Abstract: An electric current is passed through an acidic solution containing one or more soluble metal salts in an electrolytic cell divided by an anion exchange membrane. The acidic solution is fed into the cathode compartment whereby the passage of electric current at sufficient voltage causes the generation of hydrogen at the cathode. This gives rise to a localized very highly polarized region at the cathode resulting in a localized effective high relative pH. This causes the metal cation species to precipitate as a hydroxide (or oxide) species and electroadsorption/electrocoagulation causes the finely precipitated hydroxide (or oxide) species to adhere to the cathode. Electrodialytic transport of the liberated acid anions across the anion exchange membrane selectively removes the acid anions. Oxygen and hydrogen ions are formed by hydrolysis as the counter-reaction at the anode. Hydrogen ions combine with the anions to regenerate sulfuric acid.

Abstract: An object is to provide a material suitably used for a semiconductor included in a transistor, a diode, or the like. Another object is to provide a semiconductor device including a transistor in which the condition of an electron state at an interface between an oxide semiconductor film and a gate insulating film in contact with the oxide semiconductor film is favorable. Further, another object is to manufacture a highly reliable semiconductor device by giving stable electric characteristics to a transistor in which an oxide semiconductor film is used for a channel. A semiconductor device is formed using an oxide material which includes crystal with c-axis alignment, which has a triangular or hexagonal atomic arrangement when seen from the direction of a surface or an interface and rotates around the c-axis.

Abstract: The present invention is directed to a method of making metal oxide and mixed metal oxide particles. The method includes treating a mixture formed from a metal source, such as metal alkoxide, a surfactant, and a first alcohol in an aqueous media at a very high metal oxide yield. The mixture is reacted using a catalyst to form metal oxide particles having a desired particle size in said mixture. The method is particularly suitable for forming silica particles. The metal oxide particles can then be heat treated to form synthetic fused metal oxides such as, for example, synthetic fused silica.

Abstract: An object of the present invention is to provide a method for producing metal oxide particles, in which metal oxide particles with high photocatalytic activity is produced, and a production apparatus therefor. The above object can be achieved by using a method for producing metal oxide particles, which includes subjecting a reaction gas containing metal chloride and an oxidizing gas containing no metal chloride in a reaction tube (11) to preheating, and then subjecting a combined gas composed of the reaction gas and the oxidizing gas to main heating in a main heating region (A) apart from the downstream side of the junction (5b), wherein the time until the combined gas from the junction (5b) arrives at the upstream end (A1) of the main heating region (A) is adjusted to be less than 25 milliseconds.

Abstract: A metal oxide electrode catalyst which includes a metal oxide (Y) obtained by heat treating a metal compound (X) under an oxygen-containing atmosphere. The valence of the metal in the metal compound (X) is smaller than the valence of the metal in the metal oxide (Y). Further, the metal oxide electrocatalyst has an ionization potential in the range of 4.9 to 5.5 eV.

Abstract: The present invention provides reagents that may be useful for treating wastes such as impure aqueous materials including wastewater to remove a significant proportion of the heavy metals that may be contained therein. The reagents include a calcium aluminosilicate (CAS) source and may include one or more of the following elements as an oxide: calcium oxide, aluminum oxide, silicon oxide, iron oxide, magnesium oxide, sodium oxide, potassium oxide, and sulfate. Further, the reagent comprises lime either as CaO or Ca(OH)2. In addition, the invention provides methods for treating wastes such as impure aqueous materials to remove a significant proportion of the heavy metals contained therein.

Abstract: Methods for preparing high quality and high yields of nanocrystals, i.e., metal-oxide-based nanocrystals, using a novel solvent-free method. The nanocrystals advantageously comprise organic alkyl chain capping groups and are stable in air and in nonpolar solvents.

Abstract: Disclosed is a new thermoelectric conversion material represented by the chemical formula 1: Bi1-xCu1-yO1-zTe, where 0?x<1, 0?y<1, 0?z<1 and x+y+z>0. A thermoelectric conversion device using said thermoelectric conversion material has good energy conversion efficiency.

