For Bare Metal Surface (e.g., Degreasing Composition, Etc.) Patents (Class 510/245)
  • Patent number: 6586380
    Abstract: This invention concerns a composition useful as a paint remover, comprising: alkylene carbonate such as propylene carbonate or ethylene carbonate, hydrogen peroxide, and water, and optionally an alcohol such as benzyl alcohol. In another broad respect, this invention concerns a process for removing paint, comprising: applying a composition containing alkylene carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint. In another broad respect, this invention is a composition useful as a paint remover, comprising: dialkyl carbonate, hydrogen peroxide, and water, optionally containing an alcohol, optionally containing a glycol ether. In another broad respect, this invention is a process for removing paint, comprising: applying a composition containing dialkyl carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint.
    Type: Grant
    Filed: February 1, 2002
    Date of Patent: July 1, 2003
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Edward T. Marquis, Robert E. Baldwin
  • Patent number: 6586366
    Abstract: Oil based emulsifiable concentrates include (a) at least one oil component; (b) at least one surfactant hydrocarboxyl saccharide, particularly a surfactant hydrocarbyl polysaccharide (HPS); and (c) at least one other non-ionic surfactant. The concentrates are typically homogeneous for at least 24 hours and emulsify readily on dilution into water. The concentrates preferably also include: (d) an antifoaming agent, especially a polysiloxane; and/or (e) at least one chemical agent specific to the intended use of the composition, such as an agrochemical, especially a herbicide, or a metal corrosion inhibitor. The concentrates can be diluted readily in water to give emulsion formulations which can be sprayed onto substrates, e.g. when the chemical agent is a herbicide, onto weeds.
    Type: Grant
    Filed: May 17, 1996
    Date of Patent: July 1, 2003
    Assignee: Imperial Chemical Industries Plc
    Inventors: Mahroussa Auda, Dirk Hoorne, Lodewijk Maria Rogiers
  • Patent number: 6583097
    Abstract: Versatile cleaning composition that has tremendous cleaning power, yet is compatible with many surfaces. For example, the cleaning composition easily cleans oil, grease, tar, and rubber from soiled surfaces, but does not damage metals, vehicle paints, concrete, plastics such as polycarbonate, MYLAR polyester and silicone sealants, wood, ceramic, and the like. The cleaning composition includes an oil solubilizing amount of a degreaser, a rubber solubilizing amount of a rubber solvent, and a polar, organic diluent. In preferred embodiments, the degreaser comprises a glycol ether, the rubber solvent comprises an nonaromatic naphtha, and the diluent comprises an alcohol, preferably a C2 to C5 alcohol.
    Type: Grant
    Filed: January 19, 2001
    Date of Patent: June 24, 2003
    Inventor: Mary E. McDonald
  • Patent number: 6579377
    Abstract: The present invention relates to compositions, kits and processes for the brightening of metal surfaces by the application of the chemical compositions. These compositions act to release hydrofluoric acid as a brightening agent. The solutions are preferably mixed during application of the brightening composition to a metal surface by mixing the solutions immediately prior to or even during application of the solution. This can be readily accomplished by mixing two solutions, one having a fluoride source and the other having a strong acid to release hydrofluoric acid from the fluoride source, the mixing occurring immediately before spray application, during spraying, or immediately after spraying of the two solutions. Mixing may be done on-site, which means that mixing is performed at the site of use, usually on the same day of use or even within a few (less than 10) minutes of use.
    Type: Grant
    Filed: August 26, 2002
    Date of Patent: June 17, 2003
    Assignee: Ecolab Inc.
    Inventors: Guang-jong Jason Wei, David Daniel McSherry, Mark D. Levitt
  • Patent number: 6576600
    Abstract: To provide a detergent which does not comprise a halogen-based solvent having high cleaning capabilities. The detergent of the present invention comprises (A) a glycol ether having low compatibility with water, preferably propylene glycol alkyl ether having a solubility in water at 60° C. of 50 vol % or less, (B) an imidazolidinone compound represented by the following formula (I): wherein R1 and R2 are each independently a methyl group or ethyl group, and (C) water, and forms a homogeneous phase.
