From Phenol, Phenol Ether, Or Inorganic Phenolate Patents (Class 528/86)
  • Patent number: 7196155
    Abstract: A process comprising: a) reacting a diphenol monomer A with a monomer B having two locations for reaction with A to form arylene ether monomer C and b) reacting arylene ether monomer C with a diphenol monomer D to form a polymer, where monomer A is HX1-Q1-X1H;??(II) monomer B is arylene ether monomer C is and monomer D is wherein: Q1 comprises at least one aryl or heteroaryl group; Q2 comprises at least one aryl or heteroaryl group; X1 is O bonded directly to an aryl carbon of Q1; X2 is O bonded directly to an aryl carbon of Q2; Z is a linker comprising at least one —(C(R2)2)— group; Y is a single bond or linker group (e.g., comprising up to about 50 carbons); R1 is independently at each occurrence H, a halogen, an alkyl group, a heteroalkyl group, an aryl group, or a heteroaryl group; R2 is independently at each occurrence H, an alkyl group, or a heteroalkyl group; and R3 is H or a crosslinkable group.
    Type: Grant
    Filed: February 16, 2006
    Date of Patent: March 27, 2007
    Assignee: Lumera Corporation
    Inventors: Baoquan Chen, Timothy M. Londergan
  • Patent number: 7189795
    Abstract: A poly(arylene ether) polymer includes polymer repeat units of the following structure: —(O—Ar1—O—Ar2)m—(O—Ar3—O—Ar4)n— where Ar1, Ar2, Ar3, and Ar4 are identical or different aryl radicals, m is 0.05 to 0.95, n is 1-m, and at least one of the aryl radicals is grafted to at least one hydroxyalkyl group, such as 2-undecanol. The polymer is especially useful in electrically conductive adhesives.
    Type: Grant
    Filed: July 16, 2003
    Date of Patent: March 13, 2007
    Inventors: William Franklin Burgoyne, Jr., Ching-Ping Wong, Silvia Liong
  • Patent number: 7179878
    Abstract: Poly(arylene ether) polymers are provided having polymer repeat units of the following structure: wherein Ar1, Ar2, Ar3, and Ar4 are identical or different aryl radicals, m is 0 to 1, n is 1-m, and at least one of G1, G2, G3, G4, G5, G6, G7 and G8 is a hydroxyalkyl furan group. Thin films of the polymer and methods of making the polymer are also provided.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: February 20, 2007
    Inventors: William Franklin Burgoyne, Jr., Christine Peck Kretz
  • Patent number: 7179879
    Abstract: The present invention relates to poly(arylene ethers) used as low k dielectric layers in electronic applications and articles containing such poly(arylene ethers) comprising the structure: wherein n=5 to 10000 and monovalent Ar1 and divalent Ar2 are selected from a group of heteroaromatic compounds that incorporate O, N, Se, S, or Te or combinations of the aforesaid elements, including but not limited to:
    Type: Grant
    Filed: January 4, 2005
    Date of Patent: February 20, 2007
    Assignee: Chartered Semiconductor Manufacturing Ltd.
    Inventors: Christopher Lim, Siu Choon Ng, Hardy Chan, Simon Chooi, Mei Sheng Zhou
  • Patent number: 7169844
    Abstract: An emulsion of resin having a function of oxidation inhibition obtained by subjecting an antioxidant (A) having two or more alcoholic hydroxy groups, a polyol compounds (B) as an optical ingredient, a compound (C) having a carboxy group and an active-hydrogen group, and an organic polyisocyanate (D) to urethanation reaction in an organic solvent, neutralizing the resultant resin solution with a neutralizing agent (E), and then dispersing the solution in water. A resin having the function of oxidation inhibition is obtained from the emulsion.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: January 30, 2007
    Assignee: Daicel Chemical Industries, Ltd.
    Inventor: Kiyotaka Inokami
  • Patent number: 7166250
    Abstract: The present invention relates to poly(arylene ethers) used as low k dielectric layers in electronic applications and articles containing such poly(arylene ethers) comprising the structure: wherein n=5 to 10000 and monovalent Ar1 and divalent Ar2 are selected from a group of heteroaromatic compounds that incorporate O, N, Se, S, or Te or combinations of the aforesaid elements, including but not limited to:
    Type: Grant
    Filed: January 4, 2005
    Date of Patent: January 23, 2007
    Assignee: Chartered Semiconductor Manufacturing Ltd.
    Inventors: Christopher Lim, Siu Choon Ng, Hardy Chan, Simon Chooi, Mei Sheng Zhou
  • Patent number: 7166689
    Abstract: An aryl amine polymer is provided which contains a specific repeat unit, its use in preparing an organic semiconductor material which contains the aryl amine polymer and an additional specific compound and in the preparation of organic light emitting devices (OLED), organic thin film transistors (TFT) and so on, along with an organic TFT including a substrate, an organic semiconductor layer which contains the organic semiconductor material and is located overlying the substrate, an electrode pair of a source electrode and a drain electrode; and a third electrode.
