantalum or rhenium. Heat treatment and preoxidation procedures may be used to form the desirable bonds and materials.Type: GrantFiled: October 2, 1998Date of Patent: January 2, 2001Assignee: Asea Brown Boveri AGInventors: Michael Cybulsky, Thomas B. Gibbons
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Patent number: 6159621Abstract: The invention concerns a transparent substrate provided with a thin-film stack comprising at least one metallic film with reflective properties in the infrared, under which is disposed a first antireflection coating consisting essentially of one or more metal oxides, and an upper protective metallic film characterized in that the protective metallic film consists of an alloy of Ti, Zr or Hf with Al, Pt or Pd or an AlSi alloy.According to the invention, the second upper antireflection coating includes at least two metal oxide films, one of which is ZnO based and contains 0.1 to 10% by weight of at least one of the elements B, Si, Ga, Sm, Al, Co, Mg, Mn, Fe, Ni and/or Cr and the other is SnO.sub.2 or Bi.sub.2 O.sub.3 based, and a final, hard oxide based film.Type: GrantFiled: July 31, 1998Date of Patent: December 12, 2000Assignee: Saint-Gobain VitrageInventors: Heinz Schicht, Uwe Schmidt, Wilfried Kaiser, Bodo Hryniw
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Patent number: 6153320Abstract: A magnetic device uses laminated ferromagnetic layers containing antiferromagnetically coupled ferromagnetic films coupled together with improved antiferromagnetically coupling (AFC) films. The AFC films are formed of the binary and ternary alloys comprising combinations of Ru, Os and Re. The ferromagnetic film thicknesses, the AFC film thicknesses and the compositions of the films in the laminated layer can be varied to engineer the magnetic properties of the device. The magnetic devices whose properties are improved with the improved laminated layers include spin valve magnetoresistive read heads and magnetic tunnel junction (MTJ) devices for use as magnetic memory cells and magnetoresistive read heads.Type: GrantFiled: May 5, 1999Date of Patent: November 28, 2000Assignee: International Business Machines CorporationInventor: Stuart Stephen Papworth Parkin
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Patent number: 6110605Abstract: A jointed member, such as a tappet, obtained by brazing a disc which is ceramic member, and a tappet body which is a metal member, to each other by a brazing layer, the jointed member includes a reaction layer formed on the surface of the metal member adjacent to the brazing material and having a thickness of not less than 5 .mu.m, wherein the reaction layer contains, in addition to main elements forming the metal member, Cu in the range of 0.5 weight % to 8 weight % and Si in the range of 0.5 weight % to 8 weight %.Type: GrantFiled: August 29, 1997Date of Patent: August 29, 2000Assignee: NGK Spark Plug Co., Ltd.Inventor: Masato Taniguchi
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Patent number: 6106960Abstract: A joined article is constituted by a first member made of aluminum nitride joined to each other through a joining layer, wherein a second member is made of a material selected from a ceramic material or a metal, and the joining layer involves a continuous phase made of a metal selected from the group consisting of copper, aluminum and nickel as a main component and 10% by weight of at least one active metal selected from the group consisting of magnesium, titanium, zirconium and hafnium relative to the joining layer.Type: GrantFiled: February 2, 1996Date of Patent: August 22, 2000Assignee: NGK Insulators, Ltd.Inventors: Tomoyuki Fujii, Ryusuke Ushikoshi
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Patent number: 6090490Abstract: An article is coated with a multi-layer coating comprising a polymeric layer deposited on the surface of the article, a zirconium compound, titanium compound or zirconium/titanium alloy compound layer deposited on the polymeric layer, and a silicone resin layer deposited on the zirconium compound or titanium compound layer.Type: GrantFiled: August 1, 1997Date of Patent: July 18, 2000Assignee: MascoTech, Inc.Inventor: Subrata Mokerji
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Patent number: 6087022Abstract: A component subjected to one or more of rolling, sliding, abrasion and bending contacts is disclosed. The component has a surface and functionally graded material (FGM) thermally sprayed on the surface to form an FGM coating. The FGM coating has a thickness and a plurality of material compositions. The FGM coating also has a plurality of elastic modulus profiles. Each elastic modulus profile consists of a plurality of elastic modulii at a plurality of corresponding points within that thickness. The elastic modulii are in the range from about 28 Mpsi to about 60 Mpsi. Optionally, there is also a plurality of carbon content profiles.Type: GrantFiled: April 8, 1998Date of Patent: July 11, 2000Assignee: Caterpillar Inc.Inventors: Kenneth W. Burris, M. Brad Beardsley, Leonid Chuzhoy
