Solid Polymer Contains More Than One 1,2-epoxy Group Or Is Derived From Reactant Containing At Least One 1,2-epoxy Group Patents (Class 525/523)
  • Publication number: 20140378581
    Abstract: Mechanical strength of a composite material is enhanced by a simple process. In a composite material comprising a resin or a rubber and an oxide glass, the resin or the rubber is dispersed in the oxide glass, or the oxide glass is dispersed in the resin or the rubber. The composite material has a function that the oxide glass is softened and fluidized by electromagnetic waves.
    Type: Application
    Filed: November 19, 2012
    Publication date: December 25, 2014
    Applicant: Hitachi, Ltd.
    Inventors: Takuya Aoyagi, Takashi Naito, Tadashi Fujieda, Yuichi Sawai, Hajime Murakami, Hiroshi Yoshida, Akihiro Miyauchi, Masahiko Ogino
  • Patent number: 8916655
    Abstract: Epoxy resin compositions utilizing phosphazene blocked azole compounds as curing catalyst are provided. Also provided are epoxy resins cured with phosphazene blocked azole compounds and methods of making cured epoxy resins using curing catalysts of phosphazene blocked azole compounds.
    Type: Grant
    Filed: April 30, 2010
    Date of Patent: December 23, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Journey Lu Zhu, Ping Shao Ren, Shaoguang Feng
  • Patent number: 8916651
    Abstract: Nanocomposite materials and methods of making composite materials reinforced with carbon nanotubes are disclosed. The composite material includes an array of functionalized and aligned carbon nanotubes having a degree of functionalization of about 1% to about 10%; and a polymeric matrix material bonded to the array of functionalized and aligned carbon nanotubes.
    Type: Grant
    Filed: April 20, 2011
    Date of Patent: December 23, 2014
    Assignee: Florida State University Research Foundation, Inc.
    Inventors: Qunfeng Cheng, Richard Liang, Ben Wang, Chuck Zhang
  • Publication number: 20140368970
    Abstract: A resin composition constituting dielectric resin films of a film capacitor includes a first atom group including at least one functional group selected from among a methylene group, an aromatic ring and an ether group and having a relatively small molar polarizability, and a second atom group including at least one functional group selected from among a hydroxyl group, an amino group and a carbonyl group and having a relatively large molar polarizability. The resin composition satisfies the condition that a value calculated from the formula (sum of absorption band intensities of first atom group)/(sum of absorption band intensities of second atom group) is 1.0 or more. Herein, as absorption band intensities of the functional groups, peak intensities detected in specific wavenumber ranges are employed.
    Type: Application
    Filed: August 29, 2014
    Publication date: December 18, 2014
    Inventors: Tomomichi Ichikawa, Norihiro Yoshikawa, Shinichi Kobayashi, Yasunori Hioki, Ichiro Nakaso, Tomoki Inakura
  • Publication number: 20140371405
    Abstract: Disclosed herein are compositions and methods related to the hydroformylation of cyclododecatriene to form cyclododecatriene trialdehyde, and the conversion of the trialdehyde to the polyphenols of Formula 1: where R, m p and Q are as defined herein. Curable compositions comprising compounds of Formula 1, including powder coating compositions, and methods of curing the compositions are also disclosed.
    Type: Application
    Filed: February 22, 2013
    Publication date: December 18, 2014
    Inventors: Erich J. Molitor, Robert E. Hefner, JR.
  • Patent number: 8912113
    Abstract: Described herein are metal amidine complexes in combination with a second compound useful as catalysts in a number of polymerization reactions, including polyurethane and epoxy polymerization reactions. Also described herein are various coating compositions and methods of using same for coating substrates using the metal amidine complexes in combination with a second compound.
    Type: Grant
    Filed: March 5, 2012
    Date of Patent: December 16, 2014
    Assignee: King Industries, Inc.
