For Bare Metal Surface (e.g., Degreasing Composition, Etc.) Patents (Class 510/245)
  • Patent number: 6228179
    Abstract: A surface treatment composition containing a complexing agent as a metal deposition preventive in a liquid medium, in which the complexing agent is an ethylenediaminephenol derivative of the following general formula (1) or its salt: wherein X1 and X2 are hydroxyl groups; Y1 to Y8 are respectively independently a hydrogen atom, a hydroxyl group, a halogen atom, a carboxyl group, a phosphonic acid group, a sulfonic acid group, a carbonyl group, a nitro group, a nitroso group, an amino group, an imino group, a nitrilo group, a nitrile group, a thiocyanate group, a hydroxyamino group, a hydroxyimino group, or an alkyl or alkoxy group which may have a substituent, provided that at least one of Y1 to Y8 is not a hydrogen atom; Z1 to Z4 are respectively independently a hydrogen atom, a carboxyl group or a sulfonic acid group; and R1 to R4 are respectively independently a hydrogen atom or an alkyl group which may have a substituent.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: May 8, 2001
    Assignee: Mitsubishi Chemical Corporation
    Inventor: Hitoshi Morinaga
  • Patent number: 6221819
    Abstract: A cleaning oil which is effective in removing dirt and soot from sooty surfaces such as artillery and gun barrels without causing corrosion and toxicity. The oil is produced by frying raw animal bones with used cooking oil until the bones become brown, and the oil becomes thick. The bone is then discarded, and the residual oil filtered and deodorised.
    Type: Grant
    Filed: August 25, 1999
    Date of Patent: April 24, 2001
    Inventor: Aik Soong Chua
  • Patent number: 6221833
    Abstract: Cleaning and surface treatment compositions which are particularly useful in the cleaning of leather, vinyl, plastic, rubber and other similar surfaces as well as providing a surface coating thereupon. The cleaning compositions include reduced amounts of emulsified silicone oils in an aqueous formulation. The compositions are readily dispensible from conventional dispensing devices, and provide simultaneous cleaning to a treated surface, as well as imparting a glossy surface coating.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: April 24, 2001
    Assignee: Reckitt Benckiser Inc.
    Inventor: Andrew Francis Colurciello, Jr.
  • Patent number: 6221818
    Abstract: A hydroxylamine-gallic compound composition comprises a hydroxylamine compound, at least one alcohol amine compound which is miscible with the hydroxylamine compound and a gallic compound. A process for removing photoresist or other polymeric material or a residue from a substrate, such as an integrated circuit semiconductor wafer including titanium metallurgy, in accordance with this invention comprises contacting the substrate with a hydroxylamine compound, an alcohol amine compound which is miscible with the hydroxylamine compound and a gallic compound for a time and at a temperature sufficient to remove the photoresist, other polymeric material or residue from the substrate. Use of a gallic compound in place of catechol in the composition and process reduces attack on titanium metallurgy by, e.g., about three times.
    Type: Grant
    Filed: August 11, 2000
    Date of Patent: April 24, 2001
    Assignee: EKC Technology, Inc.
    Inventor: Wai Mun Lee
  • Patent number: 6211132
    Abstract: An acidic aqueous liquid composition for deburring/degreasing/cleaning metal, in particular aluminum, parts by mass finishing has as its active ingredients: (A) a nonionic surfactant containing halogen atoms, (B) nitrogen based surfactants such as n-alkyl pyrrolidone, builders such as silicates and boric acid, hydrotropes, corrosion inhibitors, and sequestering agents.
    Type: Grant
    Filed: June 14, 1999
    Date of Patent: April 3, 2001
    Assignee: Henkel Corporation
    Inventors: John R Pierce, Lawrence R Carlson, William J Wittke
  • Patent number: 6200942
    Abstract: A cleaning composition that can be dissolved in water to form a cleaning solution for cleaning metal articles, comprises 10% (m/m) iodine, 65% (m/m) tartaric acid, 5% (m/m) sodium lauryl sulphate and 20% (m/m) citric acid. The cleaning solution can be applied to the surface of a metal article for cleaning it. The invention extends to the cleaning solution which includes 20 grams of the chemical composition dissolved in one litre of water.
    Type: Grant
    Filed: July 23, 1999
    Date of Patent: March 13, 2001
    Inventor: Magdelena Christiana Cornelia Stols
  • Patent number: 6200939
    Abstract: Biocompatible aqueous biocompatible cleaning and deodorizing compositions comprise (i) a biocompatible high osmotic pressure material, (ii) a Polycarboxylic acid salt, (iii) a polyhydric alcohol, (iv) a nonionic surfactant, and (v) an odor elimination agent, in water. The compositions are particularly suitable for cleaning and deodorizing medical devices which are designed for receiving and/or holding human waste. Preferably, the compositions are free of non-biocompatible or toxic components and have a relatively neutral pH, whereby the compositions are not harmful to human skin upon contact.