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Patent number: 6080494Abstract: A method of fabricating a ball grid array and the array. The method comprises the steps of providing an electrically insulating substrate and forming an essentially gold-free solder ball attach region and wire bond region secured to the substrate. Formation of the solder ball attach and wire bond regions includes forming a layer of electrically conductive material on the substrate, forming a layer of nickel over the layer of electrically conductive material and forming a layer of palladium over the layer of nickel. After chip attach and gold wire bonding or flip chip bonding, solder balls are then applied to the layer of palladium and the solder balls and solder ball attach regions are heated to a temperature sufficiently high and for a sufficient time so that the solder balls extend through and incorporate therein at least a portion of the layer of said palladium and extend to and attach to the layer of nickel.Type: GrantFiled: August 28, 1998Date of Patent: June 27, 2000Assignee: Texas Instruments IncorporatedInventor: Donald C. Abbott
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Patent number: 6071629Abstract: An organic rust-roof treated copper foil characterized in that it has a metallic rust-proof layer formed on the non-adhesive side of the original copper foil and has an organic rust-proof layer formed on said metallic rust-proof layer, the organic rust-proof layer comprising a mixture of at least two kinds of chemicals selected from the group consisting of benzotriazole, its derivatives, aminotriazole and its isomers and derivatives is provided with on said metallic rust-proof layer, or it further has a chromate-treated layer formed between said metallic rust-proof layer and said organic rust-proof layer.Type: GrantFiled: January 17, 1997Date of Patent: June 6, 2000Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Toshiko Yokota, Makoto Dobashi, Hiroshi Hata, Hisao Sakai, Susumu Takahashi, Junshi Yoshioka
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Patent number: 6071627Abstract: A ceramic coating layer which is not less than 70 .mu.m in the maximum height Rmax of its profile curves and not less than 45 .mu.m in the 10-point average roughness, or which is less than 650 HV in Vickers hardness is provided on a metallic substrate. A heat-resistant member of such composition is excellent in thermal fatigue resistance and keeps an excellent heat resistance for a long period of time. Quality of a heat-resistant member is evaluated by, measuring at least one of roughness and hardness of a ceramic coating layer on a metallic substrate. According to this method, it is possible to easily and accurately evaluate a thermal resistant life of a heat-resistant member.Type: GrantFiled: March 28, 1997Date of Patent: June 6, 2000Assignee: Kabushiki Kaisha ToshibaInventors: Kazuhiro Yasuda, Seiichi Suenaga, Kunihiko Wada, Hiroki Inagaki, Masako Nakahashi
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Patent number: 6066405Abstract: A nickel-base superalloy substrate includes a surface region having an integrated aluminum content of from about 18 to about 24 percent by weight and an integrated platinum content of from about 18 to about 45 percent by weight, with the balance components of the substrate. The substrate is preferably a single-crystal advanced superalloy selected for use at high temperatures. The substrate may optionally have a ceramic layer deposited over the platinum-aluminide region, to produce a thermal barrier coating system. The platinum-aluminide region is produced by diffusing platinum into the substrate surface, and thereafter diffusing aluminum into the substrate surface.Type: GrantFiled: December 22, 1995Date of Patent: May 23, 2000Assignee: General Electric CompanyInventor: Jon C. Schaeffer
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Patent number: 6060178Abstract: A heat-resistant transparent glass article is formed with a film stack deposited on a glass substrate, the film stack comprising one or more infrared reflective films each bearing on its surface facing away from the substrate a barrier film of niobium metal having a thickness of up to 25 .ANG. and preferably in the range of about 7 .ANG. to 20 .ANG.. A barrier film of niobium metal or, preferably, a metal oxide may be formed on the other surface (facing the substrate) of each infrared reflective film. Metal nitride films such as silicon nitride may be employed between neighboring infrared reflective films, and as an outer protective film.Type: GrantFiled: May 30, 1997Date of Patent: May 9, 2000Assignee: Cardinal IG CompanyInventor: Annette J. Krisko