    Type: Grant
    Filed: May 24, 2001
    Date of Patent: June 10, 2003
    Assignee: Tokuyama Corporation
    Inventors: Tetsuo Imai, Satoshi Mochizuki
  • Patent number: 6564812
    Abstract: A two carbon atom linkage alkanolamine compound composition comprises the two carbon atom linkage alkanolamine compound, gallic acid or catechol, and optionally, an aqueous hydroxylamine solution. The balance of the composition is made up of water, preferably high purity deionized water, or another suitable polar solvent. A process for removing photoresist or other residue from a substrate, such as an integrated circuit semiconductor wafer including titanium metallurgy, comprises contacting the substrate with the composition for a time and at a temperature sufficient to remove the photoresist or other residue from the substrate. Use of the two carbon atom linkage alkanolamine compound in the composition and process provides superior residue removal without attacking titanium or other metallurgy, oxide or nitride layers on the substrate.
    Type: Grant
    Filed: June 4, 2002
    Date of Patent: May 20, 2003
    Assignee: EKC Technology, Inc.
    Inventor: Wai Mun Lee
  • Patent number: 6566321
    Abstract: A low-foaming, liquid composition is disclosed. Methods of making and using the low-foaming, liquid composition are also disclosed.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: May 20, 2003
    Assignee: Kay Chemical, Inc.
    Inventors: Joseph T. Thekkekandam, Frank Lama
  • Patent number: 6562779
    Abstract: Emulsifiable ethylene polymers comprising copolymers of from 90 to 95% by weight of ethylene, from 4 to 10% by weight of one or more C3-C12 alkenecarboxylic acids, and from 0 to 1.2% by weight of one or more tertiary esters of the corresponding C3-C12 alkenecarboxylic acids, where the wax has a cinematic melt viscosity of from 800 to 3000 mm2/s, measured at 120° C.; and a process for preparing the novel emulsifiable ethylene polymers, emulsions comprising the novel ethylene polymers, a process for preparing the emulsions from the novel ethylene polymers, and also floor cleaners, car cleaners, leather cleaners and stone cleaners, and coatings for surfaces made from wood, metal, paper, glass or from plastics, comprising aqueous emulsions of the novel emulsifable waxes.
    Type: Grant
    Filed: February 14, 2001
    Date of Patent: May 13, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Lars Wittkowski, Andreas Deckers, Wilhelm Weber, Stefan Weiss, Michael Ehle, Siegfried Gast
  • Patent number: 6554908
    Abstract: Process for pickling stainless steel carried out at a temperature of between 20° and 70° C., with the use of a pickling solution containing the following basic ingredients: H2SO4 (free acid): 50 to 200 g/l HF (free acid): 0 to 60 g/l F− anion (total): 5 to 150 g/l SO42− anion (total): 50 to 350 g/l Total free acidity (H2SO4+HF): between 1 and 7 g. equiv./l where by “free acid” is meant the acid that does not constitute the anion bound in the form of salts or complexes with the metal cations present in the solution; and, in addition: Fe3+ in a quantity of at least 15 g/l chloride anion in a quantity of between 0.1 and 10 g/l, into which solution is fed, during the pickling process, an oxidant that is able to oxidize Fe2+ to Fe3+ in order to maintain the redox potential of the solution at a value of between +230 and +800 mV.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: April 29, 2003
    Assignees: Henkel Kommanditgesellschaft auf Aktien, Acciai Speciali Terni S.p.A.
    Inventors: Dario Negri, Paolo Bruno Giordani
  • Patent number: 6554912
    Abstract: Compositions for the removal of polymeric material from a substrate are provided where the compositions include a polyol compound selected from (C3-C20)alkanediols, substituted (C3—C20)alkanediols, (C3-C20)alkanetriols or substituted (C3-C20)alkanetriols, a glyco ether, at least 5% wt water based on the total weight of the composition, and a fluoride salt selected from ammonium fluoride, ammonium bifluoride, ammonium-tetramethylammonium bifluoride or mixtures thereof. Methods of removing polymeric material using these compositions are also provided.
    Type: Grant
    Filed: August 2, 2001
    Date of Patent: April 29, 2003
    Assignee: Shipley Company, L.L.C.
