Processes Of Coating Utilizing A Reactive Composition Which Reacts With Metal Substrate Or Composition Therefore Patents (Class 148/240)
  • Patent number: 6368425
    Abstract: Techniques are disclosed for improving the tribology between an air bearing surface of a magnetic recording head and a magnetic recording medium. In addition, techniques are described for reducing resistance to wear and corrosion of the air bearing surface of the recording head as well as resistance to corrosion of the recording medium. Various ion beam techniques can be used to enhance the properties of the recording head and recording medium, and include ion implant techniques, ion mixing techniques and ion burnishing techniques.
    Type: Grant
    Filed: January 27, 1999
    Date of Patent: April 9, 2002
    Assignee: Seagate Technology LLC
    Inventors: Peter R. Segar, Bal K. Gupta, Jeffery K. Berkowitz, Sanghamitra Sahu
  • Publication number: 20020029826
    Abstract: Disclosed herein is a surface treatment agent for steel, characterized in that, said agent contains 0.1-15% by mass of chromium sulfate and 10-40% by mass of a binder resin containing butyral resin or a mixture of butyral resin with another resin which is compatible with butyral resin.
    Type: Application
    Filed: August 2, 2001
    Publication date: March 14, 2002
    Inventors: Hirofumi Kishikawa, Masato Yamashita, Atsumu Kanda, Hiroshi Ono
  • Publication number: 20020023695
    Abstract: Disclosed is a rolling apparatus having a surface-treated rolling member composed of a metallic rolling element and a metallic race element which have been used with a lubricant, in which the surface of at least one of the rolling element and the race element has a reaction product subsurface layer, wherein the reaction product subsurface layer has been produced by the reaction between the metallic component of the rolling element or the race element and at least one compound selected from the group consisting of a phosphorus compound, a sulfur compound, a halogen compound and an organometallic compound, and the lubricant containing at least one compound selected from the group consisting of an organic phosphorus compound, an organic sulfur compound, an organic halogen compound and an organometallic compound as an extreme pressure component is present between the metallic contact surfaces of the rolling member.
    Type: Application
    Filed: July 30, 1997
    Publication date: February 28, 2002
    Inventors: DAI KINNO, KOICHI HACHIYA
  • Publication number: 20020023694
    Abstract: An aqueous metal surface treatment composition that includes (A) an aqueous dispersion of a phenolic novolak resin that includes water and a reaction product of a phenolic resin precursor, a modifying agent and a multi-hydroxy phenolic compound wherein the modifying agent includes at least one functional moiety that enables the modifying agent to react with the phenolic resin precursor and at least one ionic moiety, (B) an acid and, optionally, (C) a flexibilizer. According to one embodiment the modifying agent is an aromatic compound. According to another embodiment the ionic moiety of the modifying agent is sulfate, sulfonate, sulfinate, sulfenate or oxysulfonate and the dispersed phenolic resin reaction product has a carbon/sulfur atom ratio of 20:1 to 200:1.
    Type: Application
    Filed: January 22, 1999
    Publication date: February 28, 2002
    Inventors: HELMUT KUCERA, YUAN HE
  • Publication number: 20020023696
    Abstract: The reactive element is introduced to the surface of the metal substrate in the form of an oxide powder and the aluminide-type coating is then formed.
    Type: Application
    Filed: August 27, 2001
    Publication date: February 28, 2002
    Applicant: SNECMA MOTEURS
    Inventors: Yann Jaslier, Alain Martinez, Marie-Christine Ntsama Etoundi, Guillaume Oberlaender
  • Publication number: 20020020471
    Abstract: Hardening protection compositions based on substances which form boron glass for partial carburization of metallic components, which contain magnesium-silicon compounds as an additive. These hardening protection compositions can be used very advantageously in processes for the partial carburization of metallic components and in particular are outstandingly suitable for vacuum carburization.
    Type: Application
    Filed: August 7, 2001
    Publication date: February 21, 2002
    Inventors: Stefan Wigger, Ulrich Baudis
  • Publication number: 20020018896
    Abstract: The invention relates to composite metallic ultrafine particles which have excellent dispersion stability and can be produced on an industrial scale, and a process for producing the same, and a method and an apparatus for forming an interconnection with use of the same. A surface of a core metal produced from a metallic salt, a metallic oxide, or a metallic hydroxide and having a particle diameter of 1 to 100 nm is covered with an organic compound including a functional group having chemisorption capability onto the surface of the core metal.
