Transition Metal-base Component Patents (Class 428/655)
  • Patent number: 6887587
    Abstract: The present invention relates to a method for forming an article having a protective ceramic coating which reduces radiation heat transport through the ceramic coating. The protective ceramic coating includes one or more embedded reflective metallic layers for reducing the radiation heat transport. The method for forming the protective coating broadly comprises the steps of forming a ceramic coating on a substrate and embedding at least one reflective metallic layer within the ceramic coating.
    Type: Grant
    Filed: June 10, 2003
    Date of Patent: May 3, 2005
    Assignee: United Technologies Corporation
    Inventors: William P. Allen, William A. Veronesi, Robert J. Hall, Michael J. Maloney, John W. Appleby, Douglas C. Hague, Abdus Khan
  • Patent number: 6881498
    Abstract: A surface processing method and power transmission component includes refining a surface region of a metal from a first roughness to a second roughness less than the first roughness. A solid lubricous coating or a hard coating is then deposited on the surface region. The metal has a surface hardness above 50 Rc to reduce the risk that the metal will deform under the coating and leave the coating unsupported. The surface region of the metal may be transformed into a nitrogen-containing compound or solid solution surface region before the surface refining step and deposition of the coating.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: April 19, 2005
    Assignee: Sikorsky Aircraft Corporation
    Inventors: Clark VanTine Cooper, Harsh Vinayak
  • Publication number: 20040258946
    Abstract: The present invention relates to a method for forming an article having a protective ceramic coating which reduces radiation heat transport through the ceramic coating. The protective ceramic coating includes one or more embedded reflective metallic layers for reducing the radiation heat transport. The method for forming the protective coating broadly comprises the steps of forming a ceramic coating on a substrate and embedding at least one reflective metallic layer within the ceramic coating.
    Type: Application
    Filed: June 10, 2003
    Publication date: December 23, 2004
    Inventors: William P. Allen, William A. Veronesi, Robert J. Hall, Michael J. Maloney, John W. Appleby, Douglas C. Hague, Abdus S. Khan
  • Publication number: 20040241490
    Abstract: Titanium and aluminum cathode targets are disclosed for sputtering absorbing coatings of titanium and aluminum-containing materials in atmospheres comprising inert gas, reactive gases such as nitrogen, oxygen, and mixtures thereof, which can further comprise inert gas, such as argon, to form nitrides, oxides, and oxynitrides, as well as metallic films. The titanium and aluminum-containing coatings can be utilized as an outer coat or as one or more coating layers of a coating stack.
    Type: Application
    Filed: March 25, 2004
    Publication date: December 2, 2004
    Inventor: James J. Finley
  • Patent number: 6818321
    Abstract: A high-temperature strength member comprises a substrate of Ni-based single crystal alloy or a Ni-based unidirectional solidified alloy and a coating of a B-containing alloy having a specified B content formed on the surface thereof by a spraying process or a vapor deposition process.
    Type: Grant
    Filed: October 25, 2002
    Date of Patent: November 16, 2004
    Assignee: Tocalo Co., Ltd.
    Inventors: Masakazu Okazaki, Yoshio Harada, Tatsuo Suidzu
  • Publication number: 20040209110
    Abstract: A beta-phase NiAl overlay coating containing a dispersion of ceramic particles and a process for depositing the overlay coating. If the coating is used to adhere a thermal barrier coating (TBC), the TBC exhibits improved spallation resistance as a result of the dispersion of ceramic particles having a dispersion-strengthening effect on the overlay coating. The overlay coating contains at least one reactive element and is deposited so that the some of the reactive element deposits as the ceramic particles dispersed in the overlay coating.
    Type: Application
    Filed: April 18, 2003
    Publication date: October 21, 2004
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Jeffrey Allan Pfaendtner, Ramgopal Darolia, William Scott Walston, Brett Allen Rohrer Boutwell, Irene Spitsberg, James Anthony Ruud, Joseph David Rigney
  • Publication number: 20040206726
    Abstract: Disclosed is a hardfacing alloy capable of withstanding service abrasion of the order of silicious earth particles and weldable on industrial products, such as tool joints and stabilizers used in oil and gas well drilling, and other industrial products. The hardfacing alloy has a low coefficient of friction resulting from excellent metal to metal resistance and significant reduction in industrial wear on industrial products, such as casing wear. Other embodiments of the invention include tool joints having the hardbanding alloy welded to the outer cylindrical surface to its box and pin members and to stabilizer ribs on the stabilizer used in earth boring, such as boring for oil and gas, other industrial products, and methods of applying the hardfacing alloy to their surfaces.
