Radiation Sensitive Composition Comprising Ethylenically Unsaturated Compound Patents (Class 430/281.1)
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Patent number: 8329382Abstract: Imageable elements can be imaged and then processed using a solution containing core-shell particles that are designed to complex with non-coalesced particles in the non-exposed regions of imaged element. A separate development step is not needed, but the non-coalesced particles and complexed core-shell particles can be removed from the resulting printing plate before using the resulting lithographic printing plate for printing.Type: GrantFiled: September 2, 2009Date of Patent: December 11, 2012Assignee: Eastman Kodak CompanyInventors: Mathias Jarek, Domenico Balbinot
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Patent number: 8329773Abstract: The invention relates to holographic media containing specific photopolymers, a process for the production thereof, and unsaturated glycidyl ether acrylate urethanes as writing monomers which are suitable for the preparation of photopolymers.Type: GrantFiled: February 16, 2010Date of Patent: December 11, 2012Assignee: Bayer MaterialScience AGInventors: Thomas Fäcke, Friedrich-Karl Bruder, Marc-Stephan Weiser, Thomas Rölle, Dennis Hönel
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Publication number: 20120306961Abstract: A photosensitive resin composition includes a cationically polymerizable compound, a photoacid generating agent having an anion portion and a cation portion, and a salt having a cation portion having either one of a quaternary ammonium structure and a quaternary phosphonium structure and an anion portion, wherein the anion portion of the salt is exchanged with the anion portion of a first acid derived from the anion portion of the photoacid generating agent to form a second acid having acid strength that is lower than acid strength of the first acid.Type: ApplicationFiled: January 27, 2011Publication date: December 6, 2012Applicant: CANON KABUSHIKI KAISHAInventors: Hyo Takahashi, Ken Ikegame, Masako Shimomura
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Publication number: 20120307363Abstract: A method of forming a polarizing material is provided including exposing a layer of dichroic material to activating light illumination to provide an ordered structure with a distinguished absorption axis and thus photo-induce polarization, and fixing the induced polarization by polymerization of the dichroic layer. Novel polarizing materials formed thereby are also provided. By selectively exposing regions of the dichroic material to differing activating radiation, different regions with different polarization axes can be created. The polarizing material can also be provided with a coating or coatings to alter the spectral responses, and a stack formed of a plurality if dichroic layers can be provided.Type: ApplicationFiled: September 28, 2010Publication date: December 6, 2012Applicant: The Hong Kong University of Science and TechnologyInventors: Vladimir Markovich Kozenkov, Wing Chiu Yip, Vladimir Grigorievich Chigrinov, Elena Karlovna Prudnikova, Hoi Sing Kwok
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Patent number: 8323854Abstract: Dynamic range enhancing dopants for photopolymeric media are described. Also described are optical articles using these dopants and methods for making such optical articles.Type: GrantFiled: April 23, 2010Date of Patent: December 4, 2012Assignee: Akonia Holographics, LLCInventor: Fredric R. Askham
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Patent number: 8323536Abstract: A near-infrared absorbing dye has an anion of formula (1) wherein A1 is H or CF3, R0 is OH or —OC(?O)—R?, and R? is a monovalent hydrocarbon group. The dye has excellent solvent solubility as well as good optical properties and heat resistance, offering the advantages of easy coating and effective working during film formation. The dye free of heavy metal in its structure is advantageously used in the process of fabricating semiconductor devices.Type: GrantFiled: May 16, 2011Date of Patent: December 4, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masaki Ohashi, Takeshi Kinsho, Kazumi Noda, Seiichiro Tachibana
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Patent number: 8323873Abstract: A photosensitive adhesive composition comprising: (A) a polyimide having a carboxyl group as a side chain, whereof the acid value is 80 to 180 mg/KOH; (B) a photo-polymerizable compound; and (C) a photopolymerization initiator.Type: GrantFiled: December 13, 2010Date of Patent: December 4, 2012Assignee: Hitachi Chemical Company, Ltd.Inventors: Takashi Kawamori, Takashi Masuko, Shigeki Katogi, Masaaki Yasuda