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Patent number: 6060174Abstract: A substrate (12) such as a superalloy turbine component is coated with a basecoat (14) of the type MCrAlY which also contains boron, where the amount of boron in the basecoat is in a concentration gradient where more boron is present near the top (16) than the bottom (20) of the basecoat (14) and boron is present in an average amount of over 0.50 wt. % throughout the basecoat cross-section (14) of the composite (10).Type: GrantFiled: May 26, 1999Date of Patent: May 9, 2000Assignee: Siemens Westinghouse Power CorporationInventors: Stephen M. Sabol, John G. Goedjen
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Patent number: 6046907Abstract: A heat conductor used by being disposed between a heat sink and electronic parts mounted on a printed circuit board. The heat conductor is layered by a heat conductive layer, made of silicone gel with alumina as a heat conductive filler dispersed therein, and a potentially adhesive layer. The potentially adhesive layer consists of a hot melt layer, with alumina as a heat conductive filler dispersed therein, and a heat resistant film, to facilitate formation of the hot melt layer, adhered to the heat conductive layer on one face of the heat resistant film. The heat conductor is set on the electronic parts so that the potentially adhesive layer abuts them, and is made to adhere to the electronic parts due to heating by means of reflow soldering to reach the phase change temperature of the adhesive.Type: GrantFiled: September 16, 1999Date of Patent: April 4, 2000Assignee: Kitigawa Industries Co., Ltd.Inventor: Akio Yamaguchi
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Patent number: 6042951Abstract: A ceramic-coated blade of a gas turbine and a method of producing the same, in which the thickening of an Al.sub.2 O.sub.3 layer at the interface between a ceramic layer and a primary layer is sufficiently prevented for a long period of time, thereby positively suppressing the separation of the ceramic layer. Using powder of MCrAlY alloy (Co-32% Ni-21% Cr-8% Al-0.5% Y), a primary layer (alloy coating layer) is formed on a surface of a substrate made of a heat-resistant Ni base alloy (Rene'-80). Further, a heat-resistant ceramic layer, comprising a mixture of ion-conductive ZrO.sub.2 -8 wt. % Y.sub.2 O.sub.3 ceramic and insulative ceramic (e.g. Al.sub.2 O.sub.3), is formed on the alloy coating layer. This mixture has a columnar structure in which columnar crystals are grown by a gas phase in a direction of a thickness of the coating, or a porous structure in which flattened particles brought about from molten particles caused to fly at high velocity are laminated.Type: GrantFiled: February 2, 1998Date of Patent: March 28, 2000Assignees: Hitachi, Ltd., The Tokyo Electric Power Co., Inc.Inventors: Yoshitaka Kojima, Hideyuki Arikawa, Mitsuo Haginoya, Katsuo Wada, Ryuta Watanabe, Yoshiaki Matsushita, Shin Yoshino
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Patent number: 6027823Abstract: A molded article of metal matrix composite (MMC) includes a preform infilted in a casting process with metal or metal alloy, with the preform comprised of a plurality of spaced preform plates arranged in mosaic disposition in at least one plane, or stacked in several planes above one another, and formed with bores. The spacing between neighboring preform plates and the spacing between overlying planes of preform plates are filled with infiltration metal or metal alloy, without permeation of infiltration metal into the bores.Type: GrantFiled: July 8, 1996Date of Patent: February 22, 2000Assignee: Electrovac, Fabrikation elektrotechnischer Specialartikel Ges. m.b.H.Inventor: Theodore Nicolas Schmitt
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Patent number: 6020076Abstract: A joined ceramic structure including a ceramic member and a metallic joining member joined to each other through a joining layer made of a brazing material wherein a metallic member is buried in the ceramic member in the state that a metal-exposed portion is formed through partial exposure of the metallic member from such a joining surface of the ceramic member as contacting said joining layer, and the ceramic member and the metal-exposed portion are also joined to the joining layer along the joining surface of the ceramic member.Type: GrantFiled: February 2, 1996Date of Patent: February 1, 2000Assignee: NGK Insulators, Ltd.Inventors: Tomoyuki Fujii, Ryusuke Ushikoshi