    Type: Grant
    Filed: February 13, 2004
    Date of Patent: January 23, 2007
    Assignee: Ricoh Company, Ltd.
    Inventors: Toshiya Sagisaka, Masaomi Sasaki, Masafumi Torii, Shinichi Kawamura, Takashi Okada, Yoshinobu Nakayama, Yoshikazu Akiyama, Hitoshi Kondoh, Hidenori Tomono, Takumi Yamaga
  • Patent number: 7163988
    Abstract: Disclosed is an aromatic sulfonic acid ester derivative represented by the formula (1); in the formula, X is an atom or a group selected from a halogen atom excluding fluorine, —OSO3CH3 and —OSO3CF3, A is a divalent electron attractive group, B is a divalent electron donating group or a direct bonding, Ra is a hydrocarbon group of 1 to 20 carbon atoms, Ar is an aromatic group having a substituent of —SO3Rb (wherein Rb is a hydrocarbon group of 1 to 20 carbon atoms), m is an integer of 0 to 10, n is an integer of 0 to 10 and k is an integer of 1 to 4. Also disclosed is a process for producing a polyarylene having a sulfonic acid group, which process comprises the steps of coupling polymerization of an aromatic compound containing the derivative of the formula (1), to prepare a polyarylene and hydrolysis of the polyarylene, and which process has high safety and is easily capable of controlling the amount of sulfonoc acid group introduced into a polymer and the introducing position thereof.
    Type: Grant
    Filed: August 19, 2003
    Date of Patent: January 16, 2007
    Assignee: JSR Corporation
    Inventors: Igor Rozhanskii, Masayuki Takahashi, Kohei Goto, Yousuke Konno, Toshihiro Ohtsuki, Yoshitaka Yamakawa, Toshiaki Kadota
  • Patent number: 7151156
    Abstract: The present invention provides a block polymer that comprises a plurality of block segments, wherein at least one block segment comprises a repeating unit having an ester moiety bonded to a main chain in a forward direction through a connecting group of two or more atoms, and the block polymer has a molecular weight distribution (Mw/Mn) of 1.3 or less. Also provided is a polymer composition containing the above block polymer and a functional material.
    Type: Grant
    Filed: August 3, 2004
    Date of Patent: December 19, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koichi Sato, Masayuki Ikegami, Sakae Suda, Ikuo Nakazawa, Keiichiro Tsubaki
  • Patent number: 7144970
    Abstract: An insulating-film forming material comprising a resin (A) that has a structure represented by formula (I): wherein Y1, Y2, Ar1 and Ar2 are the same or different; each of Y1, Y2, Ar1 and Ar2represents an aromatic ring-containing divalent organic group; at least one of Y1 and Y2 is a divalent aromatic polycyclic group having a specific structure; m and n each indicates a molar percentage of the repeating units; and m falls between 0 and 100 with (m+n)=100.
    Type: Grant
    Filed: March 22, 2004
    Date of Patent: December 5, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yutaka Adegawa
  • Patent number: 7115706
    Abstract: Polyether polymers providing a backbone substituted at intervals with electron stabilizing groups containing electron withdrawing groups are described. The polymers capture electrons and are electronegative. The polymers act to solvate alkali metals so that electrons are withdrawn from the alkali metal into the polymer. The polymer compositions are conductive under certain conditions and are magnetic. The compositions are useful in electronic applications.
    Type: Grant
    Filed: March 17, 2004
    Date of Patent: October 3, 2006
    Assignee: Board of Trustees of Michigan State University
    Inventors: Rawle I. Hollingsworth, Yuqing Chen
  • Patent number: 7115699
    Abstract: Provided are a sulfonated polymer capable of high hot water resistance even if it has an increased amount of the sulfonic groups introduced therein, and a solid polymer electrolyte containing the sulfonated polymer that has high proton conductivity and excellent generating performance. The sulfonated polymer has repeating units represented by the formula (1?): wherein B's are each independently an oxygen or a sulfur atom, R1 to R3 may be the same or different and are selected from a hydrogen atom, a fluorine atom, a nitrile group and an alkyl group, n is an integer of 2 or greater, and Q is a structure represented by the formula (q): wherein A is independently a divalent atom or organic group or a direct bond, and R4 to R11 may be the same or different and are selected from a hydrogen atom, a fluorine atom, an alkyl group and an aromatic group.
