Abstract: A system and method for acid-gas capture wherein organic acid-gas capture materials form hetero-atom analogs of alkyl-carbonate when contacted with an acid gas. These organic-acid gas capture materials include combinations of a weak acid and a base, or zwitterionic liquids. This invention allows for reversible acid-gas binding to these organic binding materials thus allowing for the capture and release of one or more acid gases. These acid-gas binding organic compounds can be regenerated to release the captured acid gasses and enable these organic acid-gas binding materials to be reused. This enables transport of the liquid capture compounds and the release of the acid gases from the organic liquid with significant energy savings compared to current aqueous systems.

Abstract: Processes and methods exist for decreasing emissions of mercury upon combustion of fossil fuels such as coal. Halide salts can be effective when used at locations where they are thermally decomposed to form reactive halogen species, or in combination with an adsorbent material such as activated carbon. Halide salts, such as calcium bromide and sodium bromide, are not typically used at locations downstream of the economizer, where the temperature is typically below around 500° C., because these salts are non-thermolabile and do not decompose to produce reactive halogen species. However, in flue gas streams that certain flue gas constituents, such as sulfur trioxide or sulfuric acid, reactive halogen species can be produced via chemical reaction. These species react with elemental mercury through various means to form an oxidized form of mercury that is more easily captured in downstream pollution control devices such as particulate control devices or SO2 scrubbers.

Abstract: A process for the clean-up of a crude syngas stream having widely varying composition and particulate load. The process includes quenching the crude syngas stream with a liquid stream to cool the syngas stream and remove particulates, tars and heavier hydrocarbon compounds. The process further includes co-scrubbing the syngas stream to remove both HCl and NH3 from the syngas stream, removing particulate matter from the syngas stream, and removing sulfur from the syngas stream. A syngas treatment system is also disclosed.

Abstract: A method is illustrated and described for reducing unwanted substances by injecting a reactant into a flue gas of a steam generator. In order that the reactant can also be used in larger steam generators and/or combustion chambers, a method is proposed, in which the reactant is injected into the combustion chamber of the steam generator via a reactant opening of a multi-component nozzle, in which an enveloping medium is injected into the combustion chamber through at least one enveloping medium opening arranged outside the reactant opening, and in which the enveloping medium at least partly envelops the reactant in the combustion chamber and in this way at least partly shields the reactant from the flue gas.

Abstract: A method and plant for reducing mercury (Hg) and other metal emissions including injecting a chemical reagent into the process in such a way as to convert elemental mercury into a mercury compound that is more readily captured using normal particulate control equipment associated with kilns, smelters, furnaces, and boilers of cement plants and other industrial plants.

Abstract: Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a blend of piperazine and at least one diamine or triamine.

Abstract: Provided in one embodiment is a method of making an aerogel, comprising: (A) subjecting a suspension or a solution comprising a concentration of at least one chemical reactant to at least one of a hydrothermal and a solvothermal process for at least a reaction time to form an in-situ hydrogel, wherein the hydrogel comprises particulates having an asymmetric geometry, and (B) removing a liquid from the hydrogel to form an aerogel.

Abstract: The disclosure provides an improved means of controlling mercury emissions from coal-fired boiler applications. Specifically, the disclosure comprises a static mixing device placed in the flue gas stream. The static mixing device can enhance dispersion of injected sorbents in the flue gas, resulting in improved mercury capture at a lower sorbent injection rate.

Abstract: A method and an arrangement 22 for supplying and mixing a reducing agent into a flue gas FG flowing through a gas duct 14 and into a selective catalytic reduction (SCR) reactor 18 arranged downstream of the arrangement 22. The subject arrangement 22 is useful in both high and low dust environments to mitigate ash and like particulate accumulation on reducing agent nozzles 42 and to provide more uniform reducing agent flow distribution upstream of the SCR reactor 18.

Abstract: The purpose of the present invention is to provide a method for removing offensive odors from various discharge gases other than exhaust gases of motor vehicle. A method for treating a discharge gas including a discharge-gas treatment device in using an aqueous solution containing strong alkaline electrolyzed water, and directly contacting the discharge gas with the strong alkaline electrolyzed water, having a pH of 9 or higher and an ORP kept at 0 mV or less.

