Abstract: A method of manufacturing a secondary battery including an electrode body having a positive electrode plate (40) having a positive electrode tab (4c), a negative electrode plate (5) having a negative electrode tab (5c), and a separator, in which the positive electrode tab (4c) is connected to a positive electrode collector in a curved state and the negative electrode tab (5c) is connected to a negative electrode collector in a curved state, and in which, as the positive electrode plate (4), one provided with a cutaway (4e) at a base of the positive electrode tab (4c) in a region where a positive electrode active material mixture layer (4a) is formed on a positive electrode core body is used.
Abstract: A negative electrode for an electric device includes a silicon-containing alloy containing silicon and tin, a carbon cover layer including a carbon material and covering the silicon-containing alloy, and a negative electrode electric conducting additive. A ratio of an average particle diameter of the silicon-containing alloy to an average particle diameter of the carbon material is 240 or greater. The negative electrode for an electric device and an electric device using the negative electrode can improve cycle durability.
Abstract: A negative electrode material for a lithium ion secondary battery includes a silicon oxide and having a diffraction peak attributable to Si (111) in an X-ray diffraction spectrum, in which a size of a silicon crystallite calculated from the diffraction peak is from 2.0 nm to 8.0 nm.
Abstract: There is produced a Li-containing silicon oxide powder containing a crystallized lithium silicate that is mostly water-insoluble Li2Si2O5 and containing little crystalline Si. This object is attained through the mixing of a lower silicon oxide powder represented by a compositional formula SiOx (0.5<x<1.5) with a powdered lithium source that involves grinding of the powdered lithium source; controlling a median diameter D1 of the lower silicon oxide powder and a median diameter D2 of the powdered lithium source so as to fulfill 0.05?D2/D1?2; and calcining the mixed powder at 300° C. or higher and 800° C. or lower.
Abstract: Provided is a method for manufacturing an active material composite powder by which an active material composite powder that can inhibit increase in its reaction resistance at a high voltage state can be manufactured. The method includes: spraying a solution containing lithium and a peroxo complex of niobium to an active material, and at the same time drying the solution; carrying out a heating treatment, after the spraying and drying, for obtaining a powder including the active material and a coating layer attached to a surface of the active material; producing a mixed liquid by mixing the powder and a solvent that can dissolve lithium nitrate and does not dissolve lithium niobate included in the coating layer obtained by the heat treatment, and stirring the mixed liquid; and carrying out, after the mixing and stirring, a solid-liquid separation on the mixed liquid; and drying a solid obtained by the separation.
Abstract: Electrodes, production methods and mono-cell batteries are provided, which comprise active material particles embedded in electrically conductive metallic porous structure, dry-etched anode structures and battery structures with thick anodes and cathodes that have spatially uniform resistance. The metallic porous structure provides electric conductivity, a large volume that supports good ionic conductivity, that in turn reduces directional elongation of the particles during operation, and may enable reduction or removal of binders, conductive additives and/or current collectors to yield electrodes with higher structural stability, lower resistance, possibly higher energy density and longer cycling lifetime. Dry etching treatments may be used to reduce oxidized surfaces of the active material particles, thereby simplifying production methods and enhancing porosity and ionic conductivity of the electrodes.
Abstract: Improvements in the structural components and physical characteristics of lithium battery articles are provided. Standard lithium ion batteries, for example, are prone to certain phenomena related to short circuiting and have experienced high temperature occurrences and ultimate firing as a result. Structural concerns with battery components have been found to contribute to such problems. Improvements provided herein include the utilization of thin metallized current collectors (aluminum and/or copper, as examples), high shrinkage rate materials, materials that become nonconductive upon exposure to high temperatures, and combinations thereof. Such improvements accord the ability to withstand certain imperfections (dendrites, unexpected electrical surges, etc.) within the target lithium battery through provision of ostensibly an internal fuse within the subject lithium batteries themselves that prevents undesirable high temperature results from short circuits.