    Inventors: Ramanathan Ravichandran, Robert Coughlin, Bing Hsieh, Farouk Abi-Karam, John Florio
  • Patent number: 8911586
    Abstract: The present invention is one liquid type cyanate-epoxy composite resin composition that is comprised of cyanate ester resin (A), epoxy resin (B) and latent curing agent (C) and has high thermal resistance as well as excellent fast curing properties and storage stability, characterized in that the above latent curing agent is comprised of a modified amine compound (a) and a phenol resin (b). Where, the modified-amine compound (a) is obtained by the reaction of at least one kind of amine compounds (a-1), selected from amine compounds having one or more tertiary amino groups and one or more primary and/or secondary amino groups, with an epoxy compound (a-2), in particular. It is preferable that one liquid type cyanate-epoxy composite resin composition of the present invention contains 1-10,000 mass parts of the epoxy resin component of the component (B) relative to 100 mass parts of cyanate-ester resin component of the component (A).
    Type: Grant
    Filed: June 12, 2009
    Date of Patent: December 16, 2014
    Assignee: Adeka Corporation
    Inventors: Ryo Ogawa, Shinsuke Yamada, Mitsunori Ide
  • Patent number: 8912291
    Abstract: Embodiments include oxazolidone ring containing adducts obtainable by combining an aliphatic epoxy compound, an aromatic epoxy compound, and a diisocyanate. Embodiments further include a curable powder coating composition including a resin component and a hardener component, where the resin component includes the oxazolidone ring containing adduct.
    Type: Grant
    Filed: December 20, 2010
    Date of Patent: December 16, 2014
    Assignee: DOW Global Technologies LLC
    Inventors: Joseph Gan, Emile C. Trottier
  • Publication number: 20140357811
    Abstract: The use of Michael addition curing chemistries in compositions comprising sulfur-containing polymers such as polythioethers and polysulfides useful in aerospace sealant applications are disclosed. Sulfur-containing adducts comprising terminal Michael acceptor groups are also disclosed.
    Type: Application
    Filed: August 19, 2014
    Publication date: December 4, 2014
    Inventors: Lawrence G. Anderson, Juexlao Cai, Marfi Ito, Raquel Keledjian, Renhe Lin
  • Publication number: 20140357812
    Abstract: The use of Michael addition curing chemistries in compositions comprising sulfur-containing polymers such as polythioethers and polysulfides useful in aerospace sealant applications are disclosed. Sulfur-containing adducts comprising terminal Michael acceptor groups are also disclosed.
    Type: Application
    Filed: August 19, 2014
    Publication date: December 4, 2014
    Inventors: Lawrence G. Anderson, Juexiao Cai, Marfi Ito, Raquel Keledjian, Renhe Lin
  • Publication number: 20140357762
    Abstract: The invention relates to the use of bis- or multifunctional N,N?-(dimethyl) urons as curing agents for curing epoxy resin compositions in a controlled manner.
    Type: Application
    Filed: November 14, 2012
    Publication date: December 4, 2014
    Applicant: ALZCHEM AG
    Inventors: Torsten Eichhorn, Claudia Winkler, Martin Ebner, Hans-Peter Krimmer
  • Publication number: 20140357763
    Abstract: An epoxy system having a Part A and a Part B, where the Part A has an epoxy resin component present in a range of 20 weight percent (wt %) to 70 wt %, based on the total weight of the Part A; a flexibilizer present in a range from 20 wt % to 60 wt %, based on the total weight of the Part A; and a catalyst present in the range of 3 wt % to 7 wt % based on the total weight of the Part A, where the wt % of the components of the Part A of the epoxy system totals 100 wt %; and a Part B having a Mannich base hardener. Embodiments of the present disclosure also include a concrete structure that includes a reaction product of the epoxy system.
    Type: Application
    Filed: December 21, 2012
    Publication date: December 4, 2014
    Applicant: Dow Global Technologies LLC
    Inventors: Bharati Balijepalli, Rajesh H. Turakhia, Hemant A. Naik
  • Publication number: 20140343234
    Abstract: Curable compositions including an epoxy resin, a hardener, and a block copolymer having a thermoset-philic block and a thermoset-phobic block, where the block copolymer is from 20 weight percent to 80 weight percent of the curable composition are described herein.