Abstract: A method for producing a sulphided copper sorbent includes the steps of: (i) contacting a sorbent precursor material containing one or more sulphidable copper compounds, with a sulphiding gas stream including hydrogen sulphide to form a sulphided sulphur-containing sorbent material, and (ii) subjecting the sulphided sulphur-containing sorbent material to a heating step in which it is heated to a temperature above that used in the sulphiding step and ?110° C., under an inert gas selected from nitrogen, argon, helium, carbon dioxide, methane, and mixtures thereof, the inert gas optionally including hydrogen sulphide. The method provides sulphided copper sorbents that have reduced levels of elemental sulphur.

Abstract: The invention relates to a gas purifier that removes moisture and oxygen from inert gases and reducing gases, for example, at sub-atmospheric pressures. The purifier can remove part per million levels of moisture in a gas stream to less than 100 parts per trillion by volume, and has a low pressure drop and a sharp breakthrough curve.

Abstract: Methods for reducing the acidic gas content of effluent gas streams are disclosed. The methods generally involve reducing the acidic gas content of combustion gases passing through a duct by injecting hydrated lime or pulverized quicklime into the duct by use of a shrouded injector which reduces the incidence of occlusion of the injector.

Abstract: The present invention relates to a method and a system for cleaning a CO2 rich flue gas stream containing water vapor and NOX prior to CO2 sequestration. The method and system include heating the flue gas stream to a temperature suitable for selective catalytic reduction (SCR) of NOX in a flue gas heater, reducing at least some of the NOX in the heated flue gas stream to N2 by SCR, and removing at least some of the water vapor from the NOX depleted flue gas stream by adsorption in an adsorption drier.

Abstract: An acid gas absorbent according to an embodiment includes at least one kind of amino acid salt represented by the following general formula (1). In the above-described formula (1), R1 indicates a cyclic alkyl group having 3 to 8 carbon atoms, R2 indicates a cyclic alkyl group having 3 to 8 carbon atoms, a chain alkyl group having 1 to 8 carbon atoms, or a hydrogen atom, R3 indicates a methylene group, an alkylene group having 2 to 4 carbon atoms, an alkylidene group having 2 to 4 carbon atoms, or a polymethylene group having 3 to 4 carbon atoms, and M indicates alkali metal.

Abstract: In a method for removing a portion of contaminants, such as nitrogen oxides, from an exhaust gas stream of a combustion process, the exhaust gas stream is conveyed through a gas distributor at an inlet of a wet horizontal spray scrubber. A distributor separates the gas stream into a plurality of spaced apart partitioned gas streams. The gas stream is partitioned in the chamber of the scrubber without the need for any physical partitions or obstructions positioned in the chamber. A preselected number of the partitioned gas streams are mixed with ozone to oxidize the contaminants in the gas streams. The oxidized gas streams are then sprayed with an aqueous medium to capture the oxidized contaminants and remove them from the treated gas streams. The treated gas streams are then recombined with the untreated gas streams. Excess ozone present in the treated gas streams is consumed by oxidation of contaminants in the untreated gas streams before the combined gas stream is released to the atmosphere.

Abstract: The waste disposal system disclosed herein includes a chamber operated at high ampere and low voltage, the chamber configured to inject smoke on a stream of free radicals. In one implementation, the stream of free radicals is generated from a plasma igniter and the smoke is generated from waste products, such as hospital waste products.

Abstract: The present disclosure is directed to the use of elemental or speciated iodine and bromine to control total mercury emissions.

Abstract: A highy alkalized humic and fulvic filter reagent for the removal of multiple contaminants from a gas is provided. The contaminants removed from the gas stream may include, but are not limited to, Carbon Dioxide, Sulfur Oxide, Nitrogen Oxides, Hydrogen Sulfides, radionuclides, mercaptans, ammonia, toxic metals, particulates, volatile vapors, and organics. The present invention further includes the disposal of the filter reagent by way of using the highly alkalized humic and fulvic filter for soil fertility, releasing the carbon dioxide from the filter reagent , converting the liquid filter reagent into a solid for disposal or for use as a contaminant removal filter for waters, wastes, and chemicals.

Abstract: The present invention concerns the elimination of heavy metals, in particular mercury and possibly arsenic and lead, present in a gaseous or liquid effluent by means of a capture mass comprising a support essentially based on alumina obtained by the gel method and at least one element selected from the group constituted by copper, molybdenum, tungsten, iron, nickel and cobalt. The invention is advantageously applicable to the treatment of gas of industrial origin, synthesis gas, natural gas, gas phase condensates and liquid hydrocarbon feeds.

