Abstract: A process is provided for the removal of peroxides from gaseous or liquid media. The improvement is provided by the use of a carbonaceous char active for peroxide decomposition which is prepared by the carbonization and oxidation of a bituminous coal or bituminous coal-like material at temperatures below 700.degree. C. followed by exposure of the carbonized, oxidized char to a nitrogen-containing compound during the initial calcination and condensation of the carbon structure as the temperature is raised to above 700.degree. C.

Abstract: An improved process is provided for the manufacture of a catalytically-active carbonaceous char capable of rapidly decomposing hydrogen peroxide in aqueous solutions. The process of the invention uses a low temperature carbonization and extensive oxidation of a bituminous coal or bituminous coal-like material followed by exposure to a nitrogen-containing compound at high temperatures during the initial calcination and/or activation. The resultant catalytically-active chars have the ability to rapidly decompose aqueous solutions of hydrogen peroxide and are useful for catalytic conversion of H.sub.2 S, SO.sub.x, NO.sub.x, chloramines, and/or peroxides in liquid and/or gaseous streams.

Abstract: A generator for producing a flow of excited oxygen in the singlet delta electronic state comprising a vacuum chamber, an inlet feed system, an internal reaction zone, a method for cooling said reaction zone, an outlet system for separating the gas from the liquid, and a means for interfacing this device to a lasing device for directing the flowing singlet delta gas into a laser cavity.

Abstract: A solid body having extremely narrow passages formed therein for the separation and conveyance of gases by surface diffusion. Because of the relatively high flow resistance resulting from the extremely small cross sections of the passages, the gas conveyance through the solid body can be performed substantially exclusively by surface diffusion. Only those gas particles which are adsorbed on the solid body or on the wall of the passages will be conveyed through the solid body. The surface diffusion can be controlled by suitable selection of the gas/solid body combination. The diffusion is influenced particularly by the temperature of the solid body. When, in the case of a two-gas mixture, the solid body is heated to a temperature above the desorption temperature of one of the gases and below the desorption temperature of the other gas, only the gas particles of the adsorbed gas are conveyed on the passage walls by surface diffusion.

Abstract: Separate recovery of high and low molecular weight gases from a gaseous starting mixture, e.g. a mixture resulting from thermal water splitting. A set of three chambers is used which are arranged in series and separated by membranes permeable preferentially to the low molecular gas. Gases permeate from the first to the second chamber and from there to the third chamber. A gaseous mixture enriched with the high molecular weight gas is withdrawn from the first chamber and a gaseous mixture enriched with the low molecular weight gas is withdrawn from the third chamber. Undesired gaseous components are rendered non-gaseous and the remaining low and high molecular weight gases are withdrawn separately.

Abstract: Potassium superoxide can be used to generate and regenerate Basic Hydrogen Peroxide, the primary fuel for Chemical Oxygen-Iodine Lasers. The solid reacts with depleted BHP/H.sub.2 O.sub.2 solution consuming one equivalent of hydrogen peroxide and producing two equivalents of hydroperoxide, reversing the chlorine/BHP reaction that evolves singlet delta oxygen, the energetic species in the COIL system. This same regeneration reaction can be used to generate new BHP solutions by reaction of potassium superoxide with dilute hydrogen peroxide or a protic mineral acid such as hydrochloric acid. These reactions of potassium superoxide provide new and useful methods of generating and regenerating BHP, that significantly decrease COIL system weights and environmental impact.

Abstract: A method and apparatus for storing and retrieving oxygen are provided on a steady flow basis. The temperature of a storage vessel containing lithium perchlorate (LiClO.sub.4) in the solid state is raised until a molten bath of the LiClO.sub.4 is formed. The molten bath of LiClO.sub.4 is maintained at a setpoint temperature which is less than the temperature at which substantial decomposition of the LiClO.sub.4 occurs. The molten LiClO.sub.4 is then caused to flow from the storage vessel to a reaction vessel whose temperature is raised sufficiently to assure essentially instantaneous and complete decomposition of the LiClO.sub.4. Specifically, within the reaction vessel, a spray of the molten LiClO.sub.4 is directed toward an internal target surface, upon the impingement with which decomposition of the molten LiClO.sub.4 into LiCl and O.sub.2 occurs.

Abstract: Carbonaceous chars capable of catalytically decomposing aqueous hydrogen peroxide at higher rates at given char densities than other known catalytic chars are provided for. This improvement is provided by an increase in the catalytic activity at a given char density of the said catalytically-active carbonaceous char. The catalytically-active carbonaceous chars are useful for, but not limited to, the catalytic conversion of H.sub.2 S, SO.sub.x, NO.sub.x, peroxides, and/or chloramines in liquid and/or gaseous media.