    Type: Application
    Filed: March 20, 2001
    Publication date: February 14, 2002
    Inventors: Akira Fukunaga, Hiroshi Nagasawa, Kaori Kagoshima, Makiko Emoto
  • Patent number: 6340438
    Abstract: A corrosion inhibiting admixture for concrete is disclosed comprising a combination of organic (amines) and inorganic (nitrites) fractions that provide a synergistic effect when present at a specific ratio. Such a synergistic effect occurs when the amine:nitrite ratio (% by weight) is between 1.5 to 2.5 resulting in the admixture providing excellent corrosion inhibiting capabilities.
    Type: Grant
    Filed: April 19, 1999
    Date of Patent: January 22, 2002
    Assignee: Tomahawk, Inc.
    Inventors: Donald R. Lane, Jose A. Melendez, Violeta F. Munteanu, Frederick D. Kinney
  • Publication number: 20020000263
    Abstract: A titanium layer is formed on a substrate with chemical vapor deposition (CVD). First, a seed layer is formed on the substrate by combining a first precursor with a reducing agent by CVD. Then, the titanium layer is formed on the substrate by combining a second precursor with the seed layer by CVD. The titanium layer is used to form contacts to active areas of substrate and for the formation of interlevel vias.
    Type: Application
    Filed: August 28, 2001
    Publication date: January 3, 2002
    Applicant: Micron Technology, Inc.
    Inventors: Gurtej Singh Sandhu, Donald L. Westmoreland
  • Patent number: 6332931
    Abstract: A process for forming a diffusion aluminide-hafnide coating on an article, such as a component for a gas turbine engine. The process is a vapor phase process that generally entails placing the article in a coating chamber containing a halide activator and at least one donor material. The donor material collectively consists essentially of at least 0.5 weight percent hafnium and at least 20 weight percent aluminum with the balance being chromium and/or cobalt.
    Type: Grant
    Filed: December 29, 1999
    Date of Patent: December 25, 2001
    Assignee: General Electric Company
    Inventors: Nripendra N. Das, Thomas E. Mantkowski, Raymond W. Heidorn, Joshua L. Miller, Jeffrey A. Pfaendtner
  • Patent number: 6331329
    Abstract: A method of modifying a surface is disclosed. The method includes contacting the surface with a hydridosilane under conditions and for a time sufficient to form a covalent bond between a silicon atom of the hydridosilane and the oxygen atom of a hydroxyl group on the surface. The hydridosilane has the formula where at least one of Ra, Rb, Rc, and Rd is H, and at least one of Ra, Rb, Rc, and Rd is not H.
    Type: Grant
    Filed: May 17, 1999
    Date of Patent: December 18, 2001
    Assignee: University of Massachusetts
    Inventors: Thomas J. McCarthy, Alexander Y. Fadeev
  • Patent number: 6316123
    Abstract: The present invention is directed to a method of forming a new material layer or region near an interface region of two dissimilar materials, and an optional third layer, wherein at least one of said dissimilar materials or optional third is capable of being heated by microwave energy. The method of the present invention includes a step of irradiating a structure containing at least two dissimilar materials and an optional third layer under conditions effective to form the new material layer in the structure. An apparatus for conducting the microwave heating as well as the structures formed from the method are also described herein.
    Type: Grant
    Filed: January 27, 2000
    Date of Patent: November 13, 2001
    Assignee: International Business Machines Corporation
    Inventors: Kam Leung Lee, David Andrew Lewis, Ronnen Andrew Roy, Raman Gobichettipalayam Viswanathan
  • Patent number: 6270571
    Abstract: A method for producing narrow wires including titanium oxide of high crystallinity and diameter of the order of nanometer, in particular whiskers of titanium oxide, and including a first step of preparing a base having a titanium-including surface, second step of discretely depositing a material other than titanium over the above surface, and third step of thermally treating the above surface, obtained by the second step, in a titanium-oxidizing atmosphere.
    Type: Grant
    Filed: November 9, 1999
    Date of Patent: August 7, 2001
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tatsuya Iwasaki, Tohru Den
  • Patent number: 6193814
    Abstract: The present invention relates to the preparation of activated metal, particularly activated tinplate, and the activated metal itself. The activated metal is highly reactive with oxygen and can be used as a pyrophoric decoy material or as a catalyst.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: February 27, 2001
    Assignee: Alloy Surfaces Company
    Inventor: Alfonso L. Baldi
  • Patent number: 6139976
    Abstract: The invention relates to an article of manufacture comprising: a substrate composed of a superalloy containing chromium and a base element selected from the group consisting of iron, cobalt, and nickel; and an enrichment layer containing chromium and placed on the substrate. Therein, the enrichment layer comprises a continuous matrix composed of a gamma-phase solid solution of chromium in the base element. The invention also relates to the manufacture of such an article. The article may in particular be a gas turbine component.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: October 31, 2000
    Assignee: Siemens Aktiengesellschaft
    Inventors: Norbert Czech, Knut Halberstadt, John Smith, Adrian Kempster
  • Patent number: 6113709
    Abstract: The present invention is drawn to a method of lowering the net resistivity of an interconnect by depositing a monomer layer upon an aluminum bonding pad, the treatment thereof to cross link the monomer to form an electrically conductive polymer, and simultaneously, the substantial reduction of alumina, Al.sub.2 O.sub.3, to metallic aluminum. In the method of the present invention, deposition of a monomer layer in a solvent, volatilization of the solvent, and contact with a strong oxidizer such as a potassium permanganate allows for the use of the strong oxidizer without the hindrance of having to deal with a manganese oxide husk on the surface of the aluminum bonding pad. Preferably, the chemical qualities of the monomer will include the tendency to be a reducing agent to the native oxide film of the bonding pad. By selecting a monomer that tends to reduce rather than to oxidize, the problem of thickening the native oxide film is avoided.