Abstract: The present invention relates to a process for dissolving metals in perhalide containing ionic liquids, and to the extraction of metals from mineral ores; the remediation of materials contaminated with heavy, toxic or radioactive metals; and to the removal of heavy and toxic metals from hydrocarbon streams.

Abstract: The present invention relates to a process for producing a nanocomposite material from a) at least one inorganic or organometallic metal phase; and b) an organic polymer phase; comprising the polymerization of at least one monomer M which have at least one first polymerizable monomer unit A which has a metal or semimetal M, and at least one second polymerizable organic monomer unit B which is joined to the polymerizable unit A via a covalent chemical bond, under polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond between A and B, the monomers M to be polymerized comprising a first monomer M1 and at least one second monomer M2 which differs at least in one of the monomer units A and B from the monomer M1 (embodiment 1), or the monomers to be polymerized comprising, as well as the at least one monomer M, at least one further monomer other than the monomers M, i.e.

Abstract: Provided is a roasting method capable of reducing both C and S components in minerals down to 0.5% or less, respectively, and securing a yield ratio of 90% or more for the Mo component. In a rotary kiln 7, a V, Mo and Ni containing material containing C and S components is subjected to oxidizing roasting to remove the C and S components from the material before reducing the material by means of a reducing agent in order to recover valuable metals composed of V, Mo and Ni. The rotary kiln is equipped with a burner 11 disposed on a material charge side 8a of the roasting furnace 8 to which the material is charged. In the roasting furnace, a direction along which the material moves and a flow of oxygen-containing gas introduced into the roasting furnace 8 are set to be parallel with each other.

Abstract: A method for manufacturing a cathode active material for a lithium rechargeable battery, including: selecting a first metal compound from a group consisting of a halide, a phosphate, a hydrogen phosphate and a sulfate of Mg or Al; selecting a second metal compound from a group consisting of an oxide, a hydroxide and a carbonate of Mg or Al; combining the first metal compound and the second metal compound to obtain a metal compound, the metal compound containing either Mg or Al atoms; mixing a lithium compound, a transition metal compound and the metal compound to obtain a mixture; and sintering the mixture.

Abstract: In processes for removing ruthenium by distilling RuO4 from ruthenate-containing solutions with these steps of the treatment of the ruthenate-containing solution with an oxidising agent, distilling off of the RuO4 formed, absorbing the RuO4 from step II in hydrochloric acid, the oxidising agent is recycled into step I following step III. The processes can be carried out in reactor modules with A a reactor with a stirrer, gas inlet and gas outlet, B at least one scrubber connected in series downstream with the gas outlet via a line, C one or several gas absorbers connected in series downstream with the at least one scrubber via lines, E at least one line from the optionally last absorber for recycling into the gas inlet of the reactor or into a further module or into a facility for off-gas treatment.

Abstract: A process for producing metal oxide from a metal salt includes supplying a first part of the metal salt to a hydrate drier so as to indirectly heat the first part of the metal salt in the hydrate drier using a heat transfer medium from a first stage of a multi-stage indirect cooler so as to dry the first part of the metal salt in the hydrate drier and so as to control a waste gas temperature of the process. A second part of the metal salt is guided as a partial stream past the hydrate drier. The metal salt is preheated in a first preheating stage and precalcined in a second preheating stage. The metal salt and a fluidizing gas having a temperature of 150° C. or less are supplied to a fluidized bed reactor so as to calcine the metal salt to form a metal oxide product. The metal oxide product is cooled in at least one suspension heat exchanger and then in the multi-stage indirect cooler.

Abstract: A method for producing a densified fumed metal oxide having an increased bulk density and substantially the same surface area as an undensified fumed metal oxide with the same molecular composition is provided. The fumed metal oxide is wetted with a solvent to form a wetted fumed metal oxide. The wetted fumed metal oxide is dried to form a dried fumed metal oxide. The dried fumed metal oxide is calcined.

