Cellular Products Or Processes Of Preparing A Cellular Product, E.g., Foams, Pores, Channels, Etc. Patents (Class 521/50)
  • Patent number: 6174952
    Abstract: The present invention includes processes and resulting structures for producing a modified polymer having interconnecting channels. The interconnecting channels act as controlled transmission passages through the polymer. A hydrophilic agent is blended into the polymer so that it is distributed within the polymer. In one embodiment, a water-absorbing material is blended into the polymer so that the water-absorbing material is distributed within the product. The product is solidified so that the hydrophilic agent forms passages in the product through which a desired composition is communicable to the water-absorbing material that is entrained within the product. The solidified product may be used to form a desired shaped article such as plug type inserts and liners for closed containers, or it may be formed into a film, sheet, bead or pellet.
    Type: Grant
    Filed: September 18, 1998
    Date of Patent: January 16, 2001
    Assignee: Capitol Specialty Plastics, Inc.
    Inventors: Ihab M. Hekal, Robert S. Langer, Alexander M. Klibanov, Edith Mathiowitz
  • Patent number: 6158144
    Abstract: This invention relates to a method and several exemplary apparatus for capillary dewatering of foam materials. The apparatus may include felt which is applied to an exposed face of the foam material, or a double felt arrangement applied to two opposed surfaces of the foam material. The apparatus may provide a temperature differential between the two exposed surfaces of the foam material. An alternative embodiment utilizes a roll having a capillary dewatering medium. The capillary dewatering medium may be maintained at a vacuum either above or below the breakthrough vacuum of the capillaries. The disclosed apparatus and method are particularly useful for dewatering foams having relatively fine open capillaries.
    Type: Grant
    Filed: July 14, 1999
    Date of Patent: December 12, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Gerald Martin Weber, Osman Polat, Daniel Joseph Valerio, Jr., Kofi Aduwusu, Thomas Allen Desmarais
  • Patent number: 6130264
    Abstract: A synthetic sponge having a high density is rinsed while changing the hydrostatic pressure of rinsing solution in pore spaces of the sponge to remove chemical residue and particulate matter more completely. The hydrostatic pressure can be changed by varying fluid supply pressure or varying centrifugal force. A rinsing apparatus includes a rotatable container and a fluid supply for supplying rinsing solution to sponge material in the container.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: October 10, 2000
    Assignee: Xomed Surgical Products, Inc.
    Inventors: Ronald J. Cercone, F. Barry Bays
  • Patent number: 6130263
    Abstract: The present invention includes processes and resulting structures for producing moisture absorbing desiccant entrained polymers. A polymer is caused to assume a molten state, typically by applying heat and melting the polymer. To achieve certain results in the hardened end product, such as rigidity and durability, the polymer normally acts as a moisture barrier in a solidified state, both before and after melting. A desiccating agent is blended into the polymer so that the desiccating agent is distributed within the polymer. A channeling agent is also blended into the polymer so that it is distributed within the polymer. The blending of the components is preferably done before the polymer is caused to assume a molten state. Together, the polymer, desiccating agent and channeling agent create a blended mixture. The mixture is solidified so that the channeling agent forms passages in the mixture through which moisture is communicable to desiccating agent that is entrained within the mixture.
    Type: Grant
    Filed: March 5, 1997
    Date of Patent: October 10, 2000
    Assignee: Capitol Specialty Plastics, Inc.
    Inventor: Ihab M. Hekal
  • Patent number: 6127437
    Abstract: A molded closure for a liquid container comprising a thermoplastic elastomer and a blowing agent. The molded closure is particularly suitable for use as a synthetic wine cork in a wine bottle. The molded closure does not permit passage of oxygen into the container, does not absorb oxygen from the contents of the container, can be removed from the container using a corkscrew without significant expansion, crumbling or disintegration, does not significantly taint a liquid in the container, permits the container to be placed horizontally immediately after insertion of the molded closure, and can permanently retain printed matter on its surface.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: October 3, 2000
    Assignee: Supreme Corq, Inc.
