Abstract: A lithium-transition metal complex compound has an nth order hierarchical structure in which n type structures represented by at least one unit of ath order units in a range of 1×10?(a+5) m to 10×10?(a+5) m exist in a complex form, wherein n is a natural number that is 2 or greater, and a is a natural number in a range of 1 to 5. The lithium-transition metal complex may be prepared by heat-treating a mixture including a lithium source, a transition metal source, and solvent in contact with a natural material having a hierarchical structure. A lithium battery includes an electrode including the lithium-transition metal complex compound having the nth order hierarchical structure. The lithium battery can have improved rapid charging characteristics, high power characteristics, and cycle characteristics.
Type:
Grant
Filed:
March 6, 2009
Date of Patent:
January 8, 2013
Assignee:
Samsung Electronics Co., Ltd.
Inventors:
Yoonsok Kang, Joungwon Park, Guesung Kim, Jaegu Yoon
Abstract: An oxide evaporation material in the present invention comprises a sintered body containing indium oxide as a main component thereof and cerium with the Ce/In atomic ratio of more than 0.110 and equal to or less than 0.538, and has an L* value of 62 to 95 in the CIE 1976 color space. The oxide evaporation material with the L* value of 62 to 95 has an optimal oxygen amount. Accordingly, even when a small amount of oxygen gas is introduced into a film-formation vacuum chamber, a high-refractive-index transparent film having a refractive index of 2.15 to 2.51 at a wavelength of 550 nm, a low resistance, and a high transmittance in the visible to near-infrared region is formed by vacuum deposition methods. Since the introduced oxygen gas amount is small, the difference in composition between the film and the evaporation material is made small.
Abstract: There is provided an anisotropically shaped powder preferred as plate-like crystals used in the process of producing niobate-based KNbO3—NaNbO3—LiNbO3-based crystal-oriented ceramics and the like, and a method for producing the same. The production method includes, an oxide powder, such as Nb2O5, and a surfactant are added to an aqueous solution of alkali hydroxides, such as NaOH and KOH to perform hydrothermal synthesis, the product obtained after this reaction is washed with an organic solvent, and further, the product after the washing is fired at 170° C. to 700° C. In addition, according to this production method, it is possible to obtain an anisotropically shaped powder having a ratio of an average particle length in a major axis direction to an average particle length in a thickness direction in the range of 2 to 20 and having a pseudo-cubic perovskite structure in which a crystal face is oriented in a (100) plane.
Abstract: A method for the preparation of functionalized particles includes providing a feedstock made of particles, a surface treatment agent reactive with the particles, and solvent. The feedstock is exposed to microwave radiation to heat the feedstock and react the particles with the surface treatment agent to provide the functionalized particles in less than about 60 minutes.
Type:
Grant
Filed:
April 17, 2009
Date of Patent:
November 27, 2012
Assignee:
3M Innovative Properties Company
Inventors:
James M. Nelson, Matthew N. Archibald, Wendy L. Thompson, Grant F. Tiefenbruck
Abstract: The present invention relates to (i) a plant growth-improving agent containing a growth-improving component that increases a concentration of an oxoanion in an area around a plant, the oxoanion being heavier than a sulfate ion and containing four oxygen atoms, (ii) a seed to which such a plant growth-improving agent has been applied, and (iii) a plant growth-improving method including a cultivating step of growing a plant in the presence of such a growth-improving component.
Type:
Application
Filed:
January 26, 2011
Publication date:
November 8, 2012
Applicant:
Incorporated Administrative Agency National Agricu lture and Food Research Organization
Abstract: A method of forming a metal oxide nanostructure comprises disposing a chelated oligomeric metal oxide precursor on a solvent-soluble template to form a first structure comprising a deformable chelated oligomeric metal oxide precursor layer; setting the deformable chelated oligomeric metal oxide precursor layer to form a second structure comprising a set metal oxide precursor layer; dissolving the solvent-soluble template with a solvent to form a third structure comprising the set metal oxide precursor layer; and thermally treating the third structure to form the metal oxide nanostructure.