    Type: Grant
    Filed: April 15, 1998
    Date of Patent: September 5, 2000
    Assignee: Micron Technology, Inc.
    Inventors: Tongbi Jiang, Li Li
  • Patent number: 6068001
    Abstract: Process for stainless steel pickling consisting in placing the material to be treated in a bath kept at a temperature ranging from 30.degree. C. to 70.degree. C. and containing:a) HClb) Fe.sup.3+c) HFd) emulsifiers, wetting agents, polishing agents, acid attack inhibitors;the bath being fed continuously with:an air flow equal to at least 3 m.sup.3 /h per m.sup.3 bath min. and an oxidizer quantity adjusted to the bath redox potential to be kept at 250 mV min.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: May 30, 2000
    Assignee: Novamax ITB S.R.L.
    Inventors: Cesare Pedrazzini, Paolo Giordani
  • Patent number: 6040054
    Abstract: A chromium-free composition for treating metal surface comprising (a) a hydroxyl group-containing organic resin, (b) a phosphoric acid and (c) at least one of ions and compounds of at least one metal selected from the group consisting of Cu, Co, Fe, Mn, Sn, V, Mg, Ba, Al, Ca, Sr, Nb, Y and Zn, and (d) at least one of colloids (sol) or powders of SiO.sub.2, SnO.sub.2, Fe.sub.2 O.sub.3, Fe.sub.3 O.sub.4, MgO, ZrO.sub.2, Al.sub.2 O.sub.3 and Sb.sub.2 O.sub.5 ; as well as a metal sheet or metal article having thereon (i) a coating film of the chromium-free composition and optionally (ii) a coating film of a coating composition comprising an organic resin and if desired a colloid (sol) or a powder.
    Type: Grant
    Filed: January 29, 1997
    Date of Patent: March 21, 2000
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Hisao Odashima, Tomomi Takahashi, Toshiyuki Shimizu
  • Patent number: 6033492
    Abstract: The uniformity of gloss of a dried autodeposited resin film on a metal surface can be increased by rinsing the wet autodeposited film initially formed with an aqueous modifying rinse having a pH from 6 to 11 and comprising from 0.2 to 10.0 g/L in total of polymers of carboxylic acid monomers having an ethylenic double bond and salts thereof.
    Type: Grant
    Filed: January 26, 1998
    Date of Patent: March 7, 2000
    Assignee: Henkel Corporation
    Inventors: Takumi Honda, Mutsumi Hirota, Norifumi Hatano
  • Patent number: 6033495
    Abstract: The disclosure relates to aqueous-based gels and, in some cases, usage of such gels to impart corrosion resistance to steel and/or zinc containing surfaces, e.g., galvanized steel. The gel comprises water, at least one thickener, at least one silica containing material and an optional surfactant.
    Type: Grant
    Filed: January 30, 1998
    Date of Patent: March 7, 2000
    Assignee: Elisha Technologies Co LLC
    Inventors: Nancy M. McGowan, John Hahn
  • Patent number: 6024805
    Abstract: A method for reducing the corrosion potential of steel vessels and piping used in nuclear reactors, in particular steel vessels and piping carrying high temperature water and/or steam which has a concentration of oxygen therein. A metal hydride is added to the water, the hydrogen of such metal hydride combining with oxidizing agents, typically oxygen, present in the water to reduce the concentration of such oxidizing agents. In the preferred embodiment the metal of the metal hydride is a metal that is capable of reacting with oxygen to form a substantially non-water soluble and substantially electrically insulating compound on the surface of the steel, and in particular is one that may react with and become deposited or incorporated into a pre-existing thin oxide film layer on the surface of the steel to thereby render such thin oxide layer substantially non-electrically conducting.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: February 15, 2000
    Assignee: General Electric Company
    Inventors: Young Jin Kim, Peter Louis Andresen, George Charles Sogoian
  • Patent number: 5985045
    Abstract: A chemical-mechanical polisher (10) includes a mixer section (12) that mixes components of a polishing fluid prior to introducing the polishing fluid into a polishing section (13) of the polisher (10). In one embodiment, components from feed lines (113 and 114) are combined in a manifold (121) and flowed through a static in-line mixer (123) to mix the components to form the polishing fluid. The polishing rate of the polishing fluid is relatively high because the mixing occurs near the point of use. Local concentrations of the components of the polishing fluid near a substrate (134) should be relatively uniform because the polishing fluid is mixed prior to reaching the substrate (134).