    Inventor: Dennis L. Burns
  • Patent number: 6126825
    Abstract: The present invention relates to a microporous membrane and a process for producing thereof, especially a microporous membrane which can be used for microfiltration, has excellent resistance to chemicals, and a process for producing thereof.The present invention provides a microporous membrane having excellent resistance to chemicals, and a microporous membrane which facilitates waste disposal, and a process for producing thereof.The microporous membrane has a bubble point value measured by the use of ethanol (by the test method of JIS K3832) falling in the range of from 10 kPa to 1000 kPa and comprises a polymer prepared by ring opening polymerization of a compound represented by chemical formula (I) or a polymer which is a ring opening polymer or ring opening copolymer represented by chemical formula (II). An example of the ring opening ring polymer or ring opening copolymer is a norbornene resin.
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: October 3, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukio Shinagawa, Sumio Ohtani
  • Patent number: 6110983
    Abstract: Foamed and expanded beads of a crosslinked aliphatic polyester resin having a gel fraction of at least 5% by weight. The expanded beads may be obtained by crosslinking beads of a non-crosslinked aliphatic polyester resin with a crosslinking agent including an organic peroxide to obtain crosslinked resin beads having a gel fraction of at least 5% by weight, and then expanding the crosslinked resin beads. A biodegradable foamed article may be obtained by thermally foaming the crosslinked, expanded aliphatic polyester resin beads in a mold.
    Type: Grant
    Filed: November 18, 1999
    Date of Patent: August 29, 2000
    Assignee: JSP Corporation
    Inventors: Hisao Tokoro, Satoru Shioya, Mitsuru Shinohara
  • Patent number: 6087411
    Abstract: A document feed component is presented comprising a foamed epichlorohydrin elastomer, a curing agent, and a blowing agent. The elastomer optionally further includes activators, polymerization accelerators, and a filler material. An important feature of the present invention is that the use of a foamed epichlorohydrin elastomer in accordance with the present invention does not require the use of processing aids and migratory additives. Consequently, the document feed component of this invention has the advantage of not contaminating paper or other media with which they come into contact, even for extended periods of time, while maintaining other advantageous properties, such as a high coefficient of friction, low hardness, low compression set, and excellent resistance to ultraviolet light and ozone. The document feed component of the present invention may be shaped as a roller, wheel, belt, pad or the like.
    Type: Grant
    Filed: May 6, 1999
    Date of Patent: July 11, 2000
    Assignee: World Properties, Inc.
    Inventors: Debra A. Cox, William D. Smith
  • Patent number: 6085923
    Abstract: A stopper for use in a substantially cylindrical bottle opening is disclosed. The stopper is made of a synthetic elastomer body with a portion with a substantially cylindrical shape to seal the bottle opening. The elastomer body also contains a fiber portion or a plurality of fiber portions oriented substantially longitudinally in the elastomer body. The synthetic stopper is preferably designed to replace traditional wood bark corks in wine bottles. In one embodiment, the fiber reinforcement is in the form of a porous plug surrounded by an elastomer skin. In another embodiment, fibrous strips are dispersed throughout the stopper structure. The method of producing a stopper for use in a substantially cylindrical bottle opening is also disclosed as is a method of protecting a liquid in a bottle with a fiber reinforced synthetic elastomer stopper.
    Type: Grant
    Filed: August 13, 1996
    Date of Patent: July 11, 2000
    Assignee: Neocork Technologies, Inc.
    Inventor: Stuart Yaniger
  • Patent number: 6083456
    Abstract: A biodegradable air freshener that breaks down in the presence of water to minimize solid waste, comprising a water soluble substrate substantially comprising foamed vegetable starch, and a liquid fragrance carried in the substrate. The substrate is preferably made of corn and or potato starch. The liquid fragrance may be from about 0.01 to about 10 times the weight of the substrate. A coloring agent may optionally be provided in the liquid fragrance to impart color to the air freshener. Because the substrate is made from a water soluble starch, it dissolves in water leaving little or no solid waste.
    Type: Grant
    Filed: May 6, 1993
    Date of Patent: July 4, 2000
    Assignee: Chemia, Inc.