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Publication number: 20120301829Abstract: A resist composition comprising a base component (A) which exhibits changed solubility in a developing solution under action of acid and an acid-generator component (B) which generates acid upon exposure, the acid-generator component (B) comprising an acid generator (B1) composed of a compound represented by general formula (b1-1) shown below [wherein, X represents a cyclic group of 3 to 30 carbon atoms which may have a substituent, provided that a ring skelton of the cyclic group contains an —SO2— bond or an —O—SO2— bond, and at least one carbon atom which is not adjacent to the —SO2— bond or the —O—SO2— bond has an oxygen atom as a substituent; Q1 represents a divalent linking group or a single bond; Y1 represents an alkylene group which may have a substituent or a fluorinated alkylene group which may have a substituent; and A+ represents an organic cation].Type: ApplicationFiled: May 23, 2012Publication date: November 29, 2012Applicant: TOKYO OHKA KOGYO CO., LTD.Inventors: Akiya Kawaue, Yoshiyuki Utsumi
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Patent number: 8318053Abstract: Disclosed is a photosensitive resin composition including (A) a photopolymerizable monomer including a compound represented by the following Chemical Formula 1, wherein the substituents of Chemical Formula 1 are the same as defined in the specification, (B) a binder resin, (C) a photopolymerization initiator, (D) a pigment and (E) a solvent, and a color filter using the same.Type: GrantFiled: August 25, 2011Date of Patent: November 27, 2012Assignee: Cheil Industries Inc.Inventors: Jung-Sik Choi, Chang-Min Lee, Jin-Woo Park, Kyung-Won Ahn, Myung-Ho Cho
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Publication number: 20120292412Abstract: A photosensitive resin composition includes (a) a compound polymerizable in the presence of an acid, and (b) a photoacid generating agent including an onium salt having a cationic part structure represented by formula (b1) below and an anionic part structure represented by formula (b2) below, wherein the component (b) absorbs 50% or more of the amount of 365 nm wavelength light absorbed by the photosensitive resin composition,Type: ApplicationFiled: February 1, 2011Publication date: November 22, 2012Applicant: CANON KABUSHIKI KAISHAInventors: Hyo Takahashi, Ken Ikegame, Masako Shimomura
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Publication number: 20120296053Abstract: A photosensitive composition capable of forming a cured film having small internal stress; a cured film formed from the composition; and an electronic part including the cured film. The photosensitive composition includes: an alkali soluble resin (A), which includes at least 80% by mass of a novolak resin; a photosensitive compound (B); and a crosslinking agent (C), which includes at least a compound represented by the following formula (C1): wherein R1 is an alkyl group having 1 to 6 carbon atoms or the like; R2 is hydroxyl group or the like; R3 is a (a+1)valent hydrocarbon group or the like; R5 is a (c+1)valent hydrocarbon group or the like; R4 is a single bond or the like; a and c are each independently integers of 1 to 3, wherein the sum a+c is an integer of 3 to 6; and b is an integer of 0 or more.Type: ApplicationFiled: April 18, 2012Publication date: November 22, 2012Applicant: JSR CORPORATIONInventors: Masaaki HANAMURA, Futoshi YAMATO, Akito HIRO, Akari SAKO, Jun MUKAWA
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Publication number: 20120295201Abstract: A compound represented by formula (I): wherein T1 represents a single bond or a C6-C14 aromatic hydrocarbon group, L1 represents a C1-C17 divalent saturated hydrocarbon group in which a methylene group may be replaced by an oxygen atom or a carbonyl group, L2 and L3 each independently represent a single bond or a C1-C6 divalent saturated hydrocarbon group in which a methylene group may be replaced by an oxygen atom or a carbonyl group, ring W1 and ring W2 each independently represent a C3-C36 hydrocarbon ring, R1 and R2 each independently represent a hydrogen atom, a hydroxyl group, or C1-C6 alkyl group, R3 and R4 each independently represent a hydroxyl group, or C1-C6 alkyl group, R5 represents a hydroxyl group or a methyl group, m represents 0 or 1, and t and u each independently represent an integer of 0 to 2.Type: ApplicationFiled: May 18, 2012Publication date: November 22, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Koji ICHIKAWA, Isao YOSHIDA
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Patent number: 8313888Abstract: The present invention provides a photosensitive flexographic printing original plate provided with a heat sensitive mask layer having high light blocking effect and durability yet prepared as a thin film. A photosensitive flexographic printing original plate including at least (A) a supporting member, (B) a photosensitive resin layer, (C) a protective layer and (D) a heat sensitive mask layer that are successively laminated, wherein the heat sensitive mask layer (D) contains carbon black and, as a dispersion binder therefor, a butyral resin as well as polyamide containing polar group selected from the group consisting of polyamide containing a tertiary amine group, polyamide containing a quaternary ammonium salt group, polyamide containing an ether group and polyamide containing a sulfonic group.Type: GrantFiled: December 5, 2008Date of Patent: November 20, 2012Assignee: Toyo Boseki Kabushiki KaishaInventors: Kazuya Yoshimoto, Tetsuma Kawakami, Yasuyuki Munekuni, Keiichi Motoi, Yukimi Yawata, Toru Wada