    Type: Application
    Filed: April 21, 2003
    Publication date: October 21, 2004
    Inventors: Roger Auguste Daemen, Keith E. Moline
  • Patent number: 6793124
    Abstract: The present invention relates to a diffusion bonding target assembly of a high purity cobalt target and a copper alloy backing plate diffusion bonded with an aluminum or aluminum alloy having a thickness of 0.5 mm or more as the insert material. Provided is a diffusion bonding target assembly of a high-purity cobalt target and a copper alloy backing plate capable of effectively sputtering a high purity cobalt ferromagnetic target and which does not generate warping or peeling upon diffusion bonding even under severe conditions such as bonding with the backing plate and high power sputtering, and the manufacturing method thereof.
    Type: Grant
    Filed: September 23, 2002
    Date of Patent: September 21, 2004
    Assignee: Nikko Materials Company, Limited
    Inventors: Kazushige Takahashi, Hirohito Miyashita
  • Publication number: 20040166360
    Abstract: Hot press forming of a steel material is made possible by coating the surface of the steel material with a plated layer of zinc or a zinc alloy and forming thereon a barrier layer which prevents the vaporization of zinc even when heated to 700-1000° C. Corrosion resistance can also be guaranteed without requiring post treatment, and hot press forming of high tensile steel sheet and stainless steel sheet is made possible. The barrier layer is formed by forming an upper plated layer, by surface oxidation, by contact with an oxidizing agent, by contact with Zn and an oxidizing agent, by anodic electrolysis, by cathodic electrolysis, or by coating with a ZnO sol.
    Type: Application
    Filed: December 10, 2003
    Publication date: August 26, 2004
    Inventors: Kazuhito Imai, Tamotsu Toki, Yukihiro Yoshikawa, Masaru Takahashi, Toshinobu Nishibata, Nobusato Kojima
  • Patent number: 6749952
    Abstract: The tin-plated steel sheet includes a base steel sheet; a tin plating layer coating approximately more than 97.0% of the base steel sheet; and a chemical conversion coating having approximately 0.5 to 100 mg/m2 phosphorus and approximately 0.1 to 250 mg/m2 silicon formed on the tin plating layer and an unplated region corresponding to approximately less than 3.0%. The tin-plated steel sheet does not contain chromium which is harmful to the environment but has superior overcoat adhesion property, discoloration resistance, and rust resistance.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: June 15, 2004
    Assignee: JFE Steel Corporation
    Inventors: Tomofumi Shigekuni, Hisatada Nakakoji, Chiaki Kato
  • Patent number: 6746782
    Abstract: A barrier coating is disclosed, containing about 15 atom % to about 95 atom % chromium; and about 5 atom % to about 60 atom % of at least one of rhenium, tungsten, and ruthenium. Nickel, cobalt, iron, and aluminum may also be present. The barrier coating can be disposed between a metal substrate (e.g., a superalloy) and an oxidation-resistant coating, preventing the substantial diffusion of various elements at elevated service temperatures. A ceramic overcoat (e.g., based on zirconia) can be applied over the oxidation-resistant coating. Related methods for applying protective coatings to metal substrates are also described.
    Type: Grant
    Filed: June 11, 2001
    Date of Patent: June 8, 2004
    Assignee: General Electric Company
    Inventors: Ji-Cheng Zhao, Melvin Robert Jackson
  • Patent number: 6733871
    Abstract: A process for producing a ceramic member for bonding, which comprises: a first step of preparing a lower layer paste with the use of a first mixture comprising nickel, tungsten and molybdenum, applying the lower layer paste to a surface of a ceramic base which is a sintered ceramic, and drying the resultant coating layer to form a lower layer after the applying; a second step of preparing an upper layer paste with the use of a second mixture comprising one of nickel and nickel oxide and at least one of copper, copper oxide, manganese and manganese oxide, applying the upper layer paste to the lower layer, and drying the resultant coating layer to form an upper layer after the applying; and a third step of heating the lower layer and the upper layer to bake the lower layer and the upper layer.
    Type: Grant
    Filed: October 7, 2002
    Date of Patent: May 11, 2004
    Assignee: NGK Spark Plug Co., Ltd.
    Inventor: Yusuke Makino
  • Patent number: 6727007
    Abstract: A magneto-optical recording medium includes at least a reflective layer and a recording layer formed in this order on a substrate, in which record and reproduction of information are carried out by irradiating the medium with laser beam from a recording layer side. The reflective layer includes two or more thin film layers different in surface roughness, of which one near the substrate has a surface tension smaller than a surface tension of one near the recording layer. The medium exhibits a coercive force and CNR of a recording layer of a magneto-optical recording medium to realize high density recording by contriving the constitution of the recording layer.
