Metal Containing Patents (Class 423/592.1)
  • Patent number: 7914755
    Abstract: Wet-chemical methods involving the use of water-soluble hydrolytically stable metal-ion chelate precursors and the use of a nonmetal-ion-containing strong base can be used in a coprecipitation procedure for the preparation of ceramic powders. Examples of the precipitants used include tetraalkylammonium hydroxides. A composition-modified barium titanate is one of the ceramic powders that can be produced. Certain metal-ion chelates can be prepared from 2-hydroxypropanoic acid and ammonium hydroxide.
    Type: Grant
    Filed: March 7, 2006
    Date of Patent: March 29, 2011
    Assignee: EEStor, Inc.
    Inventors: Richard D. Weir, Carl W. Nelson
  • Patent number: 7901656
    Abstract: The present invention provides a copper oxide-containing composition that includes copper oxide nanoparticles and one or more heteroatom donor ligands bonded to the surface of the nanoparticles, where x and y are numbers having a ratio that is equal to the ratio of the average number of M atoms to the average number of O atoms in the nanoparticles. The nanoparticles are stabilized by the one or more heteroatom donor ligands which act as a protective layer that cap the surface of the nanoparticles. The present invention also provides a solution of the copper oxide nanoparticles that may be applied to a substrate and then subsequently reduced to copper metal. Finally, the invention provides a method of preparing the copper oxide nanoparticles.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: March 8, 2011
    Assignee: Wayne State University
    Inventors: Charles H. Winter, Charles L. Dezelah, IV
  • Patent number: 7901657
    Abstract: The invention relates to amphiphilic, nanoscalar particles comprising lipophilic hydrolyzable groups on their surface. The invention also relates to methods for producing amphiphilic, nanoscalar particles and to compositions containing said particles.
    Type: Grant
    Filed: February 25, 2005
    Date of Patent: March 8, 2011
    Assignee: Leibniz-Institut Fuer Neue Materialien Gemeinnuetzige GmbH
    Inventors: Ertugrul Arpac, Helmut Schmidt, Murat Akarsu
  • Patent number: 7892447
    Abstract: Nanoplatelet forms of metal hydroxide and metal oxide are provided, as well as methods for preparing same. The nanoplatelets are suitable for use as fire retardants and as agents for chemical or biological decontamination.
    Type: Grant
    Filed: August 9, 2007
    Date of Patent: February 22, 2011
    Assignee: Aqua Resources Corporation
    Inventor: Orville Lee Maddan
  • Patent number: 7892643
    Abstract: Metal oxides and metals are described. The metal oxides and metals, such as silica, are preferably obtained by removing a removable template to obtain a metal oxide or metal material. Applications and uses of the material are further described.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: February 22, 2011
    Assignee: Cabot Corporation
    Inventor: Yakov E. Kutsovsky
  • Patent number: 7879265
    Abstract: It is an object of the present invention to provide an active material for lithium ion battery capable of producing a lithium ion battery having an excellent high rate charge and discharge performance and a lithium ion battery having an excellent high rate charge and discharge performance. The present invention provides an active material for lithium ion battery represented by a composition formula: Li[Li(1-x)/3AlxTi(5-2x)/3]O4 (??x<1) lithium titanate is substituted with Al, and a lithium ion battery using this active material as a negative electrode active material.
    Type: Grant
    Filed: March 22, 2006
    Date of Patent: February 1, 2011
    Assignee: GS Yuasa Corporation
    Inventors: Daisuke Endo, Tokuo Inamasu, Toshiyuki Nukuda, Yoshihiro Katayama
  • Patent number: 7879303
    Abstract: Described is a method for the production of metal salts, wherein the cationic metal is preferably selected from Group I to IV metals and mixtures thereof and the anionic group is selected from phosphates, silicates, sulfates, carbonates, hydroxides, fluorides and mixtures thereof, and wherein said method comprises forming a mixture of at least one metal source that is a metal carboxylate with a mean carbon value per carboxylate group of at least 3 and at least one anion source into droplets and oxiding said droplets in a high temperature environment, preferably a flame. This method is especially suited for the production of calcium phosphate biomaterials such as hydroxyapatite (HAp,Cal0(P04)6(OH)2) and tricalcium phosphate (TCP,Ca3(P04)2) that exhibit excellent biocompatibility and osteoconductivity and therefore are widely used for reparation of bony or periodontal defects, coating of metallic implants and bone space fillers.
    Type: Grant
    Filed: March 15, 2004
    Date of Patent: February 1, 2011
    Assignee: Eidgenossische Technische Hochschule Zurich
    Inventors: Wendelin Jan Stark, Sotiris-Emmanuel Pratsinis, Marek Maciejewski, Stefan Fridolin Loher, Alfons Baiker
  • Publication number: 20110005968
    Abstract: This invention relates to coking process additives and, related processes, such as upgrading heavy hydrocarbons, producing petroleum coke and lighter hydrocarbon products, and/or thermally cracking heavy hydrocarbons. The additive includes an anionic clay to increase a liquid product yield. Suitable anionic clays may include hydrotalcite materials and hydrotalcite-like materials.
