Abstract: A non-aqueous redox flow battery includes a catholyte including a compound of formula (I) or a compound of formula (II): Where X1 is a moiety of formula I-A or I-B:

Abstract: An electrochemical cell provided with two half cells. A pressure or density differential is created between the cathode and anode electrodes, each of which is contained in one of the half cells. The pressure or density differential is created by single or multiple sources including compression, vacuum, weight (gravity) of mass, chemical, molecular, or, pressure or density differentials created by thermal gradients.

Abstract: The main object of the present invention is to provide an all solid state battery with capability of inhibiting heat generation of an anode layer. The present invention solves the problem by providing an all solid state battery comprising a cathode layer, an anode layer, and a solid electrolyte layer formed between the cathode layer and the anode layer, wherein at least one of the anode layer and the solid electrolyte layer contains a sulfide solid electrolyte material; the anode layer contains an anode active material that is graphite, and contains an additive; and the additive has an oxide that is at least one kind of MoO3, Sb2O3, and MnCO3, and a coating portion that coats at least a part of the oxide and includes a resin with a hydrocarbon chain as a main chain.

Abstract: A secondary battery includes a cathode, an anode, and non-aqueous electrolytic solution. The non-aqueous electrolytic solution includes a boron compound. The boron compound includes six or more boron (B) atoms, and includes an octavalent boron-hydrogen-containing structure represented by Formula (1), a dodecavalent boron-carbon-containing structure represented by Formula (2), or both.

Abstract: Stable solutions comprising high concentrations of charged coordination complexes, including iron hexacyanides are described, as are methods of preparing and using same in chemical energy storage systems, including flow battery systems. The use of these compositions allows energy storage densities at levels unavailable by other iron hexacyanide systems.

Abstract: The present disclosure relates to a positive electrode for a lithium secondary battery including an electrode current collector, and a positive electrode active material layer coated on at least a part of the electrode current collector, wherein the positive electrode active material layer includes a manganese-based positive electrode active material, and a porosity is from 30% to 35%, to improve high-temperature storage characteristics and high-temperature cycle characteristics.

Abstract: Stable solutions comprising high concentrations of charged coordination complexes, including iron hexacyanides are described, as are methods of preparing and using same in chemical energy storage systems, including flow battery systems. The use of these compositions allows energy storage densities at levels unavailable by other iron hexacyanide systems.

Abstract: Described are organosilicon electrolyte compositions having improved thermostability and electrochemical properties and electrochemical devices that contain the organosilicon electrolyte compositions.

Abstract: The present disclosure relate to a method for preparing a cathode electrolyte for redox flow batteries including the steps of: forming a first cathode electrolyte by reducing vanadium pentoxide (V2O5) in an acidic solution in the presence of a specific reducing compound; forming a second cathode electrolyte by reducing vanadium pentoxide (V2O5) in an acidic solution in the presence of a linear or branched aliphatic alcohol having 2 to 10 carbon atoms; and mixing the first cathode electrolyte and the second cathode electrolyte, and to a redox flow battery including the cathode electrolyte obtained by the preparation method.

Abstract: Provided is a redox flow battery that can suppress generation of a precipitation on a positive electrode. The redox flow battery performs charging and discharging by supplying a positive electrode electrolyte and a negative electrode electrolyte to a battery cell that includes a positive electrode, a negative electrode, and a separating membrane interposed between the two electrodes. The positive electrode electrolyte contains a manganese ion and an additional metal ion, the negative electrode electrolyte contains at least one metal ion selected from a titanium ion, a vanadium ion, a chromium ion, and a zinc ion, and the additional metal ion contained in the positive electrode electrolyte is at least one of an aluminum ion, a cadmium ion, an indium ion, a tin ion, an antimony ion, an iridium ion, a gold ion, a lead ion, a bismuth ion, and a magnesium ion.

Abstract: Methods are presented for synthesizing metal cyanometallate (MCM). A first method provides a first solution of AXM2Y(CN)Z, to which a second solution including M1 is dropwise added. As a result, a precipitate is formed of ANM1PM2Q (CN)R.FH2O, where N is in the range of 1 to 4. A second method for synthesizing MCM provides a first solution of M2C(CN)B, which is dropwise added to a second solution including M1. As a result, a precipitate is formed of M1[M2S(CN)G]1/T.DH2O, where S/T is greater than or equal to 0.8. Low vacancy MCM materials are also presented.