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Patent number: 8313885Abstract: A heat-sensitive lithographic printing plate precursor comprising on a grained and anodized aluminum support a compound which is capable of converting form a hydrophobic state to a hydrophilic state or vice versa upon exposure to heat, and is represented by the following formula: A-(L)n-B wherein L represents a linking group, n represents 0 or 1 and B represents a thermo-labile group; characterized in that the compound further comprises the group A which is a functional group capable of interacting with the surface of a grained and anodized aluminum support and is selected from the list consisting of a halosilanyl group, an alkoxysilanyl group, a phosphonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a salicylic acid group or a salt thereof, a boronic acid group or an ester or a salt thereof, an optionally substituted di or tri-hydroxyaryl group, an optionally substituted salicaldoxime group, an optionally substituted salicaldimine group, an optionally substituted hydroxyheteroaType: GrantFiled: October 12, 2006Date of Patent: November 20, 2012Assignee: AGFA Graphics NVInventors: Johan Loccufier, Hieronymus Andriessen
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Publication number: 20120287524Abstract: Disclosed are a novel compound, a pigment dispersion composition including the same, a photosensitive resin composition including the same, and a color filter using the same.Type: ApplicationFiled: June 22, 2010Publication date: November 15, 2012Applicant: CHEIL INDUSTRIES INC.Inventors: Seong-Yong Uhm, Seong-Ryong Nam, Taek-Jin Baek, Tae-Gyu Chun, Kyung-Hee Hyung
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Publication number: 20120288796Abstract: A resist composition is provided comprising a polymer comprising recurring units having a hydroxyl group substituted with an acid labile group, an onium salt PAG capable of generating a sulfonic acid, imide acid or methide acid, and an onium salt PAG capable of generating a carboxylic acid. A resist film of the composition is improved in dissolution contrast during organic solvent development, and from which a hole pattern having minimized nano-edge roughness can be formed via positive/negative reversal.Type: ApplicationFiled: May 11, 2012Publication date: November 15, 2012Inventors: Kazuhiro KATAYAMA, Jun Hatakeyama, Youichi Ohsawa, Koji Hasegawa, Tomohiro Kobayashi
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Publication number: 20120287393Abstract: A positive photosensitive resin composition and a method for forming patterns by using the same are disclosed. The photosensitive resin composition comprises a novolac resin (A), an ortho-naphthoquinone diazide sulfonic acid ester (B), a dye (C) and a solvent (D). The novolac resin (A) includes a high-ortho novolac resin (A-1) that has ortho-ortho methylene bonding to all methylene bonding in a ratio of 18% to 25%, thereby exhibiting excellent temporal stability and forming patterns with high resolution.Type: ApplicationFiled: April 26, 2012Publication date: November 15, 2012Applicant: CHI MEI COOPERATIONInventors: Chi-Ming LIU, Chun-An SHIH
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Publication number: 20120288798Abstract: A positive photosensitive resin composition including: (a) a resin capable of being dissolved in an aqueous alkaline solution; (b) a compound having two or more oxetanyl groups; (c) a diazonaphthoquinone compound; and (d) a solvent.Type: ApplicationFiled: January 18, 2011Publication date: November 15, 2012Applicant: HITACHI CHEMICAL DUPONT MICROSYSTEMS, LTD.Inventors: Masashi Kotani, Masayuki Ooe, Taku Konno, Tomonori Minegishi, Keishi Ono
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Patent number: 8309294Abstract: A lithographic printing plate precursor includes: an aluminum support; an intermediate layer; and an image-recording layer, in this order, wherein at least one of the intermediate layer and the image-recording layer contains a compound having an amino group and a functional group capable of interacting with the aluminum support in a molecule.Type: GrantFiled: June 23, 2008Date of Patent: November 13, 2012Assignee: Fujifilm CorporationInventors: Shota Suzuki, Yu Iwai, Junji Kawaguchi
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Publication number: 20120282546Abstract: Disclosed are: a cyclic compound which has high solubility in a safe solvent, is highly sensitive, enables the formation of a resist pattern having a good shape, and rarely causes resist pattern collapse; a process for producing the cyclic compound; a radiation-sensitive composition containing the cyclic compound; and a resist pattern formation method using the composition. Specifically disclosed are: a cyclic compound having a specific structure; a process for producing the cyclic compound; a radiation-sensitive composition containing the compound; and a resist pattern formation method using the composition.Type: ApplicationFiled: November 25, 2010Publication date: November 8, 2012Inventors: Masaaki Takasuka, Masatoshi Echigo, Yu Okada
