Abstract: A method for the oxidative coupling of hydrocarbons includes providing an oxidative catalyst inside a reactor and carrying out the oxidative coupling reaction under a set of reaction conditions. The reactor surfaces that contact the reactants and products do not provide a significant detrimental catalyzing effect. In an embodiment the reactor contains an inert lining or a portion of the reactor inner surface is treated to reduce the detrimental catalytic effects. In an embodiment the reactor contains a lining that includes an oxidative catalyst.

Abstract: A device for mixing and cooling two reactive liquids, comprising a bundle type heat exchanger with parallel tubes, a head space open to one end of all tubes, a first inlet to the head space for introducing a first liquid and a second inlet to the head space with a multitude of nozzles for introducing a second liquid, the nozzles being located within the head space and oriented to direct the introduced liquid transverse to the axis of the tubes of the tube bundle, is useful for making peroxomonosulphuric acid from 85 to 98% by weight sulphuric acid introduced into the first inlet of the device and 50 to 80% by weight aqueous hydrogen peroxide introduced into the second inlet of the device.

Abstract: Embodiments of apparatuses and methods for reforming of hydrocarbons including recovery of products are provided. In one example, a method comprises separating a reforming-zone effluent into a H2, C6? hydrocarbon-containing gas phase and a C5+ hydrocarbon-containing liquid phase. The H2, (C1-C11) hydrocarbon-containing gas phase is partially condensed and separated to form a H2, C6? hydrocarbon-containing net gas stream and a C3+ hydrocarbon-containing liquid stream. The C5+ hydrocarbon-containing liquid phase, the C3+ hydrocarbon-containing liquid stream, and at least a portion of the H2, C6? hydrocarbon-containing net gas stream are introduced to a re-contacting recovery zone for forming a H2-rich stream, a C3/C4 hydrocarbon-rich LPG stream, and a C5+ hydrocarbon-rich reformate stream.

Abstract: Disclosed herein are mono-functional silylating compounds that may exhibit enhanced silylating capabilities. Also disclosed are method of synthesizing and using these compounds. Finally methods to determine effective silylation are also disclosed.

Abstract: A fuel processor with a floating catalyst has a reactant gas passage and a product gas passage separated by a separating wall which is fixed at one end and free at the other end, to permit differential thermal expansion. The catalyst is received inside the separating wall proximate to the free end. An outer wall at least partially surrounds the separating wall and the fixed end of the separating wall may be joined to the outer wall. The fuel processor may comprise a plurality of concentric tubes, and may include a third tube located inside the separator wall. The gas passages are provided with gas permeable support structures such as turbulizers or fins which support the separating wall relative to the outer wall, but the support structures are bonded to only one tube in order to permit differential thermal expansion of the walls.

Abstract: An apparatus for a radial-flow reactor according to various approaches includes an inner partition assembly having an inwardly tapered bottom portion. According to various approaches, an inner partition assembly support includes a socket with a tapered upper rim. A process according to various aspects includes assembling a radial-flow reactor by installing an inner partition assembly by aligning a bottom portion of the inner partition assembly with an opening of a inner partition assembly support socket and lowering the bottom portion into the opening.

Abstract: Disclosed herein is a system for recovering flash gas from an oil storage tank. In one example of the invention, the system may include a flexible storage tank that receives the flash gas and temporarily stores the flash gas; a compressor having an input receiving the flash gas from the flexible storage tank, the compressor compressing the flash gas to form compressed gas; and an oxygen reduction subsystem receiving the compressed gas, the oxygen reduction subsystem reducing an amount of oxygen from the compressed gas. In this manner, the resulting compressed oxygen-reduced gas that has been recovered can be injected into a sales gas line for use, under certain conditions.

Abstract: Objects of the present invention are to provide a novel dehydrogenation reaction catalyst, to provide a method that can produce a ketone, an aldehyde, and a carboxylic acid with high efficiency from an alcohol, and to provide a method for efficiently producing hydrogen from an alcohol, formic acid, or a formate, and they are accomplished by a catalyst containing an organometallic compound of Formula (1).

Abstract: An agricultural fertigation method includes the continuous charging of crop-quality-enhancer-feedstock comprised of one or more crop-quality enhancers (fertilizers, soil amendments and the like) to an irrigation system upstream of the agricultural field being irrigated. The crop-quality-enhancer-feedstock is diluted upon so charging to a level within the system solubility limits and the stream of flowing irrigation water dampens the resultant dissolution exotherm. A system wherein crop-quality enhancers are efficiently continuously fed to the irrigation system main line or a side-arm mixing chamber efficiently implements the method.

Abstract: The present invention relates to an apparatus for the treatment of liquids, comprising a filter module with a filter, an inlet for liquid, a first outlet for liquid and a second outlet for filtered liquid, wherein the inlet and the first outlet are positioned on a first side of the filter, and the second outlet is positioned on the second side of the filter, a first UV-treatment module with a first UV-light source, wherein the first UV-treatment module is connected with the first outlet of the filter module and adapted to receive liquid from the filter module, and to expose said liquid to UV-light from the first UV-light source, and a second UV-treatment module with a second UV-light source, wherein the second UV-treatment module is connected with the second outlet of the filter module adapted to receive filtered liquid from the filter module, and to expose said liquid to UV-light from the second UV-light source.

Abstract: An agricultural fertigation method includes the continuous charging of crop-quality-enhancer-feedstock comprised of one or more crop-quality enhancers (fertilizers, soil amendments and the like) to an irrigation system upstream of the agricultural field being irrigated. The crop-quality-enhancer-feedstock is diluted upon so charging to a level within the system solubility limits and the stream of flowing irrigation water dampens the resultant dissolution exotherm. A system wherein crop-quality enhancers are efficiently continuously fed to the irrigation system main line or a side-arm mixing chamber efficiently implements the method.