Abstract: The improved method achieves effective and economical decomposition of hydrogen peroxide and may be used in recycling hydrogen peroxide containing spent sulfuric acid that has been used in wafer cleaning and other operations in the process of semiconductor fabrication or in removing residual hydrogen peroxide that will occur either within the papermaking process or in plant effluents as a consequence of a shift from chlorine-containing bleaching agents to oxygen-containing bleaching agents.When coke was added in an amount of 10 wt % to a solution of 0.88 wt % hydrogen peroxide in 72.8 wt % sulfuric acid, followed by treatment at 60.degree.-70.degree. C. for 4 hours, the concentration of hydrogen peroxide dropped to 0.0001 wt % and below. When coke was added in an amount of 10 wt% to each of a solution (pH, 0.94) of 1.0 wt % hydrogen peroxide in 1.1 wt % sulfuric acid and a solution (pH, 2.58) of 1.04 wt % hydrogen peroxide in sulfuric acid followed by treatment at 60.degree.-70.degree. C.

Abstract: A method is provided for removing residual amounts of oxygen and water vapor from the controlled atmosphere of an enclosed chamber. A small volume of high-purity silicon is heated in a crucible placed inside the chamber. The silicon is typically heated with a power source separate from that used for heating the chamber and its primary contents. The heated silicon functions as an effective oxygen getter for removing residual oxygen and water vapor from the controlled atmosphere before and/or during a process conducted in the chamber. Heating the silicon to a molten state can induce beneficial convective stirring that keeps the silicon surface fresh for effective, efficient, and continuous capturing of oxygen.

Abstract: An internal passive catalytic device operating in the water phase of a boiling water reactor vessel downstream of the steam/water separator location. The device consists of catalytic material arranged and situated such that all (except perhaps a small leakage flow) water phase exiting the water/steam separator device flows over the surface of the catalytic material. The catalytic surfaces decompose dissolved hydrogen peroxide into water and oxygen. When the substrate of the catalytic material is plated or alloyed with a water recombination catalyst such as a noble metal, the catalytic surfaces also catalyze the recombination of dissolved hydrogen and oxygen molecules into water. The passive catalytic device is constructed to ensure that the pressure drop of the reactor water across the device is very small.

Abstract: A passive decomposer operating in the water/steam mixture exiting the core of a boiling water reactor. The decomposer comprises a catalytic material arranged and situated such that substantially all of the water/steam mixture entering the water/steam separator device flows over the surface of the catalytic material. The catalytic decomposing surfaces decompose hydrogen peroxide molecules dissolved in the liquid phase to form water and oxygen molecules. The passive catalytic decomposer is constructed to ensure that the pressure drop of the reactor water across the device is very small. The decomposer can include a plurality of stainless steel flow-through housings packed with stainless steel catalytic decomposer material, which could take the form of tangled wire or strips, crimped ribbon, porous sintered metal composite or any other structure having a high surface area-to-volume ratio.

Abstract: There are disclosed saltmen-type metallo Schiff base complexes and oxygen-sorbing and -desorbing solutions of the same, pressure- and temperature-swing oxygen separation processes using the complexes and solutions, and methods of regenerating such complexes and solutions.

Abstract: A process is provided for the synthesis for metal oxides of high specific surface area and high porosity which are particularly useful as catalyst supports. The process comprises forming a mixture of a salt of at least one metal and a molten salt medium comprising at least one alkali metal salt having an oxidizing effect, maintaining this mixture at the reaction temperature for the time necessary to convert the salt to oxide and thereafter isolating the metal oxide formed.

Abstract: Ruthenium tetroxide is obtained by oxidation of an alkali metal ruthenate in aqueous solution. The oxidizing agent used is ozone. The oxidation is carried out at a pH greater than or equal to 8.

Abstract: This invention comprises a method and apparatus for obtaining from air an oxygen enriched gas mixture containing at least 40 mole % nitrogen. The apparatus comprises a gas turbine, an oxygen separation unit which is in fluid communication with the turbine air compressor and means for maintaining a proper mass balance tolerance between the turbine compressor/unit and the turbine energy production unit.This invention comprises a method and apparatus for recovering large quantities of an oxygen enriched gas from the volume of a compressed air stream produced by a gas turbine by compensation of the mass loss to the energy production unit section thereof by providing means for maintaining the turbine in proper mass and thermal balance as the turbine is utilized to provide the duty/power requirements of a process which utilizes the oxygen enriched gas stream as a reactant.