    Type: Application
    Filed: July 7, 2009
    Publication date: January 13, 2011
    Applicant: BP CORPORATION NORTH AMERICA INC.
    Inventors: Sudhakar Chakka, Bang Xu
  • Patent number: 7867471
    Abstract: A process of producing a ceramic powder including providing a plurality of precursor materials in solution, wherein each of the plurality of precursor materials in solution further comprises at least one constituent ionic species of a ceramic powder, combining the plurality of precursor materials in solution with an onium dicarboxylate precipitant solution to cause co-precipitation of the ceramic powder precursor in a combined solution; and separating the ceramic powder precursor from the combined solution. The process may further include calcining the ceramic powder precursor.
    Type: Grant
    Filed: April 3, 2009
    Date of Patent: January 11, 2011
    Assignee: SACHEM, Inc.
    Inventor: Wilfred Wayne Wilson
  • Publication number: 20110003085
    Abstract: A porous metal oxide is formed by creating a metal oxide material with a hydrolysis reaction in solution. The hydrolysis reaction or reaction products of a metal oxide precursor react simultaneously or in conjunction with a metal salt or a disassociation species of a metal salt. The metal oxide material is conditioned, and is refined to produce metal oxide particles having a porous structure containing crystallites.
    Type: Application
    Filed: September 7, 2010
    Publication date: January 6, 2011
    Applicant: CARRIER CORPORATION
    Inventors: Treese Hugener-Campbell, Thomas Henry Vanderspurt, Wayde R. Schmidt, Steven M. Zhitnik
  • Publication number: 20100324191
    Abstract: Successful dispersion approaches are described for the formation of dispersion of dry powders of inorganic particles. In some embodiments, it is desirable to form the dispersion in two processing steps in which the particles are surface modified in the second processing step. Composites can be formed using the well dispersed particles to form improved inorganic particle-polymer composites. These composites are suitable for optical applications and for forming transparent films, which can have a relatively high index or refraction. In some embodiments, water can be used to alter the surface chemistry of metal oxide particles.
    Type: Application
    Filed: May 24, 2010
    Publication date: December 23, 2010
    Inventors: Shivkumar Chiruvolu, Hui Du, Nobuyuki Kambe
  • Publication number: 20100284884
    Abstract: Methods of making colloidal metal oxide particles and compositions containing colloidal metal oxide particles are disclosed.
    Type: Application
    Filed: December 4, 2008
    Publication date: November 11, 2010
    Inventor: James Neil Pryor
  • Patent number: 7820136
    Abstract: To provide a process for production of compound oxides having homogeneously diffused and mixed elements, there is provided a process for production of compound oxides, comprising contacting an organic phase having dissolved therein an organic compound which produces the hydroxide of a first element when hydrolyzed, with an aqueous phase containing a second element as an ion, to produce the hydroxide of the first element by hydrolysis reaction of the organic compound at the interface while incorporating the second element in the product, and firing the resulting product to produce a compound oxide of the first element and second element. Third or additional elements may be included in the aqueous phase to produce compound oxides comprising third or additional elements.
    Type: Grant
    Filed: February 26, 2004
    Date of Patent: October 26, 2010
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Shinichi Takeshima
  • Patent number: 7820124
    Abstract: A material comprising a plurality of nanoparticles. Each of the plurality of nanoparticles includes at least one of a metal phosphate, a metal silicate, a metal oxide, a metal borate, a metal aluminate, and combinations thereof. The plurality of nanoparticles is substantially monodisperse. Also disclosed is a method of making a plurality of substantially monodisperse nanoparticles. The method includes providing a slurry of at least one metal precursor, maintaining the pH of the slurry at a predetermined value, mechanically milling the slurry, drying the slurry to form a powder; and calcining the powder at a predetermined temperature to form the plurality of nanoparticles.
    Type: Grant
    Filed: October 5, 2006
    Date of Patent: October 26, 2010
    Assignee: General Electric Company
    Inventors: Kalaga Murali Krishna, Sergio Paulo Martins Loureiro, Mohan Manoharan, Geetha Karavoor, Shweta Saraswat
  • Publication number: 20100266485
    Abstract: A process comprises (a) combining (1) at least one base and (2) at least one metal carboxylate salt comprising (i) a metal cation selected from metal cations that form amphoteric metal oxides or oxyhydroxides and (ii) a lactate or thiolactate anion, or metal carboxylate salt precursors comprising (i) at least one metal salt comprising the metal cation and a non-interfering anion and (ii) lactic or thiolactic acid, a lactate or thiolactate salt of a non-interfering, non-metal cation, or a mixture thereof; and (b) allowing the base and the metal carboxylate salt or metal carboxylate salt precursors to react.