Abstract: A negative electrode active material for the lithium ion secondary battery contains silicon oxide that is obtained by heat-treating, under an inert gas atmosphere, a hydrogen silsesquioxane polymer (HPSQ) obtained by allowing hydrolysis of a silicon compound represented by formula (1) and then a condensation reaction of the resulting material, contains Si, O and H, and has, in an infrared spectrum, a ratio (I1/I2) in the range of 0.01 to 0.35 with regard to intensity (I1) of peak 1 at 820 to 920 cm?1 due to a Si—H bond to intensity (I2) of peak 2 at 1000 to 1200 cm?1 due to a Si—O—Si bond, and is represented by general formula SiOxHy (1<x<1.8, 0.01<y<0.4): HSi(R)3 (1), in which R is groups selected from hydrogen, alkoxy having 1 to 10 carbons and the like.
Abstract: An anode structure for rechargeable lithium-ion batteries that have a high-capacity are provided. The anode structure, which is made utilizing an anodic etching process, is of unitary construction and includes a non-porous region and a porous region including a top porous layer (Porous Region 1) having a first thickness and a first porosity, and a bottom porous layer (Porous Region 2) located beneath the top porous layer and forming an interface with the non-porous region. At least an upper portion of the non-porous region and the entirety of the porous region are composed of silicon, and the bottom porous layer has a second thickness that is greater than the first thickness, and a second porosity that is greater than the first porosity.
Type:
Grant
Filed:
July 3, 2018
Date of Patent:
November 10, 2020
Assignee:
International Business Machines Corporation
Inventors:
Joel P. de Souza, John Collins, Devendra K. Sadana, John A. Ott, Marinus J. P. Hopstaken, Stephen W. Bedell
Abstract: A main object of the present disclosure is to provide a method for producing an all solid state battery capable of satisfying both of improving capacity durability and suppressing the increase of an initial resistance. The above object is achieved by providing a method for producing an all solid state battery, the method comprising: a preparing step of preparing an all solid state battery including a cathode layer, a solid electrolyte layer, and an anode layer, in this order; and an initial charging step of initially charging the all solid state battery, wherein the anode layer includes a metal particle capable of being alloyed with Li, and having two kinds or more of crystal orientation in one particle, as an anode active material, and in the initial charging step, the all solid state battery is charged to a battery voltage of 4.35 V or more and 4.55 V or less.
Abstract: There is provided an electrode for a rechargeable lithium battery including a current collector, and an active material layer on the current collector, the active material layer including a plurality of active material patterns having a band shape and a plurality of carbon layers between the neighboring active material patterns, wherein neighboring ones of the carbon layers have a gap of greater than about 1 mm and less than about 10 mm.
Abstract: Systems and methods which provide nickel-zinc textile batteries formed from highly conductive yarn-based components which are configured to facilitate textile material processing, such as weaving, knitting, etc., are described. Embodiments of a conductive yarn-based nickel-zinc textile battery may be constructed using scalably produced highly conductive yarns, such as stainless steel yarns, coated or covered with zinc (anodes) and nickel (cathode) materials, wherein the foregoing yarn anode and cathode components may be coated with an electrolyte to form yarn-based battery assemblies. A conductive yarn-based nickel-zinc textile battery may be constructed by weaving or knitting such yarn-based battery assemblies into a textile material, such as using industrial weaving or knitting machines, hand weaving or knitting processes, etc.
Abstract: An all solid type three-dimensional (“3D”) battery may include a cathode collector, a cathode structure in contact with the cathode collector, an electrolyte structure in contact with the cathode structure, an anode structure in contact with the electrolyte structure, the anode structure not being in contact with the cathode structure and the cathode collector, and an anode collector in contact with the anode structure, where the electrolyte structure is in contact with the cathode collector around the cathode structure. An entirety of a surface of the cathode structure which is used for a battery operation may be in contact with the cathode collector and the electrolyte structure.
Type:
Grant
Filed:
April 21, 2017
Date of Patent:
October 13, 2020
Assignee:
SAMSUNG ELECTRONICS CO., LTD.
Inventors:
Huisu Jeong, Hwiyeol Park, Kyounghwan Kim, Hojung Yang, Sungjin Lim, Jin S. Heo
Abstract: The present invention relates to a silicon-based anode active material and a method for manufacturing the same. The silicon-based anode active material according to an embodiment of the present invention comprises: particles comprising silicon and oxygen combined with the silicon, and having a carbon-based conductive film coated on the outermost periphery thereof; and boron doped inside the particles, wherein with respect to the total weight of the particles and the doped boron, the boron is included in the amount of 0.01 weight % to 17 weight %, and the oxygen is included in the amount of 16 weight % to 29 weight %.