Abstract: The present invention relates to a highly conductive electrolyte comprising an ionic liquid and to a polymer electrolyte membrane using same, and more particularly, to a highly conductive polymer electrolyte membrane impregnated with a heterocyclic diazole-based ionic liquid and to a method for manufacturing same.

Abstract: A nonaqueous electrolytic solution that can provide a high energy density nonaqueous electrolyte secondary battery having a high capacity, excellent storage characteristics, and excellent cycle characteristics and suppressing the decomposition of an electrolytic solution and the deterioration thereof when used in a high-temperature environment includes an electrolyte, a nonaqueous solvent, and a compound represented by general formula (1): wherein R1, R2, and R3 each independently represent a hydrogen atom, a cyano group, or an optionally halogen atom-substituted hydrogen group having 1 to 10 carbon atoms, with the proviso that R1 and R2 do not simultaneously represent hydrogen atoms.

Abstract: Stable solutions comprising high concentrations of charged coordination complexes, including iron hexacyanides are described, as are methods of preparing and using same in chemical energy storage systems, including flow battery systems. The use of these compositions allows energy storage densities at levels unavailable by other iron hexacyanide systems.

Abstract: Provided are a system and method for a non-hazmat shippable portable power device (“NHSPD”). The NHSPD includes at least one cell block providing a plurality of electrically isolated encased electrochemical cells each in a predetermined location, each cell having one positive and one negative terminal in a predetermined location. At least one backplane circuit board is disposed adjacent to each cell block and, for each positive and negative terminal of each cell, the adjacent circuit board provides electrically isolated traces from each cell to at least one grouping area, the grouping area providing a connection point for each trace.

Abstract: A rechargeable battery includes an electrode assembly including a first electrode plate, a second electrode plate, and a separator between the first and second electrode plates, an electrolyte having viscosity of about 1 Pa·s to about 15 Pa·s at a temperature from about 20° C. to about 25° C., a can having an opening on one surface through which the electrode assembly is inserted, the electrode assembly and the electrolyte being accommodated inside the can, and a cap plate that seals the opening of the can. A ratio of the height of the can to a cross-sectional area of the can is from about 12.5% to about 25%.

Abstract: According to one embodiment, there is provided a nonaqueous electrolyte battery. The negative electrode of the battery includes a negative electrode active material which can absorb and release lithium ions at a negative electrode potential of 0.4 V (V.S. Li/Li+) or more. The battery satisfying the following equations (I) and (II): 1?Q2/Q1??(I) 0.5?C/A?0.

Abstract: A method for stabilizing electrodes against dissolution and/or hydrolysis including use of cosolvents in liquid electrolyte batteries for three purposes: the extension of the calendar and cycle life time of electrodes that are partially soluble in liquid electrolytes, the purpose of limiting the rate of electrolysis of water into hydrogen and oxygen as a side reaction during battery operation, and for the purpose of cost reduction.

Abstract: A positive electrode active material layer comprises a coating layer for coating at least part of surfaces of positive electrode active material particles. The coating layer comprises alternate layers of a cationic material layer containing a cationic material having a positive zeta potential and an anionic material layer containing an anionic material having a negative zeta potential under neutral conditions, and a material layer having a zeta potential of opposite sign to that of the positive electrode active material particles is bonded to the surfaces of the positive electrode active material particles. The coating layer is thin and uniform, and has a high strength for bonding to the positive electrode active material particles, so the coating layer suppresses direct contact of the positive electrode active material particles and an electrolytic solution even when a nonaqueous secondary battery is used at a high voltage.

Abstract: A polymer including a first repeating unit represented by Formula 1, a second repeating unit represented by Formula 2, and a third repeating unit: wherein R1 to R3, X, and Rf in Formula 1 and R4 to R6, R, and a in Formula 2 are the same as those defined in the detailed description, and wherein the polymer has a glass transition temperature of about 25° C. or less or a Young's modulus of about 10 megaPascals or greater.

Abstract: Methods of determining concentrations and/or amounts of redox-active elements at each valence state in an electrolyte solution of a redox flow battery are provided. Once determined, the concentrations and/or amounts of the redox-active elements at each valence state can be used to determine side-reactions, make chemical adjustments, periodically monitor battery capacity, adjust performance, or to otherwise determine a baseline concentration of the redox-active ions for any purpose.