    Type: Application
    Filed: December 16, 2008
    Publication date: October 21, 2010
    Inventor: Timothy D. Dunbar
  • Publication number: 20100258759
    Abstract: The present invention relates to nano structures of metal oxides having a nanostructured shell (or wall), and an internal space or void. Nanostructures may be nanoparticles, nanorod/belts/arrays, nanotubes, nanodisks, nanoboxes, hollow nanospheres, and mesoporous structures, among other nanostructures. The nanostructures are composed of polycrystalline metal oxides such as SnO2. The nanostructures may have concentric walls which surround the internal space of cavity. There may be two or more concentric shells or walls. The internal space may contain a core such ferric oxides or other materials which have functional properties. The invention also provides for a novel, inexpensive, high-yield method for mass production of hollow metal oxide nanostructures. The method may be template free or contain a template such as silica. The nanostructures prepared by the methods of the invention provide for improved cycling performance when tested using rechargeable lithium-ion batteries.
    Type: Application
    Filed: June 6, 2007
    Publication date: October 14, 2010
    Applicant: CORNELL RESEARCH FOUNDATION, INC.
    Inventors: Lynden A. Archer, Xiong Wen Lou
  • Patent number: 7811545
    Abstract: The present invention is directed to a process for making nanoparticles of metals, metal alloys, metal oxides and multi-metallic oxides, which comprises the steps of reacting a metal salt dissolved in water with an alkali metal salt of C4-25 carboxylic acid dissolved in a first solvent selected from the group consisting of C5-10 aliphatic hydrocarbon and C6-10 aromatic hydrocarbon to form a metal carboxylate complex; and heating the metal carboxylate complex dissolved in a second solvent selected from the group consisting of C6-25 aromatic, C6-25 ether, C6-25 aliphatic hydrocarbon and C6-25 amine to produce the nanoparticles.
    Type: Grant
    Filed: November 23, 2005
    Date of Patent: October 12, 2010
    Assignee: Seoul National University Industry Foundation
    Inventors: Taeg-Hwan Hyeon, Jong-Nam Park
  • Patent number: 7811543
    Abstract: A method and apparatus for producing surface stabilized nanometer-sized particles includes the steps of mixing reactants, a surface-stabilizing surfactant, and a high boiling point liquid to form a mixture, continuously passing the mixture through an ultrasonic spray nozzle to form a mist of droplets of the mixture, injecting the mist directly into a furnace to cause a reaction between species of the mixture, and collecting the nanometer-sized products. The ultrasonic nozzle is positioned directly at one end of the heating furnace, preferably the top end, for travel of the droplets through the furnace. The continuous liquid-flow process, along with certain operating parameters, eliminates the need for dilution of the high boiling point liquid with a low boiling point solvent as in the prior art, significantly increases the yield, improves the quality of the product, and makes the process scalable.
    Type: Grant
    Filed: October 9, 2008
    Date of Patent: October 12, 2010
    Assignee: Irilliant, Inc.
    Inventors: Yuri T. Didenko, Yuhua Ni
  • Publication number: 20100255404
    Abstract: Electrocatalyst layers include an electrocatalyst having high oxygen reduction activity that is useful as an alternative material to platinum catalysts. Uses of the electrocatalyst layers are also disclosed. The electrocatalyst layer includes an electrocatalyst that is formed of a metal oxide obtained by thermally decomposing a metal organic compound. The metal element forming the electrocatalyst is preferably one selected from the group consisting of niobium, titanium, tantalum and zirconium.
    Type: Application
    Filed: August 22, 2008
    Publication date: October 7, 2010
    Applicant: SHOWA DENKO K.K.
    Inventors: Tadatoshi Kurozumi, Toshikazu Shishikura, Ryuji Monden
  • Publication number: 20100254890
    Abstract: The present invention relates to a method of forming a particulate porous metal oxide or metalloid oxide, as well as uses of the obtained a particulate porous metal oxide or metalloid oxide. A solution of a non-ionic surfactant and either an ionic surfactant or an inorganic salt is formed in an acidic aqueous solution. A metal oxide precursor or a metalloid oxide precursor is added. The formed reaction mixture is heated under reflux upon agitation for a period sufficient to obtain a particulate porous metal oxide or metalloid oxide.