    Type: Grant
    Filed: March 27, 2002
    Date of Patent: April 27, 2004
    Assignee: Fujitsu Limited
    Inventors: Takuya Kamimura, Tsutomu Tanaka, Koji Matsumoto
  • Publication number: 20040058190
    Abstract: A titanium article having improved corrosion resistance resulting from a direct or indirect attachment of a platinum group metal or alloy thereof or incorporation of this metal or alloy thereof into a minor surface portion of the article.
    Type: Application
    Filed: June 3, 2003
    Publication date: March 25, 2004
    Inventors: James S. Grauman, James G. Miller, Roy E. Adams
  • Patent number: 6709745
    Abstract: A method for effectively decreasing electromagnetic radiation by means of active absorbing material in a broad frequency band, preferably from 100 MHz-10 GHz, is provided wherein the material combines the desired shielding properties with the heat insulating properties of a porous material in addition to providing a favourable ratio between density and resistance. The method includes use of an absorber granulate which consists of a highly porous glass and/or ceramic granulate which is coated or filled with ferrite and/or an electrically conductive material.
    Type: Grant
    Filed: August 13, 2002
    Date of Patent: March 23, 2004
    Assignees: Hermsdorfer Institut Fuer Technische Karamik E.V., Colfirmit Rajasil GmbH & Co. KG
    Inventors: Josef Kuchler, Jan-Thomas Kuehnert, Klaus Kupfer, Stefan Rossmayer, Wolfgang Schoeps, Hans-Werner Zier
  • Patent number: 6710239
    Abstract: A solar cell includes electrodes coated with lead-free solder. This solar cell can provide satisfactory output characteristics and also does not cause lead pollution.
    Type: Grant
    Filed: January 8, 2002
    Date of Patent: March 23, 2004
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Satoshi Tanaka
  • Patent number: 6692833
    Abstract: The present invention is directed to a process for depositing at least one layer (3) based on tungsten and/or on molybdenum by chemical vapor deposition on a non-conductive substrate (1), such as glass, ceramic, glass-ceramic, or polymer, which includes providing at least one tungsten- and/or molybdenum-containing precursor in the form of a metal halide and/or of an organometallic compound, and at least one reducing agent, such as hydrogen or silane, to form the at least one metal layer. The present invention also relates to the substrate obtained by the preceding process and its applications, especially for producing a glazing, mirrors, or emissive screens.
    Type: Grant
    Filed: March 11, 2002
    Date of Patent: February 17, 2004
    Assignee: Saint-Gobain Vitrage
    Inventor: Georges Zagdoun
  • Publication number: 20040023020
    Abstract: The present invention relates to an overlay coating which has improved strength properties. The overlay coating comprises a deposited layer of MCrAlY material containing discrete nitride particles therein. The nitride particles are present in a volume fraction in the range of 0.1% to 15.0% and have a particle size in the range of from 0.1 microns to 10.0 microns. The coating may also have oxide particles dispersed therein.
    Type: Application
    Filed: August 5, 2002
    Publication date: February 5, 2004
    Inventors: Sudhangshu Bose, Daniel A. Bales, Mark T. Ucasz, Merritt W. Wight, Steven M. Burns, Tyrus E. Royal
  • Publication number: 20040013899
    Abstract: The target for the transparent conductive thin film having indium oxide as its major component and containing tungsten and/or molybdenum, obtained by forming a body of indium oxide powder, and tungsten oxide power and/or molybdenum oxide powder and then heating or sintering the formed body such that the thin film after sputtering has indium oxide as the main component and contains tungsten and/or molybdenum with an atomic ratio (W+Mo)/In of 0.0040 to 0.0470, whereby a transparent conductive thin film having excellent surface smoothness and low specific resistance of 6.0×10−4 &OHgr;·cm or less, and whose surface smoothness and specific resistance properties do not change even when heated at 170° C. is provided.
    Type: Application
    Filed: May 27, 2003
    Publication date: January 22, 2004
    Inventor: Yoshiyuki Abe
  • Publication number: 20040001965
    Abstract: A coated article, a coating for protecting an article, and a method for protecting an article are provided. The article comprises a metallic substrate and a substantially single-phase coating disposed on the substrate, wherein the coating comprises nickel (Ni) and at least about 30 atomic percent aluminum (Al); the coating further comprises a gradient in Al composition, the gradient extending from a first Al concentration level at an outer surface of the coating to a second Al concentration level at an interface between the substantially single-phase coating and the substrate, wherein the first Al concentration level is greater than the second Al concentration level and the second concentration level is at least about 30 atomic percent Al.