    Type: Application
    Filed: November 9, 2012
    Publication date: November 20, 2014
    Inventors: Radhakrishnan Karunakaran, Nikhil E. Verghese
  • Patent number: 8889802
    Abstract: A composition comprising a reaction product of reactants comprising (a) a compound comprising (i) a polysulfide moiety and (ii) an oxygen atom in a ?-position to a sulfur link having the formula: where each R is independently selected from H or a C1 to C20 organyl group, R? is independently selected from a C1 to C20 organyl group, R?? is independently selected from H or a C1 to C20 organyl group, and x has an average of greater than 2, (b) a compound comprising a nucleophilic moiety; and (c) a compound comprising a moiety reactive to active hydrogen.
    Type: Grant
    Filed: January 31, 2012
    Date of Patent: November 18, 2014
    Assignee: POLYMERight, Inc.
    Inventors: Leonid Rappoport, Alexander Vainer, Aleksander Yam
  • Publication number: 20140336339
    Abstract: Compositions and methods for forming epoxy resin are provided, and compositions and methods for forming epoxy resin composites are provided. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component comprising a glycidyl ether of an aryl substituted phenolic compound, a curing agent component, and a substrate. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component and a curing agent component comprising an aryl substituted phenolic compound, and a substrate.
    Type: Application
    Filed: May 12, 2014
    Publication date: November 13, 2014
    Applicant: Momentive Specialty Chemicals Inc.
    Inventors: Larry Steven CORLEY, Robert Dale FARRIS, Carlton E. ASH
  • Publication number: 20140336340
    Abstract: The curable composition is a curable composition including a liquid polysulfide polymer containing 8% by weight or more of thiol groups in one molecule, an epoxy resin, and an amine, in which the liquid polysulfide polymer is HS—(R—Sx)n—R—SH wherein R is a two valent or three valent organic group containing a —O—CH2—O— bond, the average of n is less than 10, x is an integer of 1 to 5, and the average of x is 1 to 2.5.
    Type: Application
    Filed: December 5, 2012
    Publication date: November 13, 2014
    Inventors: Yasukazu Suga, Yukiko Hamada, Kazunori Matsumoto, Rika Umano
  • Publication number: 20140336301
    Abstract: The invention provides highly functional epoxy resins that may be used themselves in coating formulations and applications but which may be further functionalized via ring-opening reactions of the epoxy groups yielding derivative resins with other useful functionalities. The highly functional epoxy resins are synthesized from the epoxidation of vegetable or seed oil esters of polyols having 4 or more hydroxyl groups/molecule. In one embodiment, the polyol is sucrose and the vegetable or seed oil is selected from corn oil, castor oil, soybean oil, safflower oil, sunflower oil, linseed oil, tall oil fatty acid, tung oil, vernonia oil, and mixtures thereof. Methods of making of the epoxy resin and each of its derivative resins are disclosed as are coating compositions and coated objects using each of the resins.
    Type: Application
    Filed: February 4, 2011
    Publication date: November 13, 2014
    Inventors: Dean C. Webster, Partha Pratim Sengupta, Zhigang Chen, Xiao Pan, Adlina Paramarta
  • Patent number: 8883883
    Abstract: Disclosed is a resin composition for encapsulating a semiconductor including a phenol resin (A) having one or more components containing a component (A1) composed of a polymer having a first structural unit and a second structural unit, an epoxy resin (B), and an inorganic filler (C). Also disclosed is a semiconductor device obtained by encapsulating a semiconductor element with a cured product of the resin composition for encapsulating a semiconductor.
    Type: Grant
    Filed: May 28, 2010
    Date of Patent: November 11, 2014
    Assignee: Sumitomo Bakelite Co., Ltd.
    Inventor: Masahiro Wada
  • Patent number: 8877878
    Abstract: A sulfonium borate complex that is capable of reducing the amount of fluorine ions generated during thermal cationic polymerization, and is capable of providing a thermal cationic polymerizable adhesive with low-temperature fast curing properties is represented by a structure represented by the formula (1). In the formula (1), R1 is an aralkyl group, R2 is a lower alkyl group, and R3 is a lower alkoxycarbonyl group. X is a halogen atom, and n is an integer of from 1 to 3.