    Type: Grant
    Filed: June 18, 1999
    Date of Patent: March 13, 2001
    Assignee: National Research Labs
    Inventor: Gerald L. Maurer
  • Patent number: 6200945
    Abstract: The present invention provides a solvent composition that is environmentally safe and has a palatable odor. The solvent composition can be used in numerous applications such as cleaning metal and non-metal surfaces and as a thinning agent. The solvent composition of the invention includes acetone, methyl propyl ketone, isopropyl alcohol, and n-butyl acetate; includes less than 3% methyl isobutyl ketone; and is substantially free of other undesirable chemicals such as methylene chloride, 1,1,1-trichloroethane, methyl ethyl ketone, and toluene. The present invention also includes a method of cleaning a metal or non-metal surface and thinning a composition using the solvent composition of the invention.
    Type: Grant
    Filed: May 20, 1999
    Date of Patent: March 13, 2001
    Assignee: McDonnell Douglas Corporation
    Inventors: Edward D. Lally, Richard J. Menke
  • Patent number: 6200941
    Abstract: Fully diluted hard surface cleaners are disclosed which are particularly effective on cleaning soap scum. The cleaners contain at least 0.45 eq/kg of a dissolved anion which reacts with calcium ion to form an insoluble salt. The cleaners also contain a particular amine oxide, or a different surfactant in conjunction with a solvent. Preferred embodiments include a bleach, which provide for a cleaner which is effective on soap scum and mold and mildew.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: March 13, 2001
    Assignee: S. C. Johnson & Son, Inc.
    Inventors: Gary M. Strandburg, Daniel H. Haigh, John M. Gardner, Kevin J. Wagers, Erin D. O'Driscoll
  • Patent number: 6194366
    Abstract: A cleaning solution is provided for cleaning copper-containing microelectronic substrates, particularly for post-CMP or Via formation cleaning. The cleaning solution comprises a quaternary ammonium hydroxide, an organic amine, a corrosion inhibitor, and water. A preferred cleaning solution comprises tetramethylammonium hydroxide, monoethanolamine, gallic acid, and water. The pH of the cleaning solution is greater than 10.
    Type: Grant
    Filed: November 16, 1999
    Date of Patent: February 27, 2001
    Assignee: ESC, Inc.
    Inventors: Shahriar Naghshineh, Jeff Barnes, Yassaman Hashemi, Ewa B. Oldak
  • Patent number: 6194369
    Abstract: The invention relates to an aqueous preparation for the pickling and activation of aluminum-steel composites prior to electroless dip tinning. Specifically, the invention provides pickling/activation solutions for the pretreatment of aluminum-steel composites prior to dip tinning which comprise sulfuric acid, hexafluorosilicic acid, at least one wetting agent, at least one transition metal cation and nitrate and/or nitrite ions.
    Type: Grant
    Filed: June 25, 1999
    Date of Patent: February 27, 2001
    Assignee: Th. Goldschmidt AG
    Inventors: Jan Eberhardt, Dieter Guhl, Frank Honselmann
  • Patent number: 6191086
    Abstract: Non-corrosive cleaning compositions that are aqueous based and useful for removing photoresist, plasma etch and CMP residues from a substrate. One preferred cleaning composition comprises: (i) a hydroxylamine or a hydroxylamine salt compound; (ii) at least one fluorine-containing compound; and (iii) water. Another cleaning composition comprises: (i) a compound selected from the group consisting of: an amine, a quatenary ammonium hydroxide, and ammonium hydroxide; (ii) at least one fluorine-containing compound; and (iii) water.
    Type: Grant
    Filed: December 15, 1999
    Date of Patent: February 20, 2001
    Assignee: Arch Specialty Chemicals, Inc.
    Inventors: Vincent G. Leon, Kenji Honda, Eugene F. Rothgery
  • Patent number: 6191094
    Abstract: An alkaline aqueous cleaning composition for cleaning a substrate contaminated with industrial-type soil contaminants contains (i) an aqueous portion and (ii) an active-ingredient portion composed of (A) an alkalinity-providing agent and (B) a surfactant mixture containing (a) an active concentration of an ethoxylated C12-14 alkanol surfactant having an HLB value at 25° C. of from 8 to 12 and (b) an active concentration of at least one aminocarboxylic acid surfactant of the general formula R—N(H)—R′, wherein R is a straight or branched chain aliphatic organic group having from 10 to 20 carbon atoms, and R′ is a straight or branched chain carboxylic acid having from 1 to 7 carbon atoms. At an active-concentration ratio of surfactant (a) to surfactant (b) of about 2.5:1, the surfactants have a synergistic effect on the cleaning composition's ability to remove certain types of industrial-soil contaminants.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: February 20, 2001
    Assignee: Church & Dwight Co., Inc.