    Inventor: Javad J. Sahbari
  • Patent number: 6551411
    Abstract: A detergent composition useful for cleaning away a resin remaining in a molding machine after molding, comprising a thermoplastic resin, water and wollastonite.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: April 22, 2003
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Mikihiko Ito, Noriko Yamauchi
  • Patent number: 6546939
    Abstract: A composition for removal of chemical residues from metal or dielectric surfaces or for chemical mechanical polishing of a copper or aluminum surface is an aqueous solution with a pH between about 3.5 and about 7. The composition contains a monofunctional, difunctional or trifunctional organic acid and a buffering amount of a quaternary amine, ammonium hydroxide, hydroxylamine, hydroxylamine salt, hydrazine or hydrazine salt base. A method in accordance with the invention for removal of chemical residues from a metal or dielectric surface comprises contacting the metal or dielectric surface with the above composition for a time sufficient to remove the chemical residues. A method in accordance with the invention for chemical mechanical polishing of a copper or aluminum surface comprises applying the above composition to the copper or aluminum surface, and polishing the surface in the presence of the composition.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: April 15, 2003
    Assignee: EKC Technology, Inc.
    Inventor: Robert J. Small
  • Patent number: 6548471
    Abstract: A process for removing contaminants from the surface of a substrate comprises contacting the substrate with a cleaning composition comprising at least one mono-, di-, or trialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms. The compounds exhibit good solvency properties while being environmentally acceptable.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: April 15, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Richard M. Flynn, George G. I. Moore
  • Patent number: 6548464
    Abstract: A composition useful as a paint remover, including alkylene carbonate such as propylene carbonate or ethylene carbonate, and an alcohol such as benzyl alcohol. Also, a process for removing paint, comprising: applying a composition containing alkylene carbonate and an alcohol to a painted surface for a time and under conditions effective to reduce adhesion between the top coats and the primer or undercoat of the paint. In another aspect, this paint remover includes dialkyl carbonate and an alcohol, optionally containing a glycol ether. In another aspect, the process includes applying a composition containing dialkyl carbonate and an alcohol. This paint remover may include a thickener, a surfactant, or a corrosion inhibitor.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: April 15, 2003
    Assignee: Huntsman Petrochemical Corporation
    Inventors: James R. Machac, Jr., Edward Chung-Yit Nieh, Susan A. Woodrum, Edward T. Marquis
  • Publication number: 20030069152
    Abstract: The present invention is good for complex cleaning and degreasing agent which can save energy, and can shorten the cleaning time and show good cleaning and degreasing proficiency without changing the systems being used, and impairing the raw materials. The present invention is also for cleaning and degreasing agent that maintains the best alkalinity and can be used according to each characteristics of process, without being restrained under the scope of available temperature. The present invention includes the surfactant and alkaline builder of the below formula 1: R—O—(CH2CH2O)m-H. formula 2, formula 3: R-Ph-O—(CH2CH2O)-m-H, and formula 4: R-Ph-SO3−M+. Wherein, from 1 to formula 4 R is alkyl group of which carbon number is 3-19, Ph is phenyl group, m is 1.5-12 mol for formula 1 and 2, and 13-19 moles for formula 3, n is 2-15 mol, and M is counter ion.
    Type: Application
    Filed: August 9, 2002
    Publication date: April 10, 2003
    Inventor: Dai-Uk Kim
  • Patent number: 6544349
    Abstract: A method is provided for in situ cleaning of lubricated parts of a machine in which the machine is operated with a lubricating fluid that contains an effective concentration of a cleaning composition comprising a synthetic ester of a naturally occurring fatty acid for an amount of time sufficient to remove from the lubricated parts adhered debris which is not removed by the lubricating fluid conventionally used in the machine.
    Type: Grant
    Filed: November 16, 2000
    Date of Patent: April 8, 2003
    Assignee: The Fanning Corporation
    Inventors: Donald R. Donahue, Frank J. Miller
  • Patent number: 6541442
    Abstract: The present invention relates to a clear and stable, highly alkaline composition with controlled foaming, containing a high amount of surface active nonionic alkylene oxide adduct and a hexyl glycoside as a hydrotrope. This composition has a very good wetting and cleaning ability and can be used for cleaning of hard surfaces, in a mercerization process and for a cleaning, desizing or scouring process of fibres and fabrics.
    Type: Grant
    Filed: May 1, 2000
    Date of Patent: April 1, 2003
    Assignee: Akzo Nobel N.V.