Abstract: Methods and compositions for processing biomass using [Co(CN)5]3? are disclosed. The resulting products include monomeric carbohydrate units that can also be converted to basic alcohols, including ethanol, for a variety of uses including transportation fuels and the generation of electricity.

Abstract: The present invention aims to provide an electrolyte solution for forming, for example, a secondary battery having excellent oxidation resistance and high voltage cycle characteristics; an electrochemical device such as a lithium-ion secondary battery that contains the electrolyte solution; and a module that contains the electrochemical device. The present invention provides an electrolyte solution containing a solvent and an electrolyte salt, wherein the solvent contains a fluorine-containing compound (A) represented by formula (1) shown below, and a fluorine-containing compound (B) represented by formula (2) shown below: Rf1OCOOR??(1) wherein Rf1 is a C1-C4 fluorine-containing alkyl group, and R is a C1-C4 non-fluorinated alkyl group, and Rf2OCOORf3??(2) wherein Rf2 and Rf3 are the same or different, and each is a C1-C4 fluorine-containing alkyl group.

Abstract: An aqueous redox flow battery system includes an aqueous catholyte and an aqueous anolyte. The aqueous catholyte may comprise (i) an optionally substituted thiourea or a nitroxyl radical compound and (ii) a catholyte aqueous supporting solution. The aqueous anolyte may comprise (i) metal cations or a viologen compound and (ii) an anolyte aqueous supporting solution. The catholyte aqueous supporting solution and the anolyte aqueous supporting solution independently may comprise (i) a proton source, (ii) a halide source, or (iii) a proton source and a halide source.

Abstract: A Mg battery has a positive-electrode can, a positive-electrode pellet made of a positive-electrode active material or the like, a positive electrode composed of a metallic net supporting body, a negative-electrode cup, a negative electrode made of a negative-electrode active material, and a separator impregnated with an electrolytic solution and disposed between the positive-electrode pellet and the negative-electrode active material. By adopting a structure that copper contacts the positive-electrode active material, the electrochemical device can be given a large discharge capacity.

Abstract: An object of the present invention is to provide a high-capacity, long-life lithium secondary cell suppressing a reduction in capacity particularly with respect to use under a high-temperature environment, and having improved cycle properties. The lithium secondary cell comprises a positive electrode active material layer containing a positive electrode active material, a negative electrode active material layer containing a silicon-based material as a negative electrode active material, and an electrolytic solution in which the positive electrode active material layer and the negative electrode active material layer are immersed, the electrolytic solution contains one or more of specific cyclic acid anhydrides.

Abstract: Disclosed are a method of manufacturing an electrode for secondary batteries that includes surface-treating a current collector so as to have a morphology wherein a surface roughness Ra of 0.001 ?m to 10 ?m is formed over the entire surface thereof to enhance adhesion between an electrode active material and the current collector and an electrode for secondary batteries that is manufactured using the method.

Abstract: A non-aqueous electrolyte secondary battery according to the present invention includes a positive electrode, a negative electrode, and a non-aqueous electrolyte solution. The negative electrode includes a coating derived from lithium bis(oxalate)borate. The coating derived from lithium bis(oxalate)borate includes a coating containing boron element and a coating containing oxalate ion. A ratio of the boron element contained in the coating derived from lithium bis(oxalate)borate to the oxalate ion is equal to or more than 5. Accordingly, it is possible to provide a non-aqueous electrolyte secondary battery capable of reliably obtaining the effect due to the formation of a coating.

Abstract: Stable solutions comprising high concentrations of charged coordination complexes, including iron hexacyanides are described, as are methods of preparing and using same in chemical energy storage systems, including flow battery systems. The use of these compositions allows energy storage densities at levels unavailable by other iron hexacyanide systems.

Abstract: A first method for fabricating an anode for use in sodium-ion and potassium-ion batteries includes mixing a conductive carbon material having a low surface area, a hard carbon material, and a binder material. A carbon-composite material is thus formed and coated on a conductive substrate. A second method for fabricating an anode for use in sodium-ion and potassium-ion batteries mixes a metal-containing material, a hard carbon material, and binder material. A carbon-composite material is thus formed and coated on a conductive substrate. A third method for fabricating an anode for use in sodium-ion and potassium-ion batteries provides a hard carbon material having a pyrolyzed polymer coating that is mixed with a binder material to form a carbon-composite material, which is coated on a conductive substrate. Descriptions of the anodes and batteries formed by the above-described methods are also provided.