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: November 16, 1999
    Assignee: Motorola, Inc.
    Inventor: Thomas S. Kobayashi
  • Patent number: 5958152
    Abstract: To provide heat-resistant alloy members that maintain the resistance to corrosion at high temperature of the chromized layer formed on Ni- or Co-base heat-resistant alloys and which yet are improved in various mechanical properties. The improved Ni- or Co-base heat-resistant alloy member having a chromized layer that is characterized by having a chromium concentration of 25-80% and a thickness of 10-100 .mu.m. This member is produced by controlling both the vapor pressure of a chromium halide being used in chromization and the temperature therefor in such a way that the chromized layer being formed is adjusted to have a chromium concentration and a thickness within the ranges specified above.
    Type: Grant
    Filed: May 23, 1997
    Date of Patent: September 28, 1999
    Assignees: Ebara Corporation, Tocalo Co., Ltd.
    Inventors: Shuhei Nakahama, Hisamichi Nagahara, Masamichi Kawasaki, Yoshio Harada
  • Patent number: 5944917
    Abstract: A stainless steel having excellent corrosion resistance to ozone added water, such as ozone added ultrapure water used in semiconductor manufacturing processes and the like, as well as a manufacturing method. The stainless steel comprises a base metal and an oxide film formed on the surface of the base metal, the base metal being a stainless steel which contains 12 to 30% of Cr, 0 to 35% of Ni, and 1 to 6% of Al and Si while the contents of the other alloying elements are limited to as low a level as possible, the oxide film mainly comprising Al oxide or a Si oxide or both. The oxide film may be formed on the base metal surface through the dry oxidation process or the wet oxidation process. In the stainless steel, metallic ions are rarely dissolved from the base metal into the ozone added water.
    Type: Grant
    Filed: May 29, 1997
    Date of Patent: August 31, 1999
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Kiyoko Takeda, Shigeki Azuma, Yoshio Tarutani, Yoshitaka Nishiyama, Yasushi Matsuda
  • Patent number: 5901071
    Abstract: The composition of an alloy is inhomogeneous, so that the Fermi level of electrons in the surface of the alloy differs depending upon positions. It is accordingly considered that a part susceptible to corrosion and a part less susceptible thereto will coexist in the alloy. The corrosion rate of the alloy is indicated as the exponential function of a potential difference (.DELTA..PHI..sub.H) within an electric double layer. The potential difference remains unchanged as long as the Fermi level lies within the forbidden band of the electrons. However, in a range in which the Fermi level falls within the valence band of the electrons, the lowering thereof leads to the increase of the potential difference.
    Type: Grant
    Filed: June 28, 1995
    Date of Patent: May 4, 1999
    Assignee: Hitachi, Ltd.
    Inventors: Masanori Sakai, Noriyuki Ohnaka, Yuichi Ishikawa, Haruo Fujimori, Yusuke Isobe, Takuya Takahashi
  • Patent number: 5882439
    Abstract: To provide heat-resistant alloy members that maintain the resistance to corrosion at high temperature of the chromized layer formed on Ni- or Co-base heat-resistant alloys and which yet are improved in various mechanical properties. The improved Ni- or Co-base heat-resistant alloy member having a chromized layer that is characterized by having a chromium concentration of 25-80% and a thickness of 10-100 .mu.m. This member is produced by controlling both the vapor pressure of a chromium halide being used in chromization and the temperature therefor in such a way that the chromized layer being formed is adjusted to have a chromium concentration and a thickness within the ranges specified above.
    Type: Grant
    Filed: September 11, 1996
    Date of Patent: March 16, 1999
    Assignees: Ebara Corporation, Tocalo Co., Ltd.