    Inventors: Francis R. Cala, Richard A. Reynolds
  • Patent number: 6191087
    Abstract: A solvent that is biodegradable, provides effective solvency for a broad range of tasks and is generally benign to human health is disclosed. This solvent is a mixture of a lactate ester and an edible oil ester having a closed cup flash point in excess of 60° C., and can include other non-halogenated solvents and surfactants.
    Type: Grant
    Filed: June 5, 2000
    Date of Patent: February 20, 2001
    Assignee: Vertec BioSolvents, LLC
    Inventors: James E. Opre, Eugene P. Bergemann, Mark Henneberry
  • Patent number: 6187737
    Abstract: A cleaning agent concentrate is presented having (a) at least one glycol ether corresponding to the formula: R—O—(CH2—CH(CH3)O)n—H where R is an alkyl group having 1 to 4 carbon atoms or a phenyl group, and n is a number of from 1 to 5; and (b) at least one cationic surfactant, where the weight ratio of (a) to (b) is from 8:1 and 100:1, and where the cleaning agent concentrate comprises less than 0.1 percent by weight of fatty alcohol alkoxylates, amphoteric surfactants, or mixtures thereof. When diluted to 0.5 to 5% by weight with water, a cleaning agent is formed that is low-foaming. The cleaning agent is especially useful for cleaning and passivating metal surfaces using a spray application.
    Type: Grant
    Filed: February 8, 2000
    Date of Patent: February 13, 2001
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Juergen Geke, Bernd Stedry, Nicole Voeller
  • Patent number: 6187730
    Abstract: A hydroxylamine-gallic compound composition comprises a hydroxylamine compound, at least one alcohol amine compound which is miscible with the hydroxylamine compound and a gallic compound. A process for removing photoresist or other polymeric material or a residue from a substrate, such as an integrated circuit semiconductor wafer including titanium metallurgy, in accordance with this invention comprises contacting the substrate with a hydroxylamine compound, an alcohol amine compound which is miscible with the hydroxylamine compound and a gallic compound for a time and at a temperature sufficient to remove the photoresist, other polymeric material or residue from the substrate. Use of a gallic compound in place of catechol in the composition and process reduces attack on titanium metallurgy by, e.g., about three times.
    Type: Grant
    Filed: April 17, 1996
    Date of Patent: February 13, 2001
    Assignee: EKC Technology, Inc.
    Inventor: Wai Mun Lee
  • Patent number: 6187736
    Abstract: A solvent mixture comprising an alcohol, an aromatic hydrocarbon or an organic compound containing carboxyl but not hydroxyl moieties, and optionally and preferably a non-aromatic hydrocarbon or halohydrocarbon is particularly effective in removing incompletely cured residues of a variety of sealing compounds from the surfaces of automobile bodies, without damaging intermediate or final finish coatings for the automobile bodies. The solvent mixture may advantageously be absorbed in a wiping cloth for convenient use.
    Type: Grant
    Filed: March 11, 1999
    Date of Patent: February 13, 2001
    Assignee: Henkel Corporation
    Inventor: Chester P. Jarema
  • Patent number: 6184195
    Abstract: An aqueous concentrated liquid disinfectant composition which blooms when added to a larger volume of water which comprises the following constituents: a terpene based solvent; germicidal cationic surfactant, preferably a quaternary ammonium compound having germicidal properties; organic solvent constituent; a binary co-solvent system comprising alkyl diphenyl solvent and a co-solvent; one or more nonionic surfactants; optionally but desirably at least one optional constituent selected from: chelating agents, coloring agent, light stabilizers, fragrances, thickening agents, hydrotropes, pH adjusting agents, pH buffers one or more detersive surfactant constituents particularly non-ionic and amphoteric surfactants, as well as others known the art and useful in similar compositions; and, the balance being water. The liquid disinfectant compositions feature good blooming characteristics, particularly good long term blooming retention. Process for the use of the compositions are also disclosed.
    Type: Grant
    Filed: October 23, 1998
    Date of Patent: February 6, 2001
    Assignee: Reckitt Benckiser Inc.
    Inventors: Tak Wai Cheung, Dennis Thomas Smialowicz, Minaxi Hemansu Mehta, Ralph Edward Rypkema
  • Patent number: 6179927
    Abstract: A method for decontaminating the copper surfaces (e.g. circuits) of an electronic card from copper salts which can be formed after the soldering of the electronic components onto the substrate employing a water free solution which comprises an alcohol and at least one neutral ammonium salt of an organic acid.