Abstract: Provided is an active material used for a sodium ion battery or a lithium ion battery, the active material including: (COONa)3-trioxotriangulene represented by the following Formula (1) or (COOLi)3-trioxotriangulene represented by the following Formula (2). In Formulae (1) and (2), a double line including a solid line and a broken line represents a single bond or a double bond.

Abstract: Provided is an active material for a sodium ion battery including: (t-butyl)3-trioxotriangulene shown below. In Formula (1), a double line including a solid line and a broken line represents a single bond or a double bond.

Abstract: An object of the present invention is to provide a liquid electrolyte for batteries, which has excellent ion conductivity, a method for producing the liquid electrolyte and a battery including the liquid electrolyte. Disclosed is a liquid electrolyte for batteries, comprising a mesoionic compound represented by the following general formula (1): wherein R1 and R2 are each independently an alkyl group having 1 to 3 carbon atoms.

Abstract: The invention relates to the use of nitrogen-containing compounds belonging to the classes of N-alkyl pyridinium halide, N-alkyl-2-alkyl pyridinium halide and 1-alkyl-3-alkyl imidazolium halide, as additives in electrolyte solutions for zinc bromine membraneless flow cells. The invention also provides electrolyte solutions comprising such additives and processes for operating said cells.

Abstract: A polymer including a reaction product of a sulfonated polyarylene ether sulfone and at least one compound selected from a sulfonated compound having a thiol group at a terminal thereof and a sulfonated compound having a hydroxy group at a terminal thereof.

Abstract: A solid-phase electrolyte is provided having a magnesium salt. The salt contains a magnesium cation and a boron cluster anion and can include an ether or other weakly-coordinating molecule in dative interaction with the magnesium cation. A magnesium electrochemical cell is also provided. The magnesium electrochemical cell includes the solid-phase electrolyte, and also includes an anode in ionic communication with the solid-phase electrolyte. The anode, when charged, contains reduced magnesium.

Abstract: Disclosed is an additive for an electrochemical cell wherein the additive includes an N—O bond. The additive is most preferably included in a nonaqueous electrolyte of the cell. Also disclosed are cells and batteries including the additive, and methods of charging the batteries and cells. An electrochemical cell including the additive preferably has an anode that includes lithium and a cathode including an electroactive sulfur-containing material.

Abstract: Disclosed is an anode for secondary batteries, in which an anode mixture including an anode active material and a binder is coated on a current collector, wherein the binder includes a homopolymer having a molecular weight of 1,000,000 to 1,400,000 and the anode active material includes a lithium metal oxide represented by Formula 1 below: LixMyOz??(1) wherein M is Ti, Sn, Cu, Pb, Sb, Zn, Fe, In, Al, or Zr; and x, y, and z are determined according to oxidation number of M.

Abstract: An electrolyte includes an eutectic mixture composed of (a) a hetero cyclic compound having a predetermined chemistry figure, and (b) an ionizable lithium salt. An electrochemical device having the electrolyte. The eutectic mixture included in the electrolyte exhibits inherent characteristics of an eutectic mixture such as excellent thermal stability and excellent chemical stability, thereby improving the problems such as evaporation, ignition and side reaction of an electrolyte caused by the usage of existing organic solvents.

Abstract: A primary lithium battery having an electrode body that is arranged with a sheet-like cathode and a sheet-like anode opposing each other via a separator and sealed inside a jacket body together with a non-aqueous organic electrolyte including the cathode being made by applying or compressively bonding to a surface of a sheet-like current collector cathode material including cathode active material allowing occlusion of lithium ions, and the anode being made by applying anode material including carbon active material allowing occlusion and separation of lithium ions on a one main side face side of a sheet-like current collector having formed holes penetrating from a front to a back, and an anode active material made of a lithium metal or a lithium alloy being affixed to another face side of the current collector.