    Type: Application
    Filed: April 5, 2010
    Publication date: October 7, 2010
    Applicant: NANYANG TECHNOLOGICAL UNIVERSITY
    Inventors: Yanhui Yang, Siu-Choon Ng, Xianbin Liu, Laisheng Li, Yu Du
  • Publication number: 20100254875
    Abstract: A material comprising a plurality of nanoparticles. Each of the plurality of nanoparticles includes at least one of a metal phosphate, a metal silicate, a metal oxide, a metal borate, a metal aluminate, and combinations thereof. The plurality of nanoparticles is substantially monodisperse. Also disclosed is a method of making a plurality of substantially monodisperse nanoparticles. The method includes providing a slurry of at least one metal precursor, maintaining the pH of the slurry at a predetermined value, mechanically milling the slurry, drying the slurry to form a powder; and calcining the powder at a predetermined temperature to form the plurality of nanoparticles.
    Type: Application
    Filed: October 5, 2006
    Publication date: October 7, 2010
    Inventors: Kalaga Murali Krishna, Sergio Paulo Martins Loureiro, Mohan Manoharan, Geetha Karavoor, Shweta Saraswat
  • Patent number: 7807128
    Abstract: Multimetallic anionic clays (MACs) are prepared using economical raw materials or reactants and a procedure for obtaining a series of multimetallic mixed oxides derived from the thermal decomposition of the MACs which comprises: (1) dissolving water-soluble bimetallic and/or trimetallic sources in water, (2) dispersing and homogenizing separate water-insoluble divalent and/or trivalent metal precursors with a high-speed stirrer in order to obtain small and reactive particles; depending on the nature of the water-insoluble divalent and/or trivalent metal precursors, this process can be adjusted to a desired pH, (3) adding the suspension obtained in (2) to solution (1) with the reaction medium still dispersed to facilitate solid particle's reduction/dissociation, and (4) afterwards the slurry is aged for several hours and finally dried. This process enables raw materials or reactants to be easily handled, and eliminates unit operations involving product washing and/or purification steps.
    Type: Grant
    Filed: October 29, 2007
    Date of Patent: October 5, 2010
    Assignee: Instituto Mexicano del Petroleo
    Inventors: Jaime Sanchez-Valente, Esteban Lopez-Salinas, Manuel Sanchez-Cantu
  • Publication number: 20100248967
    Abstract: The invention herein is directed towards a material exhibiting superconductivity characteristics which includes a laser processed region of a metal oxide crystal. The material has a transition temperature greater than a transition temperature of the metal oxide crystal, preferably greater than 140K. The transition temperature of the material may be considered greater than the transition temperature of the metal oxide crystal if the material has a transition temperature and the metal oxide crystal has no transition temperature. The present invention is also directed to a material which includes a laser processed strontium ruthenate crystal wherein the material has a greater oxygen content than the starting strontium ruthenate crystal. The present invention is also directed towards a method for manufacturing a material exhibiting superconductivity characteristics that includes providing a metal oxide crystal and laser ablating the metal oxide crystal and a material made by this process.
    Type: Application
    Filed: September 12, 2006
    Publication date: September 30, 2010
    Inventors: Armen Gulian, Kent S. Wood, Deborah Van Vechten, Vahan R. Nikoghosyan
  • Patent number: 7803347
    Abstract: A technique for bonding an organic group with the surface of fine particles such as nanoparticles through strong linkage is provided, whereas such fine particles are attracting attention as materials essential for development of high-tech products because of various unique excellent characteristics and functions thereof. Organically modified metal oxide fine particles can be obtained by adapting high-temperature, high-pressure water as a reaction field to bond an organic matter with the surface of metal oxide fine particles through strong linkage. The use of the same condition enables not only the formation of metal oxide fine particles but also the organic modification of the formed fine particles. The resulting organically modified metal oxide fine particles exhibit excellent properties, characteristics and functions.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: September 28, 2010
    Assignee: Tohoku Techno Arch Co., Ltd.
    Inventor: Tadafumi Ajiri
  • Patent number: 7799311
    Abstract: Process of making high purity, synthetic FeS2, and an electrochemical battery employing such synthetic FeS2 in the positive electrode. Synthetic FeS2 may be prepared by a sulfidation process comprising reacting ferric oxide, hydrogen sulfide, and elemental sulfur at a temperature above the melting point of element sulfur. Synthetic FeS2 may also be produced by a milling process that comprises (i) milling iron powder and sulfur powder in the presence of a milling media and a processing agent to provide a homogenous powder mixture, and (ii) treating the powder mixture to form FeS2. In the milling process, the powder mixture may be treated to form FeS2 by heating the powder mixture or subjecting the powder mixture to a subsequent milling operation.
    Type: Grant
    Filed: September 24, 2008
    Date of Patent: September 21, 2010
    Assignee: Eveready Battery Company, Inc.