    Type: Grant
    Filed: December 2, 2009
    Date of Patent: November 4, 2014
    Assignee: Dexerials Corporation
    Inventors: Yoshihisa Shinya, Jun Yamamoto, Ryota Aizaki, Naoki Hayashi, Misao Konishi, Yasuhiro Fujita
  • Patent number: 8871347
    Abstract: An aluminum chelate-based latent curing agent having excellent latency and thermal response includes a latent curing agent in which an aluminum chelating agent is retained in a porous resin obtained by interfacial polymerization of a polyfunctional isocyanate compound, and an enzyme-treated gelatin film coating such latent curing agent. This microcapsule-type latent curing agent can be produced by dissolving an aluminum chelating agent and a polyfunctional isocyanate compound in a volatile organic solvent, charging the obtained solution into a gelatin-containing aqueous phase, carrying out interfacial polymerization by heating and stirring, and subjecting the gelatin to an enzyme treatment by adding an enzyme to the obtained polymerization reaction mixture.
    Type: Grant
    Filed: March 18, 2008
    Date of Patent: October 28, 2014
    Assignee: Dexerials Corporation
    Inventor: Kazunobu Kamiya
  • Publication number: 20140316080
    Abstract: The present invention relates to hardeners for epoxy resins, which contain secondary amino groups having pyridinyl groups. They harden surprisingly quickly together with epoxy resins even under cold and humid conditions and without producing blushing to give films with a high degree of hardness, the highest degrees of hardness being obtained with a surprisingly low amount of hardener required. They are especially suitable for low-emission coatings with high resistance requirements.
    Type: Application
    Filed: November 8, 2012
    Publication date: October 23, 2014
    Inventors: Andreas Kramer, Edis Kasemi
  • Patent number: 8865917
    Abstract: A multifunctional aromatic amine hardener composition including the reaction condensation product of (a) at least one aniline and (b) at least one non-aromatic cyclic dicarboxaldehyde; and a reactive thermosettable resin composition including (i) at least one multifunctional aromatic amine hardener composition curing agent, (ii) at least one thermoset resin, and optionally (c) at least one catalyst; and a process for preparing a thermoset product from the thermosettable composition. The hardener composition above and a thermoset resin may be used to prepare a thermoset product with improved thermo-mechanical behavior.
    Type: Grant
    Filed: May 12, 2011
    Date of Patent: October 21, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Mark B. Wilson, Stephanie L. Potisek, Ashwin Bharadwaj, Michael J. Mullins, Steven J. Guillaudeu
  • Patent number: 8865823
    Abstract: A poly(phenylene ether)-poly(hydroxy ether)-poly(phenylene ether) (PPE-PHE-PPE) triblock copolymer is formed by reaction of a monohydroxy-terminated poly(phenylene ether) with a diepoxy-terminated poly(hydroxy ether) in the presence of a base. The PPE-PHE-PPE triblock copolymer is useful as a compatibilizer in blends of polar polymers and non-polar polymers. The PPE-PHE-PPE triblock copolymer is also useful as a compatibilizer for non-polar polymers and polar fillers.
    Type: Grant
    Filed: February 1, 2013
    Date of Patent: October 21, 2014
    Assignee: Sabic Global Technologies B.V.
    Inventor: Edward Norman Peters
  • Patent number: 8865862
    Abstract: A hydroxyphenyl or alkoxyphenyl phosphine oxide composition comprising (i) a first mixture of mono-(hydroxyphenyl) or (alkoxyphenyl) phosphine oxide isomers, (ii) a second mixture of bis-(hydroxyaryl) or (alkoxyphenyl) phosphine oxide isomers, (iii) a third mixture of tris-(hydroxyaryl) or (alkoxyphenyl) phosphine oxide isomers, and optionally iv) a minority amount of non-hydroxy or non-alkoxy tris-phenyl phosphine oxides is provided. Also provided are epoxy resins compositions with excellent flame retardancy and physical properties, which resins comprise the phosphine oxide composition.
    Type: Grant
    Filed: February 4, 2013
    Date of Patent: October 21, 2014
    Assignee: Chemtura Corporation
    Inventors: Larry D. Timberlake, Mark V. Hanson, James D. Siebecker
  • Publication number: 20140309343
    Abstract: Provided herein is a multifunctional particle and methods of forming the same. The multifunctional particle includes: a silica particle; a hydrophobic silane; and a silane coupling agent; where each of the hydrophobic silane and the silane coupling agent are chemically bonded to the surface of the silica particle; where the multifunctional particle is superhydrophobic and chemically reactive.