    Inventors: Ingegard Johansson, Bo Karlsson, Christine Strandberg, Gunvor Karlsson, Karin Hammarstrand
  • Patent number: 6541435
    Abstract: Engine cleaner compositions are reported comprising a single phase solution comprising a polar solvent having a Hildebrand solubility parameter of about 10 cal½ cm−3/2 or greater; a non-polar solvent, immiscible with the polar solvent, having a Hildebrand solubility parameter of about 10 cal½ cm−3/2 or less; and a fugitive cosolvent having a higher evaporation rate than the polar solvent and the non-polar solvent. The engine cleaner compositions are suitable for cleaning internal combustion engines.
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: April 1, 2003
    Assignee: 3M Innovative Properties Company
    Inventor: Kenneth G. Gatzke
  • Patent number: 6537957
    Abstract: The present invention describes liquid acidic cleaning compositions suitable for cleaning bathroom surfaces comprising a homo- or copolymer or vinylpyrrolidone, or a mixture thereof, a polysaccharide polymer, or a mixture thereof, an anionic surfactant, and an acid. These compositions deliver improved shine to the treated surface as well as improved next-time cleaning benefit on said surface.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: March 25, 2003
    Assignee: The Procter & Gamble Company
    Inventors: Sergio Cardola, Panos Iakovides, Laura Orlandini, Maria Rosa Rescio
  • Patent number: 6528478
    Abstract: To provide a cleaner composition suitable for removing oxidized grease stains adhering to the surface of floor, wall and cooking instruments in the kitchen. A cleaner composition is constructed to have the concentrated form and comprise a water-insoluble organic solvent, amines and a nonionic amine oxide-based surfactant.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: March 4, 2003
    Inventor: Takatushi Totoki
  • Patent number: 6528468
    Abstract: The present invention relates to a pickling agent for the chemical conversion coating of a heat exchanger which is capable of cleaning the complicated structure comprising fins and tubes of a heat exchanger in preparation for the successful formation of a chemical conversion film, a method of pickling a heat exchanger, a method of treating a heat exchanger comprising said pickling method, and a heat exchanger produced by using said treating method. The present invention provides pickling agent for the chemical conversion coating of a heat exchanger which comprises an acidic aqueous solution containing nitric acid and/or sulfuric acid and at least one metal and/or metal oxoanion salt derived from any metal selected from the group consisting of iron, nickel, cobalt, molybdenum and cerium.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: March 4, 2003
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Masahiko Matsukawa, Kentaro Saito, Toshio Inbe, Kasuyoshi Yamasoe
  • Patent number: 6525010
    Abstract: A composition for adding to an aqueous rinse which is applied to a ferrous metal surface after treatment of the ferrous metal surface with an aqueous acid solution is disclosed. The composition includes a base. The base is present in the composition in an amount sufficient to adjust the pH of the aqueous rinse to a value greater than 7.0 after the composition is added to the aqueous rinse. The composition also includes a salt of gluconic acid. The composition further includes a polyquaternium compound. An associated method for inhibiting stain formation on a ferrous metal surface is also disclosed.
    Type: Grant
    Filed: July 23, 2002
    Date of Patent: February 25, 2003
    Assignee: Crown Technology, Inc.
    Inventors: Joseph C. Peterson, Darren R. Bowman, Tucker D. Maurer
  • Patent number: 6524392
    Abstract: Cleaning compositions which, as powder or as aqueous formulation based on sodium bicarbonate, sodium chloride and/or sugar, comprise a water-soluble polymeric polycarboxylate as dispersant with the exception of those formulations containing only sodium bicarbonate and polyaspartic acids and/or their salts, to the use of these cleaning compositions for the abrasive cleaning of hard surfaces. A method for cleaning surfaces contaminated with deposits using these cleaning compositions.
    Type: Grant
    Filed: March 14, 2000
    Date of Patent: February 25, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Joachim Traenckner, Hartwig Wendt, Thomas Menzel
  • Publication number: 20030035824
    Abstract: A treated substrate with improved availability of a beneficial component for transfer to a target surface and methods for making the same are described. The substrate has a contacting surface with a beneficial component that is transferred from the contacting surface to a target surface during use of the article. The beneficial component is applied to the article in such a way as to “Top-Bias” the component on or near the contacting surface of the article.
    Type: Application
    Filed: June 29, 2001
    Publication date: February 20, 2003
    Applicant: The Procter & Gamble Company
    Inventors: Olaf Isele, Joseph Anthony Gatto, Thomas James Klofta, Matthew Gerald McNally, Julie Charlene Rule, James Anthony Staudigel, Kirsten Kae Stone, Sherman Lee Taylor
  • Patent number: 6521579
    Abstract: A cleaning corrosion inhibitor based on N-alkyl-beta-alanine derivatives and their salts.