Abstract: A positive electrode for lithium-ion secondary battery is provided, the positive electrode being able to endure high-temperature and high-voltage driving modes or operations. At least parts of the surface of positive-electrode active-material particles are covered by a polymer coating layer, and an amino group and phosphoric-acid group are included in the polymer coating layer. Since the polymer coating layer includes a phosphoric-acid-based polymer, capacity declines are inhibited at the time of cycle tests.

Abstract: A transition metal hexacyanoferrate (TMH) cathode battery is provided. The battery has a AxMn[Fe(CN)6]y.zH2O cathode, where the A cations are either alkali or alkaline-earth cations, such as sodium or potassium, where x is in the range of 1 to 2, where y is in the range of 0.5 to 1, and where z is in the range of 0 to 3.5. The AxMn[Fe(CN)6]y.zH2O has a rhombohedral crystal structure with Mn2+/3+ and Fe2+/3+ having the same reduction/oxidation potential. The battery also has an electrolyte, and anode made of an A metal, an A composite, or a material that can host A atoms. The battery has a single plateau charging curve, where a single plateau charging curve is defined as a constant charging voltage slope between 15% and 85% battery charge capacity. Fabrication methods are also provided.

Abstract: A method is provided for fabricating a transition metal hexacyanometallate (TMHCM) electrode with a water-soluble binder. The method initially forms an electrode mix slurry comprising TMHCF and a water-soluble binder. The electrode mix slurry is applied to a current collector, and then dehydrated to form an electrode. The electrode mix slurry may additionally comprise a carbon additive such as carbon black, carbon fiber, carbon nanotubes, graphite, or graphene. The electrode is typically formed with TMHCM greater than 50%, by weight, as compared to a combined weight of the TMHCM, carbon additive, and binder. Also provided are a TMHCM electrode made with a water-soluble binder and a battery having a TMHCM cathode that is made with a water-soluble binder.

Abstract: An anode usable in a cell of a lithium-ion battery comprising an electrolyte based on a lithium salt and a non-aqueous solvent, to a process for manufacturing this anode and to a lithium-ion battery having one or more cells incorporating this anode. This anode is based on a polymer composition, obtained by melt processing and without solvent evaporation, that is the product of a hot compounding reaction between an active material and additives having a polymer binder and an electrically conductive filler. The binder is based on at least one crosslinked elastomer and the additives furthermore include at least one non-volatile organic compound usable in the electrolyte solvent, the composition advantageously includes the active material in a mass fraction greater than or equal to 85%.

Abstract: Disclosed are a method of manufacturing an electrode for secondary batteries that includes surface-treating a current collector so as to have a morphology wherein a surface roughness Ra of 0.001 ?m to 10 ?m is formed over the entire surface thereof to enhance adhesion between an electrode active material and the current collector and an electrode for secondary batteries that is manufactured using the method.

Abstract: Aqueous Li/Air secondary battery cells are configurable to achieve high energy density and prolonged cycle life. The cells include a protected a lithium metal or alloy anode and an aqueous catholyte in a cathode compartment. The aqueous catholyte comprises an evaporative-loss resistant and/or polyprotic active compound or active agent that partakes in the discharge reaction and effectuates cathode capacity for discharge in the acidic region. This leads to improved performance including one or more of increased specific energy, improved stability on open circuit, and prolonged cycle life, as well as various methods, including a method of operating an aqueous Li/Air cell to simultaneously achieve improved energy density and prolonged cycle life.

Abstract: The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it. The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. R1(O)n—X1—R2??(I) (In the formula, X1 represents a group —C(?O)—, a group —C(?O)—C(?O)—, a group —S(?O)2—, a group —P(?O) (—R3)—, or a group —X3—S(?O)2O—.

Abstract: An organic electrolyte solution and a lithium battery using the same are disclosed. The organic electrolyte solution includes a lithium salt, an organic solution, a thiophene-based compound and a nitrile-based compound.

Abstract: A cathode for a lithium-sulfur battery cell includes positive active material comprising sulfur and carbon coated onto an electrode substrate and gold nanoparticles affixed to the positive active material and configured to direct growth and deposition of lithium sulfide. A lithium ion battery cell, battery stack and method of making the cathodes are also provided.

Abstract: An electrolyte for a lithium battery, the electrolyte including a compound represented by Formula 1; a nonaqueous organic solvent; and a lithium salt. wherein, in Formula 1, X, Ya, Z, R1, and R2 are as defined.