    Type: Application
    Filed: November 11, 2012
    Publication date: October 16, 2014
    Inventors: Peter Craig Venema, Brent William Barbee, Jordan Moriah Larson
  • Publication number: 20140309335
    Abstract: An epoxy curative is provided comprising: a) a Lewis base, b) calcium nitrate, and c) a polyamine amide salt. The present disclosure additionally provides a composition which is a mixture obtained by mixing the epoxy curative and a curable epoxy resin. The present disclosure additionally provides cured compositions which result from cure of such a mixture.
    Type: Application
    Filed: November 30, 2012
    Publication date: October 16, 2014
    Inventor: Sohaib Elgimiabi
  • Publication number: 20140308863
    Abstract: The invention relates to the use of alkyl or dialkyl-semicarbazone as a hardener for hardening epoxy resin and to a method for controlling the hardening of epoxy resin and epoxy resin compounds.
    Type: Application
    Filed: November 14, 2012
    Publication date: October 16, 2014
    Applicant: ALZCHEM AG
    Inventors: Monika Brandl, Martin Ebner, Hans-Peter Krimmer
  • Patent number: 8859694
    Abstract: An epoxy resin composition comprising an epoxy resin component combined with a sufficient amount of an imidazole curative to provide curing of the epoxy resin composition. The epoxy resin composition further includes a non-hydroxyl containing cure accelerator for the imidazole curative.
    Type: Grant
    Filed: July 12, 2010
    Date of Patent: October 14, 2014
    Assignee: Hexcel Composites Limited
    Inventors: Philip C. Hadley, Michelle M. Irons, John Cawse
  • Patent number: 8859695
    Abstract: A hem-curing epoxy resin composition, that includes an epoxy resin A having more than one epoxy group per molecule on average; a curing agent B for epoxy resins, which is activated at a temperature in a range of 100° C. to 220° C.; and an activator C for epoxy resin compositions, wherein activator C is a compound of formula (I), or is a reaction product between a compound of formula (Ia) and an isocyanate or an epoxide.
    Type: Grant
    Filed: May 29, 2013
    Date of Patent: October 14, 2014
    Assignee: Sika Technology AG
    Inventors: Karsten Frick, Ulrich Gerber, Juergen Finter, Andreas Kramer
  • Publication number: 20140302733
    Abstract: Composite parts may be bonded together at room temperature using an adhesive resin film that is chemically activated to cure when placed in contact with a scrim containing a catalyst.
    Type: Application
    Filed: April 9, 2013
    Publication date: October 9, 2014
    Applicant: THE BOEING COMPANY
    Inventor: The Boeing Company
  • Patent number: 8852734
    Abstract: The present invention is to provide an epoxy resin composition uniformly containing a large amount of inorganic fillers, excellent in heat resistance and flame resistance, and having good impregnation into a base material, and a prepreg using the epoxy resin composition, having good tackiness, and being easy in handling. Furthermore, it is to provide a printed wiring board using a metal-clad laminate formed using the prepreg and/or the prepreg or the epoxy resin composition, capable of easily conducting an ENEPIG process, and a semiconductor device using the printed wiring board, excellent in performances. An epoxy resin composition comprises a solid epoxy resin, a silica nanoparticle having an average particle diameter of 1 nm or more and 100 nm or less, and a silica particle having an average particle diameter larger than that of the silica nanoparticle, in the range of 0.1 ?m or more and 5.0 ?m or less.
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: October 7, 2014
    Assignee: Sumitomo Bakelite Company, Ltd.
    Inventors: Nobuki Tanaka, Seiji Mori
  • Publication number: 20140296379
    Abstract: An amine-terminated, substantially linear siloxane compound comprises siloxane repeating units conforming to specified structures, one of which contains pendant aromatic groups. The amine-terminated, substantially linear siloxane compound further comprises amine-substituted terminal siloxy groups. An epoxy product is made by reacting an epoxy resin and the amine-terminated, substantially linear siloxane compound.