    Inventor: Norman A. Van Rees
  • Patent number: 6083999
    Abstract: A process for preparing super lightweight sheet of the present invention comprises the steps of mixing a low density polyethylene (LDPE), a first blowing agent, a surface activation agent and a separation agent; heating the obtained mixture at a temperature higher than 160.degree. C. to obtain a molten mass; heating said molten mass at a temperature higher than the gasification temperature of said first blowing agent to separate said first blowing agent; cooling the obtained mixture; and forming the cooled mass in a sheet.In a preferred embodiment, the process of the present invention process further comprises the steps of introducing a second gaseous blowing agent in the cooled mass to obtain a foamed mass; maintaining the foamed mass at a stabilizing temperature to stabilize the foamed mass; and cooling the foamed mass at 20-25.degree. C. and maintaining the cooled mass at said temperature for 24 hours.
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: July 4, 2000
    Assignee: Elio Davide Cattan
    Inventor: Hyung Seob Moon
  • Patent number: 6080795
    Abstract: Foams based on the following components:a) a fluid emulsion comprising:a perfluoropolyether, as main protective agent,polar and non polar oils,an acrylic copolymer characterized by hydrophilic and hydrophobic groups, and activity of primary emulsifier after neutralization with alkales,an ionic surfactant (as foaming agent) waterb) a propellant.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: June 27, 2000
    Assignee: Ausimont S.p.A.
    Inventor: Giovanni Pantini
  • Patent number: 6075063
    Abstract: A method for foaming or foam-coating components is used for foaming hollow cavities of double-walled or multiple-walled components or foam-coating component parts with decorative surfaces so as to improve haptic properties of component parts. A material is introduced or applied in an unfoamed state to be foamed through the use of microwave energy. In order to achieve high dielectric losses and to ensure that the heat effect is evently distributed and essentially restricted to the material to be foamed, the material is adjusted in a polar manner by addition of certain substances such as conductive soot. Reflecting agents are used to improve the distribution and effect of the microwaves. The method ensures fully foamed hollow cavities and foam layers of uniform thickness. A foamable material for foaming or foam-coating components is also provided.
    Type: Grant
    Filed: August 23, 1999
    Date of Patent: June 13, 2000
    Assignee: Moeller Plast GmbH
    Inventor: M. Zouheir Jandali
  • Patent number: 6071976
    Abstract: A high-speed agitation type mixer of a continuous extruding method including a plurality of agitating members provided around a rotational shaft inside a fixed casing is used to mix and react a water absorbing resin containing a carboxyl group with an aqueous liquid containing, for example, a crosslinking agent that can react with the carboxyl group. The agitating members of the mixer of a continuous extruding method are provided so as to form in the ejection side a second area whose thrusting force is weaker than the thrusting force in a first area in which the water absorbing resin supplied into the casing is dispersed. A device for manufacturing a water absorbing agent is thus offered which boasts good absorbency under pressure and always maintain its excellent performance with end products.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: June 6, 2000
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yorimichi Dairoku, Toshimasa Kitayama, Kinya Nagasuna, Takanori Murakami, Akito Yano, Kunihiko Ishizaki
  • Patent number: 6051620
    Abstract: Polyester polyols which contain at least one dihydrazide linkage --C(.dbd.O)--NHNH--C(.dbd.O)-- reduce the incidence of scorching when used as a reactant in the manufacture of polyurethane foam. Also disclosed are compounds of structures (2) and (3):D--HN(--NH--C(.dbd.O)--R--C(.dbd.O)NH).sub.0-1 --NH--D (2)(A--C(.dbd.T)--NH)--.sub.
    Type: Grant
    Filed: June 11, 1997
    Date of Patent: April 18, 2000
    Assignee: CK Witco Corporation
    Inventors: Ibrahim Bechara, Thomas R. Baranowski, James Stogis, Thomas H. Morong
  • Patent number: 6040381
    Abstract: The present invention is a continuous process for preparing formulations useful for making filled polymer carpet backings. The present invention particularly incorporates polyisocyanate as a reactive diluent in a continuous process for preparing filled polyurethane polymers. Use of the present invention allows production of carpet backings that incorporate high loadings of filler materials.
    Type: Grant
    Filed: March 12, 1999
    Date of Patent: March 21, 2000
    Assignee: The Dow Chemical Company
    Inventors: James K. Jennings, Randall C. Jenkines, Larry W. Mobley
  • Patent number: 6013686
    Abstract: The present invention relates generally to blowing agent concentrates for forming porous, molded thermoplastic items, and, more particularly to blowing agent concentrates that are compatible with polycarbonate homopolymers, but which can be extruded without causing thermal decomposition of the blowing agent.