Abstract: An exemplary method and associated architecture for reducing NOx and particulate matter emissions in an exhaust stream may include passing the exhaust stream through a catalytic oxidation reactor; passing the exhaust stream through a two-way selective reduction catalyst particulate filter located downstream of the catalytic oxidation reactor, wherein the two-way selective reduction catalyst particulate filter may include a wall flow filter substrate having internal walls coated with a first selective catalytic reduction catalyst; and passing the exhaust stream through a catalytic reduction reactor located downstream of the two-way selective reduction catalyst particulate filter, wherein the catalytic reduction reactor may include a second selective catalytic reduction catalyst.

Abstract: A biomass gasification gas purification system includes a dust collector for removing dust in biomass gasification gas (containing tar components) acquired by gasifying biomass by a biomass gasification furnace, a desulfurizer for removing sulfur oxide components in the dust-removed biomass gasification gas, a pre-reforming reactor for reforming tar components in the desulfurized biomass gasification gas, a steam feed unit for feeding steam to an upstream side of the pre-reforming reactor, and a natural-gas feed unit for feeding natural gas on an upstream side of the desulfurizer.

Abstract: This invention relates to processes for the selective removal of contaminants from effluent gases. More particularly, various embodiments of the present invention relate to selective removal and recovery of sulfur dioxide from effluent gases in a regenerative sulfur dioxide absorption/desorption process that achieves favorable energy efficiency. Energy is recovered from a wet stripper overhead gas stream produced in the desorption cycle by indirect transfer of heat from the stripper gas to a cooling medium and used to generate steam for use in stripping contaminants from the absorption liquor. The absorption zone may optionally be cooled to enhance the capacity of the absorption medium for absorption of a contaminant gas, thereby lowering the volume of absorption medium and contaminant-enriched absorption liquor that must be pumped, handled, heated and cooled in the absorption/desorption cycle.

Abstract: A wet scrubber (10) useful for cleaning a process gas (F) comprising at least a first spray level system (40) and a second spray level system (48) arranged compactly vertically above the first spray level system (40) in a wet scrubber tower (14). Each spray level system (40, 48) is equipped with a plurality of atomizing flattened relatively wide spray angle nozzles (56) for atomizing an absorption liquid (AL) supplied thereto for contact and intermixing with the process gas (F) for removal of environmental pollutants therefrom.

Abstract: The present disclose is directed to a method for controlling iodine levels in wet scrubbers, and, in particular, recirculating wet scrubbers by removing the iodine from the scrubbing solution, such as by using ion exchange, absorption, adsorption, precipitation, filtration, solvent extraction, ion pair extraction, and an aqueous two-phase extraction.

Abstract: The invention relates to a so-called zero emission ‘AST-CNR/ITM system’ modular plant for removal of pollutants from flue gases produced by industrial processes. The plant comprises prefabricated modular elements with programmed and automatic operation, easy to mount and assemble on site without undergoing expensive plant stoppage. Each module or ‘reaction tower’ comprises a plurality of sections vertically arranged on top of one another, which carry out the following functions: Removal of particulate matter with treatment and removal of chemical pollutants, such as heavy metals, chlorides, fluorides Treatment and removal of SOx Treatment and removal of NOx Capture of CO2 Production of hydrogen Production of methanol. The various sections may be combined according to the requirements of the plant and of the flue gases to be treated.

Abstract: An exemplary embodiment of the present invention provides an induced-draft injection system comprising an injection line in fluid communication with a duct under negative pressure, a particulate storage containing particulate, and a feeder receiving the particulate from the particulate storage and feeding the particulate to the injection line. The negative pressure in the duct supports the transportation of at least a portion of the particulate through the injection line and into the duct. Inside the duct, a binding portion of the particulate is bound to a portion of mercury in a flue gas passing through the duct, thus enabling a portion of the mercury to be filtered out of the flue gas.

Abstract: After absorbing oxygen together with carbon dioxide in an absorber 103, absorbing liquid 104a is supplied to oxygen collecting units 13 and 14. The oxygen collecting units 13 and 14 include silver to collect the oxygen in the absorbing liquid 104a and eliminate the oxygen from the absorbing liquid 104a. A regenerating unit 15 separates and recovers the oxygen collected in one of the two oxygen collecting units 13 and 14 to regenerate the oxygen collecting unit when the other oxygen collecting unit is supplied with the absorbing liquid 104a. A continuous operation can be achieved by switching and using the two oxygen collecting units 13 and 14.