    Type: Application
    Filed: March 18, 2014
    Publication date: October 2, 2014
    Applicant: Milliken & Company
    Inventors: Steven P. Christiano, Olha V. Hoy, John G. Lever, Nathaniel O. Hayes
  • Patent number: 8846856
    Abstract: A novel hydroxyl-functional polyether derived from the reaction of (a) a divinylarene dioxide, particularly a divinylarene dioxide derived from divinylbenzene such as divinylbenzene dioxide (DVBDO); and (b) a diphenol; wherein the reaction product is thermally stable and exhibits an absence of self-polymerization (crosslinking or gelling) upon heating at elevated temperatures. The novel hydroxyl-functional polyether offers improved properties compared to known hydroxyl-functional polyethers such as solid epoxy resins, phenolic epoxy resins (hardeners), and poly(hydroxyl ethers).
    Type: Grant
    Filed: November 23, 2009
    Date of Patent: September 30, 2014
    Assignee: Dow Global Technologies LLC
    Inventor: Maurice J. Marks
  • Publication number: 20140288247
    Abstract: The invention relates to hardeners for epoxy resin containing secondary amino groups having dialkyl amino phenyl groups. The hardeners have a surprisingly low viscosity and harden surprisingly fast together with the epoxy resins, even in moist, cold conditions, and without blushing to form films with high hardness and stability. They are suitable, in particular, for low-emission coatings.
    Type: Application
    Filed: November 8, 2012
    Publication date: September 25, 2014
    Inventors: Urs Burckhardt, Edis Kasemi
  • Publication number: 20140288214
    Abstract: A two-pack type epoxy resin composition for fiber-reinforced composite materials includes components [A] to [D], with component [D] being a liquid at room temperature or a solid having a melting point of 130° C. or less: [A] an epoxy resin; [B] an acid anhydride; [C] a compound that has an average of 2.5 or more hydroxyphenyl structures in each molecule; and [D] an organic phosphorus compound or imidazole derivative.
    Type: Application
    Filed: October 23, 2012
    Publication date: September 25, 2014
    Inventors: Hideki Oka, Nobuyuki Tomioka, Shirou Honda
  • Publication number: 20140275342
    Abstract: Advanced epoxy resins comprising the reaction product of an epoxy resin comprising a diglycidyl ether of Formula 1 as defined herein, and at least on difunctional compound selected from an aromatic diol and a dicarboxylic acid are described. The diglycidyl ether contains a cycloaliphatic ring of 3-5 carbon atoms. Purified diglycidyl ether is used to obtain substantially linear, high molecular weight, advanced epoxy resin. Curable compositions, cured compositions, and articles comprising the advanced epoxy resins are also disclosed. The advanced epoxy resins provide cured coatings having improved flexibility and low total chlorine content.
    Type: Application
    Filed: March 10, 2014
    Publication date: September 18, 2014
    Inventors: Yinzhong Guo, Robert E. Hefner, JR., Ray E. Drumright, Houxiang Tang
  • Publication number: 20140275446
    Abstract: The present invention relates to hardeners for epoxy resins, which contain secondary aliphatic and primary aromatic amino groups. They harden surprisingly quickly together with epoxy resins even under cold and humid conditions and without blushing effects to give films with a high degree of hardness. They are especially suitable for coatings with high resistance requirements.
    Type: Application
    Filed: November 8, 2012
    Publication date: September 18, 2014
    Applicant: Sika Technology AG
    Inventors: Andreas Kramer, Edis Kasem
  • Publication number: 20140275336
    Abstract: A molding composition formulation includes a thermoset cross-linkable 12 to 45 micron polymeric resin. Hollow glass microspheroids are present from 2 to 12 total weight percent. An article formed from such a composition is further strengthened by the addition of a surface activating agent bonded to the surface of the glass microspheroids. Conventional particulate fillers when added to an inventive formulation provide enhanced performance when the filler particle has a size sufficiently small to insert within adjacent microspheroid interstitial voids. An unsaturated polyester resin so formed is particularly well suited for the formation of sheet molding compound formulations.
    Type: Application
    Filed: May 28, 2014
    Publication date: September 18, 2014
    Applicant: Continental Structural Plastics, Inc.