    Type: Grant
    Filed: October 6, 2004
    Date of Patent: October 3, 2006
    Assignee: JSR Corporation
    Inventors: Yoshitaka Yamakawa, Makoto Higami, Toshiaki Kadota
  • Patent number: 7101957
    Abstract: Crosslinked polymer blends comprising a poly(arylene ether) and a nonlinear optical chromophore. Also featured are electro-optic devices incorporating these blends.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: September 5, 2006
    Assignee: Lumera Corporation
    Inventors: Diyun Huang, Timothy M. Londergan
  • Patent number: 7087701
    Abstract: A polymer comprising units having the formula (I) wherein: Q1 comprises at least one aryl or heteroaryl group; Q2 comprises at least one aryl or heteroaryl group; X1 is O bonded directly to an aryl carbon of Q1; X2 is O bonded directly to an aryl carbon of Q2; Z is a linker comprising at least one —C(R2)2)— group; Y is a single bond or linker group (e.g., comprising up to about 50 carbons); R1 is independently at each occurrence H, a halogen, an alkyl group, a heteroalkyl group, an aryl group, or a heteroaryl group; R2 is independently at each occurrence H, an alkyl group, or a heteroalkyl group; and R3 is H or a crosslinkable group.
    Type: Grant
    Filed: March 30, 2005
    Date of Patent: August 8, 2006
    Assignee: Lumera Corporation
    Inventor: Timothy M. Londergan
  • Patent number: 7087799
    Abstract: An object of the present invention is to provide a material which resolves the drawbacks associated with polyimide polymers, and yet retains the advantages offered by conventional polyimide polymers. An amino group containing phenol derivative of the present invention is represented by a general formula (1) show below, and the present invention also provides a polyimide precursor produced using such an amino group containing phenol derivative. (wherein, R1, R2 and R3, which may be the same or different, each represent an alkyl group of 1 to 9 carbon atoms, an alkoxy group of 1 to 10 carbon atoms, a COOR group (in which R represents an alkyl group of 1 to 6 carbon atoms) or a hydrogen atom; R4 and R5, which may be the same or different, each represent an alkyl group of 1 to 9 carbon atoms or a hydrogen atom; X represents —O—, —S—, —SO2—, —C(CH3)2—, —CH2—, —C(CH3)(C2H5)—, or —C(CF3)2—; and n represents an integer of 1 or greater).
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: August 8, 2006
    Assignee: Gun Ei Chemical Industry Co., Ltd.
    Inventors: Takeshi Tsuihiji, Michiyasu Yamazaki
  • Patent number: 7087707
    Abstract: A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links.
    Type: Grant
    Filed: April 14, 2004
    Date of Patent: August 8, 2006
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M. Keller, Matt Laskoski
  • Patent number: 7084231
    Abstract: Disclosed are a polyarylene compound and polymers thereof, which can be used as core materials for an organic or polymeric electro-luminescence (EL) element or for other optical devices, a preparation method thereof, and an EL element using the same.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: August 1, 2006
    Assignee: Korea Institute of Science and Technology
    Inventors: Hyun-Nam Cho, Sung Hyun Jung, Seok Jin Park
  • Patent number: 7084236
    Abstract: A polymer comprising structural units of the formula I has a number average molecular weight of less than 300.103 g/mole and a weight average molecular weight of less than 500.103 g/mole. A preferred example is a polyphenylene-vinylene. A composition of this polymer can be deposited on a substrate by means of inkjet printing excellently.
    Type: Grant
    Filed: May 27, 2002
    Date of Patent: August 1, 2006
    Assignee: Koninklijke Philips Electronics N.V.
    Inventors: Paulus Cornelis Duineveld, Margaretha Maria De Kok-Van Breemen, Priscilla Amber Majella Lips, Jochem Petrus Maria De Koning, Cornelis Dirk Roelandse
  • Patent number: 7081491
    Abstract: A method for fabricating a polybenzoxazole/clay nanocomposite material includes performing an ion exchange reaction between an organic amine and Na+-montmorillonite to form a swelled organoclay. A polycondensation reaction is conducted between two types of monomers, isophthaloyl chloride and 2,2-bis (3-amino-4-hydroxyphenyl) hexafluoropropane to form a polybenzoxaxole precursor polyhydroxyamide to form a PBO/clay composite material.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: July 25, 2006
    Assignee: National Cheng-Kung University
    Inventors: Steve Lien-Chung Hsu, Keng-Chuan Chang
  • Patent number: 7071281
    Abstract: The present invention relates to poly(arylene ethers) used as low k dielectric layers in electronic applications and articles containing such poly(arylene ethers) comprising the structure: wherein n=5 to 10000 and monovalent Ar1 and divalent Ar2 are selected from a group of heteroaromatic compounds that incorporate O, N, Se, S, or Te or combinations of the aforesaid elements, including but not limited to:
    Type: Grant
    Filed: January 4, 2005
    Date of Patent: July 4, 2006
    Assignee: Chartered Semiconductor Manufacturing Ltd.