Abstract: A method for converting solid organic fuels, most particularly coals, into high temperature gases that can easily be transformed into useful energy. This method employs a substantially closed reactor, referred to as a gasifier, having an internal reaction chamber or cavity made of materials that can tolerate the presence of oxygen at high temperatures, that possess low thermal mass, that limit or restrict the passage of heat, that function as almost perfect black bodies at high temperatures, and that are resistant to the abrasive effects of the solid fuels.

Abstract: A rotating disk reactor for producing singlet delta oxygen is disclosed. The reactor includes a plurality of closely spaced coaxial disks partially immersed in a pool of liquid basic hydrogen peroxide (BHP) inside a reactor vessel. A thin film of BHP is picked up and carried on the rotating disks. Chlorine gas, diluted with helium, is flowed into the reactor vessel to pass between the disks and react with the BHP to produce singlet delta oxygen. The singlet delta oxygen flows out of the reactor through a liquid separator to remove liquids and then through an impurity cold trap to remove by condensation gaseous H.sub.2 O.sub.2 and H.sub.2 O.

Abstract: A radioactive catalyst is disclosed which comprises a fine particle of semiconductor and a high radioactive platinum group element deposited on the particle of semiconductor. The radioactive catalyst serves as a source of radiation and also as a catalyst for oxidation-reduction reaction. By bringing the radioactive catalyst into contact with water, the water is decomposed by the oxidation-reduction reaction to produce hydrogen and oxygen.

Abstract: The present invention relates to a method for the preparation of ultrafine oxide particles using organized reaction media. Integrated circuit (IC) densities have necessitated the use of ultrahigh purity process fluids in state of the art fabrication facilities. It is the purpose of the present invention to synthesize monodispersed submicron particles of some representative contaminants, such as ultrafine oxide particles, using organized reaction media, and study their characteristics in relation to their removal from process fluids.

Abstract: A method for producing oxygen and methane from carbon dioxide, and hydrogen utilizing a methanation reactor, a reforming reactor, and an electrolyzer. Carbon dioxide and hydrogen are reacted to produce methane and water. A portion of the water along with a portion or all of the methane is directed to a reforming reactor where it is reacted to produce hydrogen and carbon monoxide, while the remaining portion of the methane is stored. The hydrogen is recycled to the methanation reactor while the carbon monoxide is vented or stored for use as a fuel. The second portion of the water is electrolyzed to its constituents, hydrogen and oxygen. The oxygen is stored or used for life support while the hydrogen is recycled to react with additional carbon dioxide.

Abstract: A binuclear metal complex, comprising a metal-complexed ligand which ligand is formed by the reaction of a dialdehyde and a poly primary amine, which complex is capable of reacting reversibly with molecular oxygen.

Abstract: An electron beam is directed into a first region containing gaseous molecules which capture electrons from the beam and then dissociate to produce negative ions. The ions are accelerated to the desired energy electrostatically and drawn to a second region where they are exposed to an intra-cavity laser beam which traverses their path. The laser is chosen to have a wevelength which will cause photodetachment of electrons to form neutral atoms. Simultaneously with the above, the electron beam and ions are collimated with a magnetic field. The neutral atoms are separated from any remaining ions or electrons by a repelling electrical potential provided by a repeller plate or the like.

Abstract: There is disclosed a catalyst structure for ozone decomposition which comprises a thin porous carrier material which has many micropores in the direction of the thickness of the carrier material and has an ozone decomposition catalyst supported thereon.Also disclosed is a method of ozone decomposition using such a catalyst structure, in which preferably the catalyst structure comprises a thin porous carrier material which has many micropores not less than 30 .mu.m in diameter in the direction of the thickness of the carrier material and has an ozone decomposition catalyst supported thereon. The carrier material may be of an electrically resistant material, and may be electrified and heated while a gas containing ozone is forcibly passed therethrough.

Abstract: The present invention is concerned with a synthetic crystalline titanium-boron-oxide, synthetic crystalline materials based thereon that contain an oxide of aluminum or silicon or their combination and the methods for their preparation. These materials are useful as catalysts for many reactions and in their metal-loaded form as photocatalysts for the cleavage of water.

Abstract: Compound oxides of bismuth, strontium, calcium and copper of a specific metal content ratio can be prepared by refluxing an organic solvent solution containing alkoxides of bismuth, strontium, calcium and an organic acid salt, an alkoxy-.beta.-keto complex, .beta.-diketo complex or .beta.-ketoester complex in said specific metal content ratio, and thermally decomposing the refluxed reaction product.