    Type: Application
    Filed: June 27, 2002
    Publication date: January 1, 2004
    Applicant: General Electric Company One Reserach Circle
    Inventors: Ji-Cheng Zhao, Don Mark Lipkin
  • Patent number: 6670050
    Abstract: Oxidation protection of a titanium heat exchanger is provided by a titanium aluminide or solgel coating. The coating protects bare titanium and brazed surfaces of the heat exchanger.
    Type: Grant
    Filed: June 5, 2001
    Date of Patent: December 30, 2003
    Assignee: Honeywell International Inc.
    Inventors: Derek Raybould, Paul Chipko, Matthew J. Pohlman
  • Patent number: 6652987
    Abstract: The present invention relates to a method for forming an article having a protective ceramic coating which reduces radiation heat transport through the ceramic coating. The protective ceramic coating includes one or more embedded reflective metallic layers for reducing the radiation heat transport. The method for forming the protective coating broadly comprises the steps of forming a ceramic coating on a substrate and embedding at least one reflective metallic layer within the ceramic coating.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: November 25, 2003
    Assignee: United Technologies Corporation
    Inventors: William P. Allen, William A. Veronesi, Robert J. Hall, Michael J. Maloney, John W. Appleby, Douglas C. Hague, Abdus Khan
  • Patent number: 6641929
    Abstract: An article protected by a protective coating includes a substrate made of a first nickel-base superalloy substrate material that is susceptible to the formation of a secondary reaction zone when overlaid by a diffusion aluminide coating or an aluminide overlay coating. A protective coating including a deposited coating at the substrate surface. The deposited coating is a second nickel-base superalloy different from the first nickel-base superalloy and which does not produce a secondary reaction zone when interdiffused with the first nickel-base superalloy. In one version, the deposited coating has a nominal composition, in weight percent, of about 3.1 percent cobalt, about 7.6 percent chromium, about 7.8 percent aluminum, about 5.45 percent tantalum, about 3.85 percent tungsten, about 1.65 percent rhenium, about 0.02 percent carbon, about 0.016 percent hafnium, about 0.015 percent boron, about 0.5 percent silicon, balance nickel and incidental impurities.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: November 4, 2003
    Assignee: General Electric Co.
    Inventors: Thomas Joseph Kelly, P. Kennard Wright, III
  • Publication number: 20030191354
    Abstract: The invention refers to a system having a substrate as carrier and a coating deposited on the substrate.
    Type: Application
    Filed: June 5, 2003
    Publication date: October 9, 2003
    Inventor: Udo Grabowy
  • Patent number: 6613452
    Abstract: A system and method for producing a corrosion-resistant article includes a metal substrate and a multi-layer resistant coating disposed over the metal substrate. The coating is operable to resist corrosion and hydrogen embrittlement of the metal substrate. The coating includes a first layer comprising a material galvanically similar to the metal substrate. The coating also includes a second layer disposed over the first layer. The second layer comprises a metal anodic to the metal substrate. The corrosion resistant article may also include a corrosion resistant interface layer at the boundary of the first and second layers. The interface layer may be formed by diffusing a portion of the second layer into the first layer.
    Type: Grant
    Filed: January 16, 2001
    Date of Patent: September 2, 2003
    Assignee: Northrop Grumman Corporation
    Inventor: John Douglas Weir
  • Patent number: 6610421
    Abstract: A spin electronic material exhibiting a spin-dependent electronic effect includes zincblende TE-VE, where TE stands for V, Cr or Mn and VE stands for As or Sb.
    Type: Grant
    Filed: September 7, 2001
    Date of Patent: August 26, 2003
    Assignee: National Institute of Advanced Industrial Science and Technology
    Inventors: Hiroyuki Akinaga, Masafumi Shirai, Takashi Manago
  • Publication number: 20030148138
    Abstract: A process for producing a ceramic member for bonding, which comprises: a first step of preparing a lower layer paste with the use of a first mixture comprising nickel, tungsten and molybdenum, applying the lower layer paste to a surface of a ceramic base which is a sintered ceramic, and drying the resultant coating layer to form a lower layer after the applying; a second step of preparing an upper layer paste with the use of a second mixture comprising one of nickel and nickel oxide and at least one of copper, copper oxide, manganese and manganese oxide, applying the upper layer paste to the lower layer, and drying the resultant coating layer to form an upper layer after the applying; and a third step of heating the lower layer and the upper layer to bake the lower layer and the upper layer.