Type:
Grant
Filed:
July 2, 2009
Date of Patent:
September 25, 2012
Assignee:
International Business Machines Corporation
Inventors:
Ho-Cheol Kim, Robert D. Miller, Oun Ho Park
Abstract: There are provided a method of manufacturing a ceramic powder having a perovskite structure and a ceramic powder having a perovskite structure manufactured by the same. The method includes: mixing a compound of an element corresponding to site A in an ABO3 perovskite structure as well as a compound of an element corresponding to site B in the same structure, with supercritical water in a continuous mode to form seed crystals; and mixing the seed crystals in a batch mode to conduct grain growth thereof.
Type:
Application
Filed:
March 2, 2012
Publication date:
September 6, 2012
Inventors:
Chang Hak Choi, Kum Jin Park, Kang Heon Hur, Hye Young Baeg, Jung Hwan Kim, Hyung Joon Jeon, Sang Hoon Kwon
Abstract: A method for preparing nanotubes by providing nanorods of a piezoelectric material having an asymmetric crystal structure and by further providing hydroxide ions to the nanorods to etch inner parts of the nanorods to form the nanotubes.
Type:
Grant
Filed:
October 26, 2009
Date of Patent:
August 28, 2012
Assignees:
Samsung Electronics Co., Ltd., Kumoh National Institute of Technology
Abstract: A process comprises (a) combining (1) at least one base and (2) at least one metal carboxylate salt comprising (i) a metal cation selected from metal cations that form amphoteric metal oxides or oxyhydroxides and (ii) a carboxylate anion comprising from one to four alkyleneoxy moieties, or metal carboxylate salt precursors comprising (i) at least one metal salt comprising the metal cation and a non-interfering anion and (ii) at least one carboxylic acid comprising from one to four alkyleneoxy moieties, at least one salt of the carboxylic acid and a non-interfering, non-metal cation, or a mixture thereof; and (b) allowing the base and the metal carboxylate salt or metal carboxylate salt precursors to react.
Abstract: Dielectric materials comprising nanocrystalline or nanoparticulate metal oxides or metal carbonates having enhanced dielectric constant values are provided. Specifically, the dielectric materials exhibit high dielectric constant values at low frequencies approaching the DC limit. The dielectric materials also exhibit low dielectric loss factors and high voltage breakdown limits making them well suited for use in capacitors, particularly high energy density capacitors.
Type:
Application
Filed:
July 13, 2007
Publication date:
July 12, 2012
Inventors:
David Jones, Slawomir Winecki, Shivanee Dargar, Justin Millette
Abstract: A novel particulate composite hydrotalcite which offers antacidic effect comparable to that of a particulate hydrotalcite so far used as a gastric antacid and, further, offers excellent stomach inner wall protection effect. A particulate composite hydrotalcite represented by the following formula (1), (MgaZnb)1-xAlx(OH)2(An?)x/n.mH2O??(1) wherein An? is CO32?, SO42? or Cl?, n is 1 or 2, and x, a, b and m are values that satisfy the following conditions, 0.18?x?0.4, 0.5?a<1, 0<b?0.5, 0?m<1, and a gastric antacid using the particulate composite hydrotalcite as an effective component. When used as a gastric antacid, the particulate composite hydrotalcite suppresses the occurrence of damage in the mucous membranes of stomach and intestines.
Abstract: Disclosed herein are processes for making a plurality of substantially phase-pure metal oxide particles, the particles comprising a garnet structure, the process comprising: subjecting a dispersion of precursors to a solvothermal treatment to form a garnet intermediate and applying a flow-based thermochemical process to said garnet intermediate.
Abstract: A photocatalytic coating composition comprising photocatalytic titanium oxide, silver, copper and a quaternary ammonium hydroxide. The photocatalytic coating composition may include a photocatalytic titanium oxide sol dispersed in a binder. Furthermore, a photocatalytic member includes a substrate having a surface coated with the photocatalytic coating composition. The photocatalyst coating composition can contain highly antibacterial silver by skillfully utilizing copper and a quaternary ammonium hydroxide, and accordingly can show an antibacterial effect not only in a dark place simply due to silver, but also a higher antibacterial effect in a conventional application of employing ultraviolet sterilization by concomitantly using the photocatalyst titanium oxide sol according to the present invention and an ultraviolet sterilizer.