    Inventors: Brian A. Beach, Probir K. Guha, Brad Haskell, Michael J. Siwajek
  • Publication number: 20140275343
    Abstract: An epoxy resin adduct comprising the reaction product of an epoxy resin comprising a diglycidyl ether of Formula 1 as defined herein, and at least one reactive compound having two or more active hydrogen atoms per molecule, wherein the active hydrogen atoms are reactive with epoxide groups are described. The diglycidyl ether contains a cycloaliphatic ring of 3-5 carbon atoms. Curable compositions, methods of curing, cured compositions, and articles comprising the epoxy resin adducts are also disclosed. The epoxy resin adduct has improved cure behavior and provides cured compositions having increased glass transition temperature, good weatherability, and a low total chlorine content.
    Type: Application
    Filed: March 7, 2014
    Publication date: September 18, 2014
    Inventors: Robert E. Hefner, JR., Ray E. Drumright
  • Patent number: 8828268
    Abstract: The present invention pertains to the field of thermosetting or thermoset polymers mainly used as materials, coatings or adhesives. The invention more specifically relates to the use of specific molecules having associative groups including a nitrogen heterocycle as a hardener or co-hardener of thermosetting polymers.
    Type: Grant
    Filed: June 3, 2013
    Date of Patent: September 9, 2014
    Assignee: Arkema France
    Inventors: Bruno Van Hemelryck, Manuel Hidalgo
  • Patent number: 8828267
    Abstract: The present invention provides a composition which comprises at least one epoxy resin and a mixture comprising the 7 stereoisomers of diaminomethylcyclohexane in very specific ratios relative to one another, a process for preparing the composition, the use of the composition for producing hardened epoxides, adhesives, composite materials and moldings, a mixture comprising the 7 stereoisomers of diaminomethylcyclohexane in the specific ratios, and the use of this mixture for producing the composition.
    Type: Grant
    Filed: September 20, 2010
    Date of Patent: September 9, 2014
    Assignee: BASF SE
    Inventors: Joachim Pfeffinger, Daniela Malkowsky, Stephan Goettke
  • Publication number: 20140242394
    Abstract: A curable resin composition which is in a liquid form at ordinary temperature and provides a cured product having excellent heat resistance and a low thermal expansion rate is provided. The curable resin composition according to the present invention comprises: a cyanate ester compound (A) represented by the following formula (I); and a curing accelerator (B): wherein R1 represents a hydrocarbon group having 2 to 20 carbon atoms.
    Type: Application
    Filed: July 2, 2012
    Publication date: August 28, 2014
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Makoto Tsubuku, Taketo Ikeno, Masayuki Katagiri, Yuuichi Sugano
  • Patent number: 8815401
    Abstract: A prepreg for a printed wiring board, comprising a cyanate ester resin having a specific structure, a non-halogen epoxy resin, a silicone rubber powder as a rubber elasticity powder, an inorganic filler and a base material, which prepreg retains heat resistance owing to a stiff resin skeleton structure, has high-degree flame retardancy without the use of a halogen compound or a phosphorus compound as a flame retardant, and has a small thermal expansion coefficient in plane direction without using a large amount of inorganic filler, and a laminate comprising the above prepreg.
    Type: Grant
    Filed: July 11, 2008
    Date of Patent: August 26, 2014
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Yoshihiro Kato, Takeshi Nobukuni, Masayoshi Ueno
  • Patent number: 8815400
    Abstract: An epoxy resin composition including (A) an epoxy resin that is solid at room temperature and has a softening point of 40° C. to 110° C., (B) a curing agent that is solid at room temperature and has a softening point of not less than 40° C. to 110° C., (C) a curing accelerator, (D) an inorganic filler having a mass-average particle size of 0.05 to 5 ?m, (E) a diluent, and (F) a specific dimethyl silicone, in which at least one of the component (A) and the component (B) is silicone-modified is provided. The composition can be used in a silicon chip die attach method or to produce a semiconductor device containing a silicon chip, a substrate and a cured product of the composition, in which the silicon chip is bonded to the substrate via the cured product.