    Type: Grant
    Filed: August 24, 2001
    Date of Patent: February 18, 2003
    Assignee: Goldschmidt AG
    Inventors: Michael Richter, Thorsten Kröller
  • Publication number: 20030032572
    Abstract: The present invention is directed to a process for reducing the passive layer on a metal. The process includes reacting a treatment composition having a non-metallic compound with metal ions in the passive layer of a metal, thereby forming an organometallic complex precipitate, and removing the organometallic complex precipitate. In one embodiment the non-metallic compound is a thiuram. In another embodiment, the treatment composition further includes a non-metallic compound that is a dithiocarbamate.
    Type: Application
    Filed: August 1, 2002
    Publication date: February 13, 2003
    Inventor: Peter Morton
  • Patent number: 6514922
    Abstract: Methods for cleaning screw extruder, especially powder-coating extruders, include filling the extruder barrel with a gel purge formulation comprised of a high-boiling pyrrolidone or piperidone (lactam) solvent (most preferably N-methyl pyrrolidone (NMP)), thickened with 5-50 wt. % of a thermoplastic resin thickening agent, most preferably polystyrene (PS). Once the extruder barrel is filled with the gel purge formulation, the screws are stopped and the gel allowed to soak for between about 10 to about 30 minutes. The screws are then restarted and the gel is discharged from the extruder. Immediately after the gel purge formulation exits the machine, a small amount of a thermoplastic “rinse” polymer (e.g., polyethylene) may be added so as to remove any vestigial amount of the gel purge formulation therefrom.
    Type: Grant
    Filed: April 25, 2002
    Date of Patent: February 4, 2003
    Assignee: BASF Corporation
    Inventor: Mark W. Waldrop
  • Patent number: 6511950
    Abstract: A cleaning composition for treating and removing stains from a non-porous surface has one or more salts, such as quaternary ammonium salts, sulfates and chlorides, a chelator and a dispersant, dissolved in an aqueous solution of alcohol. Optional active ingredients include methyl cellosolve and ammonia. The quaternary ammonium salts are myristyltrimethylammonium bromide and benzethonium chloride, the chelator is tetrasodium salt ethylenediamine of tetraacetic acid, and the dispersant is polyvinyl alcohol. The cleaning composition is incorporated into a product, which has a non-woven polyester carrier impregnated with the cleaning composition.
    Type: Grant
    Filed: July 30, 2002
    Date of Patent: January 28, 2003
    Inventor: Earl Jenevein
  • Patent number: 6509309
    Abstract: A process for removing contaminants from the surface of a substrate comprises contacting the substrate with a cleaning composition comprising at least one mono-, di-, or trialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms. The compounds exhibit good solvency properties while being environmentally acceptable.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: January 21, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Richard M. Flynn, George G. I. Moore, John G. Owens
  • Patent number: 6506459
    Abstract: A process for removing contaminants from the surface of a substrate comprises contacting the substrate with a cleaning composition comprising at least one mono-, di-, or trialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms. The compounds exhibit good solvency properties while being environmentally acceptable.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: January 14, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Richard M. Flynn, Mark W. Grenfell, George G. I. Moore, John G. Owens
  • Patent number: 6506715
    Abstract: An automobile wash and wax composition suitable for simultaneously washing and waxing a soiled exterior surface of a vehicle without buffing. The automotive wash and wax composition being an aqueous emulsion containing an anionic surfactant, a silicone oil, an amino-functional silicone, a wax, and a cationic emulsifier. The wash and wax composition is applied to a pre-wetted exterior surface of a vehicle so as to substantially coat the surface of the vehicle that requires cleaning and polishing. After the coated surface has substantially dried, the surface is washed with a sufficient quantity of water to rinse away the soil particles and the residue of the anionic surfactant, leaving behind a durable, evenly distributed, high-gloss, water resistant protective film of silicones and wax on the vehicle surface, without any buffing of the surface.
    Type: Grant
    Filed: January 10, 2002
    Date of Patent: January 14, 2003
    Assignee: Turtle Wax, Inc.