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Publication number: 20120282550Abstract: A radiation-sensitive composition includes a polymer composition and a radiation-sensitive acid generator. The polymer composition includes a first polymer and a second polymer. The first polymer includes a repeating unit shown by a following formula (1). The second polymer includes a repeating unit shown by a following formula (2) and does not include a repeating unit shown by the formula (1).Type: ApplicationFiled: June 20, 2012Publication date: November 8, 2012Applicant: JSR CorportionInventors: Yuji YADA, Tooru Kimura, Tomohiro Utaka
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Publication number: 20120282548Abstract: Provided is a pattern forming method comprising (i) a step of forming a film from an actinic ray-sensitive or radiation-sensitive resin composition, (ii) a step of exposing the film, and (iii) a step of developing the exposed film by using an organic solvent-containing developer, wherein the actinic ray-sensitive or radiation-sensitive resin composition comprises (A) a resin capable of decreasing the solubility for an organic solvent-containing developer by the action of an acid, (B) a compound capable of generating an acid upon irradiation with an actinic ray or radiation, (D) a solvent, and (G) a compound having at least either one of a fluorine atom and a silicon atom and having basicity or being capable of increasing the basicity by the action of an acid.Type: ApplicationFiled: January 7, 2011Publication date: November 8, 2012Applicant: FUJIFILM CORPORATIONInventors: Yuichiro Enomoto, Shinji Tarutani, Sou Kamimura, Kaoru Iwato, Keita Kato, Akinori Shibuya
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Patent number: 8304170Abstract: Negative-working imageable elements can be imaged and processed to provide lithographic printing plates, especially with sulfuric acid-anodized aluminum substrates. These elements have an imageable outermost layer that contains two different polymeric binders, a primary polymeric binder is optionally present a discrete particles, and a secondary polymeric binder comprising a poly(vinyl acetate) that has a degree of hydrolysis of less than 60 mol %. These imageable elements can be designed for either off-press or on-press development.Type: GrantFiled: September 4, 2008Date of Patent: November 6, 2012Assignee: Eastman Kodak CompanyInventors: Ting Tao, Eric E. Clark
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Patent number: 8303862Abstract: Disclosed are a photosensitive resin composition for a color filter and a color filter including the same. The photosensitive resin composition for a color filter may include (A) an acrylic-based copolymer including a structural unit represented by the following Chemical Formula 1 and a structural unit represented by the following Chemical Formula 2, wherein the substituents of Chemical Formula 1 and Chemical Formula 2 are the same as defined in the specification; (B) an acrylic-based photopolymerizable monomer; (C) a photopolymerization initiator; (D) a pigment; and (E) a solvent.Type: GrantFiled: September 21, 2011Date of Patent: November 6, 2012Assignee: Cheil Industries Inc.Inventors: Chang-Min Lee, Kil-Sung Lee, Jae-Hyun Kim, Jun-Seok Kim, Sang-Won Cho, Gyu-Seok Han
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Patent number: 8304167Abstract: An optical information recording medium includes a recording layer that absorbs recording light in accordance with its wavelength, the recording light being condensed for information recording, and increases the temperature in the vicinity of a focus so as to form a recording mark and that has properties of increasing a light absorption amount with respect to the wavelength of the recording light by heating performed at a temperature of 120° C. or more.Type: GrantFiled: June 30, 2009Date of Patent: November 6, 2012Assignee: Sony CorporationInventors: Yusuke Suzuki, Takao Kudo, Kazuya Hayashibe, Hiroshi Uchiyama
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Publication number: 20120273924Abstract: Provided are an actinic-ray- or radiation-sensitive resin composition that excels in the sensitivity, roughness characteristics and exposure latitude, and a method of forming a pattern using the same. The composition includes (A) a resin that when acted on by an acid, is decomposed to thereby increase its solubility in an alkali developer, and (B) a compound that when exposed to actinic rays or radiation, is decomposed to thereby generate an acid, the compound being any of compounds of general formula (1-1) below.Type: ApplicationFiled: December 22, 2011Publication date: November 1, 2012Applicant: FUJIFILM CorporationInventors: Tomoki Matsuda, Akinori Shibuya, Yoko Tokugawa, Shuhei Yamaguchi, Mitsuhiro Fujita