    Type: Application
    Filed: October 7, 2002
    Publication date: August 7, 2003
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventor: Yusuke Makino
  • Patent number: 6599645
    Abstract: The invention relates to a rigid composite metal panel comprising at least two metal parallel plates and/or sheets secured to the peaks and troughs of a corrugated aluminium stiffener sheet arranged between the parallel plates and/or sheets, wherein the corrugated aluminium stiffener sheet is an aluminium brazing sheet product made from an aluminium brazing sheet product including a core sheet (1) made of an aluminium alloy having on at least one surface of the core sheet clad, and preferably on both sides, an aluminium clad layer (2), the aluminium clad layer being made of an aluminium alloy comprising silicon in an amount in the range of 2 to 18% by weight, preferably 5 to 14%, and a layer (3) comprising nickel on the outer surface of the aluminium clad layer. The invention further relates to a method of manufacturing thereof.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: July 29, 2003
    Assignee: Corus Aluminium Walzprodukte GmbH
    Inventor: Adrianus Jacobus Wittebrood
  • Patent number: 6587263
    Abstract: An method, and method of production thereof, which provides excellent performance, reduced cost, and reduced breakage due to reduced manual handling. The present invention comprises a substrate, a bond layer coating the substrate, a reflective layer coating the bond layer, and a radiative layer coating the reflective layer. Preferably, the radiative layer comprises SiO2, Si3N4 or SiOxNy, low absorbency of electromagnetic radiation having wavelengths of approximately 200 nm to approximately 2500 nm and high absorbency and emissivity electromagnetic radiation having wavelengths of approximately 2.5 &mgr;m to approximately 25 &mgr;m. Preferably, the bond layer comprises chromium, titanium, or titanium-tungsten and the substrate comprises aluminum, aluminum alloys, polyimide, carbon-filled polyimide, or carbon composite.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: July 1, 2003
    Assignee: Lockheed Martin Corporation
    Inventors: Charles Dominic Iacovangelo, Yiqun Pan, Chang Wei, Mao Chen
  • Patent number: 6576350
    Abstract: A hydride battery electrode is coated with palladium or a palladium alloy to improve hydride storage properties and recycle characteristics. A hydrogen purification membrane including a metallic substrate likewise has improved properties upon coating with palladium and a surface species of an alkali metal, alkaline earth element or alkaline earth cation. Novel metal hydrogen purification membranes include vanadium alloyed with at least 1 to 20 atomic percent nickel and/or 1 to 20 atomic percent cobalt and/or 1 to 20 atomic percent palladium.
    Type: Grant
    Filed: May 14, 2002
    Date of Patent: June 10, 2003
    Inventor: Robert E. Buxbaum
  • Patent number: 6572974
    Abstract: Changes in the infrared reflection spectrum of a thin film of silica-like resinous material sandwiched between metal electrodes can be induced by applying an electric potential to a top electrode which is semitransparent. Characteristic infrared absorption lines change in proportion to a small electric current flowing through the material. These changes occur with response times of the order of seconds, and show time constants of the order of minutes to reach stationary values.
    Type: Grant
    Filed: December 6, 1999
    Date of Patent: June 3, 2003
    Assignee: The Regents of the University of Michigan
    Inventors: Mark Angelo Biscotte, Mark Monroe Banaszak Holl, Bradford Grant Orr, Udo C. Pernisz
  • Publication number: 20030092957
    Abstract: The present invention is directed to a brachytherapy device comprising a substrate comprising at least one radioactive coating layer formed thereon. The radioactive coating layer has a total radioactivity that varies in at least one dimension of the device. Methods of making radioactive coatings, such as electrochemical deposition, electroless deposition and sol-gel are also disclosed. Suitable substrates include medical devices, such as catheters, stents, brachytherapy devices and guidewires, or components thereof. The disclosed methods produce medical devices capable of generating asymmetric, or targeted, radiation fields that correspond to the morphology of a tumor. Methods of using these devices to treat cancer of the breast, brain, prostate, uterine, head and neck are also disclosed.
    Type: Application
    Filed: April 2, 2002
    Publication date: May 15, 2003
    Inventors: Neal A. Scott, Janet M. Hampikian
  • Patent number: 6558814
    Abstract: A coating system having a low thermal conductivity, and a method by which the low thermal conductivity of the coating system is maintained through the development of cracks within a thermal-insulating layer of the coating system. The thermal-insulating layer is a mixture of two or more materials with different coefficients of thermal expansion (CTE). The materials of the thermal-insulating layer are selected and combined so that a low thermal conductivity is maintained for the coating system as the result of cracks developing and propagating from interfaces between the materials when the coating system is subjected to heating and cooling cycles.