    Inventors: Michael A. Schultz, Denis John Healy
  • Patent number: 6503880
    Abstract: The present invention relates to cationic sugar surfactants with improved biodegradability that can be used as hydrotropes for surfactants, especially for nonionic alkylene oxide adducts in alkaline solutions, and as cleaners for hard surfaces. The cationic sugar surfactants contain at least one hydrocarbon group with 6-24 carbon atoms and at least one quaternary ammonium group where at least one substituent is an alkyleneoxy containing group which is connected to a saccharide residue by a glycosidic bond. They are obtained from ethoxylated quaternary ammounium compounds and reducing saccharides or alkyl glycosides.
    Type: Grant
    Filed: June 20, 2002
    Date of Patent: January 7, 2003
    Assignee: Akzo Nobel N.V.
    Inventors: Rolf Skold, Bodil Gustavsson
  • Publication number: 20030004080
    Abstract: A long-time stable pickling agent for the removal of an oxide layer on a stainless steel after heat treatment, such as welding, which pickling agent comprises nitric acid and fillers and constitutes of a pickling paste or pickling gel to be coated on the heat treated stainless steel, or of a pickling liquid to be sprayed on the steel. According to the invention, the pickling agent also comprises urea for reduced formation of nitrous fumes when the pickling agent is used.
    Type: Application
    Filed: June 26, 2002
    Publication date: January 2, 2003
    Inventors: Sven-Eric Lunner, Fredrik Hagg
  • Patent number: 6492308
    Abstract: A cleaning solution for cleaning microelectronic substrates, particularly for post-CMP or via formation cleaning. The cleaning solution comprises a quaternary ammonium hydroxide, an organic amine, a corrosion inhibitor, and water. A preferred cleaning solution comprises tetramethylammonium hydroxide, monoethylanolamine, ascorbic acid, and water with the alkalinity of the cleaning solution greater than 0.073 milliequivalents base per gram of solution.
    Type: Grant
    Filed: June 6, 2000
    Date of Patent: December 10, 2002
    Assignee: ESC, Inc.
    Inventors: Shahriar Naghshineh, Jeff Barnes, Dingying Xu
  • Patent number: 6492311
    Abstract: An ethylenediaminetetraacetic acid or a mono- di- tri- or tetraammonium salt thereof residue cleaning composition removes photoresist and other residue from integrated circuit substrates. The balance of the composition is desirably made up of water, preferably high purity deionized water, or another suitable polar solvent. A process for removing photoresist or other residue from a substrate, such as an integrated circuit semiconductor wafer including titanium metallurgy, comprises contacting the substrate with the composition for a time and at a temperature sufficient to remove the photoresist or other residue from the substrate. Use of the ethylenediaminetetraacetic acid or a mono- di- tri- or tetraammonium salt thereof in the composition and process provides superior residue removal without attacking titanium or other metallurgy, oxide or nitride layers on the substrate.
    Type: Grant
    Filed: April 4, 1997
    Date of Patent: December 10, 2002
    Assignee: EKC Technology, Inc.
    Inventors: Wai Mun Lee, Zhefei Jessie Chen
  • Publication number: 20020183224
    Abstract: A composition for adding to an aqueous rinse which is applied to a ferrous metal surface after treatment of the ferrous metal surface with an aqueous acid solution is disclosed. The composition includes a base. The base is present in the composition in an amount sufficient to adjust the pH of the aqueous rinse to a value greater than 7.0 after the composition is added to the aqueous rinse. The composition also includes a salt of gluconic acid. The composition further includes a polyquaternium compound. An associated method for inhibiting stain formation on a ferrous metal surface is also disclosed.
    Type: Application
    Filed: July 23, 2002
    Publication date: December 5, 2002
    Applicant: Crown Technology, Inc.
    Inventors: Joseph C. Peterson, Darren R. Bowman, Tucker D. Maurer
  • Patent number: 6489276
    Abstract: The present invention concerns a composition and a method for cleaning instruments and the like. More particularly, it is concerned with compositions for removal of body fluid from surgical instruments and other surfaces such as operating tables and instrument trays.
    Type: Grant
    Filed: March 12, 2001
    Date of Patent: December 3, 2002
    Assignee: Ebiox Limited
    Inventor: Anthony Marston Gibbs
  • Patent number: 6489281
    Abstract: A cleaning composition is provided according to the invention. The cleaning composition includes a product of mixing an acid component, a source of phosphoric acid component, and an oxidant component. The molar ratio of oxidant component to phosphoric acid component is preferably between about 2:1 and about 1:2, and the molar ratio of oxidant component to acid component is preferably between about 1:3 and about 1:5. A method of cleaning an aluminum surface is provided. The method includes a step of applying the cleaning composition to an aluminum surface, and rinsing the cleaning composition from the aluminum surface.