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Patent number: 6015775Abstract: A self-lubricating sintered sliding member and its producing method, the member having excellent seizing resistance and wear resistance even in offset load and high load applications.The self-lubricating sintered sliding member is composed of an iron-family metal substrate and a sintered contact layer that is formed on a sliding side of the iron-family metal substrate and made from a sintered contact material containing an iron-family material. The sintered contact layer has, on a surface thereof, protrusions formed from solid lubricant particles including graphite. A solid lubricant layer is laid over the surface of the sintered contact layer where the protrusions are formed.Type: GrantFiled: February 4, 1998Date of Patent: January 18, 2000Assignee: Komatsu Ltd.Inventors: Takemori Takayama, Yoshikiyo Tanaka
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Patent number: 5998041Abstract: A joined article includes a ceramic member, another member, and a joining layer which is formed between the ceramic member and another member and joins both the members together, wherein the joining layer is composed mainly of nickel, and the joining layer contains beryllium as an activating component.Type: GrantFiled: March 12, 1997Date of Patent: December 7, 1999Assignee: NGK Insulators, Ltd.Inventors: Takuma Makino, Masayuki Shinkai
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Patent number: 5989730Abstract: An article is coated with a multi-layer coating comprising a nickel layer, a tin-nickel alloy layer, a non-precious refractory metal layer, a sandwich layer comprised of a plurality of alternating layers of non-precious refractory metal compound and of a non-precious refractory metal, a non-precious refractory metal compound layer, and a layer comprised of a non-precious refractory metal oxide or the reaction products of a non-precious refractory metal, oxygen and nitrogen.Type: GrantFiled: April 30, 1997Date of Patent: November 23, 1999Assignee: Masco CorporationInventors: Rolin W. Sugg, Richard P. Welty, Stephen R. Moysan, III
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Patent number: 5952110Abstract: An abrasive coating suitable for forming an abrasive blade tip of a gas turbine engine. The coating is characterized as being capable of abrading a ceramic shroud at elevated temperatures during the in-service operation of the engine, and being resistant to oxidation and hot corrosion within the engine environment. The abrasive coating includes an MCrAl alloy layer, a ceramic layer overlying the alloy layer so as to form an outer surface of the abrasive coating, and abrasive particles dispersed between the alloy layer and the ceramic layer so that at least some of the abrasive particles are partially embedded in the alloy layer and also partially embedded in the ceramic layer. In addition, at least some of the abrasive particles project above the outer surface of the abrasive coating formed by the ceramic layer.Type: GrantFiled: December 24, 1996Date of Patent: September 14, 1999Assignee: General Electric CompanyInventors: Jerry D. Schell, Howard J. Farr
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Patent number: 5932359Abstract: A surface-treated steel sheet for fuel tanks comprising a Zn--X alloy plating layer + a chromate film, in which the Zn--X alloy plating layer has an X content for the plating metal as a whole of Ni: 9-18 wt %, Co: 0.02-3 wt %, Mn: 25-45 wt %, or Cr: 8-20 wt %, the amount of deposition of the plating layer is 5-40 g/m.sup.2 and the amount of the chromate film is 10-200 mg/m.sup.2 on a metallic Cr basis, the Zn--X alloy plating layer corresponding to at least the inner surface of a tank has: (1) cracks in the surface layer, with the density of the cracks being 1000-150000 in terms of the number of plated regions surrounded by cracks in a visual field of 1 mm.times.1 mm, and the maximum width of the cracks is not more than 0.5 .mu.m, or (2) an X/(X+Zn) atomic percentage (X.sub.2) determined by surface analysis based on ESCA with X.sub.1 .noteq.X.sub.2 (wherein X.sub.1 =average value of the X content of the plating metal as a whole), and with X.sub.2 being Ni: 5-25 at %, Co: 0.Type: GrantFiled: November 4, 1996Date of Patent: August 3, 1999Assignee: Sumitomo Metal Industries, Ltd.Inventors: Hiroyuki Nagai, Yoshihiro Kawanishi, Eiji Kajiyama, Hiroyuki Kashiwagi, Shinichi Tsuchiya
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Patent number: 5932360Abstract: A hollow thin walled shell with integral internal baffles is formed by a multilayer coating process. A series of mandrels is designed to be assembled to form the outer surface of the desired shell. The mandrel surfaces hidden during assembly include the areas intended to form the internal baffles. The mandrels are coated separately, assembled, and the assembly is given a continuous overcoating that holds the assembly together and provides the shell with mechanical integrity. The assembly is machined to remove all internal and external coated surfaces not intended to be included in the shell and the mandrel is dissolved or otherwise removed, leaving the thin coatings as the desired shell with baffles at the areas where the coated mandrel surfaces were hidden during assembly.Type: GrantFiled: June 6, 1997Date of Patent: August 3, 1999Assignee: Servometer CorporationInventors: Paul Hazlitt, Edward Howanice