    Inventors: Christopher Lim, Siu Choon Ng, Hardy Chan, Simon Chooi, Mei Sheng Zhou
  • Patent number: 7067593
    Abstract: A polymer comprising units having the formula (I) wherein: Q1 comprises at least one aryl or heteroaryl group; Q2 comprises at least one aryl or heteroaryl group; X1 is O bonded directly to an aryl carbon of Q1; X2 is O bonded directly to an aryl carbon of Q2; Z is a linker comprising at least one —(C(R2)2)— group; Y is a single bond or linker group (e.g., comprising up to about 50 carbons); R1 is independently at each occurrence H, a halogen, an alkyl group, a heteroalkyl group, an aryl group, or a heteroaryl group; R2 is independently at each occurrence H, an alkyl group, or a heteroalkyl group; and R3 is H or a crosslinkable group.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: June 27, 2006
    Assignee: Lumera Corporation
    Inventor: Timothy M. Londergan
  • Patent number: 7049393
    Abstract: A process for preparing a fluorinated poly(arylene ether) comprising the repeating unit: wherein n provides a molecular weight up to about 30,000 to 100,000, X represents one of following groups: none, ketone, sulfone, sulfide, ether, hexafluoroisopropylidene, ??-perfluoroalkylene, oxadiazole, and Y is 4,4?-(hexafluoroisopropylidene)-diphenyl, 4,4?-isopropylidene diphenyl, 3,3?-isopropylidene diphenyl, phenyl, or chlorinated phenol which process comprises reacting a bis(pentafluorophenyl) compound and a bisphenol or hydroquinone in the presence of a dehydrating agent and a polar aprotic solvent is disclosed. Polymers resulting from the process show good promise as new passive optic polymer waveguide materials.
    Type: Grant
    Filed: May 28, 2003
    Date of Patent: May 23, 2006
    Assignee: National Research Council of Canada
    Inventors: Jianfu Ding, Futian Liu, Ming Zhou, Mei Li, Mike Day, Pascal Vuillaume
  • Patent number: 7049386
    Abstract: In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arlyene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.
    Type: Grant
    Filed: June 19, 2002
    Date of Patent: May 23, 2006
    Assignee: Honeywell International Inc.
    Inventors: Kreisler S. Lau, Feng Quan Liu, Boris A. Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
  • Patent number: 7041388
    Abstract: The present invention describes poly(arylenevinylenes) comprising poly(arylphenylenevinylene) units whose phenylene unit bears a further aryl substituent in the para or meta position relative to the first aryl radical (formula (I)), as a result of which the operating life in EL elements can be increased and high EL efficiencies can be maintained.
    Type: Grant
    Filed: October 28, 2000
    Date of Patent: May 9, 2006
    Assignee: Semiconductors GmbH
    Inventors: Hubert Spreitzer, Heinrich Becker, Philipp Stössel
  • Patent number: 7038004
    Abstract: A process comprising: a) reacting a diphenol monomer A with a monomer B having two locations for reaction with A to form arylene ether monomer C and b) reacting arylene ether monomer C with a diphenol monomer D to form a polymer, where monomer A is HX1—Q1—X1H;??(II) monomer B is arylene ether monomer C is and monomer D is wherein: Q1 comprises at least one aryl or heteroaryl group; Q2 comprises at least one aryl or heteroaryl group; X1 is O bonded directly to an aryl carbon of Q1; X2 is O bonded directly to an aryl carbon of Q2; Z is a linker comprising at least one —C(R2)2)— group; Y is a single bond or linker group (e.g., comprising up to about 50 carbons); R1 is independently at each occurrence H, a halogen, an alkyl group, a heteroalkyl group, an aryl group, or a heteroaryl group; R2 is independently at each occurrence H, an alkyl group, or a heteroalkyl group; and R3 is H or a crosslinkable group.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: May 2, 2006
    Assignee: Lumera Corporation
    Inventors: Baoquan Chen, Timothy M. Londergan
  • Patent number: 7022812
    Abstract: A lithium battery employs for a battery separator and a battery insulating packing and the like a battery polymeric material comprising repeating units wherein p-phenylene is combined with one type of group selected from the group composed of oxygen, a methylene group, an isopropylidene group, a carbonyl group, a carbonyldioxy group, a carboxylic acid anhydride group, an amide group, an ureylene group and a sulfonyl group, or a polymeric material comprising at least two types of repeating units wherein p-phenylene is combined with one type of group selected from the group composed of oxygen, a methylene group, an isopropylidene group, a carbonyl group, a carbonyldioxy group, a carboxylic acid anhydride group, an amide group, an ureylene group, a sulfonyl group, sulfur and a carbonyloxy group.