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Publication number: 20120275045Abstract: A blue photoresist for a color filter substrate is provided. In the wavelength 380 nm to 580 nm, the half-width of the spectrum function of the blue photoresist is represented as Ha, the half-width of the color match function defined by CIE (Commission International de L'Eclairage) at 1931 is presented as Hb, and 3.7>Ha/Hb>1.91. Therefore, the light transmittance of the blue photoresist can be improved so that the efficiency utilizations of light of a color filter substrate and display device using the blue photoresist are provided.Type: ApplicationFiled: December 16, 2011Publication date: November 1, 2012Applicant: AU OPTRONICS CORP.Inventors: Kuei-Bai CHEN, Chien-Kai CHEN, Chen-Hsien LIAO, Chia-Hao LI
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Patent number: 8298750Abstract: Positive-working imageable elements having improved sensitivity, high resolution, and solvent resistance are prepared using a water-insoluble polymeric binder comprising vinyl acetal recurring units that have pendant hydroxyaryl groups, and recurring units comprising carboxylic acid aryl ester groups that are substituted with a cyclic imide group. These imageable elements can be imaged and developed to provide various types of elements including lithographic printing plates.Type: GrantFiled: September 8, 2009Date of Patent: October 30, 2012Assignee: Eastman Kodak CompanyInventors: Moshe Levanon, Georgy Bylina, Vladimir Kampel, Marina Rubin, Larisa Postel, Tanya Kurtser, Moshe Nakash
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Patent number: 8298754Abstract: A method for forming a thick film pattern forms a thick film pattern having a large thickness, a high hardness, and a high aspect ratio and exhibiting high dimension precision and high shape precision. In the method, a photosensitive paste including an inorganic powder, a photosensitive monomer, and a photopolymerization initiator and containing substantially no polymer is applied to a support so as to form a photosensitive paste film. The resulting photosensitive paste film is subjected to an exposure treatment and, thereafter, development is conducted so as to form a predetermined thick film pattern. Alternatively, a photolithography photosensitive paste including an inorganic powder, a photosensitive monomer, a photopolymerization initiator, and a polymer is used, wherein a ratio (weight ratio) of the photosensitive monomer to a total amount of the photosensitive monomer and the polymer is about 0.86 or more.Type: GrantFiled: October 21, 2004Date of Patent: October 30, 2012Assignee: Murata Manufacturing Co., Ltd.Inventors: Hiroyuki Kanbara, Shuuichi Towata, Michiaki Iha
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Patent number: 8298747Abstract: To provide a photosensitive resin composition in which a hardened film obtained from the photosensitive resin composition has properties comparable to those of a film hardened at a high temperature, a method for manufacturing a patterned hardened film using the photosensitive resin composition, and an electronic part. The photosensitive resin composition includes (a) a polybenzoxazole precursor having a repeating unit represented by a general formula (I): wherein U and V represent a divalent organic group, and at least one of U and V is a group containing an aliphatic chain structure having 1 to 30 carbon atoms; (b) a photosensitizer; (c) a solvent; and (d) a crosslinking agent capable of causing crosslinking or polymerization by heating.Type: GrantFiled: March 6, 2008Date of Patent: October 30, 2012Assignee: Hitachi Chemical Dupont Microsystems, Ltd.Inventors: Tomonori Minegishi, Rika Nogita, Kenichi Iwashita
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Patent number: 8298726Abstract: Disclosed is a volume phase hologram recording material of high sensitivity, high contrast, and excellent record retention properties and also disclosed is a volume phase hologram recording medium using the said material. The volume phase hologram recording material mainly contains a three-dimensional crosslinked polymer matrix, a radically polymerizable monomer, and a photoradical polymerization initiator. The three-dimensional crosslinked polymer matrix is formed from a matrix-forming compound having two photoradically polymerizable unsaturated groups and two non-photoradically polymerizable hydroxyl groups represented by the following general formula (1) and another matrix-forming compound having no photoradically polymerizable group.Type: GrantFiled: February 4, 2008Date of Patent: October 30, 2012Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Takehiro Shimizu, Kazuyoshi Masaki, Hidetaka Fujimatsu
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Patent number: 8298454Abstract: Disclosed are a photosensitive resin composition and a light blocking layer using the same. The photosensitive resin composition includes (A) a cardo-based monomer represented by the following Chemical Formula 1 or 2, wherein the substituents of Chemical Formula 1 and Chemical Formula 2 are the same as defined in the detailed description, (B) a cardo-based resin, (C) a reactive unsaturated compound, (D) a pigment, (E) an initiator, and (F) a solvent.Type: GrantFiled: September 23, 2011Date of Patent: October 30, 2012Assignee: Cheil Industries Inc.Inventors: Chang-Min Lee, Jun-Seok Kim, Kil-Sung Lee, Min-Sung Kim