Abstract: This invention relates to a cerium-zirconium-base composite oxide, which is useful, e.g., for the purification of exhaust gas discharged from combustion engines such as internal combustion engines and boilers and can release a high level of oxygen in a low temperature region, a method for producing the same, an oxygen storage/release component using the same, an exhaust gas purification catalyst, and an exhaust gas purification method. The cerium-zirconium-base composite oxide satisfies requirements (1) that the oxygen release initiation temperature is 380° C. or below, (2) that the oxygen release amount is not less than 485 ?mol/g, and further (3) that the oxygen release amount at 400° C. is not less than 15 ?mol/g.
Abstract: A method of manufacturing a perovskite catalyst composed of perovskite oxide includes mixing step, firing step and acid-treating step. In the mixing step, an A-site material and a B-site material are mixed at a stoichiometric ratio such that the A-site is increased, compared to that of a theoretical composition ABO3 of perovskite oxide in which a ratio of A-site and B-site is 1:1. In the firing step, the obtained mixed powder is fired. In the acid-treating step, the obtained fired powder is acid-treated with acid of pH 2 or more and less than pH 7.
Abstract: Methods for preparing high quality and high yields of nanocrystals, i.e., metal-oxide-based nanocrystals, using a novel solvent-free method. The nanocrystals advantageously comprise organic alkyl chain capping groups and are stable in air and in nonpolar solvents.
Abstract: Metal oxide nanoparticles, production method thereof, light-emitting element assembly, and an optical material are provided. A method of producing metal oxide nanoparticles includes the steps of (A) mixing a first metal alkoxide containing a first metal, a second metal alkoxide containing a second metal different from the first metal, and a surfactant under an inert atmosphere to prepare a reaction solution; and (B) mixing a reaction initiator prepared by mixing a catalyst with a solvent and the reaction solution, and then heating the mixture of the reaction initiator and the reaction solution under an inert atmosphere to produce metal oxide nanoparticles which have a rutile-type crystal structure based on an atom of the first metal, an atom of the second metal, and an oxygen atom, and the surfaces of which are coated with the surfactant.
Abstract: Disclosed is a method for directly preparing cerium oxide powder in a solution phase by a) mixing a cerium precursor solution with a precipitant solution to cause a reaction; and b) performing oxidation treatment of the reacted solution, wherein at least one kind of pure organic solvent containing no water is used as a solvent for the cerium precursor solution as well as the precipitant solution to thereby prepare the cerium oxide powder, the particle size of which is adjusted to 50 nm to 3 ?m. Cerium oxide powder obtained from the method and CMP slurry comprising the cerium oxide powder as a polishing agent are also disclosed.
Type:
Grant
Filed:
November 20, 2007
Date of Patent:
May 8, 2012
Assignee:
LG Chem, Ltd.
Inventors:
Jun-Seok Nho, Myoung-Hwan Oh, Seung-Beom Cho, Jong-Pil Kim, Jang-Yul Kim
Abstract: Disclosed is a new thermoelectric conversion material represented by the chemical formula 1: Bi1-xCu1-yO1-zTe, where 0?x<1, 0?y<1, 0?z<1 and x+y+z>0. A thermoelectric conversion device using said thermoelectric conversion material has good energy conversion efficiency.
Type:
Grant
Filed:
October 7, 2010
Date of Patent:
May 8, 2012
Assignee:
LG Chem, Ltd.
Inventors:
Cheol-Hee Park, Se-Hui Sohn, Won-Jong Kwon, Seung-Tae Hong, Tae-Hoon Kim
Abstract: A material is fabricated for capturing CO2 at mid-high temperature. The material is a layered material containing Ca, Al carbonates. A higher ratio of Ca to Al helps capturing CO2. The temperature for capturing CO2 is around 600° C. The material can even release CO2 at a high temperature. Thus, the material can process looping cycles of carbonation and decarbonization at a CO2 carbonation scale of 45% gCO2/g.