    Type: Grant
    Filed: August 4, 2004
    Date of Patent: April 4, 2006
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Seiji Yoshimura, Hiroshi Nakajima, Maruo Kamino, Nobuhiro Nishiguchi, Masahiro Imanishi
  • Patent number: 7019045
    Abstract: An object of the present invention is to provide a material which resolves the drawbacks associated with polyimide polymers, and yet retains the advantages offered by conventional polyimide polymers. An amino group containing phenol derivative of the present invention is represented by a general formula (1) show below, and the present invention also provides a polyimide precursor produced using such an amino group containing phenol derivative. (wherein, R1, R2 and R3, which may be the same or different, each represent an alkyl group of 1 to 9 carbon atoms, an alkoxy group of 1 to 10 carbon atoms, a COOR group (in which R represents an alkyl group of 1 to 6 carbon atoms) or a hydrogen atom; R4 and R5, which may be the same or different, each represent an alkyl group of 1 to 9 carbon atoms or a hydrogen atom; X represents —O—, —S—, —SO2—, —C(CH3)2—, —CH2—, —C(CH3)(C2H5)—, or —C(CF3)2—; and n represents an integer of 1 or greater).
    Type: Grant
    Filed: May 9, 2005
    Date of Patent: March 28, 2006
    Assignee: Gun Ei Chemical Industry Co., Ltd.
    Inventors: Takeshi Tsuihiji, Michiyasu Yamazaki
  • Patent number: 7015301
    Abstract: The invention pertains to an (electro)luminescent polymer-acceptor system comprising a polymer with a plurality of chromophores doped with an acceptor for transferring excitation energy from the polymer to the acceptor wherein at least one wavelength of the polymer emission is a wavelength at which the acceptor absorbs energy, and for emitting energy as photons, characterized in that the dwell time of an exciton that is to be transferred from the polymer to the acceptor is longer than the time for transferring said exciton from the polymer to the acceptor, by satisfying the equation kETpp<kETpd, wherein kETpp is the rate constant of the energy transfer at ? between two chromophores of the polymer, kETpd is the rate constant of the energy transfer at ? between the polymer and the acceptor.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: March 21, 2006
    Assignee: Koninklijke Philips Electronics N.V.
    Inventors: Van Dijken Albert, Klemens Brunner
  • Patent number: 7008999
    Abstract: A method for forming a conjugated polymer which is doped by a dopant includes the steps of (a) adding a doping agent comprising a dopant moiety to a solution containing the conjugated polymer or a precursor thereof and, optionally, a second polymer, the dopant moiety being capable of bonding to the conjugated polymer, precursor thereof or the second polymer; (b) allowing the dopant moiety to bond to the conjugated polymer, precursor thereof or the second polymer to perform doping of the conjugated polymer, wherein the amount of doping agent added in step (a) is less than the amount required to form a fully doped conjugated polymer.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: March 7, 2006
    Assignee: Cambridge Display Technology Ltd.
    Inventors: Peter Kian-Hoon Ho, Ji-Seon Kim, Richard Henry Friend
  • Patent number: 6995215
    Abstract: Hyperbranched polymers having a plurality of at least two different types of functional groups are described. Specific embodiments include hyperbranched polymers having functional groups of a first type that are substantially uniformly distributed throughout the hyperbranched polymer molecule and a second type of functional group that is substantially uniformly distributed at the terminals of the hyperbranched polymer molecule. The hyperbranched polymers having different types of functional groups are synthesized by reacting one or more monomers having functional groups that are capable of reacting during a set of polymerization conditions to form a hyperbranched polymer, wherein at least one of the monomers contains latent functional groups that are not reactive during polymerization.
    Type: Grant
    Filed: June 2, 2003
    Date of Patent: February 7, 2006
    Assignee: Michigan Molecular Institute
    Inventors: Petar R. Dvornic, Jin Hu, Dale J. Meier, Robert M. Nowak
  • Patent number: 6987147
    Abstract: A polymeric network comprises a plurality of monomers that include a cage compound with at least three arms, wherein at least one of the arms has two or more branches, and wherein each of the branches further comprises a reactive group. Monomers in contemplated polymeric networks are covalently coupled to each other via the reactive groups. Particularly contemplated cage compounds include adamantane and diamantane, and especially contemplated branched arms comprise ortho-bis(phenylethynyl)phenyl. Especially contemplated polymeric networks have a dielectric constant of no more than 3.0, and are formed on the surface of a substrate.
    Type: Grant
    Filed: October 1, 2002
    Date of Patent: January 17, 2006
    Assignee: Honeywell International Inc.