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Patent number: 5922478Abstract: An article is coated with a multi-layer coating comprising a nickel layer, a chrome layer, a refractory metal layer, preferably zirconium layer, a sandwich layer comprised of a plurality of alternating layers of a refractory metal compound and a refractory metal compound layer, preferably zirconium nitride layer, and a refractory metal oxide layer or a layer comprised of the reaction products of refractory metal, oxygen and nitrogen. The coating provides the color of polished brass to the article and also provides abrasion protection, corrosion protection, and improved acid resistance.Type: GrantFiled: April 30, 1997Date of Patent: July 13, 1999Assignee: Masco CorporationInventors: Richard P. Welty, John H. Petersen, Patrick Jonte, Carl W. Trendelman
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Patent number: 5906896Abstract: A gas seal for rotary shaft applications in which at least a portion of a contact surface of one member of the seal that has relative motion with and in contact with a second member of the seal is coated with a chromium carbide-age hardenable nickel base alloy. The process for depositing and heating the coating is also claimed.Type: GrantFiled: July 21, 1992Date of Patent: May 25, 1999Assignee: Praxair S.T. Technology, Inc.Inventors: John Eric Jackson, Marianne O'Connor Price
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Patent number: 5904993Abstract: A joint body in which aluminum and silicon nitride are strongly joined with each other is provided at a low cost, thereby providing a lightweight part which is excellent in sliding property as a mechanical part of an internal combustion engine of an automobile or the like. The joint body includes a base material which is mainly composed of aluminum, and a member consisting of a silicon nitride sintered body which is substantially directly joined to the base material. A powdery or bulky base material (2) mainly composed of aluminum, and a member (1) consisting of a silicon nitride sintered body are charged in a mold and heated under pressurization, thereby joining the same with each other.Type: GrantFiled: May 21, 1996Date of Patent: May 18, 1999Assignee: Sumitomo Electric Industries, Ltd.Inventors: Hisao Takeuchi, Koichi Sogabe, Takao Nishioka, Takashi Matsuura, Akira Yamakawa
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Patent number: 5897954Abstract: A layer of conformationally adaptive organic molecules are used in epitaxially layered structures to accommodate lattice mismatch between layers at least one of which is of a nonorganic crystalline material. Such a layer on a substrate layer may constitute the epitaxially layered structure or the conformationally adaptive organic molecule layer may be used to accommodate a lattice mismatch between two other layers or the substrate and another layer.Type: GrantFiled: July 10, 1996Date of Patent: April 27, 1999Assignee: International Business Machines CorporationInventors: James K. Gimzewski, Thomas A. Jung, Reto R. Schlittler
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Patent number: 5879816Abstract: A metallic sliding material including at least a support member with a sliding surface and an inorganic compound coating layer formed on the sliding surface is disclosed. The sliding surface is formed from an aluminum alloy or a reinforcing material-containing aluminum alloy. The inorganic compound coating layer is formed from at least one aluminum compound, and at least one phosphorus compound, and at least one member selected from the group of molybdenum compounds, tungsten compounds, and chromium compounds. These compounds are present in such concentrations that molybdenum, tungsten, and chromium collectively constitute 2 to 48% by weight of the inorganic compound coating layer, aluminum constitutes 1 to 25% by weight of the inorganic compound coating layer, phosphorus constitutes 1 to 25% by weight of the inorganic compound coating layer, and the balance of the inorganic compound coating layer is oxygen and impurities.Type: GrantFiled: November 27, 1996Date of Patent: March 9, 1999Assignees: Nihon Parkerizing Co., Ltd., Toyota Jidosha Kabushiki KaishaInventors: Kazuhiko Mori, Jun Kawaguchi, Takashi Koyama, Yoshio Fuwa, Hirofumi Michioka