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Publication number: 20120270142Abstract: A photosensitive composition and a method of manufacturing a substrate used for a display device are disclosed. The photosensitive composition includes an acrylic based copolymer, a photo-initiator, a photo-sensitizer and a solvent. Thus, a photosensitivity of the photosensitive composition for ultra violet light of a long wavelength may be improved.Type: ApplicationFiled: January 25, 2012Publication date: October 25, 2012Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Hi-Kuk LEE, Su-Yeon SIM, Sang-Hyun YUN, Cha-Dong KIM, Jung-In PARK, Byung-Uk KIM, Jin-Sun KIM, Tae-Hoon YEO, Hyoc-Min YOUN, Sang-Hoon LEE
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Publication number: 20120270153Abstract: A photoresist composition comprising (A) a resin which has an acid-labile group-containing structural unit and a lactone ring-containing structural unit, and (B) a salt represented by formula (I): wherein Q1 and Q2 each independently represent a fluorine atom or a C1-C6 perfluoroalkyl group, n represents 0 or 1, L1 represents a single bond or a C1-C10 alkanediyl group in which a methylene group may be replaced by an oxygen atom or a carbonyl group, provided that L1 is not a single bond when n is 0, R1 represents a hydroxy group or a hydroxy group protected by a protecting group, and Z+ represents an organic cation.Type: ApplicationFiled: April 17, 2012Publication date: October 25, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Koji ICHIKAWA, Yukako ANRYU, Shingo FUJITA
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Patent number: 8293459Abstract: The present invention provides a photo-curable transfer sheet by which an optical information recording medium (e.g., DVD) having small thickness and high capacity can be advantageously prepared, and which is improved in transferring property of pits and the like and curing property. The photo-curable transfer sheet has a photo-curable transfer layer comprising a photo-curable composition deformable by application of pressure, wherein the photo-curable composition comprises a polymer having a glass transition temperature of not less than 80° C. and a reactive diluent having a photopolymerizable functional group. The invention also provides a process for the preparation of an optical information recording medium using the sheet, and the optical information recording medium.Type: GrantFiled: September 14, 2006Date of Patent: October 23, 2012Assignee: Bridgestone CorporationInventors: Takato Inamiya, Hidefumi Kotsubo, Hideki Kitano, Kenji Murayama
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Patent number: 8293149Abstract: Disclosed are a photosensitive resin composition for a color filter and a color filter using the same. The photosensitive resin composition for a color filter may include (A) a copolymer including a structural unit represented by the following Chemical Formula 1, wherein the substituents of Chemical Formula 1 are the same as defined in the specification; (B) an acrylic-based photopolymerizable monomer; (C) a photopolymerization initiator; (D) a pigment; and (E) a solvent.Type: GrantFiled: July 26, 2011Date of Patent: October 23, 2012Assignee: Cheil Industries Inc.Inventors: Chang-Min Lee, Jun-Seok Kim, Kil-Sung Lee
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Publication number: 20120264057Abstract: A resist material and methods using the resist material are disclosed herein. An exemplary method includes forming a resist layer over a substrate, wherein the resist layer includes a polymer, a photoacid generator, an electron acceptor, and a photodegradable base; performing an exposure process that exposes portions of the resist layer with radiation, wherein the photodegradable base is depleted in the exposed portions of the resist layer during the exposure process; and performing an developing process on the resist layer.Type: ApplicationFiled: June 27, 2012Publication date: October 18, 2012Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Chien-Wei Wang, Ching-Yu Chang, Tsai-Sheng Gau, Burn Jen Lin
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Publication number: 20120264056Abstract: Radiation-sensitive sol-gel compositions are provided, along with methods of forming microelectronic structures and the structures thus formed. The compositions comprise a sol-gel compound and a base generator dispersed or dissolved in a solvent system. The sol-gel compound comprises recurring monomeric units comprising silicon with crosslinkable moieties bonded to the silicon. Upon exposure to radiation, the base generator generates a strong base, which crosslinks the sol-gel compound in the compositions to yield a crosslinked layer that is insoluble in developers or solvents. The unexposed portions of the layer can be removed to yield a patterned sol-gel layer. The invention can be used to form patterns from sol-gel materials comprising features having feature sizes of less than about 1 ?m.Type: ApplicationFiled: April 10, 2012Publication date: October 18, 2012Applicant: BREWER SCIENCE INC.Inventors: Qin Lin, Yubao Wang, Tony D. Flaim