    Type: Grant
    Filed: May 30, 2000
    Date of Patent: January 30, 2001
    Assignee: International Business Machines Corporation
    Inventors: Vittorio Sirtori, Giovanni Cattaneo, Fabio Mauri
  • Patent number: 6176937
    Abstract: Aqueous acidic solutions of hydrogen peroxide used for metal surface treatments suffer from an increased decomposition rate of the hydrogen peroxide, caused by the dissolved metals such as iron, copper or titanium. A method is provided wherein stabilization can be achieved by employing a combination of a) a hydroxybenzoic acid, preferably p-hydroxybenzoic acid; b) a hydrotropic sulphonic acid, preferably p-toluene sulphonic acid; and c) a hydrophobic alkaryl sulphonic acid, preferably dodecylbenzene sulphonic acid.
    Type: Grant
    Filed: March 20, 2000
    Date of Patent: January 23, 2001
    Assignee: Solvay Interox Limited
    Inventors: Sarah J. Colgan, Neil J. Sanders, Colin F. McDonogh
  • Patent number: 6172025
    Abstract: A vehicle cleaning solution is provided including a predetermined amount of mineral spirits and a predetermined amount of jeweler's rouge mixed with the mineral spirits for cleaning various vehicular components.
    Type: Grant
    Filed: April 23, 1998
    Date of Patent: January 9, 2001
    Inventors: Bobby C. Johnson, Henry D. Shook
  • Patent number: 6165278
    Abstract: A method for removing thermal grease from an electronic card having plated via holes and including electronic components thereon, the method including the steps of providing a substantially water free solution having an alcohol and at least one compound of a neutral ammonium salt of an organic acid and immersing the electronic card in the solution for a predetermined period of time remove the thermal grease from the electronic card.
    Type: Grant
    Filed: March 27, 2000
    Date of Patent: December 26, 2000
    Assignee: International Business Machines Corporation
    Inventors: Paul Joseph Hart, Vittorio Sirtori, Sergio Varinelli, Marino Verderio, Franco Zambon
  • Patent number: 6162779
    Abstract: A composition for cleaning solid surfaces, under cold conditions, in non-aqueous medium consists essentially of a mixture of alkanes or cycloalkanes and at least one organic compound comprising at least one ketone function, the composition having a flashpoint above or equal to 40.degree. C. and below 55.degree. C., measured according to ASTM standard D56-70.
    Type: Grant
    Filed: January 27, 1998
    Date of Patent: December 19, 2000
    Assignee: Elf Atochem, S.A.
    Inventors: Pascal Michaud, Jean-Jacques Martin
  • Patent number: 6159924
    Abstract: Aqueous based cleaning compositions simultaneously featuring disinfecting, low residue deposit and good cleaning characteristics are provided. The compositions include one or more quaternary amine compounds as disinfecting active agents, an organic solvent system, one or more amine oxides, one or more nonionic alkylpolyglycosides, water and optionally further conventional additives including pH buffers, dyes, fragrances and the like.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: December 12, 2000
    Assignee: Reckitt Benckiser Inc.
    Inventors: Jeanne Marie Weller, Kenneth A. Harrison, Ann Marie Lynch
  • Patent number: 6153575
    Abstract: Describes a stabilized trans-1,2-dichloroethylene composition having a low concentration of aliphatic aldehyde hydrazone, optionally in combination with an epoxide. The aliphatic aldehyde hydrazone was found to be more efficient than commercially used hydroquinone monomethylether (HQMME) in preventing the isomeric transformation of trans-1,2-dichloroethylene to cis-1,2-dichloroethylene during storage. Also described is a process for cleaning the surface of an article with the stabilized 1,2-dichloroethylene composition.
    Type: Grant
    Filed: March 6, 2000
    Date of Patent: November 28, 2000
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Earl M. Gorton, Ronald D. Olinger
  • Patent number: 6150315
    Abstract: A viscous firearm gel cleaner that includes an organic cleaning agent such as terpene, terpene derivatives, terpenoids, terpenoid derivatives, turpentine and/or turpentine derivatives. The organic solvent includes substantially no petroleum distillates. The cleaner includes non-ionic and ionic surfactants to enhance the usability and effectiveness of the cleaner. The cleaner can also include an amine cleaning agent, a scent agent, a rust and/or corrosion inhibitor, a thickener, and/or a biocide. The cleaner removes grease, oil, carbon, plastic wad fouling and metal residues that can foul firearms. The cleaner is a water soluble, non-flammable, biodegradable cleaner. The cleaner is especially useful for cleaning outdoor sporting equipment such as firearms.