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Patent number: 5876859Abstract: A method for use with a direct metal bonding type process in which a metal layer is bonded to an insulating layer. The metal layer is applied to the insulating layer to enable a direct metal bond to be formed between the layers. The integrity of the bond between a portion of the layers is reduced by providing, prior to bonding, an interrupter between the portion of the layers. A structure in which a metal layer is directly metal bonded to an insulating layer and includes an interrupter between a portion of the metal layer and a portion of the insulating layer. The interrupter reduces the integrity of the bond between the portion of the metal layer and the portion of the insulating layer. The structure includes other features similar to those set forth with respect to the above described method.Type: GrantFiled: December 15, 1995Date of Patent: March 2, 1999Assignee: VLT CorporationInventors: John R. Saxelby, Jr., Brant T. Johnson
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Patent number: 5840429Abstract: The present invention relates to an aircraft transparency including an electroconductive metal oxide coating over a rigid plastic substrate, and a polyurethane protective liner over the metal oxide coating, and more specifically to the use of a primer for adhering the metal oxide coating to the substrate and/or a primer for adhering the polyurethane protective liner to the metal oxide coating. The metal oxide primer includes a carbonate diol-based crosslinked polyurethane. The polyurethane primer is selected from the group consisting of a crosslinked copolymer of acrylic acid and substituted acrylates such as 2-ethylhexylacrylate; a crosslinked copolymer of cyanoethylacrylate and acrylic acid; and a crosslinked terpolymer of 2-ethylhexylacrylate, cyanoethylacrylate and acrylic acid.Type: GrantFiled: November 5, 1996Date of Patent: November 24, 1998Assignee: PPG Industries, Inc.Inventors: Thomas G. Rukavina, Robert M. Hunia
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Patent number: 5830586Abstract: An article having a spallation resistant TBC comprises a metal substrate, such as a high temperature superalloy, and a TBC, such as a coating of yttria stabilized zirconia. The TBC comprises a plurality of plasma-sprayed layers. The TBC has a coherent, continuous columnar grain microstructure, wherein at least one layer has a plurality of continuous columnar grains which have been extended by directional solidification into an adjacent layer. In a preferred embodiment, the coherent, continuous columnar microstructure comprises substantially all of the volume of TBC. A coherent, continuous columnar grain microstructure is also taught wherein at least some of the plurality of coherent, continuous columnar grains which comprise a TBC extend through essentially the entire thickness of the coating.Type: GrantFiled: July 29, 1996Date of Patent: November 3, 1998Assignee: General Electric CompanyInventors: Dennis Michael Gray, Yuk-Chiu Lau, Curtis Alan Johnson, Marcus Preston Borom, Warren Arthur Nelson
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Patent number: 5827618Abstract: This invention provides a rust-proofed steel sheet for a fuel tank including an alloy layer containing at least one of Ni, Fe, Zn and Sn and deposited on the surface of a steel sheet to a thickness of 2 .mu.m per surface, and a Sn--Zn alloy plating layer consisting of 40 to 99 wt % of Sn and the balance of iron, containing not greater than 20 crystals/0.25 mm.sup.2 of zinc crystals having a major diameter of not greater than 250 .mu.m and deposited on the alloy layer to a thickness of 2 to 50 .mu.m per surface. The to-be-plated steel sheet to which the plating layer is applied has a composition consisting of C.ltoreq.0.1%, Si.ltoreq.0.1%, Mn: 0.05 to 1.2%, P.ltoreq.0.040%, Al<0.1% and if necessary, at least one of B, Ti, Nb and Cr, and the balance of Fe and unavoidable impurities. This invention provides also a production method of a rust-proofing steel sheet for a fuel tank comprising the steps of applying Ni--Fe type pre-plating to an annealed steel sheet in a quantity of 0.1 to 3.0 g/m.sup.Type: GrantFiled: November 27, 1996Date of Patent: October 27, 1998Assignee: Nippon Steel CorporationInventors: Yashichi Oyagi, Takayuki Omori, Masahiro Fuda, Ken Sawada, Nobuyoshi Okada
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Patent number: 5798185Abstract: Two metal plates are joined together by curling, where projections are formed in advance at an edge of one of the two metal plates and those projections are forcibly advanced into an edge or the other of the two metal plates so as to interlock the metal plates without any mutual displacement therebetween and not requiring any positioning of projections or cut and raised portions with respect to holes.Type: GrantFiled: October 11, 1995Date of Patent: August 25, 1998Assignee: Sanyo Machine Works, Ltd.Inventor: Akira Kato