    Inventors: Syuhei Nakahama, Hisamichi Nagahara, Masamichi Kawasaki, Yoshio Harada
  • Patent number: 5874167
    Abstract: Thin film metal particulates are removed from FEP sheetstock cheaply and quickly by immersing the coated FEP first in a base and then in an acid. Occasionally, ultrasonic vibration of the FEP may also be required. The particulates are useful as paint pigments when isolated and conversion coated. The FEP is reusable.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: February 23, 1999
    Assignee: The Boeing Company
    Inventors: Diane C. Rawlings, Micheal E. Dickson, Philip M. Lemoine, Kevin R. Malone
  • Patent number: 5866271
    Abstract: A method is provided for bonding a ceramic thermal barrier coating to a nickel or cobalt based superalloy substrate for use in high temperature applications such as gas turbine engines. The method comprises roughening the superalloy substrate itself to produce a surface roughness, preferably from 100 to 350 microinches Roughness Average (RA). The roughened surface of the substrate is treated with a diffusion coating, preferably aluminide or platinum-aluminide to provide oxidation and hot corrosion resistance, while substantially preserving the micro-topography of the roughened surface. A ceramic thermal barrier coating is applied directly to the diffusion treated surface, preferably using an air plasma spray. The surface roughness, which is left substantially undisturbed by the diffusion coating treatment, is altered by the air plasma sprayed ceramic to form a series of interlocking microstructures that firmly attach the ceramic thermal barrier coating to the diffusion treated superalloy substrate.
    Type: Grant
    Filed: October 21, 1997
    Date of Patent: February 2, 1999
    Inventors: Richard J. Stueber, Frank Boorboor, Natarajan S. Palanisamy
  • Patent number: 5858122
    Abstract: Disclosed is a material capable of readily developing natural patina, comprising a basis material made of Cu or a Cu alloy at least on the surface; and a layer of at least one compound selected from the group consisting of CuCl, CuBr and CuI formed on the surface of said basis material, and also a process for producing such material, which comprises anodizing the surface of a basis material made of Cu or a Cu alloy at least on the surface in an aqueous solution containing at least one kind of halogen ion selected from the group consisting of Cl.sup.-, Br.sup.- and I.sup.-. This material develops natural patina in a very short time after exposure outdoors.
    Type: Grant
    Filed: February 29, 1996
    Date of Patent: January 12, 1999
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Toshio Tani, Minoru Igarashi, Hideo Suda
  • Patent number: 5795408
    Abstract: The process forms a phosphate coating on a steel strip or sheet having a galvanized or alloy galvanized side and a steel side so that the phosphate coating is only present on the galvanized or alloy galvanized side. This process includes contacting the galvanized or alloy galvanized side of the steel strip or sheet with a phosphatizing solution for 4 to 20 seconds at a temperature of from 45.degree. C. to 80.degree. C. The phosphatizing solution has an S value of from 0.08 to 0.30 and contains 0.5 to 5 g/l zinc, 3 to 20 g/l P.sub.2 O.sub.5, 0.020 to 0.2 g/l nitrite, 3 to 30 g/l nitrate and 0.2 to 2.5 g/l complexing agent for iron. Chelate forming substances, such as tartaric acid, citric acid, ethylenediamine-tetraacetic acid, nitrilotriacetic acid and/or oxalic acid, may be used as the complexing agent for iron. The phosphatizing solutions may also contain other bivalent cations, particularly manganese and/or nickel cations.
    Type: Grant
    Filed: July 8, 1996
    Date of Patent: August 18, 1998
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Klaus Bittner, Walter K.M. Jansen, Klaus-Peter Mohr, Thomas Wendel, Hardy Wietzoreck
  • Patent number: 5779818
    Abstract: A process for the production of corrosion-protected metallic materials by passivation is described, in which a layer of an intrinsically conductive polymer is deposited on the metallic material, and the coated metallic material is brought into contact with oxygen-containing water until the equilibrium potential is reached, with polyaniline in particular being used as conductive polymer.
    Type: Grant
    Filed: March 6, 1996
    Date of Patent: July 14, 1998
    Assignee: Zipperling Kessler & Co.
    Inventor: Bernhard Wessling
  • Patent number: 5667845
    Abstract: A process enhances corrosion resistance of autodeposited coatings on metallic surfaces by contacting the uncured coating on the metallic surface with a reaction rinse solution containing complex fluoride anions. In a preferred use, because the protective properties of the autodeposited coatings are improved on both cold rolled and galvanized steel, both may be processed simultaneously, providing practical and economic advantages.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: September 16, 1997
    Assignee: Henkel Corporation
    Inventors: Oscar E. Roberto, Shawn E. Dolan
  • Patent number: 5620521
    Abstract: A method for surface treatment in which a fluidizable powder mixture consisting of a powder of a refractory material, and a surface layer-forming powder of a metal, or alloy or both is fluidized by a fluidizing gas supplied through a gas distributor to form above the gas distributor a fluidized bed in which a surface layer is formed on the material to be treated under heating in the presence of a halide. A layer of coarse particles is disposed between the fluidized bed and the gas distributor, and the coarse particles have a mean diameter, D(m), as defined below:(1650V.mu./PG).sup.1/2 <D<6.5dwhereV: velocity of the fluidizing gas (m/s);.mu.: viscosity coefficient of the fluidizing gas (kg/m.multidot.s);P: mean density of the coarse particles (kg/m.sup.3);G: acceleration of gravity (9.8 m/s.sup.2);d: mean particle diameter of the surface layer-forming powder (m).