Abstract: A system and method for treatment of a medium is disclosed. The system includes a plurality of separator zones and a plurality of heat transfer zones. Each of the separator zone and the heat transfer zone among the plurality of separator zones and heat transfer zones respectively, are disposed alternatively in a flow duct. Further, each separator zone includes an injector device for injecting a sorbent into the corresponding separator zone. Within the corresponding separator zone, the injected sorbent is reacted with a gaseous medium flowing in the flow duct, so as to generate a reacted gaseous medium and a reacted sorbent. Further, each heat transfer zone exchanges heat between the reacted gaseous medium fed from the corresponding separator zone and a heat transfer medium.

Abstract: A system for reducing emissions includes a gas production source that produces nitrogen oxides, sulfur oxides, hydrogen sulfide, sulfuric acid, nitric acid, formaldehyde, benzene, metal oxides, or volatile organic compound emissions. An exhaust plenum is downstream from the gas production source, and structure for dispersing a solvent is in the exhaust plenum. A collection tank is in fluid communication with the exhaust plenum to receive the solvent from the exhaust plenum, and a heat source is in the exhaust plenum downstream from the structure for dispersing the solvent. A method for reducing emissions from a gas production source includes flowing exhaust gases through an exhaust plenum, dispersing a solvent through a nozzle in the exhaust plenum, collecting the dispersed solvent in a collection tank, and heating the exhaust gases flowing through the exhaust plenum downstream from the nozzle.

Abstract: Disclosed herein are scavenging compounds and compositions useful in applications relating to the production, transportation, storage, and separation of crude oil and natural gas. Also disclosed herein are methods of using the compounds and compositions as scavengers, particularly in applications relating to the production, transportation, storage, and separation of crude oil and natural gas.

Abstract: A method is provided for replacing at least a portion of the organic linker content of a zeolitic imidazolate framework composition. The method comprises exchanging the organic linker with another organic linker. Also provided is a new material, designated as EMM-19, and a method of using EMM-19 to adsorb gases, such as carbon dioxide.

Abstract: Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components: reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or CI in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.

Abstract: A gas collection method comprises contacting a gas mixture including a weak acidic gas and a strong acidic gas with amine solution that absorbs a first portion of the gas mixture. After this first contacting step the gas mixture is contacted with amine solution that absorbs a second portion of the mixture. The amine solution after the second contacting step is heated to discharge at least some portion of the weak acid gas component absorbed therein. The method also includes adding an alkaline compound to the amine solution to generate a salt by reaction with the strong acidic component. The salt is separated from the amine solution and this amine solution can be used in the second contacting step.

Abstract: Implementations disclosed herein provide a dry chemical scrubber with a pH regulator that adjusts an internal pH value of the dry chemical scrubber by adding high pH elements to the contents of the dry chemical scrubber on a continuous or periodic basis.

Abstract: An apparatus and method is presented for removing acid gases and other trace contaminants to very low levels in combustible gases generated from thermal gasification of biomass or refuse-derived fuels. The invention includes optimization of geometric variables, temperature and pressure set points via use of a pressurized bubbling fluidized bed reactor to convert granular raw (non-activated) sorbents and auto-generated biochar sorbents) into activated, highly dispersed, and ideally sized particles for removing acid gases and toxic metals. The system can incorporate a generated gas cooler, a gas-sorbent contact chamber or zone, and a novel filter (with or without additional gas cooling and residence time stages).

Abstract: Provided is a process for controlling heavy metal (e.g., mercury) emission in S02-containing flue gas, comprising passing a stream of the flue gas (2) through a wet scrubber (1) where it is brought into contact with a liquid absorbent (8) comprising an ionic liquid, an oxidizer (11) and polar protic organic solvent, wherein the amount of said organic solvent is adjusted such that the SO2 absorption is minimized while operating said wet scrubber at a temperature lower than the normal working temperature that would be used in the absence of said solvent. The process may be preceded by an initial stage where a fluoride-containing liquid is used for reducing the amount of sulfur dioxide in the flue gas stream; the sulfur dioxide can be subsequently desorbed from the fluoride-containing liquid upon the addition of a polar solvent.

Abstract: A method of converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a zeolite catalyst containing at least one transition metal, wherein the zeolite is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir and Pt.

Abstract: Provided is an organic ligand-bound metal surface that selects one gaseous species over another. The species can be closely sized molecular species having less than 1 Angstrom difference in kinetic diameter. In one embodiment, the species comprise carbon monoxide and ethylene. Such organic ligand-bound metal surfaces can be successfully used in gas phase separations or purifications, sensing, and in catalysis.