    Type: Grant
    Filed: August 3, 2001
    Date of Patent: May 6, 2003
    Assignee: General Electric Company
    Inventors: Irene Spitsberg, Hongyu Wang
  • Publication number: 20030064244
    Abstract: A metallic component exposed to high temperature steam is provided with a coating comprising a thin primer layer deposited on the surface of the metallic component and a thicker overlay layer on top of the primer layer. The primer layer consists of highly ductile, oxidation resistant material such that it remains free of any defects over a long period of exposure. The overlay layer consists of an oxidation resistant, less ductile, and low-cost material. It protects the thin primer layer from mechanical damage and chemical degradation. The primer layer protects the base material of the metallic component from oxidizing steam that may penetrate through cracks of the overlay layer. Due to suitable choice of coating materials and thicknesses of the layers the coating is low-cost.
    Type: Application
    Filed: October 1, 2001
    Publication date: April 3, 2003
    Inventors: Richard Brendon Scarlin, Reinhard Knodler
  • Publication number: 20030054196
    Abstract: An abradable coating composition for use on shrouds in gas turbine engines (or other hot gas path metal components exposed to high temperatures) containing an initial porous coating phase created by adding a “fugitive polymer” (such as polyester or polyimide) to the base metal alloy, together with a brittle intermetallic phase such as &bgr;-NiAl that serves to increase the brittle nature of the metal matrix, thereby increasing the abradability of the coating at elevated temperatures, and to improve the oxidation resistance of the coating at elevated temperatures. Coatings having about 12 wt % polyester has been found to exhibit excellent abradability for applications involving turbine shroud coatings. An abradable coating thickness in the range of between 40 and 60 ml provides the best performance for turbine shrouds exposed to gas temperatures between 1380° F. and 1850° F.
    Type: Application
    Filed: May 24, 2001
    Publication date: March 20, 2003
    Inventors: Yuk-Chiu Lau, Farshad Ghasripoor, Dennis M. Gray, Chek Beng Ng
  • Patent number: 6534196
    Abstract: The present invention relates to articles, having an extended useful life, which are used in contact with high temperature molten aluminum or molten zinc baths. One aspect of the invention encompasses articles, such as bearings, bushings, couplings or rollers, used in contact with molten aluminum or molten zinc which is coated with a high density coating consisting of a metal selected from Groups Vb, VIb, or VIIb metals (preferably molybdenum or tungsten), in pure or alloyed form. These coatings generally have a thickness of from about 0.06 to about 0.30 inch. Another aspect of the present invention encompasses a roll for guiding steel strip through a high temperature aluminizing bath, which utilizes a multi-layer structure, the first primer layer being a Group Vb, VIb or VIIb metal, preferably tungsten or molybdenum (in pure or alloyed form), the second layer comprising MCrAlY in which M is either nickel or cobalt, and the third layer comprising a refractory metal oxide of Al, Zr, Si or Cr.
    Type: Grant
    Filed: February 26, 2001
    Date of Patent: March 18, 2003
    Assignee: Cincinnati Thermal Spray
    Inventor: Robert K. Betts
  • Patent number: 6531226
    Abstract: A multilayer brazeable metallization structure for diamond components is described. The brazeable metallization finds particular application for the attachment of diamond components such as heat spreaders in electronic packages that incorporate high power semiconductor devices. In the present invention, a diamond component is provided with a multilayer coating of metals including a first layer of chromium for adhesion, a second barrier layer of a refractory metal for a barrier that may be alloyed with chromium, and a top layer of copper, silver or gold for wetting. The refractory metals for the second layer include tungsten, molybdenum, tantalum and niobium. Tungsten or tungsten-chromium alloy is preferred as the second layer. This multilayer metallization structure provides a robust interface between diamond and standard brazing alloys which are used to join the diamond to electrical leads or a flange made of metals such as copper-tungsten.
    Type: Grant
    Filed: May 30, 2000
    Date of Patent: March 11, 2003
    Assignee: Morgan Chemical Products, Inc.
    Inventor: Ronald R. Petkie
  • Patent number: 6528189
    Abstract: In order to form a novel article of manufacture, a nickel or cobalt-based superalloy substrate is covered with a protective system resistant to thermal, corrosive and erosive attack. A bonding layer is disposed on the substrate and an anchoring layer on the bonding layer. The anchoring layer is formed as a nitride compound. The nitride compound is aluminum nitride in particular. A ceramic coating is disposed on the anchoring layer. The anchoring layer prevents transmission of diffusion active elements through the anchoring layer to the thermal barrier layer, reduces oxidation of layers therebelow and provides for good heat transmission therethrough.