    Type: Grant
    Filed: February 13, 1998
    Date of Patent: January 11, 2000
    Assignee: General Electric Company
    Inventors: Douglas G. Hamilton, Steven R. Peak, Randall A. Reed
  • Patent number: 5981609
    Abstract: A process for the preparation of polyurethane foams by reacting a polyisocyanate composition with an isocyanate-reactive composition under foam-forming conditions, wherein the isocyanate-reactive composition comprises a monofunctional alcohol and an isocyanate-reactive cyclic urea.
    Type: Grant
    Filed: March 17, 1999
    Date of Patent: November 9, 1999
    Assignee: Imperial Chemical Industries PLC
    Inventors: Guy Jean Leon Ghislain, Els Jeanne Francine Van Isterdael
  • Patent number: 5968993
    Abstract: A method for the preparation of microcellular elastomeric polyurethane foams from a reaction mixture comprising a polyisocyanate component containing at least 85% by weight of 4,4'-diphenylmethane diisocyanate or a variant thereof, a polyol composition comprising at least one polyoxyalkylene polyol having an average nominal hydroxyl functionality of from 2 to 6, an average hydroxyl equivalent weight of at least 1300 and an average oxyethylene content of between 50 and 85% by weight, water, a chain extender having an average hydroxyl equivalent weight of from 15 to 250 and optionally a crosslinking agent, the hardblock-content being more than 45% by weight.
    Type: Grant
    Filed: June 10, 1997
    Date of Patent: October 19, 1999
    Assignee: Imperial Chemical Industries PLC
    Inventor: Gerard Jozef Bleys
  • Patent number: 5853618
    Abstract: The present invention concerns a foam having a bulk density of less than 250 g/l; the foam having a stability in air of at least 15 seconds (and preferably at least 30 seconds), the stability being defined as the time for the foam to collapse to half its volume when measured in a 111 mm internal diameter and 62 mm internal height glass beaker; wherein the foam has a stability on water at 20.degree. C. of less than 2 hours, the stability on water being defined as the time taken for a 150 ml foam mass on the surface of 450 ml distilled water in a 111 mm internal diameter and 62 mm internal height glass beaker, to collapse to reveal a 2 cm diameter area of the water surface which is substantially free from foam.
    Type: Grant
    Filed: May 5, 1998
    Date of Patent: December 29, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Catherine Louise Barker, Patrick Jean-Fran.cedilla.ois Etesse, Jose Louis Vega, Jan Hendrik Maria Verbiest
  • Patent number: 5834583
    Abstract: A poly(ethyleneoxy) block copolymer including a hydrophobic block segment useful in making a porous polymer article with improved surface hydrophilicity. Also disclosed is a method of making such a polymer article.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: November 10, 1998
    Assignee: Circe Biomedical, Inc.
    Inventors: Lawrence Francis Hancock, Alan Jay Kishbaugh, Marc Ellous Parham
  • Patent number: 5791085
    Abstract: a porous solid material for plant propagation which includes granules of a porous expanded mineral, such as perlite or vermiculite, distributed within a porous, open-cell foamed hydrophilic water-retentive polyurethane matrix. The material may be molded into sheets of break-off units for seed germination and propagation.
    Type: Grant
    Filed: August 1, 1997
    Date of Patent: August 11, 1998
    Assignee: University of Strathclyde
    Inventors: Robert Aleksander Karasinski Szmidt, Neil Bonnette Graham
  • Patent number: 5789494
    Abstract: Methods and compositions for encapsulated polymeric gels swollen with nonaqueous reactive materials are provided. The methods include gel synthesis, swelling of a gel precursor with a first nonaqueous reactive material, and encapsulation of the swollen gel with a second nonaqueous reactive material. Gels precursors may be synthesized from crosslinking polymers, or alternatively, may be formed by crosslinking and polymerizing a monomer starting material. An accelerator may be utilized to facilitate swelling of the gel precursor with the first nonaqueous reactive material. Foams and composites may also be swollen with the first nonaqueous reactive material. The swollen gel is then contacted with a second nonaqueous reactive material such that an encapsulation layer is formed thereby. The encapsulated gels may be stored for subsequent use.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 4, 1998
    Assignee: Medlogic Global Corporation
    Inventors: Barry Joseph Hand, E. C. Lupton, Jr., Lev Bromberg, Xiaohong Yu
  • Patent number: 5779775
    Abstract: The object of the present invention is to provide a stock solution composition for use in production of hard polyurethane foam, which composition can disperse the flame retardant filler component stably therein when allowed to stand and, when subjected to stirring or an external pressure, has a reduced viscosity, promising easy transfer of the composition and easy foaming in production of hard polyurethane foam at the site. The present invention provides a stock solution composition for use in production of hard polyurethane foam, which comprises, as the essential components, a polyol, a foaming agent, a flame retardant filler, a flame retarder and a solvent-swollen clay mineral. The swollen clay mineral has thixotropy; that is, it is a gel owing to the interaction between molecules when allowed to stand and, when subjected to an external pressure or the like, said interaction between molecules is cut and the gel changes into a liquid sol.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: July 14, 1998
    Assignee: Nisshinbo Industries, Inc.