Abstract: A process for producing metal oxide from metal salts includes cleaning a metal salt in a filter. After cleaning, the metal salt is dried in a drying apparatus. Steam is formed in the drying apparatus. The metal salt is preheated in at least one preheating stage. The metal salt is calcined to metal oxide in a fluidized-bed reactor. The metal oxide is cooled. The steam formed in the drying apparatus is recirculated into the filter.

Abstract: The present invention relates to the synthesis of nanoparticles by laser hydrolysis. For this purpose, a precursor interacts with a laser beam (LAS) in a pyrolysis reactor (REAC) for producing nanoparticles (nP), characterized in that the precursor is firstly in the liquid state and is then converted into the vapor phase and in that the flow rate of the precursor is controlled in the liquid phase.

Abstract: Disclosed is a porous metal oxide obtained by subjecting metal alkoxide and/or a partially hydrolyzed condensate of the metal alkoxide to a sol-gel reaction in the presence of terminally branched copolymer particles represented by the following general formula (1) and having a number average molecular weight of not more than 2.

Abstract: The invention relates to a cutting tool having a substrate base body and a single or multi-layered coating attached thereupon, wherein at least one layer of the coating is a metal oxide layer produced in the PVD process or in the CVD process and the metal oxide layer has a grain structure wherein there is structural disorder within a plurality of the existing grains that are characterized in that in electron diffraction images of the grains, point-shaped reflections occur up to a maximum lattice spacing dGRENZ and for lattice spacing greater than dGRENZ no point-shaped reflections occur, but rather a diffuse intensity distribution typical for amorphous structures.

Abstract: A nanoparticle including a Group 3 atom-containing shell. In various embodiments, the nanoparticle includes a metal or metal catalyst-containing core, or a substantially metal-free core. In other embodiments, the nanoparticle shell is hollow. A method of preparing the nanoparticle and methods of using such particles are also provided.

Abstract: The invention concerns a method for manufacturing nanoporous metal oxide or metal active sites frameworks in which the metal oxide precursor is distributed into the framework in the form of a metal soap surfactant. The invention also covers a nanostructure framework comprising metal oxide active sites which are evenly distributed in the framework.

Abstract: This invention relates, in general, to a method of producing magnetic oxide nanoparticles or metal oxide nanoparticles and, more particularly, to a method of producing magnetic or metal oxide nanoparticles, which comprises (1) adding a magnetic or metal precursor to a surfactant or a solvent containing the surfactant to produce a mixed solution, (2) heating the mixed solution to 50-6001 C to decompose the magnetic or metal precursor by heating so as to form the magnetic or metal oxide nanoparticles, and (3) separating the magnetic or metal oxide nanoparticles. Since the method is achieved through a simple process without using an oxidizing agent or a reducing agent, it is possible to simply mass-produce uniform magnetic or metal oxide nanoparticles having desired sizes compared to the conventional method.

Abstract: An optical element is disclosed which includes transparent superconductor material.

Abstract: The present invention provides an approach to control the generation and grow of nanocrystal with membrane diffusion method and related apparatuses to produce inorganic oxide nanopowders and metal nanoparticles. With this method, the size and size distribution of inorganic oxide nanopowders and metal nanoparticles can be tuned. It overcomes the shortcomings possessed by the common chemical and physical method of preparing nanoparticles.

Abstract: Nanoscale UV absorbing particles are described that have high UV absorption cross sections while being effectively transparent to visible light. These particles can be used to shield individuals from harmful ultraviolet radiation. These particles can also be used in industrial processing especially to produce solid state electronic devices by creating edges of photoresist material with a high aspect ratio. The UV absorbing particles can also be used as photocatalysts that become strong oxidizing agents upon exposure to UV light. Laser pyrolysis provides an efficient method for the production of suitable particles.