    Inventors: George L. Schimek, Michael W. Wemple, Jarod J. LeClaire
  • Patent number: 7785560
    Abstract: Process for removing halide compounds adhering to finely divided metal oxide particles by means of steam, wherein the metal oxide particles are applied to the upper part of an upright column and migrate downwards by means of gravity, the steam is applied at the bottom end of the column, the metal oxide particles and the steam are fed counter-currently, the metal oxide particles freed of halide residues are removed at the base of the column, steam and halide residues are removed at the head of the column, wherein the column is heated in such a manner that the temperature difference Tbottom?Ttop between the lower part and the upper part of the column is at least 20° C. and a maximum temperature of 500° C. prevails in the column, and the metal oxide particles have a residence time in the column of from 1 second to 30 minutes.
    Type: Grant
    Filed: June 22, 2004
    Date of Patent: August 31, 2010
    Assignee: EVONIK DEGUSSA GmbH
    Inventors: Kai Schumacher, Juergen Flesch, Volker Hamm
  • Publication number: 20100213646
    Abstract: Disclosed is a highly functional low-cost metal complex oxide having low resistivity and excellent high-temperature stability, which places only little burden on the environment. Specifically, a metal complex oxide is produced by a method which is characterized by comprising a calcination step for obtaining a calcine containing a metal complex oxide, a cleaning step for cleaning the calcine with purified water, and a firing step for firing the cleaned calcine. Preferably, the calcine is cleaned with purified water a plurality of times for obtaining a sintered body having less structural defects. Since a perovskite oxide produced by this method has a low resistivity and a high output factor, it can be used as a thermoelectric material.
    Type: Application
    Filed: August 27, 2008
    Publication date: August 26, 2010
    Applicant: UNIVERSAL ENTERTAINMENT
    Inventor: Koh TAKAHASHI
  • Patent number: 7780936
    Abstract: Process for manufacturing an electrochemical device including a cathode, an anode and at least one electrolyte membrane disposed between the anode and the cathode, wherein at least one of the cathode, the anode and the electrolyte membrane, contains at least a ceramic material.
    Type: Grant
    Filed: March 30, 2004
    Date of Patent: August 24, 2010
    Assignee: Pirelli & C. S.p.A.
    Inventors: Agustin Sin Xicola, A. Yuri Dubitsky, Enrico Albizzati, Evgeny Kopnin, Elena Roda
  • Patent number: 7771871
    Abstract: The present invention aims to realize (1) manufacture of a mesoporous composite powder or thin film composed of nanocrystalline metal oxide—glass having a three-dimensional structure with a large specific surface area, (2) construction of a porous structure framework with nanocrystalline metal oxide crystal and a slight amount of glass phase (SiO2 or P2O5, B2O3), (3) control of crystal growth of metal oxide with a slight amount of glass phase (SiO2 or P2O5, B2O3), (4) simplification of the manufacturing process, and (5) use thereof in manufacture of a lithium intercalation electric device, photocatalytic device, solar battery and energy storage device. Provided are a nanocrystal oxide—glass mesoporous composite powder or thin film having a three-dimensional structure with regularly arranged mesopores, and a secondary battery comprising the same.
    Type: Grant
    Filed: November 16, 2004
    Date of Patent: August 10, 2010
    Assignee: National Institute of Advanced Industrial Science and Technology
    Inventors: Haoshen Zhou, Itaru Homma
  • Publication number: 20100179046
    Abstract: Disclosed is a sensitive glass for use in a pH-sensitive glass electrode, which comprises at least Me2O3 (Me represents a lanthanoid) and further comprises Y2O3 or Sc2O3 in an amount smaller than that of the Me2O3. Also disclosed is a sensitive glass for use in a cation-sensitive glass electrode, which comprises at least Y2O3 or Sc2O3.
    Type: Application
    Filed: September 6, 2007
    Publication date: July 15, 2010
    Applicant: HORIBA, LTD.
    Inventors: Yasukazu Iwamoto, Yuji Nishio
  • Patent number: 7754651
    Abstract: Disclosed is an Cu/Zn/Al-catalyst containing copper oxide and zinc oxide as catalytically active components and aluminium oxide as thermostabilising component. The catalyst is characterized in that the Cu/Zn atomic ratio is <2.8 and the aluminium oxide component is obtained from an aluminium hydroxide sol.
    Type: Grant
    Filed: November 6, 2002
    Date of Patent: July 13, 2010
    Assignee: Süd -Chemie AG
    Inventors: Jurgen Ladebeck, Jurgen Koy, Tiberius Regula
  • Publication number: 20100155650
    Abstract: An amidine-carboxylic acid complex in accordance with an aspect of the invention has an amidine ligand and a carboxylic acid ligand that are coordinated to one metal atom or a plurality of metal atoms of the same element. A multiple-complex-containing compound, i.e. a bridged polynuclear complex, in accordance with the aspect of the invention is formally derived from two or more such amidine-carboxylic acid complexes, linked by a polyvalent carboxylic acid ligand. The bridged polynuclear complex may be used in a production method to support metal (oxide) clusters on a porous support by impregnating these with a solution thereof, followed by drying and firing.