Abstract: Oxygen is extracted from a fluid mixture feedstock by circulating a carrier fluid from an oxygen loading station to an electrochemical cell. The carrier fluid includes a carrier compound capable of reversibly binding oxygen, with oxygen binding dependent on the oxidation state of the compound. Oxygen bound to the carrier compound in a first oxidation state is released as the oxidation state is altered at the first electrode of the electrochemical cell. The carrier compound is then returned to the first oxidation state at the second electrode at the electrochemical cell. The loading station typically comprises an oxygen-permeable membrane which prevents bulk mixing of the fluid mixture and the carrier fluid.

Abstract: The present invention is directed to a chemical air separation process using a molten salt solution of alkali metal nitrate and nitrite wherein the materials of construction of the containment for the process are chosen from intermetallic alloys of nickel and/or iron aluminide wherein the aluminum content is 28 atomic percent or greater to impart enhanced corrosion resistance.

Abstract: A reactor capable of continuously producing activated species of oxygen molecules, specifically those known as "Delta Singlet Oxygen". Uses of "Delta Singlet Oxygen" include the maintenance of high oxidation potential during the deposition of layers of high temperature superconductors. Delta singlet oxygen is particularly effective in obtaining ultra-smooth surfaces when used as the etching gas in plasma milling of a diamond-like carbon film. The film can be used as an ideal insulating barrier for construction of high-temperature superconducting Josephson junctions.

Abstract: An electron beam is directed into a first region containing gaseous molecules which capture electrons from the beam and then dissociate to produce negative ions. The ions are accelerated to the desired energy electrostatically and drawn to a second region where they are exposed to an intra-cavity laser beam which traverses their path. The laser is chosen to have a wavelength which will cause photodetachment of electrons to form neutral atoms. Simultaneously with the above, the electron beam and ions are collimated with a magnetic field. The neutral atoms are separated from any remaining ions or electrons by a repelling electrical potential provided by a repeller plate or the like.

Abstract: A process for degrading hypochlorite waste and lithium hypochlorite solutions uses a cobalt oxide/molybdenum oxide catalyst formed from about 1-10 w/w % cobalt oxide and 1-15 w/w % molybdenum oxide disposed on a suitable substrate. The major advantage of the catalyst lies in its high degree of effectiveness and its very low cost.

Abstract: Methods and apparatus for electrochemical extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefor comprising macrocyclic amines having the general formulas: ##STR1## where: A, B, C, D, E, and F are each nitrogen, oxygen, sulfur, or phosphorous;m, n, o, p, q, and r are each typically 2, 3, 4, 5, or 6;the R substituents are each generally H or short chain (linear or branched) alkyl, although R.sub.2 may represent ketyl (.dbd.o); andM is a suitable transition metal ion.

Abstract: Separation of oxygen from air is performed in a continuous, cyclic manner using vanadium bronze liquid slurries as reversible chemical absorbents, absorbing at elevated temperature and desorbing at lowered temperature.

Abstract: Salts containing cations of the formula: ##STR1## (in which M is Co, Fe, Cr or Mn, X, Y, R.sub.1,The Government has rights in this invention pursuant to Contract Number CHE-75-14837 awarded by the National Science Foundation.

Abstract: An apparatus in the form of a disk for the separation of oxygen from gases, or for the pumping of oxygen, uses a substantially circular disk geometry for the solid electrolyte with radial flow of gas from the outside edge of the disk to the center of the disk. The reduction in available surface area as the gas flows toward the center of the disk reduces the oxygen removal area proportionally to provide for a more uniform removal of oxygen.

Abstract: A method for producing an atomic oxygen beam is provided by the present invention. First, a material 10' is provided which dissociates molecular oxygen and dissolves atomic oxygen into its bulk. Next, molecular oxygen is exposed to entrance surface 11' of material 10'. Next, material 10' is heated by heater 17' to facilitate the permeation of atomic oxygen through material 10' to the UHV side 12'. UHV side 12' is interfaced with an ultra-high vacuum (UHV) environment provided by UHV pump 15'. The atomic oxygen on the UHV side 12' is excited to a non-binding state by exciter 14' thus producing the release of atomic oxygen to form an atomic oxygen beam 35'.

Abstract: An ozone decomposing agent comprises at least one terpenoide capable of decomposing ozone, a liquid alcohol for dissolving therein the terpenoide, dibenzylidenesorbitol or sodium bis (4-t-butylphenyl)phosphate, and a solvent for dissolving therein dibenzylidenesorbitol or sodium bis (4-t-butyl-phenyl)phosphate, or the ozone decomposing agent may comprise such terpenoide and a water-soluble gelation agent for holding the terpenoide.