Type:
Grant
Filed:
December 30, 2015
Date of Patent:
October 6, 2020
Assignee:
Nexeon Ltd.
Inventors:
Young Tai Cho, Yong Gil Choi, Seung Chul Park, Seon Park, Hee Young Seo, Jee Hye Park, Yong Eui Lee, Chul Hwan Kim
Abstract: According to one embodiment, a battery module includes a battery unit. The battery unit includes a nonaqueous lithium ion battery including a nonaqueous electrolyte, and an aqueous lithium ion battery including an electrolytic solution in which an electrolyte is dissolved in an aqueous solvent. In the battery unit, the aqueous lithium ion battery is connected in parallel to the nonaqueous lithium ion battery.
Abstract: A non-aqueous electrolyte secondary battery includes a housing, a stack-type electrode array accommodated in the housing, and an electrolyte solution. The electrolyte solution includes an infiltrated portion infiltrated into the stack-type electrode array and an excess portion other than the infiltrated portion. In a set-up state that the non-aqueous electrolyte secondary battery is arranged such that a direction of stack of the stack-type electrode array is orthogonal to a vertical direction, a lower end of the separator projects below lower ends of the positive electrode and the negative electrode. In the set-up state, within a range of an operating state of charge, a projecting portion of any of the plurality separators is always in contact with the excess portion and the plurality of positive electrodes and the plurality of negative electrodes are not in contact with the excess portion at any time.
Abstract: Disclosed is a copper foil including a copper layer and having a tensile strength of 29 to 65 kgf/mm2, a mean width of roughness profile elements (Rsm) of 18 to 148 ?m and a texture coefficient bias [TCB(220)] of 0.52 or less.
Abstract: Provided are processes for the formation of electrochemically active materials such as lithiated transition metal oxides that solve prior issues with throughput and calcination. The processes include forming precursor materials into agglomerates prior to calcination. The use of the agglomerates improves gas flow into and out of the materials thereby improving calcination results, electrochemical properties of the resulting materials, and allows for use of high temperature kilns not previously suitable for such materials thereby lowering production costs.
Type:
Grant
Filed:
June 6, 2018
Date of Patent:
September 29, 2020
Assignee:
BASF Corporation
Inventors:
William C. Mays, Diana F. Wong, Xue Liu, Benjamin Reichman, Martin Panchula, Gary Yacobian
Abstract: The present application provides a lithium ion battery and a negative electrode thereof. The negative electrode comprises: a negative electrode active material layer and an additive comprising a metal sulfide, wherein the additive is distributed in the negative electrode active material layer, distributed on the surface of the negative electrode active material layer, or both in the negative electrode active material layer and on the surface of the negative electrode active material layer. The negative electrode of the present application may effectively improve the performance of the lithium ion battery, and greatly improve the capacity and cycle performance of the lithium ion battery.
Abstract: The present application provides a lithium cobalt oxide positive electrode material, that is, a doped lithium cobalt oxide material: A general formula of doped lithium cobalt oxide is Li1+zCo1?x?yMaxMbyO2, where 0?x?0.01, 0?y?0.01, and ?0.05?z?0.08; Ma is a doped monovalent element, and is at least one of Al, Ga, Hf, Mg, Sn, Zn, or Zr; and Mb is a doped polyvalent element, and is at least one of Ni, Mn, V, Mo, Nb, Cu, Fe, In, W, or Cr. Through substitutional doping of a monovalent element, mutation of a layered structure caused by lithium deintercalation is minimized. Through interstitial doping of a polyvalent element, oxidation of Co3+ is alleviated and delayed during charging.
Abstract: A battery electrode composition is provided that comprises composite particles. Each composite particle may comprise, for example, active fluoride material and a nanoporous, electrically-conductive scaffolding matrix within which the active fluoride material is disposed. The active fluoride material is provided to store and release ions during battery operation. The storing and releasing of the ions may cause a substantial change in volume of the active material. The scaffolding matrix structurally supports the active material, electrically interconnects the active material, and accommodates the changes in volume of the active material.
Type:
Grant
Filed:
March 4, 2019
Date of Patent:
September 22, 2020
Assignee:
SILA NANOTECHNOLOGIES INC.