    Type: Application
    Filed: June 7, 2007
    Publication date: June 24, 2010
    Inventors: Kazushi Mashima, Masato Ohashi, Akihiro Yagyu, Hirohito Hirata
  • Patent number: 7740828
    Abstract: Multimetallic anionic clays (MACs) are prepared using economical raw materials or reactants and a procedure for obtaining a series of multimetallic mixed oxides derived from the thermal decomposition of the MACs which comprises: (1) dissolving water-soluble bimetallic and/or trimetallic sources in water, (2) dispersing and homogenizing separate water-insoluble divalent and/or trivalent metal precursors with a high-speed stirrer in order to obtain small and reactive particles; depending on the nature of the water-insoluble divalent and/or trivalent metal precursors, this process can be adjusted to a desired pH, (3) adding the suspension obtained in (2) to solution (1) with the reaction medium still dispersed to facilitate solid particle's reduction/dissociation, and (4) afterwards the slurry is aged for several hours and finally dried. This process enables raw materials or reactants to be easily handled, and eliminates unit operations involving product washing and/or purification steps.
    Type: Grant
    Filed: December 4, 2009
    Date of Patent: June 22, 2010
    Assignee: Instituto Mexicano del Petroleo
    Inventors: Jaime Sanchez-Valente, Esteban Lopez-Salinas, Manuel Sanchez-Cantu
  • Patent number: 7741376
    Abstract: A dispersed ingredient having metal-oxygen bonds which is obtained by hydrolyzing a metal alkoxide in an organic solvent in the absence of an acid, a base, and/or a dispersion stabilizer, either with 0.5 to less than 1 mol of water per mol of the metal alkoxide or at ?20° C. or lower with 1.0 to less than 2.0 mol of water per mol of the metal alkoxide. In the organic solvent, the dispersed ingredient is stably dispersed without aggregating. Use of the dispersed ingredient enables a thin metal oxide film and a homogeneous organic/inorganic composite to be produced at a temperature as low as 200° C. or below.
    Type: Grant
    Filed: December 11, 2008
    Date of Patent: June 22, 2010
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Motoyuki Toki, Akiji Higuchi, Nobuo Kimura, Yoshitaka Fujita
  • Patent number: 7727500
    Abstract: Disclosed are adhesive coating compositions containing a metal peroxide for producing clear colorless adhesive coatings on substrates, particularly micro particulate substrates. In one preferred embodiment the nanoparticle coatings are chemically active and function at a high level of efficiency due to the high total surface area of the micro particulate substrate. Also disclosed are coated substrates and compositions having nanoparticles bound to a substrate by the coating compositions.
    Type: Grant
    Filed: March 8, 2007
    Date of Patent: June 1, 2010
    Assignee: PURETI, Inc.
    Inventor: John W. Andrews
  • Patent number: 7708969
    Abstract: In a method and an apparatus for forming metal oxide on a substrate, a source gas including metal precursor flows along a surface of the substrate to form a metal precursor layer on the substrate. An oxidizing gas including ozone flows along a surface of the metal precursor layer to oxidize the metal precursor layer so that the metal oxide is formed on the substrate. A radio frequency power is applied to the oxidizing gas flowing along the surface of the metal precursor layer to accelerate a reaction between the metal precursor layer and the oxidizing gas. Acceleration of the oxidation reaction may improve electrical characteristics and uniformity of the metal oxide.
    Type: Grant
    Filed: July 9, 2007
    Date of Patent: May 4, 2010
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Seok-Jun Won, Yong-Min Yoo, Min-Woo Song, Dae-Youn Kim, Young-Hoon Kim, Weon-Hong Kim, Jung-Min Park, Sun-Mi Song
  • Patent number: 7708974
    Abstract: Nanoparticles comprising tungsten, methods of manufacturing nanoparticles comprising tungsten, and applications of nanoparticles comprising tungsten, such as electronics, optical devices, photonics, reagents for fine chemical synthesis, pigments, and catalysts are provided.
    Type: Grant
    Filed: May 10, 2005
    Date of Patent: May 4, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Tapesh Yadav
  • Publication number: 20100102282
    Abstract: The present invention relates to pulverulent compounds of the formula NibM1cM2d(O)x(OH)y(SO4)z, a process for the preparation thereof and the use thereof as precursors for the preparation of active materials for lithium secondary batteries.
    Type: Application
    Filed: October 11, 2007
    Publication date: April 29, 2010
    Inventors: Stefan Malcus, Armin Olbrich, Juliane Messe-Marktscheffel, Matthias Jahn
  • Publication number: 20100104652
    Abstract: Disclosed herein are methodologies and compositions for enhancing cellular functions, which can be used in a variety of biological applications.