Abstract: The invention relates to a method for cleaning exhaust gases, in which an exhaust gas and a sorbent are combined in a fluidized bed reactor. In a subsequent filter system, solid matter is segregated, and thereafter, up to 99 per cent of the sorbent is re-channeled into the fluidized bed reactor, wherein the gas is subjected to a rotation around the flow axis in the fluidized bed reactor.

Abstract: A boosted no-lance injection system (BNLS) and methods of operating a combustion system to reduce acid gas or metal emissions in the flue gas is shown and described. In one embodiment, a BNLS includes an injection device, a high volumetric flow air mover, a transport air mover, a sorbent hopper and a mounting apparatus. In other embodiments, a method of operating a combustion system includes positioning the BNLS to inject into the ductwork, applying transport air and sorbent into the ductwork, and applying the high volumetric flow air into the ductwork. The result is methods and systems for reducing acid or metal emissions in the flue gas.

Abstract: Disclosed is a system for processing a combustible gas, which comprises a catalytic combusting means for receiving an oxygen-containing combustible gas that contains oxygen in addition to the combustible gas as the principal component thereof, causing this oxygen-containing combustible gas to contact an oxidation catalyst for partial combustion thereof, to produce the resultant partially combusted gas as a compressible combustible gas.

Abstract: The present invention provides a membrane, comprising in this order a first catalyst layer, an electronically and ionically conducting layer having a nanosized microstructure, and a second catalyst layer, characterized in that the electronically and ionically conducting layer is formed from an electrolyte material, a grain growth inhibitor and/or grain boundary modifier, and a method for producing same.

Abstract: A system and method is provided for the removal of mercury from flue gas. Effective removal of mercury is obtained by oxidation of elemental mercury, with highly reactive halogen species derived from dissociation of halogen compounds at moderate temperatures brought into contact with the flue gas with or without the addition of carbon.

Abstract: An exhausting apparatus includes an exhaust pump configured to extract unreacted precursor in a process chamber and vent the unreacted precursor out of the exhaust pump, and a first material supplier configured to supply a first material into the exhaust pump. The first material is adsorbable on an interior surface of the exhaust pump to prevent the unreacted precursor from being adsorbed on the interior surface of the exhaust pump.

Abstract: A process for a reduction in the amount of sulphur compounds, hydrogen cyanide, formic acid and formic acid derivatives in synthesis gas comprising these compounds, the process comprising contacting the synthesis gas with a sulphur absorbent comprising material and thereafter with a catalyst comprising one or more metals selected from the group consisting of silver, gold, copper, palladium, platinum and their mixtures and supported on a carrier comprising at least one of the oxides of scandium, yttrium, lanthanum, cerium, titanium, zirconium, aluminum, zinc, chromium and molybdenum.

Abstract: A method of producing enhanced coal combustion ash for use in pozzolanic applications or cement manufacture, in which the enhanced combustion ash has lower mercury content. A slurry is formed of the combustion ash and water and is subjected to froth flotation to form a mercury-enriched ash slurry and a mercury-depleted ash slurry. The product mercury-depleted ash slurry is isolated and may optionally be dried. The combustion ash may be pulverized prior to being used to form the slurry, reducing its mean particle size. The mercury-depleted combustion ash product has reduced levels of mercury and ammonia, and reduced particle size.

Abstract: A method for generating and purifying syngas and to an apparatus for generating and purifying syngas is presented.

Abstract: A substance is treated using a device having: (a) a volute or cyclone head, (b) a throat connected to the volute or cyclone head, (c) a parabolic reflector connected to the throat, (d) a first wave energy source comprising a first electrode within the volute or cyclone head that extends through the outlet into the opening of the throat along the central axis, and a second electrode extending into the parabolic reflector and spaced apart and axially aligned with first electrode, and (e) a second wave energy source disposed inside the throat, embedded within the throat or disposed around the throat. The substance is directed to the inlet of the volute or cyclone head and irradiated with one or more wave energies produced by the first and second wave energy sources as the substance passes through the device.

Abstract: Systems and methods of capturing and sequestering carbon dioxide, comprising mixing a substantially non-aqueous solvent and an alkali such that the solvent and alkali form a solvent suspension, mixing water and a flue gas containing carbon dioxide with the solvent suspension such that a reaction occurs, the reaction resulting in the formation of a carbonate, water and heat.