    Type: Grant
    Filed: December 6, 1999
    Date of Patent: November 21, 2000
    Assignee: Sports Care Products, Inc.
    Inventors: David Stanley Komocki, Robert Joseph Harmacek
  • Patent number: 6147006
    Abstract: A cleaning gas which is employed to remove an unnecessary deposited material formed in a thin film forming apparatus by thermal decomposition of pentaethoxytantalum or tetraethoxysilane without damaging a reactor, tools, parts and piping of a silicon oxide film-forming apparatus or a tantalum oxide film-forming apparatus. The cleaning gas comprises HF gas and at least one of an oxygen-containing gas, a fluorine gas, a chlorine fluoride gas, a bromine fluoride gas and an iodine fluoride gas.
    Type: Grant
    Filed: January 7, 2000
    Date of Patent: November 14, 2000
    Assignee: Central Glass Company, Limited
    Inventors: Isamu Mouri, Tetsuya Tamura, Mitsuya Ohashi, Tadayuki Kawashima
  • Patent number: 6147042
    Abstract: The cleaner of the present invention contains, as an active ingredient, a polyphosphoric-acid-urea condensate or phosphoric-acid-urea polymer which is a reaction product from orthophosphoric acid and urea and is used for cleaning a metal surface and/or a glass surface in at least one process of a semiconductor device production process and a liquid crystal device production process. According to the present invention, an etching residue and impurities on metal (including semimetal) and glass surfaces can be cleaned off with high environmental and working safety and effectively without causing the problem of metal corrosion.
    Type: Grant
    Filed: July 2, 1999
    Date of Patent: November 14, 2000
    Assignees: Kishimoto Sangyo Co., Ltd., Otsuka Chemical Co., Ltd.
    Inventors: Takashi Yata, Yutaka Koinuma, Kazunori Fukumura, Yoshihito Fukumura
  • Patent number: 6143706
    Abstract: A surface treatment composition containing a complexing agent as a metal deposition preventive in a liquid medium, in which the complexing agent is an ethylenediaminephenol derivative of the following general formula (1) or its salt: ##STR1## wherein X.sub.1 and X.sub.2 are hydroxyl groups; Y.sub.1 to Y.sub.8 are respectively independently a hydrogen atom, a hydroxyl group, a halogen atom, a carboxyl group, a phosphonic acid group, a sulfonic acid group, a carbonyl group, a nitro group, a nitroso group, an amino group, an imino group, a nitrilo group, a nitrile group, a thiocyanate group, a hydroxyamino group, a hydroxyimino group, or an alkyl or alkoxy group which may have a substituent, provided that at least one of Y.sub.1 to Y.sub.8 is not a hydrogen atom; Z.sub.1 to Z.sub.4 are respectively independently a hydrogen atom, a carboxyl group or a sulfonic acid group; and R.sub.1 to R.sub.4 are respectively independently a hydrogen atom or an alkyl group which may have a substituent.
    Type: Grant
    Filed: January 26, 1998
    Date of Patent: November 7, 2000
    Assignee: Mitsubishi Chemical Corporation
    Inventor: Hitoshi Morinaga
  • Patent number: 6140287
    Abstract: An etching residue remover for cleaning etching residue from a substrate, derived from a mixture of at least hydroxylamine, an alkanolamine which is miscible with said hydroxylamine, water, and, optionally, a chelating agent, wherein the hydroxylamine and the alkanolamine are present in amounts sufficient to clean etching residue from the substrate.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: October 31, 2000
    Assignee: EKC Technology, Inc.
    Inventor: Wai Mun Lee
  • Patent number: 6140284
    Abstract: Aqueous concentrated liquid hard surface cleaning compositions which bloom when added to a larger volume of water which comprises the following constituents:botanical oil constituent;at least one botanical oil solubilizing surfactant which is preferably an amine oxide surfactant;a binary solvent system which includes at least one organic alcohol constituent and at least one glycol solvent constituent;optionally but desirably a polyoxycarboxylate constituent;optionally but desirably an effective amount of a chelating agent which includes at least one non-ionized acetate group, most preferably a mono-, di- or tri- alkali or alkaline ethylenediaminetetraacetic acid;optionally but desirably at least one optional constituent selected from: chelating agents, coloring agents, light stabilizers, fragrances, thickening agents, hydrotropes, pH adjusting agents, pH buffers one or more detersive surfactant constituents particularly non-ionic and amphoteric surfactants, as well as others known the art.
    Type: Grant
    Filed: March 11, 1999
    Date of Patent: October 31, 2000
    Assignee: Reckitt Benekiser Inc.