    Type: Application
    Filed: October 23, 2009
    Publication date: April 29, 2010
    Inventors: Alexandru S. Biris, Meena Mahmood, Peder Jensen
  • Patent number: 7704918
    Abstract: The invention relates to platinum-metal oxide composite particles and their use as electrocatalysts in oxygen-reducing cathodes and fuel cells. The invention particularly relates to methods for preventing the oxidation of the platinum electrocatalyst in the cathodes of fuel cells by use of these platinum-metal oxide composite particles. The invention additionally relates to methods for producing electrical energy by supplying such a fuel cell with an oxidant, such as oxygen, and a fuel source, such as hydrogen. The invention also relates to methods of making the metal-metal oxide composites.
    Type: Grant
    Filed: June 8, 2007
    Date of Patent: April 27, 2010
    Assignee: Brookhaven Science Associates, LLC
    Inventors: Radoslav Adzic, Miomir Vukmirovic, Kotaro Sasaki
  • Patent number: 7704413
    Abstract: The invention relates to a method for the preparation of a composition of nanoparticles of at least one crystalline metal oxide from at least one organometallic precursor. One precursor(s) which can react spontaneously to oxidation is selected; a liquid solution of the precursor(s) is produced in a solvent non-aqueous medium, and the liquid solution is placed in contact with at least one oxidant in adapted reactional conditions in order to directly result in the production of nanoparticles of crystalline metal oxide(s). The invention also relates to a composition of nanoparticles obtained in the form of a colloidal liquid solution.
    Type: Grant
    Filed: April 6, 2004
    Date of Patent: April 27, 2010
    Assignee: Centre National de la Recherche Scientifique (C.N.R.S.)
    Inventors: Myrtil Kahn, Miguel Monge, André Maisonnat, Bruno Chaudret
  • Patent number: 7704906
    Abstract: A semiconductor porcelain composition [(BiNa)x(Ba1-yRy)1-x]TiO3 with 0<x?0.2, 0<y?0.02 and R being selected from the group consisting of La, Dy, Eu, Gd or Y is prepared by separately calcining a composition of (BaR)TiO3 at a temperature of 900° C. through 1300° C. and calcining a composition of (BiNa)TiO3 at a temperature of 700° C. through 950° C., and then mixing the two calcined powders and forming and sintering the mixed calcined powder. Similarly, a semiconductor porcelain composition [(BiNa)x(Ba1-x][Ti1-zMz]O3 with 0<x?0.2, 0<z?0.005 and M being selected from the group consisting of Nb, Ta and Sb is prepared by separately calcining a composition of (BaM)TiO3 at a temperature of 900° C. through 1300° C. and calcining a composition of (BiNa)TiO3 at a temperature of 700° C. through 950° C., and then mixing the two calcined powders, and forming and sintering the mixed calcined powders.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: April 27, 2010
    Assignee: Hitachi Metals, Ltd.
    Inventors: Takeshi Shimada, Koichi Terao, Kazuya Toji
  • Patent number: 7700509
    Abstract: A method of producing a semiconductor disk represented by a composition formula [(Bi0.5Na0.5)x(Ba1?yRy)1?x]TiO3, in which R is at least one element of La, Dy, Eu, Gd and Y and x and y each satisfy 0?x?0.14, and 0.002?y?0.02 includes carrying out a sintering in an inert gas atmosphere with an oxygen concentration of 9 ppm to 1% and wherein a treatment at an elevated temperature in an oxidizing atmosphere after the sintering is not carried out.
    Type: Grant
    Filed: March 31, 2006
    Date of Patent: April 20, 2010
    Assignee: Hitachi Metals, Ltd.
    Inventors: Takeshi Shimada, Koichi Terao, Kazuya Toji
  • Patent number: 7682596
    Abstract: A powdery compound selected from the group consisting of Li4Ti5O12 and its derivatives selected from the group consisting of Li4?xMxTi5O12 and Li4Ti5?yNyO12 (x and y between 0 and 0.2, M and N selected from the group consisting of Na, K, Mg, Nb, Al, Ni , Co, Zr, Cr, Mn, Fe, Cu, Zn, Si and Mo), used as active material of an electrode for a lithium storage battery, consists of unitary particles having a diameter not greater than 1 ?m and 10-50% volume agglomerated particles having a diameter not greater than 100 ?m wherein the agglomerated particles formed by agglomeration of said unitary particles. The method for producing such a compound preferably consists in grinding the synthesized oxide for a duration comprised between 24 hours and 48 hours in a planetary mill and in then performing thermal treatment at a temperature comprised between 450° C. and 600° C.