Type:
Grant
Filed:
February 9, 2010
Date of Patent:
May 1, 2012
Assignee:
Atomic Energy Council-Institute of Nuclear Energy Research
Abstract: A plate-like polycrystalline particle is produced by forming inorganic particles into a self-supported, sheet-like shaped body with a predetermined thickness, firing the shaped body, and crushing and classifying the fired shaped body by passing through a mesh having openings with a predetermined size. The inorganic particles are composed of an oxide having a perovskite structure and grow into crystal grains with an isotropic and polyhedral shape. Since grain growth in the thickness direction is limited and grain growth in the surface direction of the sheet is promoted, it is possible to obtain crystal grains having a high aspect ratio and a high degree of orientation. Therefore, in the plate-like polycrystalline particle, in most parts, the number of crystal grains present in the thickness direction of the particle at any one point is one, and a high aspect ratio and a high degree of orientation are achieved.
Abstract: A method for manufacturing a cathode active material for a lithium rechargeable battery, including: selecting a first metal compound from a group consisting of a halide, a phosphate, a hydrogen phosphate and a sulfate of Mg or Al; selecting a second metal compound from a group consisting of an oxide, a hydroxide and a carbonate of Mg or Al; combining the first metal compound and the second metal compound to obtain a metal compound, the metal compound containing either Mg or Al atoms; mixing a lithium compound, a transition metal compound and the metal compound to obtain a mixture; and sintering the mixture.
Abstract: A process for producing a lithium-containing composite oxide for a positive electrode active material for use in a lithium secondary battery, the oxide having the formula LipNxMmOzFa (wherein N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, alkaline earth metal elements and transition metal elements other than N, 0.9?p?1.2, 0.9?x<1.00, 0<m?0.03, 1.9?z?2.2, x+m=1 and 0?a?0.02), which comprises using as an M element source a solution comprising a complex containing the M element dissolved in an organic solvent.
Abstract: A sputtering target including an oxide sintered body, the oxide sintered body containing indium (In) and at least one element selected from gadolinium (Gd), dysprosium (Dy), holmium (Ho), erbium (Er) and ytterbium (Yb), and the oxide sintered body substantially being of a bixbyite structure.
Type:
Application
Filed:
February 28, 2008
Publication date:
December 29, 2011
Applicant:
IDEMITSU KOSAN CO., LTD.
Inventors:
Kazuyoshi Inoue, Koki Yano, Masashi Kasami
Abstract: The invention relates to a cutting tool having a substrate base body and a single or multi-layered coating attached thereupon, wherein at least one layer of the coating is a metal oxide layer produced in the PVD process or in the CVD process and the metal oxide layer has a grain structure wherein there is structural disorder within a plurality of the existing grains that are characterized in that in electron diffraction images of the grains, point-shaped reflections occur up to a maximum lattice spacing dGRENZ and for lattice spacing greater than dGRENZ no point-shaped reflections occur, but rather a diffuse intensity distribution typical for amorphous structures.
Type:
Application
Filed:
March 18, 2010
Publication date:
December 22, 2011
Applicant:
WALTER AG
Inventors:
Veit Schier, Oliver Eibl, Wolfgang Engelhart
Abstract: This invention relates, in general, to a method of producing magnetic oxide nanoparticles or metal oxide nanoparticles and, more particularly, to a method of producing magnetic or metal oxide nanoparticles, which comprises (1) adding a magnetic or metal precursor to a surfactant or a solvent containing the surfactant to produce a mixed solution, (2) heating the mixed solution to 50-6001 C to decompose the magnetic or metal precursor by heating so as to form the magnetic or metal oxide nanoparticles, and (3) separating the magnetic or metal oxide nanoparticles. Since the method is achieved through a simple process without using an oxidizing agent or a reducing agent, it is possible to simply mass-produce uniform magnetic or metal oxide nanoparticles having desired sizes compared to the conventional method.
Type:
Grant
Filed:
November 26, 2004
Date of Patent:
November 29, 2011
Assignee:
Industry-Academic Cooperation Foundation, Yonsei University
Inventors:
Jin-Woo Cheon, Jung-Wook Seo, Jae-Hyun Lee
Abstract: The invention relates to a process for recovering Group VIB metals from a catalyst, in particular a spent bulk catalyst, comprising one or more Group VIB metals and one or more Group VIII metals. Further, the invention relates to a solid Group VIB metal compound obtainable by the process according to the invention having the general formula H2XO4, wherein X=W1-yMoy, wherein y is between 0 and 1 and to its use in a process for the manufacture of a fresh catalyst.