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Publication number: 20120264061Abstract: A resist composition including a base component (A) which exhibits changed solubility in an alkali developing solution under action of acid and an acid-generator component (B) including a compound represented by (b1-1), a compound represented by (b1-1?) and/or a compound represented by (b1-1?) (R1?-R3? represents an aryl group or an alkyl group, provided that at least one of R1?-R3? represents a substituted aryl group being substituted with a group represented by (b1-1-0), and two of R1?-R3? may be mutually bonded to form a ring with the sulfur atom; X represents a C3-C30 hydrocarbon group; Q1 represents a carbonyl group-containing divalent linking group; X10 represents a C1-C30 hydrocarbon group; Q3 represents a single bond or a divalent linking group; Y10 represents —C(?O)— or —SO2—; Y11 represents a C1-C10 alkyl group or a fluorinated alkyl group: Q2 represents a single bond or an alkylene group; and W represents a C2-C10 alkylene group).Type: ApplicationFiled: May 23, 2012Publication date: October 18, 2012Applicant: Tokyo Ohka Kogyo Co., Ltd.Inventors: Hideo HADA, Yoshiyuki Utsumi, Takehiro Seshimo, Akiya Kawaue
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Publication number: 20120264055Abstract: The present invention provides a photoresist composition comprising a salt represented by the formula (I): wherein R1 and R2 independently each represent a fluorine atom or a C1-C6 perfluoroalkyl group, X1 represents a C1-C17 divalent saturated hydrocarbon group, etc., s1 represents 1 or 2, and t1 represents 0 or 1, with proviso that sum of s1 and t1 is 1 or 2, R3 represents a C1-C12 saturated hydrocarbon group, etc., u1 represents an integer of 0 to 8, and (z1)+ represents an organic cation, a salt represented by the formula (II-0): wherein R4 represents a C1-C24 hydrocarbon group etc., X2 represents a C1-C6 alkanediyl group etc., and (Z2)+ represents an organic cation, and a resin being insoluble or poorly soluble in an aqueous alkali solution but becoming soluble in an aqueous alkali solution by the action of an acid.Type: ApplicationFiled: April 10, 2012Publication date: October 18, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Koji ICHIKAWA, Hiromu SAKAMOTO, Yuichi MUKAI
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Publication number: 20120264058Abstract: A resist composition for negative development including a base component (A) which exhibits decreased solubility in an organic solvent under the action of acid and an acid generator component (B) which generates acid upon exposure; and the resist composition used in a method of forming a resist pattern which includes: forming a resist film on a substrate using the resist composition; conducting exposure of the resist film; and patterning the resist film by negative development using a developing solution containing the organic solvent to form a resist pattern, wherein the acid generator component (B) contains an acid generator (B1) that generates an acid having a log P value of 2.7 or less and also a pKa value of at least ?3.5.Type: ApplicationFiled: April 5, 2012Publication date: October 18, 2012Applicant: TOKYO OHKA KOGYO CO., LTD.Inventors: Yoshiyuki Utsumi, Hiroaki Shimizu
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Publication number: 20120264059Abstract: A resist composition includes (A) a resin being insoluble or poorly soluble in alkali aqueous solution, but becoming soluble in an alkali aqueous solution by the action of an acid, (B) an acid generator having a structure to be cleaved by the action of an alkaline developer, and (C) a compound represented by the formula (I), wherein R1 and R2 in each occurrence independently represent a C1 to C12 hydrocarbon group, a C1 to C6 alkoxyl group, a C2 to C7 acyl group, a C2 to C7 acyloxy group, a C2 to C7 alkoxycarbonyl group, a nitro group or a halogen atom; m and n independently represent an integer of 0 to 4.Type: ApplicationFiled: April 6, 2012Publication date: October 18, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Koji ICHIKAWA, Takahiro YASUE, Tatsuro MASUYAMA
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Patent number: 8288079Abstract: A photocurable resin composition containing a photopolymerization initiator and a (meth)acrylate monomer and/or oligomer, said (meth)acrylate monomer or oligomer having a cyclic structure, in which the atomic weight of carbon (Mcr) in said cyclic structure and the number of whole carbon atoms (MTOT) in said composition have the relation of Mcr/MTOT>0.1, or the total number (N) of carbon atoms in said cyclic structure, the total number of carbon atoms (Nc) in said composition and the total number of oxygen atoms (No) have the relation of N/(Nc?No)<4, and the composition has a kinetic viscosity of 10 mPa·s or below. This low-viscosity photocurable resin composition has excellent dry etching resistance and is applicable to optical nanoprinting.Type: GrantFiled: January 12, 2007Date of Patent: October 16, 2012Assignee: Hitachi Chemical Company, Ltd.Inventors: Masahiko Ogino, Makoto Kaji, Hanako Yori