    Type: Grant
    Filed: August 8, 2005
    Date of Patent: March 23, 2010
    Assignee: Commissariat à l'Energie Atomique
    Inventors: Carole Bourbon, Séverine Jouanneau, Frédéric Le Cras, Hélène Lignier
  • Publication number: 20100069229
    Abstract: A method for the synthesis of nano-products, such as atomic titanium oxide wires. The method allows wires of anatase titanium oxide wires to be formed in a range of tunable diameters and aspect ratios in the nanometer and subnanometer size scales. The method also allows the titanium wires to be capped by oleic acid to enhance dispersing and solubility. The method allows the titanium wires to be surface doped with nitrogen species to enhance stability and functionality such as enhanced absorption in the visible wavelength region, which is useful for photodegradation of organic wastes in water by sunlight.
    Type: Application
    Filed: August 28, 2009
    Publication date: March 18, 2010
    Applicant: THE HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Shihe YANG, Chenmin LIU
  • Publication number: 20100067175
    Abstract: The present invention concerns the field of solid state capacitors and in particular high performance capacitors for use in modern electronic devices. Specifically, the present invention relates to a method by which powders of valve-action material may be modified to make them suitable for use in the formation of capacitor anodes for solid state electrolytic capacitors. According to the present invention there is provided a method of modifying raw valve-action material powder into capacitor grade structured powder comprising: (i) providing a raw powder to be converted; (ii) compressing a portion of the powder to form a porous solid mass of powder (iii) heating the solid mass to a pre-determined sintering temperature and maintaining the temperature for a pre-determined time period to form a sintered body, (iv) pulverising the sintered body to form a processed powder and (v) optionally grading the powder particles within pre-determined size ranges so as to collect capacitor grade powder.
    Type: Application
    Filed: November 9, 2007
    Publication date: March 18, 2010
    Applicant: AVX LIMITED
    Inventors: Brady A. Jones, Colin McCracken, James Fife, Ian Margerison, Tomas Karnik
  • Patent number: 7678355
    Abstract: A method for producing a highly crystalline perovskite-type complex compound is provided that exhibits stably a high Seebeck coefficient and a low electric resistivity even at higher temperatures. A method for producing a complex perovskite-type compound with less environmental load is also provided. The method comprises a step of dissolving a nitrate salt containing a rare earth element, a nitrate salt containing an alkaline earth metal element, a nitrate salt containing manganese, and an organic polymer into a solvent to form a solution, a step of mixing and stirring the solution, a step of preparing a precursor powder from the solution through heating and drying thereof, and a step of calcining the precursor powder in atmosphere.
    Type: Grant
    Filed: May 30, 2005
    Date of Patent: March 16, 2010
    Assignee: Universal Entertainment Corporation
    Inventor: Koh Takahashi
  • Publication number: 20100055016
    Abstract: Provided is a method of manufacturing oxide-based nano-structured materials using a chemical wet process, and thus, the method can be employed to manufacture oxide-based nano-structured materials having uniform composition and good electrical characteristics in large quantities, the method having a relatively simple process which does not use large growing equipment. The method includes preparing a first organic solution that comprises a metal, mixing the first organic solution with a second organic solution that contains hydroxyl radicals (—OH), filtering the mixed solution using a filter in order to extract oxide-based nano-structured materials formed in the mixed solution, drying the extracted oxide-based nano-structured materials to remove any remaining organic solution, and heat treating the dried oxide-based nano-structured materials.
    Type: Application
    Filed: February 1, 2008
    Publication date: March 4, 2010
    Inventors: Sang-Hyeob Kim, Hye-Jin Myoung, Sung-Lyul Maeng, G.A.J. Amaratunga, Sunyoung Lee
  • Publication number: 20100040531
    Abstract: A non-lead composition for use as a thick-film resistor paste in electronic applications. The composition comprises particles of Li2RuO3 of diameter between 0.5 and 5 microns and a lead-free frit. The particles have had the lithium at or near primarily the surface of the particle at least partially exchanged for atoms of other metals.
    Type: Application
    Filed: October 23, 2009
    Publication date: February 18, 2010
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: PAUL DOUGLAS VERNOOY, ALFRED T. WALKER, KENNETH WARREN HANG
  • Patent number: 7658907
    Abstract: Titanium-aluminium mixed oxide powder with a proportion of aluminium oxide of less than 1 wt. % or a proportion of titanium dioxide of less than 5 wt. %, wherein the sum of the proportions of titanium dioxide and aluminium oxide is at least 99.7 wt. %. It is produced by transferring a vaporous starting compound of the quantitatively greater component of the mixed oxide into a mixing chamber by means of primary air and a vaporous starting compound of the quantitatively smaller component of the mixed oxide by means of an inert gas, and burning the mixture mixed with hydrogen in a mixing chamber into a reaction chamber. It can be used as a catalyst support.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: February 9, 2010
    Assignee: Degussa GmbH
    Inventors: Kai Schumacher, Roland Schilling, Harald Alff, Helmut Roth