    Inventors: Kreisler Lau, Bo Li, Boris Korolev, Edward Sullivan, Ruslan Zherebin
  • Patent number: 6962965
    Abstract: A functionalized poly(arylene ether) having a pendant carbon—carbon double bond is prepared by reacting the hydroxy end group of a poly(arylene ether) with a polyisocyanate compound to produce a urethane-capped poly(arylene ether) having pendant isocyanate functionality, which is then reacted with a polyfunctional compound having a carbon—carbon double bond and a hydroxy, thiol, or amino group. The functionalized poly(arylene ether) is useful as a component of a curable composition in which its carbon—carbon double bond copolymerizes with one or more olefinically unsaturated comonomers.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: November 8, 2005
    Assignee: General Electric Company
    Inventor: Gary William Yeager
  • Patent number: 6956100
    Abstract: An object of the present invention is to provide a polyamide resin composition from which the solvent is easily removed during film formation and which gives a film or adhesive layer reduced in residual solvent content. It is suitable for use especially as vanish. The composition and vanish are characterized by comprising as essential ingredients a phenolic hydroxyl group-having aromatic polyamide resin and a cycloalkanone as a solvent and preferably further containing a curable resin.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: October 18, 2005
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Masahiro Imaizumi, Toyofumi Asano, Masaki Shinmoto
  • Patent number: 6905785
    Abstract: Provided is a method of producing a polymeric fluorescent substance wherein one or more monomers represented by the general formula (1) are polymerized in the presence of a zerovalent nickel complex, X1—Ar1—X2??(1) wherein, Ar1 represents a divalent group selected from the group consisting of arylene groups, divalent heterocyclic compound groups, and divalent or trivalent hetero atom-bonded arylene or divalent heterocyclic compound groups, and X1 and X2 represent leaving groups. By using the polymeric fluorescent substance, a high performance polymer LED can easily be obtained.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: June 14, 2005
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takanobu Noguchi, Yoshiaki Tsubara, Shuji Doi
  • Patent number: 6897282
    Abstract: The invention relates to a method of forming a polyphenylene ether resin containing residual aliphatic unsaturation. A polyphenylene ether is reacted with a capping agent in a solvent to form the polyphenylene ether resin containing residual aliphatic unsaturation, which is precipitated from solution by combining the solution with an antisolvent. The precipitated polyphenylene ether resin containing residual aliphatic unsaturation has lower levels of residual impurities than the same compound isolated by devolatilization.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: May 24, 2005
    Assignee: General Electric
    Inventors: Amy Freshour, Hua Guo, Robert L. Howe, Edward N. Peters, Gary William Yeager
  • Patent number: 6891014
    Abstract: An aromatic ether oligomer or polyaromatic ether comprising the formula: wherein Ar is an independently selected divalent aromatic radical; formed by reacting a dihydroxyaromatic with a dihaloaromatic; and wherein the reaction is performed in the presence of a copper compound and cesium carbonate. The polyaromatic ether is formed when neither the dihydroxyaromatic nor the dihaloaromatic is present in an excess amount. The aromatic ether oligomer is formed by using an excess of either dihydroxyaromatic or dihaloaromatic. A phthalonitrile monomer comprising the formula: formed by reacting a 3- or 4-nitrophthalonitrile with a hydroxy-terminated aromatic ether oligomer. A thermoset formed by curing the phthalonitrile monomer. Processes for forming all the above.
    Type: Grant
    Filed: March 17, 2004
    Date of Patent: May 10, 2005
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M. Keller, Dawn D. Dominguez
  • Patent number: 6887967
    Abstract: A thermosetting polyimide resin composition is provided which comprises a polyimide resin and an epoxy resin, which has excellent heat resistance, low dielectric constant and low dielectric loss tangent and also yields a cured article having good mechanical properties such as tensile strength and tensile elongation. Also, a process for producing a polyimide resin used in the polyimide resin composition is provided. The thermosetting polyimide resin composition comprises a polyimide resin (X), which has a carboxyl group and a linear hydrocarbon structure having a number-average molecular weight of 300 to 6,000, and an epoxy resin (Y).
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: May 3, 2005
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Eiju Ichinose, Yohzoh Yamashina, Hidenobu Ishikawa
  • Patent number: 6887973
    Abstract: An organic polymer comprising a conjugated backbone for transporting negative charge carriers and having a first band gap and at least one side unit pendent from the backbone for transporting positive charge carriers and having a second band gap, wherein the structure of the organic polymer is selected so that the first and second band gaps are distinct from one another in the polymer.