    Inventors: Shin Kuwabara, Kazuhisa Nagata, Yasuo Imashiro, Eiji Sasaki
  • Patent number: 5744504
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo?2.2.1!heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: February 14, 1997
    Date of Patent: April 28, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono
  • Patent number: 5725733
    Abstract: A process produces foam bodies having various properties and containing cellulose-containing materials broken up and/or partially broken up and/or not broken up, and additives, if need be. The cellulose-containing starting materials are first processed further for forming a moist pulp and subsequently subjected to a heat treatment by microwave radiation. The properties of the foam bodies so produced are predetermined by admixing certain substances intensifying the formation of gas in the pulp, increasing the adhesive bond between the particles in the pulp, or which completely or partially convert into a gas either under the influence of heat or of moisture, thus supporting the foaming. Furthermore, other residual and waste materials can be added during the production process, which may be materials of a silicate nature as well, preferably with the objective of reusing such materials in a useful way and of predetermining at the same time certain product properties of the foam bodies.
    Type: Grant
    Filed: April 30, 1996
    Date of Patent: March 10, 1998
    Assignee: Schweitzer, Vodermair & Schimmer-Wottrich GBR
    Inventors: Edgar Brandauer, Norbert Habelski, Jana Loffler, Frank Ramhold, Ingwalt Friedemann
  • Patent number: 5721281
    Abstract: Opened-celled porous plastics or natural products are made flame retardant by coating the cell walls with a liquid containing carbonization auxiliaries and/or flame retardant agents. The excess liquid is removed and the mass is dried. The open-celled porous mass now has good fire characteristics. The carbonization auxiliaries and/or flame retardant agents may also be used in the production of the open-celled porous organic masses. These flame retardant porous masses may be used in furniture, mattresses, fire barriers, textile coating, laminates, linings and as insulators.
    Type: Grant
    Filed: July 1, 1996
    Date of Patent: February 24, 1998
    Inventor: David H. Blount
  • Patent number: 5714230
    Abstract: Formed products such as foams, fabrics for industrial materials, filaments, nonwoven fabrics, composite materials and films which are degradable after use with ease in the natural environment are prepared by using a high molecular weight aliphatic polyester obtained by direct polycondensation of an aliphatic polyhydric alcohol with aliphatic polybasic acid or additionally hydroxycarboxylic acid or oligomers of these materials in a reaction mixture containing a solvent.
    Type: Grant
    Filed: November 15, 1994
    Date of Patent: February 3, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Taiji Kameoka, Takeshi Kashima, Masanobu Ajioka, Akihiro Yamaguchi, Kazuhiko Suzuki
  • Patent number: 5710184
    Abstract: A molded closure for a liquid container comprising a thermoplastic elastomer and a blowing agent. The molded closure is particularly suitable for use as a synthetic wine cork in a wine bottle. The molded closure does not permit passage of oxygen into the container, does not absorb oxygen from the contents of the container, can be removed from the container using a corkscrew without significant expansion, crumbling or disintegration, does not significantly taint a liquid in the container, permits the container to be placed horizontally immediately after insertion of the molded closure, and can permanently retain printed matter on its surface.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: January 20, 1998
    Assignee: Supreme Corq
    Inventor: Dennis L. Burns
  • Patent number: 5700903
    Abstract: A poly(ethyleneoxy) block copolymer including a hydrophobic block segment useful in making a porous polymer article with improved surface hydrophilicity. Also disclosed is a method of making such a polymer article.