Abstract: Process for preparing a mixed metal oxide powder, in which oxidizable starting materials are evaporated and oxidized, the reaction mixture is cooled after the reaction and the pulverulent solids are removed from gaseous substances, wherein as starting materials, at least one pulverulent metal and at least one metal compound, the metal and the metal component of the metal compound being different and the proportion of metal being at least 80% by weight based on the sum of metal and metal component from metal compound, together with one or more combustion gases, are fed to an evaporation zone of a reactor, where metal and metal compound are evaporated completely under nonoxidizing conditions, subsequently, the mixture flowing out of the evaporation zone is reacted in the oxidation zone of this reactor with a stream of a supplied oxygen-containing gas whose oxygen content is at least sufficient to oxidize the starting materials and combustion gases completely.

Abstract: Methods for making high-surface area, high-porosity, stable metal oxides, such as, but not limited to materials used as adsorbents and catalyst supports include (i) forming a solvent deficient precursor mixture from a metal salt and a base and reacting the metal ions and base ions in the solvent deficient precursor mixture to form an intermediate hydroxide product (e.g., metal hydroxide or metal oxide hydroxide), (ii) causing the intermediate hydroxide to form nanoparticles (e.g., by heating), and (iii) calcining the intermediate nanoparticles to sinter the nanoparticles together and yield a highly porous, stable metal oxide aggregate having a pore structure.

Abstract: Disclosed is a method of manufacturing a metal oxide nano powder comprising preparing a first dispersed solution by adding a nano-sized metal powder to water and dispersing the metal powder within the water, performing a hydration reaction of the first dispersed solution at a temperature of about 30 to about 70° C. to generate a precipitation, and filtering and drying the precipitation to prepare a metal oxide powder. Also, disclosed is a metal oxide nano powder manufactured by the method described above, and having any one of a bar-form, a cube-form, and a fiber-form.

Abstract: A sintered body includes an indium oxide crystal, and an oxide solid-dissolved in the indium oxide crystal, the oxide being oxide of one or more metals selected from the group consisting of aluminum and scandium, the sintered body having an atomic ratio “(total of the one or more metals)/(total of the one or more metals and indium)×100)” of 0.001% or more and less than 45%.

Abstract: The invention provides surface-treated metal oxide particles. The surface-treated metal oxide particles have specific ratios of (1) the integrated area of the resonance signals with chemical shifts in the range from ?4 ppm to ?33 ppm to the integrated area of the resonance signals with chemical shifts in the range from ?33 ppm to ?76 ppm and (2) the integrated area of the resonance signals with chemical shifts in the range from ?76 ppm to ?130 ppm to the integrated area of the resonance signals with chemical shifts in the range from ?33 ppm to ?76 ppm in the CP/MAS 29Si NMR spectrum. The invention further provides a toner composition for electrophotographic image formation comprising toner particles and surface-treated metal oxide particles.

Abstract: There is provided a producing method of metal fine particles or metal oxide fine particles for producing metal fine particles or metal oxide fine particles by atomizing raw materials by performing processes including an oxidizing process and a reducing process to the raw materials composed of metal or a metal compound.

Abstract: An object of the present invention is to provide a method for producing a metal hydroxide fine particle, which can produce metal hydroxide fine particles with favorable crystallinity and small particle sizes. The present invention provides a method for producing a metal hydroxide fine particle by reacting a metal ion with a hydroxide ion in a solvent, which includes a mixing and reacting step of supplying the metal ion, the hydroxide ion, and a silane coupling agent to a reaction field to mix and react the ions.

Abstract: A metal oxide electrode catalyst which includes a metal oxide (Y) obtained by heat treating a metal compound (X) under an oxygen-containing atmosphere. The valence of the metal in the metal compound (X) is smaller than the valence of the metal in the metal oxide (Y). Further, the metal oxide electrocatalyst has an ionization potential in the range of 4.9 to 5.5 eV.

Abstract: Methods of producing a metal oxide are disclosed. The method comprises dissolving a metal salt in a reaction solvent to form a metal salt/reaction solvent solution. The metal salt is converted to a metal oxide and a caustic solution is added to the metal oxide/reaction solvent solution to adjust the pH of the metal oxide/reaction solvent solution to less than approximately 7.0. The metal oxide is precipitated and recovered. A method of producing adsorption media including the metal oxide is also disclosed, as is a precursor of an active component including particles of a metal oxide.