Inventors:
Gleb Yushin, Bogdan Zdyrko, Alexander Jacobs, Eugene Berdichevsky
Abstract: A protected lithium electrode structure for a lithium-air battery includes a negative electrode current collector, a negative electrode active material layer, which is made of a lithium metal, an alloy or a compound mainly containing lithium, which is stacked on the negative electrode current collector, and a separator stacked on the negative electrode active material layer. The negative electrode active material layer is sealed by the separator and the negative electrode current collector. A fine powder capturing layer for fine powder lithium metal produced during charging and discharging is provided between the negative electrode active material layer and the separator.
Abstract: A positive electrode active material for a lithium-sulfur battery, and more particularly, to a positive electrode active material for a lithium-sulfur battery including metal sulfide nanoparticles and a preparation method thereof. The metal sulfide nanoparticles with large specific surface area applied to the positive electrode active material for the lithium-sulfur battery according to the present invention acts as a redox mediator during charging and discharging of the lithium-sulfur battery, thereby reducing the shuttle response by not only inhibiting the formation itself of polysulfides with elution properties, but also, even if polysulfides are eluted, adsorbing them and thus preventing them from diffusing into the electrolyte solution, and thus the capacity and life characteristics of the lithium-sulfur battery can be improved.
Abstract: The present invention relates to a method for easily producing nanoparticles by expansion, explosion, vaporization, condensation and cooling of plasma in a liquid by means of heat resistance and, more particularly, to a method for preparing a silicon nanocomposite dispersion having a uniform carbon layer coated on the surface of silicon of which at least one area is connected to a silicon carbide formed by reacting a carbon in liquid (C) during expansion, explosion, vaporization, condensation and cooling, and applied products thereof.
Abstract: A lithium ion secondary battery includes: a negative electrode having a carbon-based negative electrode material containing graphite particles and amorphous carbon particles; and a positive electrode including a lithium composite oxide. The lithium composite oxide is represented by a general formula: LixNiyMnzCo(1-y-z)O2, where x is a numeral of 1 or more and 1.2 or less, and y and z are positive numerals satisfying the relation of y+z<1. The lithium composite oxide has a layer crystal structure and has a median particle diameter (D50) of 4.0 ?m or more and less than 6.0 ?m.
Abstract: A power storage module includes a cylindrical resin portion that extends in a direction in which a plurality of bipolar electrodes is stacked and that accommodates therein the plurality of the bipolar electrodes. The resin portion includes a first seal portion that has a cylindrical shape and is joined to peripheral edge portions of a plurality of electrode plate, and a second seal portion that has a cylindrical shape and is disposed outside the first seal portion in a direction that crosses the stacking direction of the bipolar electrodes. A plurality of separators is disposed such that outer peripheral ends of the separators are located between an outer peripheral end of the first seal portion and an inner peripheral end of the first seal portion.
Abstract: Provided are excellent coated lithium-nickel composite oxide particles which are capable of suppressing the occurrence of impurities produced by absorbing water and carbonic acid gas as a result of the high environmental stability thereof, have strong adhesion properties, do not result in easy coating layer detachment, and also exhibit lithium ion conductivity. The surfaces of the lithium-nickel composite oxide particles are coated with a polymer or copolymer comprising one or more types selected from a group consisting of a modified polyolefin resin, a polyester resin, a polyphenol resin, a polyurethane resin, an epoxy resin, a silane-modified polyether resin, a silane-modified polyester resin, a silane-modified polyphenol resin, a silane-modified polyurethane resin, a silane-modified epoxy resin, and a silane-modified polyamide resin.
Abstract: A battery electrode composition is provided that comprises composite particles. Each composite particle may comprise, for example, active lithium fluoride/metal nanocomposite material optionally embedded into a nanoporous, electrically-conductive skeleton matrix material particle(s), where each of these composite particles is further encased in a Li-ion permeable, chemically and mechanically robust, protective outer shell that is impermeable to electrolyte solvent molecules. The active lithium fluoride/metal nanocomposite material is provided to store and release Li ions during battery operation.
Type:
Grant
Filed:
July 13, 2016
Date of Patent:
August 11, 2020
Assignee:
SILA NANOTECHNOLOGIES INC.