    Type: Grant
    Filed: April 18, 1996
    Date of Patent: December 23, 1997
    Assignee: Circe Biomedical, Inc.
    Inventors: Lawrence Francis Hancock, Alan Jay Kishbaugh, Marc Ellous Parham
  • Patent number: 5700902
    Abstract: A poly(ethyleneoxy) block copolymer including a hydrophobic block segment useful in making a porous polymer article with improved surface hydrophilicity. Also disclosed is a method of making such a polymer article.
    Type: Grant
    Filed: July 27, 1995
    Date of Patent: December 23, 1997
    Assignee: Circe Biomedical, Inc.
    Inventors: Lawrence Francis Hancock, Alan Jay Kishbaugh, Marc Ellous Parham
  • Patent number: 5696174
    Abstract: Stable and water-resistant aqueous foam composition containing (1) a long chain cationic organic compound and (2) a long-chain anionic organic compound in a weight ratio of from 0.05:1 to 15:1. The stable foam composition of the invention may be mixed with various water-soluble or water-dispersible organic, polymeric, or inorganic substances and used in applications where lightweight, heat, sound or other insulative, barrier properties or homogeneous material distribution are needed. Such applications include cementitious or gypsum containing substances, adhesives, binders, paper treating materials, coatings, ceramics, landfills, geofills, and firefighting and fireproofing materials.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: December 9, 1997
    Assignee: Allied Foam Tech Corporation
    Inventors: Yen-Yau H. Chao, Kuei-Jung Chao
  • Patent number: 5652330
    Abstract: Process for preparing polycondensates of citric acid and/or isocitric acid, by converting(a) citric acid, isocitric acid or mixtures thereof in an organic solvent in the presence of a water-withdrawing agent at least partially into the anhydride form and then condensing the reaction mixture, if desired after addition of two cocondensable compounds selected from the group consisting of(b) other hydroxycarboxylic acids and/or(c) amino acids, alcohols, amines and/or at least dibasic carboxylic acids other than carboxylic acids (a) and (b), at temperatures of at least 80.degree. C. to form polycarboxylates which have an average molecular weight of at least 500, polycondensates of citric acid and/or isocitric acid obtainable thereby, anduse of said polycondensates as ingredients in phosphate-free and reduced-phosphate detergents and cleaners, and also detergents and cleaners which contain at least one surfactant and optionally builders and other customary constituents with from 0.
    Type: Grant
    Filed: August 16, 1995
    Date of Patent: July 29, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Boeckh, Angelika Funhoff, Alexander Kud, Richard Baur, Volker Schwendemann, Gunnar Schornick
  • Patent number: 5635562
    Abstract: The present invention relates to relatively inexpensive multi-purpose expandable vibration damping material compositions particularly useful in constrained layer applications. The composition essentially includes an elastomeric polymer, plasticizer, thermoplastic polymer, foaming agent, adhesion promoters and filler. In addition to the aforementioned, under certain embodiments, the expandable vibration damping material compositions may also employ rheological modifiers such as cross-linking agents and epoxy curing agents.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: June 3, 1997
    Assignee: Lear Corporation
    Inventor: Collin C. Malcolm
  • Patent number: 5627217
    Abstract: A method of preparing a porous article is provided. The method includes: contacting a porous substrate with a first reactant that enters pores of the substrate; and contacting the porous substrate bearing the first reactant with a second reactant that is capable of reacting with the first reactant in an interfacial polymerization reaction; the amounts of first and second reactant being selected such that there occurs no, or substantially no, closing of pores of the substrate by the formed polymer. The invention also provides a porous article bearing a compound which is photochemically reactive and capable of undergoing a substantially non-reversible chemical transformation upon exposure to ultra-violet, visible or near infra-red irradiation. The photochemically reactive compound can be derivatized by irradiation and further reaction to provide a wide variety of useful membranes, for example, for microfiltration or for biochemical reactions and separations.