Type:
Grant
Filed:
September 14, 2007
Date of Patent:
November 15, 2011
Assignee:
Albemarle Netherlands B.V.
Inventors:
Bob Gerardus Oogjen, Harmannus Willem Homan Free, Johannes Cornelis Sitters
Abstract: Process for preparing a mixed metal oxide powder, in which oxidizable starting materials are evaporated and oxidized, the reaction mixture is cooled after the reaction and the pulverulent solids are removed from gaseous substances, wherein as starting materials, at least one pulverulent metal and at least one metal compound, the metal and the metal component of the metal compound being different and the proportion of metal being at least 80% by weight based on the sum of metal and metal component from metal compound, together with one or more combustion gases, are fed to an evaporation zone of a reactor, where metal and metal compound are evaporated completely under nonoxidizing conditions, subsequently, the mixture flowing out of the evaporation zone is reacted in the oxidation zone of this reactor with a stream of a supplied oxygen-containing gas whose oxygen content is at least sufficient to oxidize the starting materials and combustion gases completely.
Type:
Grant
Filed:
May 9, 2007
Date of Patent:
November 1, 2011
Assignee:
Evonik Degussa GmbH
Inventors:
Stipan Katusic, Guido Zimmermann, Michael Kraemer, Peter Kress, Horst Miess
Abstract: Disclosed is a method of manufacturing a metal oxide nano powder comprising preparing a first dispersed solution by adding a nano-sized metal powder to water and dispersing the metal powder within the water, performing a hydration reaction of the first dispersed solution at a temperature of about 30 to about 70° C. to generate a precipitation, and filtering and drying the precipitation to prepare a metal oxide powder. Also, disclosed is a metal oxide nano powder manufactured by the method described above, and having any one of a bar-form, a cube-form, and a fiber-form.
Type:
Grant
Filed:
November 6, 2007
Date of Patent:
October 18, 2011
Assignee:
Korea Atomic Energy Research Institute
Inventors:
Chang Kyu Rhee, Min Ku Lee, Young Rang Uhm, Jin Ju Park, Byung Sun Han, Hi Min Lee, Seung-Hee Woo
Abstract: A method of manufacturing a complex metal oxide powder, the method including: preparing a raw material composition for forming a complex metal oxide; mixing an oxidizing solution including an oxidizing substance into the raw material composition to produce complex metal oxide particles to obtain a liquid dispersion of the particles; and separating the particles from the liquid dispersion to obtain a complex metal oxide powder. The complex metal oxide is shown by a general formula AB1?xCxO3, an element A including at least Pb, an element B including at least one of Zr, Ti, V, W, and Hf, and an element C including at least one of Nb and Ta.
Abstract: Described is a method for the production of pure or mixed metal oxides, wherein at least one metal precursor that is a metal carboxylate with a mean carbon value per carboxylate group of at least 3, e.g. the 2-ethyl hexanoic acid salt, is formed into droplets and e.g. flame oxidized. The method is performed at viscosities prior to droplet formation of usually less than 40 mPa s, obtained by heating and/or addition of one or more low viscosity solvents with adequately high enthalpy.
Type:
Grant
Filed:
May 20, 2003
Date of Patent:
August 30, 2011
Assignee:
ETH Zurich
Inventors:
Jan Wendelin Stark, Sotiris E. Pratsinis
Abstract: The present teachings are directed toward hexagonally patterned porous titania synthesized from a titanium isopropoxide precursor using a viscous template of surface-active agents separating nanoscopic bicontinuous channels of water and isooctane. Subsequent catalyst metal salt reduction in the aqueous nanochannels deposits well-separated catalyst metal nanoparticles on the pore surfaces. These nanocomposites exhibit significantly higher carbon monoxide oxidation efficiency than that obtained with known supports with higher specific surface area; efficiency is believed to be due to decreased mass transfer resistance provided the presently disclosed support material.