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Publication number: 20120258405Abstract: A resist composition includes; (A) a resin being insoluble or poorly soluble in alkali aqueous solution, but becoming soluble in an alkali aqueous solution by the action of an acid, (B) an acid generator having an acid-labile group; and (D) a compound represented by the formula (I), wherein R1 and R2 in each occurrence independently represent a C1 to C12 hydrocarbon group, a C1 to C6 alkoxyl group, a C2 to C7 acyl group, a C2 to C7 acyloxy group, a C2 to C7 alkoxycarbonyl group, a nitro group or a halogen atom; m and n independently represent an integer of 0 to 4.Type: ApplicationFiled: April 6, 2012Publication date: October 11, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Koji ICHIKAWA, Takahiro YASUE, Satoshi YAMAGUCHI
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Publication number: 20120258404Abstract: A resist composition of the invention includes: (A) a resin being insoluble or poorly soluble in alkali aqueous solution, but becoming soluble in an alkali aqueous solution by the action of an acid, (B) an acid generator represented by the formula (II), and (D) a compound represented by the formula (I), wherein R1, R2, m, n, Q1, Q2, L1, ring W1 and Z+ are defined in the specification.Type: ApplicationFiled: April 6, 2012Publication date: October 11, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Koji ICHIKAWA, Takahiro YASUE, Satoshi YAMAGUCHI
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Publication number: 20120258402Abstract: A photoresist composition includes a polymer that includes a structural unit shown by the following formula (1), and a photoacid generator. R1 in the formula (1) represents a hydrogen atom, a fluorine atom, a methyl group, or a trifluoromethyl group, Z represents a group that forms a divalent alicyclic group having 3 to 20 carbon atoms together with a carbon atom bonded to X, X represents an alkanediyl group having 1 to 6 carbon atoms, Y represents a hydrogen atom or —CR2R3(OR4), and R2 to R4 independently represent a hydrogen atom or a monovalent hydrocarbon group, provided that R3 and R4 optionally bond to each other to form a cyclic ether structure together with a carbon atom bonded to R3 and an oxygen atom bonded to R4.Type: ApplicationFiled: April 4, 2012Publication date: October 11, 2012Applicant: JSR CorporationInventors: Mitsuo SATO, Masafumi Yoshida
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Publication number: 20120258401Abstract: A resist composition contains (A) a resin being insoluble or poorly soluble in alkali aqueous solution, but becoming soluble in an alkali aqueous solution by the action of an acid, (B) an acid generator represented by the formula (II), and (D) a compound represented by the formula (I), wherein R1 and R2, m and n, R3 and R4, X1, R5 and Z1+ are defined in the specification.Type: ApplicationFiled: April 6, 2012Publication date: October 11, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Koji ICHIKAWA, Takahiro YASUE, Yuichi MUKAI
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Publication number: 20120257283Abstract: A photosensitive resin composition which can form a pattern attaining high resolution and having a high refractive index and a high transmittance is provided. The photosensitive resin composition includes a dispersion composition including (A) titanium dioxide particles having an average primary particle diameter of from 1 nm to 100 nm, (B) a graft copolymer that has a graft chain having a number of atoms other than hydrogen atoms in a range of from 40 to 10,000 and (C) a solvent, and (D) a polymerizable compound, and (E) a polymerization initiator.Type: ApplicationFiled: November 17, 2010Publication date: October 11, 2012Applicant: FUJIFILM CORPORATIONInventors: Yoichi Maruyama, Yuzo Nagata, Hiroyuki Einaga, Shinichi Kanna
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Publication number: 20120258403Abstract: The present invention provides a salt represented by the formula (I): wherein Q1 and Q2 independently each represent a fluorine atom or a C1-C6 perfluoroalkyl group, L? represents a C1-C20 divalent saturated hydrocarbon group in which one or more —CH2— can be replaced by —O— or —CO—, W represents a group represented by the formula (W1), (W2), (W3), (W4) or (W5): and Z+ represents an organic counter ion.Type: ApplicationFiled: April 4, 2012Publication date: October 11, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yukako ANRYU, Koji ICHIKAWA
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Patent number: 8283101Abstract: Single- and multi-layer positive-working imageable elements include an ink receptive outer layer that includes inorganic, non-metallic, inert discrete particles, such as nano-sized silica, aluminum oxide, or titanium dioxide particles. The presence of these particles in the outermost layer improves the abrasion and scratch resistance of the elements.Type: GrantFiled: August 30, 2007Date of Patent: October 9, 2012Assignee: Eastman Kodak CompanyInventors: Gerhard Hauck, Celin Savariar-Hauck