Inventors:
Gleb Yushin, Eugene Berdichevsky, Bogdan Zdyrko, Alexander Jacobs, Daniel Gordon, Nicholas Ingle, Laura Gerber
Abstract: Provided is a positive electrode material for a nonaqueous electrolyte secondary battery that excels in thermal stability. A positive electrode material for a nonaqueous electrolyte secondary battery, which is provided by the present invention, includes positive electrode active material particles that can reversibly store and release a charge carrier, and a metal hydroxide. Each of the positive electrode active material particles has inside thereof a void and the metal hydroxide is disposed inside the void.
Abstract: Solid-state laminate electrode assemblies and various methods for making the solid-state laminate electrode assemblies involve a lithium metal layer reactively bonded to a lithium ion conducting sulfide glass layer. During manufacture, highly reactive surfaces of the lithium metal layer and the lithium ion conducting sulfide glass layer are maintained in its substantially unpassivated state until they have been reactively bonded.
Type:
Grant
Filed:
May 10, 2017
Date of Patent:
July 7, 2020
Assignee:
POLYPLUS BATTERY COMPANY
Inventors:
Steven J. Visco, Vitaliy Nimon, Ian Wogan, Yevgeniy S. Nimon, Lutgard C. De Jonghe, Bruce D. Katz
Abstract: Provided herein are nanostructures for lithium ion battery electrodes and methods of fabrication. In some embodiments, a nanostructure template coated with a silicon coating is provided. The silicon coating may include a non-conformal, more porous layer and a conformal, denser layer on the non-conformal, more porous layer. In some embodiments, two different deposition processes, e.g., a PECVD layer to deposit the non-conformal layer and a thermal CVD process to deposit the conformal layer, are used. Anodes including the nanostructures have longer cycle lifetimes than anodes made using either a PECVD or thermal CVD method alone.
Type:
Grant
Filed:
February 2, 2018
Date of Patent:
July 7, 2020
Assignee:
Amprius, Inc.
Inventors:
Weijie Wang, Zuqin Liu, Song Han, Jonathan Bornstein, Constantin Ionel Stefan
Abstract: Provided is an anode active material for a secondary battery and a method of fabricating the anode active material. A silicon-based active material composite according to an embodiment of the inventive concept includes silicon and silicon oxide obtained by oxidizing at least a part of the silicon, and an amount of oxygen with respect to a total weight of the silicon and the silicon oxide is restricted to 9 wt % to 20 wt %.
Type:
Grant
Filed:
July 2, 2019
Date of Patent:
June 23, 2020
Inventors:
Young Tai Cho, Seung Chul Park, Seon Park, Jee Hye Park, Yong Eui Lee, Chul Hwan Kim, Hee Young Seo
Abstract: To address the need for multi-functional binders specifically tailored for sulfur cathodes ?-stacked perylene bisimide (PBI) molecules are repurposed as redox-active supramolecular binders in sulfur cathodes for Li—S cells. In operando lithiation of PBI binders permanently reduces Li—S cell impedance enabling high-rate cycling, a critical step toward unlocking the full potential of Li—S batteries.
Type:
Grant
Filed:
March 23, 2017
Date of Patent:
June 16, 2020
Assignee:
The Regents of the University of California
Inventors:
Brett A. Helms, Peter D. Frischmann, Yoon Hwa, Elton J. Cairns
Abstract: A method for producing a positive electrode containing a positive electrode active material and/or a negative electrode containing a negative electrode active material. The method includes a process for producing an electrode slurry including: a first process in which a positive or negative electrode active material, a conductive additive, and a nonaqueous solvent are mixed to obtain a slurry; and a second process in which the slurry is diluted or concentrated and then mixed to obtain the electrode slurry. In the first process, the mixing is performed such that the obtained slurry has a water content of 1000 ppm or less and a viscosity of 500 cP or more and 8000 cP or less, and, in the second process, the mixing is performed such that a water content of the obtained electrode slurry is maintained at the water content of the slurry after the first process is completed.
Abstract: Rechargeable, high-density electrochemical devices are disclosed. These electrochemical devices may, for example, include high energy densities that store more energy in a given, limited volume than other batteries and still show acceptable power or current rate capability without any liquid or gel-type battery components. Certain embodiments may involve, for example, low volume or mass of all of the battery components other than the cathode, while simultaneously achieving high electrochemically active mass inside the positive cathode.