    Type: Grant
    Filed: February 26, 2001
    Date of Patent: May 3, 2005
    Assignee: Cambridge Display Technology Limited
    Inventors: Carl Towns, Richard O'Dell, Valerie Grand
  • Patent number: 6881811
    Abstract: To provide a fluorinated aromatic polymer having excellent heat resistance and a low relative permittivity; and an insulating film for electronic devices and an insulating film for multilayered wiring boards, which are made of the polymer. A fluorinated aromatic polymer which contains two or more crosslinkable functional groups (A) per molecule and has a number average molecular weight of from 1×103 to 5×105 and an ether linkage and which is produced by e.g.
    Type: Grant
    Filed: January 12, 2004
    Date of Patent: April 19, 2005
    Assignee: Asahi Glass Company, Limited
    Inventors: Shunsuke Yokotsuka, Fusaaki Takeo
  • Patent number: 6878803
    Abstract: The invention relates to a novel and inexpensive process for the nitration and amination of aryl polymers and also to their use as blend components for producing polymer blend membranes. Such polymer blend membranes are used in membrane processes, in particular as polymeric electrolyte in electromembranes, e.g. for electrodialysis and fuel cells.
    Type: Grant
    Filed: March 1, 2001
    Date of Patent: April 12, 2005
    Assignee: Celanese Ventures GmbH
    Inventor: Wei Cui
  • Patent number: 6864343
    Abstract: A brominated polyphenylene oxide having a molecular skeleton obtained by condensing tribromophenols and satisfying the requirements: (A) its 20 wt. % solution in chloroform has an absorbance at 600 nm of not larger than 0.6; (B) when 50 ml of ion-exchanged water is added to its 1.00 g/30 ml solution in dioxane, the resulting solution has an electroconductivity of not larger than 10 ?S/cm measured at 25° C.; and (C) when a mixture comprised of 20% by weight of the brominated polyphenylene oxide and 80% by weight of triphenyl phosphate is heated at 280° C. for 20 minutes, the halide ion increase therein is not larger than 10 ?mols per gram of the brominated polyphenylene oxide, is used as a flame retardant. When it is added to resin, the resin moldings are excellent in its flame retardancy, electric properties, physical properties, thermal stability and appearance (color hue), and they do not corrode molds.
    Type: Grant
    Filed: June 9, 2003
    Date of Patent: March 8, 2005
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventor: Hideaki Onishi
  • Patent number: 6846899
    Abstract: The present invention relates to poly(arylene ethers) used as low k dielectric layers in electronic applications and articles containing such poly(arylene ethers) comprising the structure: wherein n=5 to 10000 and monovalent Ar1 and divalent Ar2 are selected from a group of heteroaromatic compounds that incorporate O, N, Se, S, or Te or combinations of the aforesaid elements, including but not limited to:
    Type: Grant
    Filed: October 1, 2002
    Date of Patent: January 25, 2005
    Assignee: Chartered Semiconductor Manufacturing Ltd.
    Inventors: Christopher Lim, Siu Choon Ng, Hardy Chan, Simon Chooi, Mei Sheng Zhou
  • Patent number: 6841650
    Abstract: There is disclosed a crystallizable poly(2,5-di-substituted-1,4-phenylene oxide), which exhibits an exothermic peak for crystallization of not less than 5 J/g at 150° C. or over when cooled after melting, and/or an endothermic peak, at the time of melting of crystals thereof, of not less than 5 J/g at 150° C. or over when re-heated after cooling of the melt, and which comprises a recurring unit of the following formula (I), and a method of preparing the same by polymerization of a 2,5-di-substituted-phenol of the following formula (II) by use of a copper complex catalyst made of a tridentate ligand of which nitrogen atoms coordinate to a copper atom in coexistence with oxygen: wherein R1's independently represent a hydrocarbon group or a substituted hydrocarbon group, and they may be the same or different. The crystallizable poly(2,5-di-substituted-1,4-phenylene oxide) is able to provide a melt molding which has a reduced degree of coloration and good heat resistance.
    Type: Grant
    Filed: May 31, 2002
    Date of Patent: January 11, 2005
    Assignees: National Institute of Advanced Industrial Science and Technology, Japan Chemical Innovation Institute
    Inventors: Hideyuki Higashimura, Kiyoshi Fujisawa, Yoshihiko Moro-Oka, Shiro Kobayashi
  • Patent number: 6835795
    Abstract: The present invention relates to a functionalized polyphenylene ether which has, in its molecule, at least one functional group selected from a carboxyl group, an acid anhydride group, an amino group, an amide group, an imide group, a silyl group, a hydroxyl group and a glycidyl group, and which gives a proton NMR spectrum with a peak area ratio (A)/(B) of 0.0001 or greater, wherein (A) is the area of peaks at chemical shifts from 2.95 to 3.04 ppm, and (B) is the area of peaks at chemical shifts from 6.00 to 6.90 ppm. Having a novel structure that has not been obtained by conventional techniques, the functionalized polyphenylene ether of the present invention has an excellent color tone, contains little black foreign substance, and provides polymer alloys with superior mechanical characteristics when blended with different polymers, and therefore makes it possible to provide products and parts in various industrial fields that will sufficiently meet the industrial demands.
