Patent number: 6872331
Abstract: An oxide ion conductor is manufactured having a relatively high mechanical strength while the ionic conduction thereof is maintained at a satisfactory level. The oxide ion conductor is represented by the formula Ln11-xAxGa1-y-z-wB1yB2zB3wO3-d. In the oxide ion conductor, Ln1 is at least one element selected from the group consisting of La, Ce, Pr, Nd, and Sm, A is at least one element selected from the group consisting of Sr, Ca, and Ba, B1 is at least one element selected from the group consisting of Mg, Al, and In, B2 is at least one element selected from the group consisting of Co, Fe, Ni, and Cu, and B3 is at least one element selected from the group consisting of Al, Mg, Co, Ni, Fe, Cu, Zn, Mn, and Zr, wherein x is 0.05 to 0.3, y is 0.025 to 0.29, z is 0.01 to 0.15, w is 0.01 to 0.15, y+z+w is 0.035 to 0.3, and d is 0.04 to 0.3.
Type:
Grant
Filed:
August 4, 2003
Date of Patent:
March 29, 2005
Assignee:
Mitsubishi Materials Corporation
Inventors:
Kiyoshi Kuroda, Takashi Yamada, Yoshitaka Tamo, Kazunori Adachi
Patent number: 6833083
Abstract: Compounds are expressed by general formula of AxBC2−y where 0≦x≦2 and 0≦y<1, and have CdI2 analogous layer structures; A-site is occupied by at least one element selected from the group consisting of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Ir, Pt, Au, Sc, rare earth elements containing Y, B, Al, Ga, In, Tl, Sn, Pb and Bi; B-site is occupied by at least one element selected from the group consisting of Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W, Ir, and Sn; C-site is occupied by at least one element selected from the group consisting of S, Se and Te; the compounds exhibit large figure of merit so as to be preferable for thermoelectric generator/refrigerator.
Type:
Grant
Filed:
February 25, 2002
Date of Patent:
December 21, 2004
Assignee:
NEC Corporation
Inventors:
Hideto Imai, Yuichi Shimakawa, Takashi Manako, Yoshimi Kubo