Abstract: 3-D magnesium voltaic cells have a magnesium anode coated on multiple opposing surfaces with a continuous protective/electrolyte layer that is ionically conductive and electronically insulating. The resulting protected 3-D magnesium anode is coated on multiple opposing surfaces with a continuous cathode layer that is electronically and ionically conductive, and includes a magnesium storage medium. Suitable magnesium anodes, in particular, magnesium foam anodes, can be made by pulsed galvanostatic deposition of magnesium on a copper substrate. The protective layer can be formed by electropolymerization of a suitable methylacrylate ester. The continuous cathode layer can be a slurry cathode having powders of an electronic conductor and a reversible magnesium storage component suspended in a magnesium electrolyte solution.
Type:
Grant
Filed:
September 26, 2017
Date of Patent:
June 9, 2020
Assignees:
Toyota Jidosha Kabushiki Kaisha, Toyota Motor Engineering & Manufacturing North America, Inc.
Inventors:
Fuminori Mizuno, Rana Mohtadi, Oscar Tutusaus, Nikhilendra Singh, Timothy S. Arthur, Ruidong Yang, Kensuke Takechi, Chen Ling, Ruigang Zhang
Abstract: The present invention relates to a silicon anode active material capable of high capacity and high output, and a method for fabricating the same. A silicon anode active material according to an embodiment of the present invention includes a silicon core including silicon particles; and a double clamping layer having a silicon carbide layer on the silicon core and a silicon oxide layer between the silicon core and the silicon carbide layer.
Type:
Grant
Filed:
February 24, 2015
Date of Patent:
June 2, 2020
Assignee:
Nexeon Ltd.
Inventors:
Young Tai Cho, Yong Gil Choi, Seon Park, Young Jae Lee, Hee Young Seo, Jee Hye Park, Yong Eui Lee, Young Jin Hong
Abstract: A secondary battery includes a cathode, an anode including an active material, and non-aqueous electrolytic solution. The active material includes a center portion and a covering portion provided on part or all of the center portion. The center portion includes silicon, tin, or both as constituent elements. The covering portion includes a plurality of fibrous carbon materials. Part or all of the fibrous carbon materials extend in a direction along a surface of the center portion and are closely attached to the center portion.
Abstract: The present invention relates to a negative electrode active material including a secondary particle in which primary particles are aggregated, wherein the primary particle includes: a core including one or more of silicon and a silicon compound; and a surface layer which is disposed on a surface of the core and contains carbon, wherein an average particle size D50 of the core is in a range of 0.5 ?m to 20 ?m, a method of preparing the same, an electrode including the same, and a lithium secondary battery including the same.
Type:
Grant
Filed:
June 2, 2017
Date of Patent:
May 19, 2020
Assignee:
LG CHEM, LTD.
Inventors:
Jung Hyun Choi, Yong Ju Lee, Eun Kyung Kim
Abstract: A negative electrode active material including a silicon-containing alloy having a ternary alloy composition expressed by Si—Sn—Ti and including a structure in which an a-Si phase containing amorphous or low-crystalline silicon formed by dissolving tin in a crystal structure of silicon is dispersed in a parent phase of a silicide phase including TiSi2, wherein when a peak intensity of a Si—O bond peak that is observed at a position where an interatomic distance in a radial wave function observed by XAFS is 0.13 nm is S(1) and a peak intensity of a Si—Si bond peak that is observed at a position where the interatomic distance is 0.2 nm is S(2), a relation of S(2)>S(1) is satisfied is used for an electrical device. When used, the negative electrode active material achieves both cycle durability and charging-discharging efficiency for an electrical device such as a lithium ion secondary battery.
Abstract: Provided are uniquely structured electrochemically active particles characterized by a first electrochemically active material and a second electrochemically active material disposed about the first material whereby at least the second material includes a modifier present as a continuous transition concentration gradient from the first material into the second material whereby the concentration is lower in the first material than the second material. Also provided are processes of producing the particle and electrochemical cells incorporating the particles as a positive electrode material in a cathode.