    Type: Grant
    Filed: September 25, 2002
    Date of Patent: December 28, 2004
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventor: Tetsuji Tokiwa
  • Patent number: 6835803
    Abstract: A method for forming a conjugated polymer which is doped by a dopant includes the steps of (a) adding a doping agent comprising a dopant moiety to a solution containing the conjugated polymer or a precursor thereof and, optionally, a second polymer, the dopant moiety being capable of bonding to the conjugated polymer, precursor thereof or the second polymer; (b) allowing the dopant moiety to bond to the conjugated polymer, precursor thereof or the second polymer to perform doping of the conjugated polymer, wherein the amount of doping agent added in step (a) is less than the amount required to form a fully doped conjugated polymer.
    Type: Grant
    Filed: February 19, 2002
    Date of Patent: December 28, 2004
    Assignee: Cambridge Display Technology Ltd.
    Inventors: Peter Kian-Hoon Ho, Ji-Seon Kim, Richard Henry Friend
  • Patent number: 6833426
    Abstract: A halogenated aromatic compound, a polyarylene (co)polymer obtained by the polymerization of such a halogenated aromatic compound as a monomer component, and a proton-conductive membrane made of a sulfonation product of such a (co)polymer are disclosed. The halogenated aromatic compound is represented by the following general formula (1bm): wherein As′ independently represent an electron-withdrawing group; Bs′ independently represent an electron-donating atom or divalent group; Xs′ independently represent a chlorine atom, an iodine atom, or a bromine atom; Z represents an aryl group; R1 to R19 may be the same or different and each represents a hydrogen atom, a fluorine atom, an alkyl group, or a fluoroalkyl group; and a and b each represents an integer of 1 to 20.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: December 21, 2004
    Assignee: JSR Corporation
    Inventors: Yoshitaka Yamakawa, Masayuki Takahashi, Kohei Goto
  • Publication number: 20040254327
    Abstract: The invention relates to bisphenol monomers containing one or more biaryl units and related polymers, derivatives and resins thereof and more particularly to Bisphenol monomers containing two biaryl units separated by a spacer group X, and to bisphenol monomers containing a biaryl unit and an aryl unit separated by a spacer group X, and to polymers, derivatives, resins and related products prepared therefrom.
    Type: Application
    Filed: October 24, 2003
    Publication date: December 16, 2004
    Inventors: David A. Boyles, John T. Bendler
  • Publication number: 20040249109
    Abstract: A polyphenylene ether resin composition comprising a polyphenylene ether, wherein the polyphenylene ether has a polymer chain comprising recurring units each represented by the following formula (1): 1
    Type: Application
    Filed: April 1, 2004
    Publication date: December 9, 2004
    Inventors: Akira Mitsui, Mutsumi Maeda
  • Patent number: 6828406
    Abstract: The organic polymers of the invention have electrical semiconductor properties. The compounds have a backbone of phenylene groups to which side groups with semiconductor properties, or which impart semiconductor properties to the polymer, are bonded. The polymers are obtained by Bergmann cyclization from compounds that contain aromatic groups to which vicinal ethynyl groups are bonded. The polymers are suitable for the production of semiconductor components, such as organic transistors or diodes.
    Type: Grant
    Filed: July 1, 2002
    Date of Patent: December 7, 2004
    Assignee: Infineon Technologies AG
    Inventors: Roland Haasmann, Marcus Halik, Günter Schmid, Andreas Walter
  • Patent number: 6828407
    Abstract: The present invention provides a polymer electrolyte composition excellent in radical resistance and/or proton conductivity. The polymer electrolyte composition comprises an aromatic polymer phosphonic acid derivative represented by the following formula (1); and at least one selected from the group consisting of a phosphoric acid derivative and a polymer electrolyte. (wherein -Z- represents —SO2— or —CO—, x and y each represent 0.01-0.99 provided that the sum of x and y is 1, —Ar— represents a divalent aromatic group of 4-18 carbon atoms which may contain a hetero atom and may contain one or more substituents, n represents the average number of substituents per unit structure of polymeric moiety containing the aromatic group and is a positive number of 8 or less, and R and R′ each independently represent a hydrogen atom or an alkyl group).
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: December 7, 2004
    Assignees: Sumitomo Chemical Company, Limited, Toyota Jidosha Kabushiki Kaisha
    Inventors: Shigeru Sasaki, Arihiro Yashiro, Yasuaki Hidaka, Takumi Taniguchi