Type:
Grant
Filed:
August 17, 2009
Date of Patent:
August 23, 2011
Assignees:
Honda Motor Co., Ltd., The Administrators of the Tulane Educational Fund, Rhode Island Board of Governors for Higher Education, Rensselaer Polytechnic Institute
Inventors:
Christopher Brooks, Arijit Bose, Jayashri Sarkar, Ganapathiraman Ramanath, Vijay T. John
Abstract: Process for the production of a metal oxide powder having a BET surface area of at least 20 m2/g by reacting an aerosol with oxygen in a reaction space at a reaction temperature of more than 700° C. and then separating the resulting powder from gaseous substances in the reaction space, wherein the aerosol is obtained by atomisation using a multi-component nozzle of at least one starting material, as such in liquid form or in solution, and at least one atomising gas, the volume-related mean drop diameter D30 of the aerosol is from 30 to 100 ?m and the number of aerosol drops larger than 100 ?m is up to 10%, based on the total number of drops, and metal oxide powder obtainable by this process.
Type:
Grant
Filed:
February 19, 2009
Date of Patent:
June 28, 2011
Assignee:
Evonik Degussa GmbH
Inventors:
Stipan Katusic, Michael Kraemer, Michael Kroell, Peter Kress, Edwin Staab
Abstract: A process for preparing a pure ammonium perrhenate includes producing a first aqueous suspension containing an ammonium perrhenate. A stoichiometric amount of a nitric acid is added to the first aqueous suspension so as to produce a second suspension. The second suspension is introduced into a cathode space of an electrolysis cell. The electrolysis cell is divided by a cation-exchange membrane into the cathode space and an anode space. The nitric acid is cathodically reduced to a nitrous acid in the cathode space by applying an electric potential. The nitrous acid is reacted with ammonium ions of the ammonium perrhenate so as to form an aqueous perrhenic acid. Potassium ions are removed from the aqueous perrhenic acid. At least a stoichiometric amount of ammonia is added to the aqueous perrhenic acid so as to produce the pure ammonium perrhenate.
Abstract: This invention relates to a 4 group metal oxide and to a method for preparation thereof and the 4 group metal oxide prepared by adding a particle growth inhibiter to a hydrosol a hydrogel or a dried product of a hydrous 4 group metal oxide represented by MO(2-x)(OH)2x (wherein M denotes a 4 group metal and x is a number greater than 0.1 or x>0.1) followed by drying and calcining has a specific surface area of 80 m2/g or more, a pore volume of 0.2 ml/g or more and a pore sharpness degree of 50% or more and excellent heat stability and is useful for a catalyst or a catalyst carrier in which a catalyst metal is dispersed to a high degree.
Abstract: An improved method for the formation of composite hydroxides or oxides comprising, on an oxide basis, Al2O3 and ZrO2, and optionally CeO2, La2O3, Nd2O3, Pr6O11, Sm2O3, Y2O3, and other rare earth oxides, comprising the steps of preparing an aqueous metal salt solution and forming a hydroxide precipitate slurry by combining the aqueous metal salt solution with an aqueous solution of a caustic alkali at a pH greater than 8.5 to precipitate out all the metal species. The variation in pH during the precipitation reaction is ±1. The invention also relates to composites formed by this method comprising 20-70 wt % Al2O3, 10-77 wt % ZrO2, 0-34 wt % CeO2 and 0-22 wt % REOs other than CeO2, and to composites per se comprising, on an oxide basis, 42-70 wt % Al2O3, 10-48 wt % ZrO2, 2-34 wt % CeO2 and 0-9 wt % REOs other than CeO2 and having the following properties after heating to 850° C. over four hours and holding at 850° C.
Abstract: Disclosed herein is a cathode active material for a lithium secondary battery, in particular, including a lithium transition metal oxide with a layered crystalline structure in which the transition metal includes a transition metal mixture of Ni, Mn and Co, and an average oxidation number of all transition metals other than lithium is more than +3, and specific conditions represented by the following formulae (1) and (2), 1.1<m(Ni)/m(Mn)<1.5 and 0.4<m(Ni2+)/m(Mn4+)<1, are satisfied. The inventive cathode active material has a more uniform and stable layered structure by controlling the oxidation number of transition metals contained in a transition metal oxide layer to form the layered structure, compared to conventional substances. Accordingly, the active material exhibits improved overall electrochemical characteristics including battery capacity and, in particular, excellent high rate charge-discharge features.