Abstract: A method of synthesizing metal chalcogenide nanocrystals involving the steps of combining an organodichalcogenide, a metal salt and a ligand compound to form a mixture; degassing the mixture to remove air and water from the mixture; heating the mixture at a temperature below the decomposition temperature of the organodichalcogenide for a period of time sufficient to form a metal chalcogenide nanocrystal.

Abstract: Described is a method for the production of pure or mixed metal oxides, wherein at least one metal precursor that is a metal carboxylate with a mean carbon value per carboxylate group of at least 3, e.g. the 2-ethyl hexanoic acid salt, is formed into droplets and e.g. flame oxidized. The method is performed at viscosities prior to droplet formation of usually less than 40 mPa s, obtained by heating and/or addition of one or more low viscosity solvents with adequately high enthalpy.

Abstract: Nanocrystalline metal powders comprising tungsten, molybdenum, rhenium or niobium can be synthesized using a combustion reaction. Methods for synthesizing the nanocrystalline metal powders are characterized by forming a combustion synthesis solution by dissolving in water an oxidizer, a fuel, and a base-soluble, ammonium precursor of tungsten, molybdenum, rhenium, or niobium in amounts that yield a soichiometric burn when combusted. The combustion synthesis solution is then heated to a temperature sufficient to substantially remove water and to initiate a self-sustaining combustion reaction. The resulting powder can be subsequently reduced to metal form by heating in a reducing gas environment.

Abstract: Wet-chemical methods involving the use of water-soluble hydrolytically stable metal-ion chelate precursors and an ammonium oxalate precipitant can be used in a coprecipitation procedure for the preparation of ceramic powders. Both the precursor solution and the ammonium oxalate precipitant solution are at neutral or near-neutral pH. A composition-modified barium titanate is one of the ceramic powders that can be produced. Certain metal-ion chelates can be prepared from 2-hydroxypropanoic acid and ammonium hydroxide.

Abstract: A method for making the metal oxide includes the following steps: mixing a metal nitrate with a solvent of octadecyl amine, and achieving a mixture; agitating and reacting the mixture at a reaction temperature for a reaction period; cooling the mixture to a cooling temperature, and achieving a deposit; and washing the deposit with an organic solvent, drying the deposit at a drying temperature and achieving a metal oxide nanocrystal. The present method for making a metal oxide nanocrystal is economical and timesaving, and has a low toxicity associated therewith. Thus, the method is suitable for industrial mass production. The metal oxide nanocrystal material made by the present method has a readily controllable size, a narrow size distribution, and good crystallinity.

Abstract: There is disclosed a process of making nano-sized or micro-sized precipitate particles. The process comprising the steps of mixing, in a reaction zone, a metal salt solution with a precipitant solution to form a precipitate, said precipitate being at least one of a metal chalcogenide, metal hydroxide and metal oxide; and applying a shear force to said mixing solutions in said reaction zone during said mixing step, wherein said shear force and the conditions within said reaction zone form said nano-sized or micro-sized precipitate particles.

Abstract: A metal-fueled cogeneration plant, comprising at least one reaction chamber, elements for introducing at least one water-based liquid oxidizer, and elements for supplying at least one metal-based fuel into the chamber, the oxidizer and the fuel being adapted to give rise to an exothermic oxidation reaction to obtain gaseous hydrogen and at least one metallic oxide. The introduction elements are adapted to introduce in the chamber a quantity of oxidizer that is substantially greater than the stoichiometric quantity to form steam and comprises at least one fluid-based motive power unit that is fed in input by at least the steam for the rotary actuation of a driving shaft, separation and recovery elements for at least the steam being interposed between the chamber and the inlet to the motive power unit, and elements for evacuation of the hydrogen being further provided.