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: March 4, 2003
    Assignee: Siemens Aktiengesellschaft
    Inventor: Wolfram Beele
  • Patent number: 6528177
    Abstract: An object of the present invention is to provide a cladding material, which has high joining strength and excellent productivity, and a manufacturing method therefor; in order to attain this object, the present invention provides a cladding material comprising: a first material to be joined which is made of aluminum or an aluminum alloy; a second material to be joined which is made of a single metal or an alloy and which is join the first material to be joined; and an intermediate layer which is provided between the first and second materials to be joined.
    Type: Grant
    Filed: October 29, 2001
    Date of Patent: March 4, 2003
    Assignees: Mitsubishi Heavy Industries, Ltd.
    Inventors: Takayuki Kawano, Yoshiaki Inoue, Katsuaki Inoue, Kawaichi Katsumi, Hiroshi Iwabuchi, Kazumasa Nishio, Shizuo Mukae, Masahiro Hirata
  • Publication number: 20030039857
    Abstract: The present invention describes the utilization of nanoscale bimetallic particles for the treatment of chlorinated contaminants in the environment, and more specifically, chlorinated contaminants in groundwater.
    Type: Application
    Filed: March 29, 2001
    Publication date: February 27, 2003
    Inventors: Wein-xian Zhang, Chuan-Bao Wang, Hsing-Lung Lien
  • Publication number: 20030008166
    Abstract: A method for forming a thermal barrier coating system on a turbine engine component includes forming a bondcoat on the turbine engine component and depositing a thermal barrier coating so as to overlie the bondcoat. The bondcoat is formed by thermally co-spraying first and second distinct alloy powders on the turbine engine component forming an oxidation-resistant region, and thermally spraying a third alloy powder on the oxidation-resistant region to form a bonding region.
    Type: Application
    Filed: October 30, 2001
    Publication date: January 9, 2003
    Inventors: Anthony Mark Thompson, Wayne Charles Hasz
  • Patent number: 6503640
    Abstract: Disclosed is a method of manufacturing an assembly of components joined by brazing, comprising the steps of: (i) forming the components of which at least one is made from a multi-layered brazing sheet product, the multi-layered brazing sheet product comprising a core sheet (a) having on at least one surface of the core sheet an aluminium clad layer (b), the aluminium clad layer being made of an aluminium alloy comprising silicon in an amount in the range of 2 to 18% by weight, a layer (c) comprising nickel on the outer surface of the aluminium clad layer, and a layer (d) comprising zinc or tin as a bonding layer between the outer surface of the aluminium clad layer and the layer comprising nickel; (ii) forming at least one other component of a metal dissimilar to the core sheet of the multi-layered brazing sheet product and selected from the group consisting of titanium, plated titanium, coated titanium, bronze, brass, stainless steel, plated stainless steel, coated stainless steel, low-carbon steel, plated
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: January 7, 2003
    Assignee: Corus Aluminium Walzeprodukte GmbH
    Inventors: Adrianus Jacobus Wittebrood, Jacques Hubert Olga Joseph Wijenberg
  • Publication number: 20030003319
    Abstract: A brass coated metallic wire for use as a reinforcing component in an elastomeric article, such as a motor vehicle tire. The brass coating is formed by depositing alternate layers of copper and zinc on the wire and then drawing the wire under conditions of temperature and pressure suitable to alloy the copper and zinc to form a brass coating on the wire.
    Type: Application
    Filed: July 25, 2002
    Publication date: January 2, 2003
    Applicant: Pirelli Pneumatici S.p.A., Viale Sarca
    Inventors: Siegfried Doujak, Federico Pavan, Andrea Pieralli
  • Publication number: 20020197502
    Abstract: A barrier coating is disclosed, containing about 15 atom % to about 95 atom % chromium; and about 5 atom % to about 60 atom % of at least one of rhenium, tungsten, and ruthenium. Nickel, cobalt, iron, and aluminum may also be present. The barrier coating can be disposed between a metal substrate (e.g., a superalloy) and an oxidation-resistant coating, preventing the substantial diffusion of various elements at elevated service temperatures. A ceramic overcoat (e.g., based on zirconia) can be applied over the oxidation-resistant coating. Related methods for applying protective coatings to metal substrates are also described.
    Type: Application
    Filed: June 11, 2001
    Publication date: December 26, 2002
    Inventors: Ji-Cheng Zhao, Melvin Robert Jackson
  • Publication number: 20020197501
    Abstract: Described is an article comprising a biaxially textured metal substrate and a layer of palladium deposited on at least one major surface of the metal substrate; wherein the palladium layer has desired in-plane and out-of-plane crystallographic orientations, which allow subsequent layers that are applied on the article to also have the desired orientations.