    Inventors: Tak Wai Cheung, Dennis Thomas Smialowicz
  • Patent number: 6140291
    Abstract: An aqueous metal cleaning composition is provided which comprises an alkalinity providing agent such as alkali metal carbonate and/or bicarbonate salts and a low foaming surfactant. The aqueous cleaning solution has specific foam height and foam collapse characteristics, and provides for substantially complete phase separation of a contaminant phase from the aqueous cleaning composition such that there is substantially no aqueous phase drag out into the contaminant phase; and the contaminant phase can be removed easily, and the aqueous cleaning solution can be recovered and reused.
    Type: Grant
    Filed: July 28, 1998
    Date of Patent: October 31, 2000
    Assignee: Church & Dwight Co., Inc.
    Inventors: Steven A. Bolkan, Gale A. Byrnes, Steven Dunn, Alfredo Vinci, Antony E. Winston, Patricia L. Phillips
  • Patent number: 6133213
    Abstract: A water free solution for decontaminating copper surfaces (e.g. circuits of an electronic card) from copper salts which includes an alcohol and at least one neutral ammonium salt of an organic acid.
    Type: Grant
    Filed: July 20, 1999
    Date of Patent: October 17, 2000
    Assignee: International Business Machines Corporation
    Inventors: Vittorio Sirtori, Giovanni Cattaneo, Fabio Mauri
  • Patent number: 6133218
    Abstract: The present invention relates to an aqueous based, solvent free degreaser composition, comprising a blend of two nonionic surfactants selected from, alcohol alkoxylate with a fatty alcohol moiety, alkoxylated fatty alcohol, fatty alcohol having oxyethylate moieties, polyoxyalkylene block copolymers, and alkyl phenol alkoxylate.
    Type: Grant
    Filed: July 29, 1997
    Date of Patent: October 17, 2000
    Assignee: BASF Corporation
    Inventors: Charles O. Kerobo, Michael C. Welch, Suzanne M. Gessner, Sonia J. Patterson
  • Patent number: 6130195
    Abstract: Compositions and methods for cleaning, degreasing, stripping, solvating and/or removing residues and contaminants such as oils, grease, dirt, flux, inks, coatings, photoresists, resins and polymers from manufactured articles and hard surfaces such as, but not limited to metals, plastics, textiles, electronic devices, silicon wafers, mechanical devices or manufacturing equipment. The compositions contain at least one 4 carbon cyclic ether solvent mixtures with at least one 3-alkoxy 3-methyl butanol, as well as other optional alkaline materials as well as other optional solvents and additives. The compositions can be contacted with a surface to be cleaned in a number of ways and under a number of conditions depending on the manufacturing or processing variables present.
    Type: Grant
    Filed: November 3, 1997
    Date of Patent: October 10, 2000
    Assignee: Kyzen Corporation
    Inventors: Kyle J. Doyel, Michael L. Bixenman, Scotty S. Sengsavang, Kristie L. Gholson, Patricia D. Overstreet, Arthur J. Thompson, Valerie G. Porter
  • Patent number: 6126755
    Abstract: Aqueous acidic solutions of hydrogen peroxide used for metal surface treatments suffer from an increased decomposition rate of the hydrogen peroxide, caused by the dissolution of metals such as iron, copper, or titanium. Stabilization can be achieved by employing a combination of a) hydroxybenzoic acid, preferably p-hydroxybenzoic acid; b) a hydrotropic sulphonic acid, preferably p-toluene sulphonic acid; and c) a hydrophobic alkaryl sulphonic acid, preferably dodecylbenzene sulphonic acid.
    Type: Grant
    Filed: May 25, 1999
    Date of Patent: October 3, 2000
    Assignee: Solvay Interox Limited
    Inventors: Sarah J. Colgan, Neil J. Sanders, Colin F. McDonogh
  • Patent number: 6124252
    Abstract: A multipurpose scale removal compound having a nonyl phenol ethoxylate with 10 moles of ethylene oxide at 0.85% of a total weight of the compound, hydrofluoric acid at 0.85% of the total weight of the compound, and softened water at 98.3% of the total weight of the compound. This multipurpose scale removal compound is formed by filling a reactor with 160 liters of softened water, adding 20 kilograms of hydrofluoric acid to the water in the first reactor, agitating the hydrofluoric acid and water in the first reactor, adding 20 kilograms of nonyl phenol ethoxylate with 10 moles of ethylene oxide to the first reactor, agitating the nonyl phenol ethoxylate, the ethylene oxide and the agitated hydrofluoric acid and water in the first reactor so as to obtain a uniform solution, adding 182.9 liters of softened water and 17.1 kilograms of the uniform solution to a second reactor, and agitating the softened water and uniform solution in the second reactor so as to obtain a uniform mixture.