    Type: Grant
    Filed: September 29, 1995
    Date of Patent: May 6, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Ken Rilling, James Dickson, Ronald Childs, David R. Gagnon
  • Patent number: 5627219
    Abstract: A foamed plastic manufactured by foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in the foams of the foamed plastic is less than atmospheric pressure, is disclosed. Further, a foamed plastic manufactured by hermetically sealing with an airtight film and foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in a gap region between the airtight film and the foamed plastic and the pressure in the foams of the foamed plastic are less than atmospheric pressure is disclosed. Further, a method of manufacturing foamed plastic comprising foaming a mixture of a volatile polymerizable foaming agent and a resin, and irradiating the foamed plastic with an energy beam.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 6, 1997
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Kazufumi Ogawa
  • Patent number: 5596039
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: February 24, 1994
    Date of Patent: January 21, 1997
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi
  • Patent number: 5591542
    Abstract: A battery having a positive electrode, a negative electrode is equipped with a diaphragm between the electrodes. The diaphragm includes a hydrophilized polymer porous body with pores in which ethylene copolymer particles are held, having a melting point of 80.degree. to 170.degree. C., and side chains.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: January 7, 1997
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Takeshi Sakamoto, Koji Hara, Akira Harada
  • Patent number: 5589577
    Abstract: The invention is related to highly substituted, water-insoluble, poorly water-permeable fatty acid esters of polysaccharides and compositions comprising said polysaccharides esters suitable for use in hot-melt adhesives and as coatings for the controlled release of active ingredients, especially fertilizers. A convenient method for preparing said polysacharide esters using e.g. dimethylformamide as a solvent is also disclosed.
    Type: Grant
    Filed: October 26, 1994
    Date of Patent: December 31, 1996
    Assignee: Alko Group Ltd.
    Inventors: Soili Peltonen, Kai Harju
  • Patent number: 5587220
    Abstract: A foamed plastic manufactured by foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in the foams of the foamed plastic is less than atmospheric pressure, is disclosed. Further, a foamed plastic manufactured by hermetically sealing with an airtight film and foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in a gap region between the airtight film and the foamed plastic and the pressure in the foams of the foamed plastic are less than atmospheric pressure is disclosed. Further, a method of manufacturing foamed plastic comprising foaming a mixture of a volatile polymerizable foaming agent and a resin, and irradiating the foamed plastic with an energy beam.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 24, 1996
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Kazufumi Ogawa
  • Patent number: 5580649
    Abstract: A foamed article of styrene type resin, in which base resin particles are styrene type resin particles obtainable by a graft polymerization of a cis-rich polybutadiene with a styrene type monomer, a blowing agent contains n-pentane as its main component and the foamed article shows a density of 0.015-0.040 g/cm.sup.3, an average foam diameter of 60-300 micrometers and a closed cell foam rate of not less than 50%.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: December 3, 1996
    Assignee: Sekisui Kaseihin Kogyo Kabushiki Kaisha
    Inventors: Ikuo Morioka, Hiroyuki Yamagata, Mutsuhiko Shimada
  • Patent number: 5567511
    Abstract: A label for containers comprises a foamed polyester film that has a density of less than 1 g/cm.sup.3. The foamed polyester film may be blown away in air and then floated away in water during the recycle process for containers. After separation from the containers the foamed polyester film may be reclaimed by a chemical process to recover raw materials for polyesters.
    Type: Grant
    Filed: March 12, 1996
    Date of Patent: October 22, 1996
    Assignee: Eastman Chemical Company
    Inventors: Wayne K. Shih, Robert J. Turney
  • Patent number: 5552448
    Abstract: A plastic foam material composed of a blended resin composition which includes at least two thermoplastic resins and a silane-modified based resin. The blended resin composition consists essentially of 100 parts by weight of at least two thermoplastic resins, from about 1 to about 50 parts by weight of a silane-modified, cross-linked, thermoplastic resin; from about 0.001 to about 2.5 parts by weight of a cross-linking catalyst for use in a silane compound and from about 1 to about 20 parts by weight of a foaming agent. According to one embodiment of the present invention, the thermoplastic resins include at least two substantially incompatible and substantially uncross-linked thermoplastic resins, while in another embodiment the two thermoplastic resins need not be substantially incompatible. The blended resin composition may further include reinforcers such as glass fibers and filler. The thermodecomposition foaming agent decomposes at sufficiently high temperatures to yield a plastic foam material.