Type:
Grant
Filed:
September 23, 2009
Date of Patent:
May 3, 2011
Assignee:
LG Chem, Ltd.
Inventors:
Sung Kyun Chang, Hong-Kyu Park, Ho Suk Shin, Seung Tae Hong, Youngsun Choi
Abstract: Provided is a cathode active material having a layered-spinel composite structure lithium metal oxide represented by Formula 1: xLi2MO3-yLiMeO2-zLi1+dM?2?dO4??(1) where x+y+z=1 where 0<x<1, 0<y<1 and 0<z<1; 0?d?0.33; M includes at least one metal selected from the group consisting of Mn, Ti, and Zn; Me includes at least one metal selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Al, Mg, Zr, and B; and M? includes at least one metal selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Al, Mg, Zr, and B. The cathode active material has a layered-spinel composite structure in which lithium can be intercalated and deintercalated so that a lithium battery including the cathode active material shows high initial coulombic efficiency and a high capacity retention ratio.
Abstract: The present invention is directed to pigment compositions with the formula BiwMnxCoyCuzO40, wherein w is between 7 and 9, x is between 3 and 13, y is between 2 and 13, z is between 0.5 and 7 and the sum of w, x, y and z is 26. The invention also is directed to thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).
Type:
Grant
Filed:
May 20, 2010
Date of Patent:
April 26, 2011
Assignee:
E.I. du Pont de Nemours and Company
Inventors:
Jerome David Smith, Pedro A. Jimenez, Tony Jackson, Veda L. Evans
Abstract: Cathode active materials including lithium composite metal oxides having layered-spine composite structures are provided. The lithium metal oxide may be represented by the formula xLi2MO3-yLiMeO2-zLi1+dM?2?dO4, in which 0?d?0.33, 0<x<1, 0<y<1, 0<z<1 and x+y+z=1. In the formula M is selected from Mn, Ti, Zn, and combinations thereof. Me is selected from Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Al, Mg, Zr, B and combinations thereof. M? is selected from Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Al, Mg, Zr, B, and combinations thereof. The cathode active materials have layered-spinel composite structures in which lithium can be intercalated and deintercalated. Lithium batteries including the cathode active materials show high initial coulombic efficiencies and high capacity retention ratios.
Abstract: Provided herein is a hydrothermal process for the rapid synthesis of inorganic nanomaterials (e.g., nanofibers) containing sodium, bismuth, titanium, and oxygen, as well as new compositions made thereby. The process involves heating an aqueous solution or suspension of suitable salts of aforementioned elements at elevated temperature and pressure under constant stirring in a hermetically sealed vessel for a predetermined amount of time (e.g., less than two hours). The powder thus obtained contains nanofibers of rectangular cross-section, with the smallest fibers typically have a cross section of 16 nm×40 nm. Example fibers made by such processes have an aspect ratio exceeding 200.
Abstract: A process for producing a piezoelectric oxide having a composition (A, B, C) (D, E, F)O3, where each of A, B, C, D, E, and F represents one or more metal elements. The composition is determined so as to satisfy the conditions (1), (2), (3), and (4), 0.98?TF(P)?1.01,??(1) TF(ADO3)>1.0,??(2) TF(BEO3)<1.0, and??(3) TF(BEO3)<TF(CFO3)<TF(ADO3),??(4) where TF(P) is the tolerance factor of the perovskite oxide, and TF(ADO3), TF(BEO3), and TF(CFO3) are respectively the tolerance factors of the compounds ADO3, BEO3, and CFO3.
Abstract: A method of producing porous complex oxides includes the steps of providing a mixture of a) precursor elements suitable to produce the complex oxide; or b) one or more precursor elements suitable to produce particles of the complex oxide and one or more metal oxide particles; and c) a particulate carbon-containing pore-forming material selected to provide pore sizes in the range of approximately 7 nm to 250 nm, and treating the mixture to (i) form the porous complex oxide in which two or more of the precursor elements from (a) above or one or more of the precursor elements and one or more of the metals in the metal oxide particles from (b) above are incorporated into a phase of the complex metal oxide and the complex metal oxide has grain sizes in the range of about 1 nm to 150 nm; and (ii) remove the pore-forming material under conditions such that the porous structure and composition of the complex oxide is substantially preserved. The method may be used to produce non-refractory metal oxides as well.