    Type: Grant
    Filed: March 17, 1999
    Date of Patent: September 26, 2000
    Assignee: Lubrimak Corporation, S.A. de C.V.
    Inventor: Mario Alberto Chavez Amaro
  • Patent number: 6124253
    Abstract: An alkaline, aqueous metal-cleaning composition capable of effectively removing industrial-type soil contaminants from a metal surface at temperatures as low as ambient temperature and in the absence of substantial agitation contains (A) an active-ingredient portion containing (1) an alkalinity-providing component, and (2) a surfactant mixture containing: (a) at least one first non-ionic, ethoxylated linear primary alcohol surfactant having a hydrophobic carbon chain length of from 9 to 11 carbon atoms and being ethoxylated with (i) an average of 2.5 moles of ethylene oxide or (ii) an average of 5.0 moles of ethylene oxide; and (b) at least one second non-ionic, ethoxylated linear primary alcohol surfactant having a hydrophobic carbon chain length of from 9 to 11 carbon atoms and being ethoxylated with an average of 6.0 moles of ethylene oxide; and (B) an aqueous portion.
    Type: Grant
    Filed: September 16, 1997
    Date of Patent: September 26, 2000
    Assignee: Church & Dwight Co., Inc.
    Inventors: Alfredo Vinci, Steven A. Bolkan, Paul E. DeCastro, Lisa M. Kurschner
  • Patent number: 6117831
    Abstract: The subject invention relates to a novel class of compounds, known as alkali metal salts of hydroxyalkyl sulfonates of aminoalkyl alkanol amines and/or aminoalkyl alkanol ethers, the methods of making such compounds, the alkali-stable solutions containing such compounds, and the use of said solutions as strong detergent compositions. Those alkali-stable solutions are temperature-stable, exhibit superior wetting characteristics, and can be made into low or high foam formulations useful for hard surface cleaning, oven and grill cleaning, metal cleaning, bottle washing, steam cleaning and wax stripping formulations.
    Type: Grant
    Filed: September 3, 1998
    Date of Patent: September 12, 2000
    Assignee: Lonza Inc.
    Inventors: Michael Yao-Chi Chiang, Daniel Wayne Lemke, Joseph William Scheblein
  • Patent number: 6110881
    Abstract: A composition for removing resists and etching residue from substrates containing at least one nucleophilic amine compound having oxidation and reduction potentials, at least one organic solvent, water and, optionally, a chelating agent is described. The chelating agent is preferred to be included since it provides added stability and activity to the cleaning composition so that the composition has long term effectiveness. If a chelating agent is not present, the composition, while providing for adequate stripping and cleaning upon initial use of the composition following mixing, has only short term stability. In this latter instance, the nucleophilic amine compound and organic solvent components of the composition preferably are maintained separate from each other until it is desired to use the composition. Thereafter, the components are combined. Following use of the composition, the non-used portion of the composition can be disposed of or be reactivated by the addition of a chelating agent.
    Type: Grant
    Filed: May 28, 1996
    Date of Patent: August 29, 2000
    Assignee: EKC Technology, Inc.
    Inventors: Wai Mun Lee, Charles U. Pittman, Jr., Robert J. Small
  • Patent number: 6100227
    Abstract: An ultra heavy duty industrial cleaner, degreaser, dispersant and emulsifier formulation is described. The formulation comprises at least one propylene glycol alkyl ether, at least one 1-alkyl-2-pyrrolidinone, at least one polyoxyethylene aliphatic ether, at least one polyoxyethylene aliphatic ether, at least one trialkanolanine, d-limonine, at least one alkylaryl sulfouate, and at least one aliphatic alkanol.
    Type: Grant
    Filed: April 17, 1999
    Date of Patent: August 8, 2000
    Assignee: Joan Docter
    Inventor: James O. Burlew
  • Patent number: 6096701
    Abstract: An improvement is described in compositions which are especially effective in disinfecting the surface being cleaned and in the removal of oily and greasy soil which contains a mixture of a disinfecting agent, a booster agent for the disinfecting agent, an anionic surfactant and a hydrocarbon ingredient, a water soluble cosurfactant, and water.
    Type: Grant
    Filed: December 15, 1999
    Date of Patent: August 1, 2000
    Assignee: Colgate Palmolive Company
    Inventors: Myriam Mondin, Claude Blanvalet, Nicole Andries, Pierre Fonsny, Didier Dormal
  • Patent number: 6096700
    Abstract: A non-chrome process for the pretreatment of substrate surfaces to simultaneously clean them and improve their bonding strength for organic coatings such as adhesives, protective primers, sealants, paints, composites and similar materials conventionally bonded to such substrates, including non-chromated or chromated curable organic resin protective coatings applied directly to bare aluminum substrates. The invention involves the use of novel wipe solvent compositions containing a major volume of an environmentally-safe volatile organic solvent which has a low composite vapor pressure or is otherwise exempt from federal, state or local regulations, and a minor volume of a polyfunctional coupling agent, preferably of the silane type.