    Type: Grant
    Filed: September 12, 2000
    Date of Patent: December 3, 2002
    Assignee: Ecolab Inc.
    Inventors: Kim R. Smith, Robert D. P. Hei, Michael E. Besse, Jerry D. Hoyt
  • Patent number: 6478880
    Abstract: Multi-component compositions comprising as a first component a fluorinated compound, as a second component a fluorinated aromatic compound and a third component comprising an alkane are disclosed. These compositions can be formulated to provide single phase systems which serve as effective solvents for fluorinated oils as well as petroleum oils. The compositions can serve as solvent cleaners or can be combined directly with oils to provide a delivery system for the oil.
    Type: Grant
    Filed: March 26, 2001
    Date of Patent: November 12, 2002
    Assignee: Henkel Loctite Corporation
    Inventor: Gary K. Shank
  • Patent number: 6475296
    Abstract: The present invention relates to a degreasing composition, to a liquid, to a gel and to a degreasing foam which comprise said composition. The composition according to the invention comprises a base, a polyethoxylated fatty alcohol, saturated or unsaturated, a copolymer of ethylene oxide and propylene oxide, and water. The invention also relates to a degreasing and/or decontamination process of a surface using said composition, said liquid, said gel, and/or said degreasing foam.
    Type: Grant
    Filed: January 25, 2001
    Date of Patent: November 5, 2002
    Assignees: Electricite de France, Commissariat A l'Energie Atomique, Compagnie Generale des Matieres Nucleaires
    Inventors: Jean-Paul Gauchon, Jacques Delagrange, Maria Faury, Bruno Fournel
  • Patent number: 6468357
    Abstract: A method for removing a ruthenium-containing metal includes the step of applying a remover to a semiconductor substrate. The remover includes a cerium (IV) nitrate salt and nitric acid.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: October 22, 2002
    Assignee: NEC Corporation
    Inventors: Hidemitsu Aoki, Kaori Watanabe, Norio Ishikawa, Kiyoto Mori
  • Patent number: 6455483
    Abstract: A well stimulation and purging composition which is typically used in well cleanup, well stimulation and formation purging applications for enhancing oil and gas production. The composition is a cationic surfactant characterized by a homogenous aqueous solution of a coco diamine amido benzyl chloride type quaternary compound, phosphate chelator/ester, isopropanol anhydrous, ammonium bisulfide, and potassium chloride or a clay stabilizer formulation, and aids in extracting water and condensate from wells and dissipates, disperses and retards bacterial growth and buildup of iron sulfide, iron oxide, calcium and salt. The composition is applied to the wells in order to clear the water and condensate and significantly enhance total well production by chelating minerals such as salt, iron and calcium; retarding bacterial growth; and flocculating and foaming the water, condensate and solids from the well.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: September 24, 2002
    Inventor: Charles C. Carey
  • Patent number: 6454870
    Abstract: A chromium oxide coating is removed from a surface of an article by cleaning the article in an alkaline degreasing/rust removal solution at a degreasing/rust removal temperature of from about 180° F. to about 200° F., scale conditioning the article in an alkaline permanganate conditioning solution at a scale-conditioning temperature of from about 160° F. to about 200° F., and contacting the article to an acidic stripping solution comprising hydrochloric acid and an etching inhibitor at a stripping temperature of from about 130° F. to about 140° F.
    Type: Grant
    Filed: November 26, 2001
    Date of Patent: September 24, 2002
    Assignee: General Electric Co.
    Inventor: William Clarke Brooks
  • Patent number: 6455486
    Abstract: Cleaning formulations and methods are provided by which solid deposition is inhibited on hydrophobic hard surfaces typically encountered in bathroom and outdoor environments without detrimentally affecting the appearance of such surfaces. The formulations most preferably include an aqueous mixture of an organically solvated nonionic copolymer, a polyacrylic acid homopolymer and a nonionic surfactant. Optionally, a hydrotrope may also be present in the formulation. Most preferably, the formulations of this invention have a pH between about 4.0 to about 7.0, most preferably around neutral (i.e., about 7.0).