    Type: Grant
    Filed: February 10, 1995
    Date of Patent: April 15, 1997
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Hideo Tachikawa, Hiromasa Takeda, Kazuyuki Nakanishi
  • Patent number: 5569334
    Abstract: Stainless steel member for semiconductor fabrication equipment having a passive state coating on the surface of the stainless steel comprising, in weight percent, 0.1% or less of C, 2.0% or less of Si, 3.0% or less of Mn, 10% or more of Ni, 15 to 25% of Cr, 1.5 to 4.5% of Mo, 0.5% or less of one or more rare earth element and Fe for substantially the whole remainder. Said passive state coating has a pitting potential of at least 900 mV (when the current density of the anode polarization curve determined with a potentiostat in 3.5% aqueous sodium chloride solution is 10 .mu.A/cm.sup.2) and has a thickness of 0.5 to 20 nm. The invention also includes a surface treatment method for the stainless steel.
    Type: Grant
    Filed: December 7, 1993
    Date of Patent: October 29, 1996
    Assignee: Hitachi Metals, Ltd.
    Inventors: Tsunehiro Kawata, Katsuhiko Kojo, Youichiro Kazama, Takayuki Fukaya, Toshihiko Tsujimura
  • Patent number: 5552027
    Abstract: A working electrode or an electrochemical-enzymatic sensor system has a metallic base body which is provided with a thin layer of amorphous hydrogenated carbon (a-C:H).
    Type: Grant
    Filed: July 18, 1995
    Date of Patent: September 3, 1996
    Assignee: Siemens Aktiengesellschaft
    Inventors: Siegfried Birkle, Johann Kammermaier, deceased, Rolf Schulte
  • Patent number: 5498484
    Abstract: A thermal barrier coating system for high temperature nickel-based and cobalt-based superalloys includes a hardenable metallic coating on the substrate and a ceramic topcoat. The metallic coating is preferably a gamma/gamma prime hardenable nickel-based superalloy, and the ceramic topcoat is preferably zirconium oxide having from about 6 to about 20 percent yttrium oxide or from about 15 to about 40 percent cerium oxide. Optionally, there may be provided between the hardenable metallic layer and the ceramic topcoat an intermetallic coating such as a nickel aluminide.
    Type: Grant
    Filed: May 7, 1990
    Date of Patent: March 12, 1996
    Assignee: General Electric Company
    Inventor: Edward C. Duderstadt
  • Patent number: 5458917
    Abstract: In a continuous surface treating method and apparatus with an inline centrifugal separator, an object to be treated is contained in a basket and hung from a hanger of an overhead type and a series of surface treatments of the object is carried out by using a continuous conveyer of a power and free type. By using a hanger attach-detach conveyer, the object is moved from a main conveyer to a sub-conveyer and an excessive treating liquid attached to the object in a previous process is separated by using the centrifugal separator. Then, the object is returned from the sub-conveyer to the main conveyer to perform a next process. The surface treating apparatus includes the rotatable basket for containing the object.
    Type: Grant
    Filed: June 18, 1993
    Date of Patent: October 17, 1995
    Assignees: Showa Aluminum Corporation, Nippon Paint Co., Ltd.
    Inventors: Tsutomu Motohashi, Masahiro Kojima, Fujio Mikami, Kiyotada Yasuhara, Kageki Fujimoto
  • Patent number: 5411606
    Abstract: (A) A process for forming an oxide film cobalt conversion coating on a metal substrate, thereby imparting corrosion resistance and paint adhesion properties. The invention was developed as a replacement for the prior art chromic acid process. The process includes the steps of: (a) providing a cobalt conversion solution comprising an aqueous reaction solution containing a soluble cobalt-III hexacoordinated complex, the concentration of the cobalt-III hexacoordinated complex being from about 0.01 mole per liter of solution to the solubility limit of the cobalt-III hexacoordinated complex; and (b) contacting the substrate with the aqueous reaction solution for a sufficient amount of time, whereby the cobalt conversion coating is formed. The substrate may be aluminum or aluminum alloy, as well as Cd plated, Zn plated, Zn--Ni plated, and steel. The cobalt-III hexacoordinated complex may be present in the form of Me.sub.m [Co(R).sub.6 ].sub.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: May 2, 1995
    Assignee: The Boeing Company
    Inventor: Matthias P. Schriever
  • Patent number: 5409156
    Abstract: An aluminum sheet for use in spot welding has an anodic oxide film with a thickness of 50 .mu.m or less on at least one surface thereof. The anodic oxide film is preferably overlaid with a plating layer predominantly comprising at least one metal selected from the group consisting of Zn, Cr, Co, Ni, Fe, and Mn. The aluminum sheet can be produced by subjecting an aluminum or aluminum alloy sheet to anodic oxidation in an acidic solution having a pH of 4 or less conditions of from 2 to 200 V in voltage and from 0.2 to 200 seconds in duration, optionally followed by electroplating in an acidic plating bath.