    Type: Grant
    Filed: August 24, 1998
    Date of Patent: August 1, 2000
    Assignee: Northrop Grumman Corporation
    Inventors: John Douglas Weir, Joanne Swiderski McLaughlin
  • Patent number: 6096699
    Abstract: A solvent that is biodegradable, provides effective solvency for a broad range of tasks and is generally benign to human health is disclosed. This solvent is a mixture of a lactate ester and an edible oil ester that has a flash point greater that 93.degree. C., and can include other non-halogenated solvents and surfactants.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: August 1, 2000
    Assignee: NTEC Versol, LLC
    Inventors: Eugene P. Bergemann, James E. Opre, Mark Henneberry
  • Patent number: 6087317
    Abstract: By using a nonionic surfactant as the primary emulsifier having an hydrophilic-lipophilic balance (HLB) greater than about 13, at a concentration sufficient to provide about 0.5-3 molecules per 100 square .ANG. of surface area of silicone particles; and a nonionic cosurfactant having an HLB less than about 11, at a concentration sufficient to provide 5-15 molecules of emulsifier per 100 square .ANG. of surface area of silicone particles; aqueous emulsions containing low molecular weight silicones can be prepared which possess improved particle size stability. In particular, the low molecular weight silicones have a molecular weight less than about 1,000, and a viscosity of not greater than about 5 mm.sup.2 /sec. These emulsions can be used in applications relating to laundry pre-spotting, automotive bug and tar removal, and hard surface cleaning.
    Type: Grant
    Filed: December 10, 1998
    Date of Patent: July 11, 2000
    Assignee: Dow Corning Corporation
    Inventor: Ronald Paul Gee
  • Patent number: 6083890
    Abstract: An improved acidic cleaning composition comprising a low acetate xanthan gum as a rheological control agent exhibits greater, longer lasting stability and shelf-life than acidic cleaning compositions with xanthan gum have exhibited in the past.
    Type: Grant
    Filed: June 6, 1997
    Date of Patent: July 4, 2000
    Assignee: Monsanto Company
    Inventors: Frank Miskiel, Yogesh Solanki
  • Patent number: 6080706
    Abstract: An improvement is described in compositions which is especially effective in disinfecting the surface being cleaned and in the removal of oily and greasy soil which contains at least one nonionic surfactant, a hydrocarbon ingredient, a water soluble solvent, a bactericide and water.
    Type: Grant
    Filed: January 29, 1999
    Date of Patent: June 27, 2000
    Assignee: Colgate Palmolive Company
    Inventors: Claude Blanvalet, Yves Lambremont
  • Patent number: 6080709
    Abstract: The present invention relates to a cleaning solution for cleaning substrates, to which a metallic wiring has been applied, being capable of easily removing the metallic impurities of the substrate surface without corroding the metal, not putting a strain on the environment, and not causing a shelf life problem.The cleaning solution comprising at least one member selected from a group consisting of oxalic acid, ammonium oxalate and polyaminocarboxylic acids, but contains no hydrogen fluoride.
    Type: Grant
    Filed: August 11, 1998
    Date of Patent: June 27, 2000
    Assignees: Kanto Kagaku Kabushiki Kaisha, NEC Corporation
    Inventors: Norio Ishikawa, Kiyoto Mori, Hidemitsu Aoki
  • Patent number: 6080244
    Abstract: Compositions and methods for cleaning metal and non-metal surfaces utilizing a nonionic surfactant and an enzyme are disclosed. A composition comprised of at least one nonionic surfactant and at least one enzyme and having a pH of between 6 and 9.5 is specifically disclosed. A method for cleaning a surface using this composition, and a method for cleaning a surface using a first composition comprising at least one nonionic surfactant and a second composition comprising at least one enzyme are also disclosed.
    Type: Grant
    Filed: September 21, 1998
    Date of Patent: June 27, 2000
    Assignee: Calgon Corporation
    Inventors: Christopher L. Wiatr, David Elliott
  • Patent number: 6071872
    Abstract: A cleaning solution including a brominated hydrocarbon and an ester. The cleaning solution is especially useful for cleaning high-voltage power cables prior to splicing.
    Type: Grant
    Filed: June 10, 1998
    Date of Patent: June 6, 2000
    Assignee: Arnco Corporation
    Inventors: Glenn Miller, Robert Washburn