Abstract: Process for the production of a metal oxide powder having a BET surface area of at least 20 m2/g by reacting an aerosol with oxygen in a reaction space at a reaction temperature of more than 700° C. and then separating the resulting powder from gaseous substances in the reaction space, wherein the aerosol is obtained by atomisation using a multi-component nozzle of at least one starting material, as such in liquid form or in solution, and at least one atomising gas, the volume-related mean drop diameter D30 of the aerosol is from 30 to 100 ?m and the number of aerosol drops larger than 100 ?m is up to 10%, based on the total number of drops, and metal oxide powder obtainable by this process.

Abstract: Dispersoids having metal-oxygen groups that are suitable for the production of metal oxide thin-films at a low temperature of 200° C. or below and for the production of homogeneous organic-inorganic hybrid materials. The dispersoid having metal-oxygen bonds may be obtained by mixing a metal compound having at least three hydrolyzable groups with at least 0.5 mole but less than 2 moles of water per mole of the metal compound in an organic solvent, in the absence of an acid, a base, and/or a dispersion stabilizer, and at a temperature at or below the temperature at which the metal compound begins to hydrolyze, then raising the temperature to at least the temperature at which hydrolysis begins.

Abstract: The invention relates to a spray pyrolysis method characterized in that it is used in the synthesis of nanoparticles with a closed structure of metal chalcogens having a lamellar crystalographic structure of general formula MaXb, wherein M represents a metal and X represents a chalcogen, a and b represent the respective proportions of metal and chalcogen, and in that it comprises pyrolysis of a liquid aerosol obtained from a solution of at least one metal precursor (M) and a chalcogen (X), or at least one precursor of said metal (M) and at least one precursor of said chalcogen (X) dissolved in a solvent, said solution being atomized into fine droplets in a suspension in a vector gas.

Abstract: A metal oxide powder includes a powder feed material structured and arranged to form molten droplets when melted in a plasma stream. The molten droplets are structured and arranged to form frozen spherical droplets under free-fall conditions such that said molten droplets have ample time for complete in-flight solidification before reaching a collection chamber.

Abstract: This invention relates to a 4 group metal oxide and to a method for preparation thereof and the 4 group metal oxide prepared by adding a particle growth inhibiter to a hydrosol a hydrogel or a dried product of a hydrous 4 group metal oxide represented by MO(2-x)(OH)2x (wherein M denotes a 4 group metal and x is a number greater than 0.1 or x>0.1) followed by drying and calcining has a specific surface area of 80 m2/g or more, a pore volume of 0.2 ml/g or more and a pore sharpness degree of 50% or more and excellent heat stability and is useful for a catalyst or a catalyst carrier in which a catalyst metal is dispersed to a high degree.

Abstract: Disclosed herein is an article having: a substrate and a RuO2 coating having nanoparticles of RuO2. Also disclosed herein is an article having: a substrate and a RuO2 coating. The coating is made by: immersing the substrate in a solution of RuO4 and a nonpolar solvent at a temperature that is below the temperature at which RuO4 decomposes to RuO2 and warming the substrate and solution to ambient temperature under ambient conditions to cause the formation of the coating.

Abstract: Disclosed is a flaky material formed of an aggregate of fine particles. The aggregate is formed by uniting fine particles to one another. The fine particles are derived from fine particles of an inorganic oxide dispersed in a solvent having an effective (OH?) content of 3×10?5 to 1×10?6 mol/l. The surface of the flaky material has a flatness degree equal to or lower than 0.5 ?m. The flaky material can provide viewers with a high brightness feeling.

Abstract: A method for preparing metal oxide particles having a primary particle size on the order of nanometers is provided. The method comprises subjecting a metal ion present in an aqueous solution and an amino alcohol to an initial stage of reaction with each other at normal temperatures under normal pressures for a given time, and adding at least once either of a metal ion or an amino alcohol or both thereof to the resulting reaction system for carrying out a subsequent stage of reaction for a given time wherein total amounts of the metal ion and the amino alcohol are such that the amino alcohol is used in the range of not less than a molar equivalent to the metal ion.

Abstract: The present invention relates to a system for generating hydrogen for an on-board device comprising a system for regenerating the material consumed by the generation of hydrogen.