    Type: Grant
    Filed: June 11, 1992
    Date of Patent: April 25, 1995
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Masanori Tsuji, Yoshihiko Hoboh, Kazuyuki Fujita
  • Patent number: 5399257
    Abstract: Hydrocarbon conversion processes having a susceptibility to coke formation on the internal surfaces of processing equipment are improved by inhibiting the formation of coke with the use of a glass bead treatment for the metal surfaces. After treating with ordinary glass bead cleaning methods, metal surfaces are found to inhibit coke formation. The glass bead treatment is easily performed and, therefore, offers advantages over other chemical treatments for the deposition of silica on reactor internals.
    Type: Grant
    Filed: November 30, 1993
    Date of Patent: March 21, 1995
    Assignee: UOP
    Inventors: Michael B. Russ, Chi-Chu D. Low, Jeffry T. Donner
  • Patent number: 5372853
    Abstract: A process of retaining or enhancing corrosion resistance of autodeposited coatings on metallic surfaces by contacting the uncured coating on the metallic surface with a rinse solution containing hydrofluorozirconic acid or a salt thereof, such as nickel or cobalt salt. The metallic surface may be cold rolled steel or galvanized steel. The resinous autodeposited coatings are poly{vinylidene chloride} polymers. Copolymers containing at least 50% by weight poly{vinylidene chloride} are suitable. Because the protective properties of the autodeposited coatings are improved on both types of steel, both may be processed simultaneously, providing practical and economic advantages.
    Type: Grant
    Filed: August 5, 1993
    Date of Patent: December 13, 1994
    Assignee: Henkel Corporation
    Inventor: Oscar E. Roberto
  • Patent number: 5342455
    Abstract: A process for generating in-situ low-cost atmospheres suitable for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals, sealing glass to metals, and sintering metal and ceramic powders in a continuous furnace from non-cryogenically produced nitrogen containing up to 5% residual oxygen is presented. The disclosed process involves mixing nitrogen gas containing residual oxygen with a predetermined amount of a hydrocarbon gas, feeding the gaseous mixture through a nonconventional device into the hot zone of a continuous heat treating furnace, converting residual oxygen to an acceptable form such as a mixture of moisture and carbon dioxide, a mixture of moisture, hydrogen, carbon monoxide, and carbon dioxide, or a mixture of carbon monoxide, moisture, and hydrogen, and using the resultant gaseous mixture for annealing and heat treating metals and alloys, brazing metals, sintering metal and ceramic powders, and sealing glass to metals.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: August 30, 1994
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Brian B. Bonner, Diwakar Garg, Donald P. Eichelberger, Donald J. Bowe
  • Patent number: 5336336
    Abstract: A process for a chemical treatment with a phosphate by bringing a steel material into contact with a phosphate chemical treatment bath maintained at 40.degree. C. or less and containing a phosphate ion, a nitrate ion, a chemical film formable metal ion and an oxidizing agent, to cause a film formation reaction between the phosphate chemical treatment bath and the steel material, whereby a phosphate chemical film is formed on the surface of the steel, wherein a circulation path for withdrawing a portion of the phosphate chemical treatment bath and returning the withdrawn phosphate chemical treatment bath to the bath is provided, and a filter comprising an inorganic material composed of SiO.sub.2 and Al.sub.2 O.sub.3 is provided in the circulation path, of which filter not only enables sludge from the phosphate chemical treating solution to be physically removed but also prevents changes the chemical structure in the form of a solution.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: August 9, 1994
    Assignee: Nippondenso Co., Ltd.