Abstract: An electrode includes a base material, and a catalyst layer provided on the base material, the catalyst layer including a plurality of catalyst units having a porous structure. The catalyst layer has a first catalyst layer provided near the base material, the first catalyst layer including a plurality of the catalyst units dispersed at a first dispersion degree. The catalyst layer has a second catalyst layer provided above the first catalyst layer, the second catalyst layer including a plurality of the catalyst units dispersed at a second dispersion degree. The second dispersion degree is different from the first dispersion degree.
Abstract: The disclosure provides a nonaqueous lithium-type power storage element having a positive electrode, a negative electrode, a separator, and a nonaqueous electrolytic solution containing lithium ions.
Abstract: An electrode for an electrochemical device has a current collector, an electrolyte layer, and an active material layer between the current collector and the electrolyte layer comprising active material. The active material layer has a first sub-layer in contact with the electrolyte layer, the first sub-layer having only an electronically conductive polymer binder as a binder material; a second sub-layer in contact with the current collector, the second sub-layer having only an ionically conductive polymer binder as the binder material; and a mid-layer between the first sub-layer and the second sub-layer.
Abstract: The present invention is a negative electrode material for a non-aqueous electrolyte secondary battery, including negative electrode active material particles composed of a silicon compound (SiOx, where 0.5?x?1.6) containing a lithium compound, the negative electrode active material particles being coated with a coating containing at least two of a substance having two or more hydroxyl groups per molecule, phosphoryl fluoride, lithium carbonate, and a hydrocarbon that exhibits a positive ion spectrum CyH2 (1?y?3 and 2?z?5) when subjected to TOF-SIMS. There can be provided a negative electrode material for a non-aqueous electrolyte secondary battery, a non-aqueous electrolyte secondary battery including a negative electrode using this negative electrode material, and a method of producing negative electrode active material particles that can increase the battery capacity and improve the cycle performance and initial charge and discharge performance.
Abstract: The invention relates to silicon/graphite/carbon composites (Si/G/C-composites), containing graphite (G) and non-aggregated, nanoscale silicon particles (Si), wherein the silicon particles are embedded in a carbon matrix (C). The invention also relates to a method for producing said type of composite, electrode material for lithium ion batteries containing said type of composite and to a lithium ion battery.
Type:
Grant
Filed:
January 23, 2015
Date of Patent:
April 21, 2020
Assignee:
WACKER CHEMIE AG
Inventors:
Dennis Troegel, Peter Gigler, Eckhard Hanelt, Stefan Haufe
Abstract: A negative electrode material applied to a lithium battery or a sodium battery is provided. The negative electrode material is composed of a first chemical element, a second chemical element and a third chemical element with an atomic ratio of x, 1?x, and 2, wherein 0<x<1, the first chemical element is selected from the group consisting of molybdenum (Mo), chromium (Cr), tungsten (W), manganese (Mn), technetium (Tc) and rhenium (Re), the second chemical element is selected from the group consisting of Mo, Cr and W, the third chemical element is selected from the group consisting of sulfur (S), selenium (Se) and tellurium (Te), and the first chemical element is different from the second chemical element.
Abstract: The volume density or weight density of lithium ions that can be received and released in and from a positive electrode active material is increased to achieve high capacity and high energy density of a secondary battery. In a lithium manganese composite oxide, each particle includes a first region including a crystal with a layered rock-salt crystal structure and a second region including a crystal with a spinel crystal structure. The second region is in contact with the outside of the first region. The lithium manganese composite oxide has high structural stability and high capacity.
Type:
Grant
Filed:
December 28, 2017
Date of Patent:
March 31, 2020
Assignee:
Semiconductor Energy Laboratory Co., Ltd.
Inventors:
Takahiro Kawakami, Tatsuya Ikenuma, Satoshi Seo
Abstract: An electrochemically active material includes, prior to incorporation in an electrochemical full cell, reversible lithium corresponding to between 4% and 50% of the reversible capacity of the electrochemically active material. The electrochemically active material has a lithium consumption rate between 0.05% and 0.2%.
Abstract: Provided is a composite electrode material. The composite electrode material is disposed on a surface of an electrode. The composite electrode material includes a plurality of conductive material layers and a plurality of active material layers. The conductive material layers and the active material layers are alternately stacked along a direction non-parallel to the surface of the electrode, and are arranged disorderly along a direction parallel to the surface of the electrode.