Type:
Grant
Filed:
July 21, 2006
Date of Patent:
April 5, 2011
Assignee:
Very Small Particle Company Limited
Inventors:
Geoffrey Alan Edwards, Peter Cade Talbot, Jose Antonio Alarco
Abstract: A compound oxide manufacturing method includes: dispersing micelles, in each of which an aqueous phase is formed, in an oil phase; producing primary particles of a precursor of compound oxide in the aqueous phases in the micelles; synthesizing secondary particles by causing the primary particles to aggregate; and causing the secondary particles to aggregate by breaking the dispersion state of the micelles, or by causing the micelles to coalesce. In particular, polarization is produced in each of the micelles with the use of a cation having an ionic radius larger than that of a metal ion at least when the secondary particles are synthesized in the micelles.
Abstract: Potassium titanate is obtained which has a novel configuration, exhibits excellent wear resistance when incorporated in a friction material and shows an excellent reinforcement performance when incorporated in a resin composition. A manufacturing method of the potassium titanate, a friction material using the potassium titanate and a resin composition using the potassium titanate are also obtained. The potassium titanate is represented by K2TinO(2n+1) (n=4.0-11.0) and has the highest X-ray diffraction intensity peak (26) in the range of 11.0°-13.5° with its half width being not less than 0.5°.
Abstract: The present invention provides a process for making a complex metal oxide comprising the formula AxByOz. The process comprises the steps of: (a) reacting in solution at a temperature of between about 75° C. to about 100° C. at least one water-soluble salt of A, at least one water-soluble salt of B and a stoichiometric amount of a carbonate salt or a bicarbonate salt required to form a mole of a carbonate precipitate represented by the formula AxBy(CO3)n, wherein the reacting is conducted in a substantial absence of carbon dioxide to form the carbonate precipitate and wherein the molar amount of carbonate salt or bicarbonate salt is at least three times the stoichiometric amount of carbonate or bicarbonate salt required to form a mole of the carbonate precipitate; and (b) reacting the carbonate precipitate with an oxygen containing fluid under conditions to form the complex metal oxide.
Type:
Grant
Filed:
April 20, 2007
Date of Patent:
March 1, 2011
Assignee:
Air Products and Chemicals, Inc.
Inventors:
Robert Quinn, Diwakar Garg, Frederick Carl Wilhelm, Terry Lee Slager
Abstract: The present invention is generally directed to a novel, economic synthesis of oxide ceramic composites. Methods of the present invention, referred to as carbon combustion synthesis of oxides (CCSO), are a modification of self-propagating high-temperature synthesis (SHS) methods in which the heat needed for the synthesis is generated by combustion of carbon in oxygen rather than that of a pure metal. This enables a more economic production of the ceramic material and minimizes the presence of intermediate metal oxides in the product. The reactant mixture generally comprises at least one oxide precursor (e.g., a metal or non metal oxide, or super oxide, or nitride, or carbonate, or chloride, or oxalate, or halides) as a reactant, but no pure metal. Pure carbon in the form of graphite or soot is added to the reactant mixture to generate the desired heat (upon ignition). The mixture is placed in a reactor and exposed to gaseous oxygen.
Abstract: A method is described for the manufacture of hydrotalcites by using at least one compound of a bivalent metal (Component A) and at least one compound of a trivalent metal (Component B), wherein at least one of these components is not used in the form of a solution, characterized in that a) at least one of the Components A and/or B which is not used in the form of a solution, shortly before or during mixing of the components, and/or b) the mixture containing the Components A and B is subjected to intensive grinding until an average particle size (D50) in the range of approx. 0.1 to 5 ?m is obtained, and optionally, after aging treatment or hydrothermal treatment, the resulting hydrotalcite product is separated, dried, and optionally calcinated.
Type:
Grant
Filed:
April 30, 2007
Date of Patent:
March 1, 2011
Assignee:
Sud-Chemie AG
Inventors:
Max Eisgruber, Jürgen Ladebeck, Jürgen Koy, Hubert Schiessling, Wolfgang Buckl, Herrmann Ebert