    Type: Grant
    Filed: October 31, 2000
    Date of Patent: September 24, 2002
    Assignee: BASF Corporation
    Inventors: Charles O. Kerobo, Michael C. Welch, Richard J. Holland, Sonia J. Patterson, Suzanne M. Gessner
  • Patent number: 6450183
    Abstract: A composition and apparatus and method of using the composition for aqueous spray descaling or conditioning of scale or oxide on metal surfaces, especially stainless steel strip or the like, in one embodiment, although it can be used to descale or condition oxide or scale on other work pieces such as metal bar, or even discrete objects. An aqueous solution having a base composition of an alkali metal hydroxide, such as sodium hydroxide, potassium hydroxide, or a mixture of alkali metal hydroxides such as sodium hydroxide and potassium hydroxide is used. The aqueous solution may contain certain additives to improve the descaling performance of the salt. In one embodiment, the solution is used to condition the scale or surface oxide on a strip of stainless steel. The strip of steel is at a temperature between the melting point of the alkali metal hydroxide in anhydrous form and a temperature at which the Leidenfrost effect appears.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: September 17, 2002
    Assignee: Kolene Corporation
    Inventors: John M. Cole, James C. Malloy, John F. Pilznienski, William G. Wood
  • Patent number: 6448211
    Abstract: A composition for adding to an aqueous rinse which is applied to a ferrous metal surface after treatment of the ferrous metal surface with an aqueous acid solution is disclosed. The composition includes a base. The base is present in the composition in an amount sufficient to adjust the pH of the aqueous rinse to a value greater than 7.0 after the composition is added to the aqueous rinse. The composition also includes a salt of gluconic acid. The composition further includes a polyquaternium compound. An associated method for inhibiting stain formation on a ferrous metal surface is also disclosed.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: September 10, 2002
    Assignee: Crown Technology, Inc.
    Inventors: Joseph C. Peterson, Darren R. Bowman, Tucker D. Maurer
  • Patent number: 6448209
    Abstract: Low VOC content brake cleaner compositions useful for removing oil and particulate contamination from braking system components of vehicles such as automobiles are reported. The brake cleaner compositions comprise about 5% to about 30% by weight methyl acetate; about 25% to about 50% of a hydrocarbon according to the formula CnH2n+x, where n is 5 to 8 and x is 0 or 2; and about 25% to about 55% by weight acetone.
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: September 10, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Ken G. Gatzke, Christine A. Sobon
  • Patent number: 6440917
    Abstract: Problems of extensive foaming and/or of sticky deposits on process equipment that often arise when metal soaps from metal articles that have been given a metal soap containing surface to aid in drawing are removed with aqueous alkaline clearners can be avoided by including in the cleaners used anions such as calcium and magnesium that are capable of precipitating the anions of the metal soaps. The cleaners advantageously also contain chelants, a mixture of nonionic and anionic surfactants, and phosphorus containing anions. Anions from the metal soaps are eventually precipitated from the cleaners used as non-sticky sludge that can be easily separated from the cleaners.
    Type: Grant
    Filed: April 27, 2000
    Date of Patent: August 27, 2002
    Assignee: Henkel Corporation
    Inventors: Richard J. Church, Kenneth J. Hacias
  • Patent number: 6440224
    Abstract: A method of treating a surface of a metal is provided. A source of fluoride ion is mixed with a source of acid to form hydrofluoric acid and, when applied to a metal surface to be treated, the hydrofluoric acid acts as a brightening agent.
    Type: Grant
    Filed: March 15, 1999
    Date of Patent: August 27, 2002
    Assignee: Ecolab Inc.
    Inventors: Guang-jong Jason Wei, David Daniel McSherry, Mark D. Levitt
  • Patent number: 6440919
    Abstract: The present invention relates to an aqueous based, solvent free degreaser composition, comprising a blend of two nonionic surfactants selected from, alcohol alkoxylate with a fatty alcohol moiety alkoxlyate, fatty alkoxlyated alcohol, fatty alcohol having oxyethylate moieties, polyoxyalkylene block copolymers, and alkyl phenol alkoxylate.
    Type: Grant
    Filed: June 26, 2000
    Date of Patent: August 27, 2002
    Assignee: BASF Corporation
    Inventors: Charles O. Kerobo, Michael C. Welch, Suzanne M. Gessner, Sonia J. Patterson