    Type: Application
    Filed: June 6, 2001
    Publication date: December 26, 2002
    Inventor: William B. Robbins
  • Publication number: 20020197507
    Abstract: A nickel base single crystal compliant layer on a ceramic blade has the capability to sustain high stresses and high operating temperature. Layers of nickel and platinum bonded on a single crystal superalloy over a sputtered gold-chromium layer support the high stress levels at elevated temperature without extrusion of the soft platinum or nickel layer and without destruction of an NiO compliant surface. The compliant layers have survived stress and temperature conditions without failure to the ceramic blade and the system can be stressed/heated and unloaded/cooled repeatedly without damage to the ceramic blades. A single crystal nickel base superalloy (i.e., SC180) has high strength properties at elevated temperature. Thin layers of chromium followed by gold are e-beam evaporated on one side of a polished surface of the alloy. Pure nickel is electroplated over this e-beam gold-chromium layer. Platinum is either electroplated or plated electrolessly over the nickel layer.
    Type: Application
    Filed: June 20, 2001
    Publication date: December 26, 2002
    Applicant: Honeywell International, Inc.
    Inventors: Dave Narasimhan, Alexander S. Kozlov, Margaret Eagan, Milton Ortiz
  • Publication number: 20020192494
    Abstract: A method for protecting low-carbon steel and stainless steel, and particularly high temperature stainless steel, from coking and corrosion at elevated temperatures in corrosive environments, such as during ethylene production by pyrolysis of hydrocarbons or the reduction of oxide ores, by coating the stainless steel with a coating of MCrAlXSiT in which M is nickel, cobalt, iron or a mixture thereof, X is yttrium, hafnium, zirconium, lanthanum, scandium or combination thereof, and T is tantalum, titanium, platinum, palladium, rhenium, molybdenum, tungsten, niobium, boron or combination thereof. A blended powder composition to produce a desired MCrAlXSiT surface alloy may be applied to the substrate. The overlay coating and stainless steel substrate preferably are heat-treated at about 1000 to 1200° C. for about 10 minutes or longer effective to metallurgically bond the overlay coating to the substrate and to form a multiphased microstructure.
    Type: Application
    Filed: May 22, 2002
    Publication date: December 19, 2002
    Inventors: Konstantin K. Tzatzov, Alexander S. Gorodetsky, Andrew Wysiekierski, Gary Anthony Fisher
  • Publication number: 20020189722
    Abstract: A turbine engine component includes a substrate and a wear coating on the substrate. The wear coating includes wear-resistant particles in a matrix phase, the wear-resistant particles being formed of chrome carbide or a cobalt alloy. Methods for forming a turbine engine component are also disclosed.
    Type: Application
    Filed: June 25, 2002
    Publication date: December 19, 2002
    Inventors: Wayne Charles Hasz, David Edwin Budinger
  • Patent number: 6488862
    Abstract: Copper can be pattern etched at acceptable rates and with selectivity over adjacent materials using an etch process which utilizes a solely physical process which we have termed “enhanced physical bombardment”. Enhanced physical bombardment requires an increase in ion density and/or an increase in ion energy of ionized species which strike the substrate surface. To assist in the removal of excited copper atoms from the surface being etched, the power to the ion generation source and/or the substrate offset bias source may be pulsed. In addition, when the bombarding ions are supplied from a remote source, the supply of these ions may be pulsed. Further, thermal phoresis may be used by maintaining a substrate temperature which is higher than the temperature of a surface in the etch chamber.
    Type: Grant
    Filed: October 27, 1999
    Date of Patent: December 3, 2002
    Assignee: Applied Materials Inc.
    Inventors: Yan Ye, Diana Xiaobing Ma, Gerald Yin
  • Patent number: 6475644
    Abstract: Radioactive coating solutions and sol-gels, and corresponding methods for making a substrate radioactive by the application of the radioactive coating solutions and sol-gels thereto. The radioactive coating solution comprises at least one carrier metal and a radioisotope, which may be soluble or insoluble, and may further comprise a reducing agent. The radioactive sol-gel comprises at least one metal alkoxide and a radioisotope, which may be soluble or insoluble. Methods of making a substrate radioactive by coating with radioactive coating solutions or sol-gels are also disclosed, including electrodeposition, electroless deposition, spin coating and dip coating. In a particular embodiment, the radioactive coating formed by the method is a composite coating. Radioactive substrates are also disclosed, comprising a substrate and one or more radioactive coatings, which coatings may be the same or different.
    Type: Grant
    Filed: August 31, 1999
    Date of Patent: November 5, 2002
    Assignee: Radiovascular Systems, L.L.C.
    Inventors: Janet M. Hampikian, Neal A. Scott