    Type: Grant
    Filed: September 21, 1994
    Date of Patent: September 3, 1996
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Tomoyuki Kobayashi, Kenji Miyazaki, Masanori Nakamura
  • Patent number: 5550167
    Abstract: Absorbent foam materials that are capable of acquiring and distributing aqueous fluids, especially discharged body fluids such as urine. These absorbent foams combine relatively high capillary absorption pressures and capacity-per-weight properties that allow them to acquire fluid, with or without the aid of gravity. These absorbent foams also give up this fluid efficiently to higher absorption pressure storage materials, including foam-based absorbent fluid storage components, without collapsing. These absorbent foams are made by polymerizing high internal phase emulsions (HIPEs).
    Type: Grant
    Filed: August 30, 1995
    Date of Patent: August 27, 1996
    Assignee: The Procter & Gamble Company
    Inventor: Thomas A. DesMarais
  • Patent number: 5536458
    Abstract: It is object of the present invention to provide a method by which a variable property component, such as two-color parts, having the interior covered with a thin film of the surface area is molded from polyurethanes by RIM, eliminating the need for separately applying a mold release agent or colorants to the cavity surface. Greater latitude in design due to varying physical characteristics is provided.
    Type: Grant
    Filed: December 16, 1994
    Date of Patent: July 16, 1996
    Assignee: Toyoda Gosei Co., Ltd.
    Inventors: Yukio Kawakita, Shogo Sugiyama, Naohisa Nagasaka
  • Patent number: 5521249
    Abstract: Copolymers of vinyl aromatic monomers and propoxylated allyl alcohols having an average of 2 or less oxypropylene groups are disclosed. The copolymers, which have hydroxyl numbers of 80-260 mg KOH/g and number average molecular weights from 500-3500, are particularly useful for polyurethanes, alkyd resins and coatings, melamine-based coatings, and unsaturated polyester resins.
    Type: Grant
    Filed: April 12, 1995
    Date of Patent: May 28, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Shao-Hua Guo
  • Patent number: 5498409
    Abstract: An insoluble material for adsorbing a pyrogen comprising a polymer of an aziridine compound. According to the present invention, a large amount of the pyrogen can be easily removed from a solution containing pyrogen, and a large amount of the material for adsorbing the pyrogen can be prepared in easy steps. Therefore, the adsorbing material can greatly contribute to the preparation of medicines.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: March 12, 1996
    Assignees: Chuichi Hirayama, Kohjin Co., Ltd.
    Inventors: Chuichi Hirayama, Keijun Hiraoka, Sunao Morimoto
  • Patent number: 5496862
    Abstract: A molded closure for a liquid container comprising a thermoplastic elastomer and a blowing agent. The molded closure is particularly suitable for use as a synthetic wine cork in a wine bottle. The molded closure does not permit passage of oxygen into the container, does not absorb oxygen from the contents of the container, can be removed from the container using a corkscrew without significant expansion, crumbling or disintegration, does not significantly taint a liquid in the container, permits the container to be placed horizontally immediately after insertion of the molded closure, and can permanently retain printed matter on its surface.
    Type: Grant
    Filed: May 5, 1993
    Date of Patent: March 5, 1996
    Assignee: Supreme Corq
    Inventor: Dennis L. Burns
  • Patent number: 5480915
    Abstract: A molded closure for a liquid container comprising a thermoplastic elastomer and a blowing agent. The molded closure is particularly suitable for use as a synthetic wine cork in a wine bottle. The molded closure does not permit passage of oxygen into the container, does not absorb oxygen from the contents of the container, can be removed from the container using a corkscrew without significant expansion, crumbling or disintegration, does not significantly taint a liquid in the container, permits the container to be placed horizontally immediately after insertion of the molded closure, and can permanently retain printed matter on its surface.
    Type: Grant
    Filed: May 4, 1994
    Date of Patent: January 2, 1996
    Assignee: Supreme Corq
    Inventor: Dennis L. Burns
  • Patent number: 5476974
    Abstract: Normally liquid, omega-hydrofluoroalkyl ether compounds (and selected mixtures thereof) have a saturated perfluoroaliphatic chain of carbon atoms interrupted by one or more ether oxygen atoms. The compounds can be prepared, e.g., by decarboxylation of the corresponding fluoroalkyl ether carboxylic acids and are useful, e.g., in cleaning and drying applications.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: December 19, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: George G. I. Moore, Miguel A. Guerra