    Inventor: Shigeki Matsuda
  • Patent number: 5320689
    Abstract: There is provided a composite copper alloy having a copper alloy core and a modified surface layer containing a nitride or carbide film. Alternatively, the modified surface layer may contain a carbo-nitride film. The alloy is formed by reacting a copper alloy with nitrogen, carbon or a nitrogen/carbon mixture at elevated temperatures. The resultant surface layer improves the tribological and mechanical properties of the alloy while maintaining useful electrical conductivity.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: June 14, 1994
    Assignee: Olin Corporation
    Inventors: Deepak Mahulikar, Brian Mravic
  • Patent number: 5312491
    Abstract: Rust inhibiting compositions having improved elasticity properties are provided. The compositions contain oxime based rust converter compounds formulated with a latex based paint to provide a flexible film coating that acts as a barrier to oxygen and water vapor diffusion to the metal surface. Methods for applying the rust inhibiting compositions to metal surfaces are also provided.
    Type: Grant
    Filed: June 8, 1992
    Date of Patent: May 17, 1994
    Inventor: Randolph K. Binter
  • Patent number: 5281484
    Abstract: Coated components are produced to withstand high stresses and are composed of the intermetallic phase titanium aluminide material for use, in particular, in piston engines, gas turbines and exhaust gas turbochargers. This material has good technical properties but otherwise only a low resistance to oxidation and wear as a result of friction processes. These disadvantages are overcome in that the components are coated, at least on the parts of their surface which are at risk of hot corrosion and/or wear, with a sheet of a solderable nickel-based alloy soldered on under vacuum. A coating thickness of 0.1 to 0.4 mm is adequate. The nickel-based alloys, of which the soldered-on sheet is composed, preferably have a melting point of below 1180.degree. C.
    Type: Grant
    Filed: January 28, 1993
    Date of Patent: January 25, 1994
    Assignee: Mercedes-Benz AG
    Inventors: Eggert Tank, Wolfgang Kleinekathofer
  • Patent number: 5259893
    Abstract: A process for generating in-situ low-cost atmospheres suitable for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals, sealing glass to metals, and sintering metal and ceramic powders in a continuous furnace from non-cryogenically produced nitrogen containing up to 5% residual oxygen is presented. The disclosed process involves mixing nitrogen gas containing residual oxygen with a predetermined amount of a hydrocarbon gas, feeding the gaseous mixture through a nonconventional device into the hot zone of a continuous heat treating furnace, converting residual oxygen to an acceptable form such as a mixture of moisture and carbon dioxide, a mixture of moisture, hydrogen, carbon monoxide, and carbon dioxide, or a mixture of carbon monoxide, moisture, and hydrogen, and using the resultant gaseous mixture for annealing and heat treating metals and alloys, brazing metals, sintering metal and ceramic powders, and sealing glass to metals.
    Type: Grant
    Filed: November 5, 1991
    Date of Patent: November 9, 1993
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Brian B. Bonner, Diwakar Garg, Donald P. Eichelberger
  • Patent number: 5221369
    Abstract: A process for generating in-situ low-cost atmospheres suitable for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals and ceramics, sealing glass to metals, and sintering metal and ceramic powders in a continuous furnace from non-cryogenically produced nitrogen containing up to 5% residual oxygen is presented. The disclosed process involves mixing nitrogen gas containing residual oxygen with a pre-determined amount of a reducing gas such as hydrogen, a hydrocarbon, or a mixture thereof, feeding the gaseous mixture through a non-conventional device into the hot zone of a continuous heat treating furnace, converting residual oxygen to an acceptable form such as moisture, a mixture of moisture and carbon dioxide, or a mixture of moisture, hydrogen, carbon monoxide and carbon dioxide, and using the resultant gaseous mixture for annealing and heat treating metals and alloys, brazing metals and ceramics, sintering metal and ceramic powders, and sealing glass to metals.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: June 22, 1993
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Donald J. Bowe, Brian B. Bonner, Diwakar Garg
  • Patent number: 5209787
    Abstract: A composite copper alloy having a modified surface is provided. An element or combination of elements both soluble in copper and reactive with nitrogen are cast with copper or a copper alloy forming a solid state solution. The alloy is reacted with a nitride former to modify the surface. A continuous surface film is formed by heating in a nitrogen containing gas. A dispersion of nitride precipitate in a copper matrix is formed by implanting nitrogen ions.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: May 11, 1993
    Assignee: Olin Corporation
    Inventors: John F. Breedis, George J. Muench
  • Patent number: RE34272
    Abstract: A composition for use in the vibratory mass finishing of magnetic stainless steel objects contains oxalic acid, sodium m-nitrobenzene sulfonate, and sodium thiocyanate, the latter two compounds being present in specified rations to one another. The preferred compositions include a hydroxyalkyl amine; for certain applications, they most desirably also include a poly(oxyethylene)alkyl alcohol surfactant.
    Type: Grant
    Filed: October 30, 1991
    Date of Patent: June 8, 1993
    Assignee: Rem Chemicals, Inc.
    Inventors: Mark D. Michaud, Robert G. Zobbi