Abstract: The present invention is directed to catalysts for the absorptive separation of oxygen from oxygen-containing gas mixtures, such as air, using reversible chemical reaction systems, such as, ##STR1## The catalytic action is the result of the addition of transition metal oxides to the oxygen accepting system.

Abstract: A new combination is disclosed of (I) a process for producing a substance enriched in a desired isotope of hydrogen and/or oxygen from a flow of liquid substance, e.g. water which becomes depleted in its content of said isotope, and (II) replenishing the liquid substance with said isotope by (a) direct contact with a flow of steam from a source external to the process, preferably geothermal steam, and (b) supplying feed flow of the process (I) from the so replenished liquid substance.

Abstract: A continuous process for the production of a gaseous product (12), and as a liquid byproduct (16), at the same time by reacting a liquid reagent in a reactor (4) is disclosed. The positive difference between the pressure at the entrance to and an pressure at the outlet of the reactor (4) is kept constant. The process can be used to generate oxygen by decomposition of hydrogen peroxide and this oxygen can be used in welding and cutting sets.

Abstract: A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite.

Abstract: A process is disclosed for selectively sorbing trace amounts of oxygen from low molecular weight olefins and inert gases by contacting with high surface area particulate coal-derived activated carbon having high ash and moisture content.

Abstract: A process for treating effluent wherein an oxidizing agent in the effluent is decomposed on contact with a catalyst bed. The oxidizing agent can be a pollutant present in the effluent, for example hypochlorite in the effluent from chlorine-producing brine electrolysis cells or from the scrubbing of chlorine gas. In an alternative the effluent may contain oxidizable pollutants and the oxidizing agent is purposefully added thereto. Passage over the catalyst bed catalyzes the decomposition of the oxidizing agent and oxidizable pollutants.The catalyst bed comprises an intimate mixture of an oxide of Group III, nickel oxide and, optionally, cobalt oxide, supported on pieces of a non-porous substantially inert material.

Abstract: Materials are described which not only extinguish fires or suppress explosions but also remove at least part of any carbon monoxide which may remain after such prior extinguishing or explosion suppressing. Examples of suitable fire extinguishants and explosion suppressants are halocarbons such as bromotrifluoromethane. The carbon monoxide removing substance may comprise Hopcalite catalysts. Other examples of suitable substances are disclosed.

Abstract: This invention relates generally to a method for producing nitrous oxide, and more specifically, to a method of producing nitrous oxide by reacting ammonia with at least one molten nitrate salt of an alkaline earth metal.

Abstract: A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs.

Abstract: A process and apparatus for the continuous dissociation of water into hydrogen and oxygen by a thermolytic reaction in contact with a surface (9a) within the reactor immersed in a body (19) of liquid water and heated by an energy input, in particular by focusing solar radiation through a transparent wall (4), so as to maintain the thermolytic temperature at the core of the body of water, whereby a state of boiling is maintained in the immediate vicinity of the surface and generates a gas film near it; the body of water is provided in sufficient quantity to preserve in liquid form the water around that gas film, and within this film the vaporized water molecules are decomposed and in-situ chilling of the decomposition products is assured by the neighboring liquid water.

Abstract: This invention relates generally to a method for producing nitrous oxide, and more specifically, to a method for producing nitrous oxide by reacting ammonia with at least one molten nitrate salt.

Abstract: A method of generating oxygen for emergency use wherein oxygen is generated by adding a catalyst such as manganese dioxide etc. to an aqueous solution prepared by intermixing an addition compound of sodium carbonate and hydrogen peroxide with water and wherein the catalyst is formed into a continuous and integral shape so as to thereby make it possible to put the catalyst into and take it out of the aqueous solution so that generation of oxygen can be started and stopped easily.

Abstract: The present invention is a cobalt complex having the structural formula: ##STR1## wherein each R.sub.1 is independently hydrogen, a phenyl or a C.sub.1 -C.sub.6 alkyl group; each R.sub.2 is independently hydrogen or a C.sub.1 -C.sub.6 alkyl group; R.sub.3 is a C.sub.4 -C.sub.30 hydrocarbyl radical connecting the two carbonyl carbons; and Y is o-phenylene, --CH.sub.2).sub.a wherein "a" is 2 or 3, --CH.sub.2).sub.b NR.sub.4 --CH.sub.2).sub.c, wherein "b" and "c" are independently 2 or 3 and R.sub.4 is hydrogen or a C.sub.1 -C.sub.12 alkyl group.These complexes have the ability to selectively and reversibly bind oxygen, thus making them useful components of oxygen separation membranes and absorbents.