    Type: Grant
    Filed: January 17, 2012
    Date of Patent: August 26, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Tatsuya Kanamaru, Shinsuke Yamaguchi
  • Publication number: 20140224529
    Abstract: To provide a flame-retardant resin composition that has superior adhesion subsequent to curing and molding when used as a printed wiring board adhesive and that provides superior printed wiring board electrical characteristics; and a flexible printed wiring board metal-clad laminate, a coverlay, a flexible printed wiring board adhesive sheet, and a flexible printed wiring board employing this resin composition. (SOLUTION) The flame-retardant resin composition comprises a thermosetting resin, a hardener, and a phosphorus-containing polymer.
    Type: Application
    Filed: June 4, 2012
    Publication date: August 14, 2014
    Applicant: ARISAWA MFG. CO., LTD.
    Inventors: Shu Dobashi, Yuji Toyama, Tsuneo Koike, Makoto Tai, Marc-Andre Lebel, Jan-Pleun Lens
  • Publication number: 20140227530
    Abstract: The present invention is directed to anti-corrosion coatings. It is particularly directed to coatings comprising a monomer, such as pyrrole, aniline, thiophene, or their analogs, and a resin. These coatings can be used with substrates such as cold-rolled steel and other metals to inhibit surface oxidation.
    Type: Application
    Filed: May 23, 2012
    Publication date: August 14, 2014
    Inventors: Simona Percec, Kayleigh J. Ferguson
  • Publication number: 20140227516
    Abstract: A carbon fiber sizing agent imparts good bonding performance to carbon fiber, is used to reinforce a thermoplastic matrix resin, and provides a carbon fiber strand applied with the sizing agent and a fiber-reinforced composite reinforced with the carbon fiber strand. The sizing agent for carbon fiber is used to reinforce thermoplastic matrix resin. The sizing agent essentially contains a polymer component having a glass transition temperature of at least 20 deg.C. and exhibits no endothermic peaks indicating an endothermic heat of fusion due to crystalline melting of at least 3 J/g in a determination with a DSC. The weight ratio of the polymer component is 10 to 100 wt % of the nonvolatile components of the sizing agent. The polymer component is at least one component selected from the group consisting of an aromatic polyester resin, aromatic polyester-polyurethane resin and amine-modified aromatic epoxy resin.
    Type: Application
    Filed: October 15, 2012
    Publication date: August 14, 2014
    Inventors: Yoshio Hashimoto, Yusuke Shimizu, Mikio Nakagawa
  • Patent number: 8802792
    Abstract: Partially hydrogenated bisphenol-A based polymers. Coating compositions for food or beverage containers and medical devices, including a partially hydrogenated bisphenol-A based polymer. Food or beverage containers and medical devices coated with partially hydrogenated bisphenol-A based polymers. Food or beverage containers and medical devices made from partially hydrogenated bisphenol-A based polymers.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: August 12, 2014
    Assignee: Empire Technology Development LLC
    Inventors: William B. Carlson, Gregory D. Phelan, Phillip A. Sullivan
  • Publication number: 20140221582
    Abstract: A hydroxyphenyl or alkoxyphenyl phosphine oxide composition comprising (i) a first mixture of mono-(hydroxyphenyl) or (alkoxyphenyl) phosphine oxide isomers, (ii) a second mixture of bis-(hydroxyaryl) or (alkoxyphenyl) phosphine oxide isomers, (iii) a third mixture of tris-(hydroxyaryl) or (alkoxyphenyl) phosphine oxide isomers, and optionally iv) a minority amount of non-hydroxy or non-alkoxy tris-phenyl phosphine oxides is provided. Also provided are epoxy resins compositions with excellent flame retardancy and physical properties, which resins comprise the phosphine oxide composition.
    Type: Application
    Filed: February 4, 2013
    Publication date: August 7, 2014
    Inventors: Larry D. Timberlake, Mark V. Hanson, James D. Sibecker
  • Publication number: 20140216655
    Abstract: Silanes of formula (I): or inorganic fillers whose surface is coated or derivatized with a silane of formula (I), are curing agents for epoxy resins that are activatable at elevated temperature. The thermosetting epoxy resin compositions allow a large reduction in the curing temperature without great impairment of their storage stability. They are therefore very well suited for single-component thermosetting epoxy adhesives, which in particular may contain impact modifiers.
    Type: Application
    Filed: April 7, 2014
    Publication date: August 7, 2014
    Applicant: SIKA TECHNOLOGY AG
    Inventor: Andreas KRAMER