Abstract: An apparatus for producing a catalyst comprising a tank configured to prepare an aqueous mixed solution containing a Mo compound, a V compound and a Nb compound, a dryer configured to spray-dry the aqueous mixed solution, and a pipe for connecting the tank with the dryer so that the aqueous mixed solution can be supplied from the tank to the dryer, wherein a heater configured to heat the aqueous mixed solution is provided in the tank and/or the pipe, and a filter configured to filtrate the aqueous mixed solution is provided in the pipe.

Abstract: A liquid phase reactor comprising a screw within a barrel, the screw and barrel being relatively rotatable and defining a mixing zone therebetween, the barrel having at least two inlets for introduction of components for mixing into the barrel and an outlet for discharge of a product of mixing from the barrel, the screw comprising a spiral groove whereby relative rotation of the screw and barrel is adapted to axially transport the components between the screw and barrel while mixing the components and to extrude the product through the outlet, wherein the reactor is adapted to achieve a substantially constant flow ratio of components into the barrel during operation of the reactor.

Abstract: Described herein are embodiments of systems and methods for oxidizing gases. In some embodiments, a reaction chamber is configured to receive a fuel gas and maintain the gas at a temperature within the reaction chamber that is above an autoignition temperature of the gas. The reaction chamber may also be configured to maintain a reaction temperature within the reaction chamber below a flameout temperature. In some embodiments, heat and product gases from the oxidation process can be used, for example, to drive a turbine, reciprocating engine, and injected back into the reaction chamber.

Abstract: An agricultural fertigation method includes the continuous charging of crop-quality-enhancer-feedstock comprised of one or more crop-quality enhancers (fertilizers, soil amendments and the like) to an irrigation system upstream of the agricultural field being irrigated. The crop-quality-enhancer-feedstock is diluted upon so charging to a level within the system solubility limits and the stream of flowing irrigation water dampens the resultant dissolution exotherm. A system wherein crop-quality enhancers are efficiently continuously fed to the irrigation system main line or a side-arm mixing chamber efficiently implements the method.

Abstract: The invention relates to a device for the preparation of radiochemical compounds. It is provided that the device comprises at least a reaction module, a dosing module, and a storage module, wherein; the reaction module has at least one reaction vessel having a closable opening through which substances needed for the preparation of a predetermined radiochemical compound can be introduced into the reaction vessel of the reaction module and through which the prepared radiochemical compound can be removed from the reaction vessel of the reaction module; the dosing module has at least one pipetting head which can be moved relative to the storage module and the reaction module and in x, y, and z directions and also has at least one dosing unit; and at least one reservoir for one of the substances needed for the preparation of the respective radiochemical compound is formed in the storage module.

Abstract: Described herein are embodiments of systems and methods for oxidizing gases. In some embodiments, a reaction chamber is configured to receive a fuel gas and maintain the gas at a temperature within the reaction chamber that is above an autoignition temperature of the gas. The reaction chamber may also be configured to maintain a reaction temperature within the reaction chamber below a flameout temperature. In some embodiments, heat and product gases from the oxidation process can be used, for example, to drive a turbine, reciprocating engine, and injected back into the reaction chamber.

Abstract: A system and process for removing catalyst fines from a gas stream overhead the slurry in a Fischer-Tropsch slurry bubble column reactor. The gas phase at the top of the slurry bubble column reactor containing small amounts of entrained liquid and catalyst particles. The unreacted gases are passed through a demister, which removes larger droplets and catalyst particles. Smaller droplets and catalyst fines are conveyed to a secondary gas cleaner, such as a cyclone, whereby substantially all remaining particles are removed from the gas phase. A particle-containing liquid produced in the secondary gas cleaner can be further subjected to a filtrate cleaning unit to filter out fine catalyst particles and produce a substantially particle-free liquid product stream and a slurry stream of liquid product containing catalyst particles.

Abstract: Disclosed is a method for continuously preparing a water-soluble azo dye by coupling a nebulizer with a pipeline. According to the method, the nebulizer is coupled with a pipeline with an interception tower plate, atomized and mixed reaction liquid flow flows through the pipeline with the interception tower plate, and mixing and reacting are further enhanced through turbulent mixing on the tower plate, so that instant separation of reaction heat generated in an atomizing contact reaction from a reactant is achieved, and normal-temperature rapid continuous production of the water-soluble azo dye is achieved. Fog drops which are atomized by using the nebulizer have small particle diameter and large specific surface area, so that a diazo salt and a coupling component are sprayed separately, move face to face and can be fully contacted, and mixing and reacting speeds are increased.

Abstract: A system for the production of ammonium sulfate granules including a pipe cross reactor (PCR) configured to contact concentrated sulfuric acid with anhydrous ammonia to produce a PCR product comprising ammonium sulfate; and a granulator fluidly connected to the PCR, whereby PCR product extracted from the PCR can be introduced into the granulator, an inlet for ammonium sulfate seed material, an ammonia sparger configured to spray liquid anhydrous ammonia directly onto a bed of ammonium sulfate granules within the granulator, a granulator vent configured for extraction of a vapor comprising unreacted ammonia from the granulator, and a granulator product outlet configured for extraction of granulator product comprising ammonium sulfate granules from the granulator. A method of producing ammonium sulfate granules is also provided.

Abstract: The invention relates to a device for continuously carrying out chemical reactions. The device comprises a microwave generator, a microwave applicator accommodating a microwave-transparent tube, and an isothermal reaction section which is arranged such that the material to be reacted is guided inside the microwave-transparent tube through a microwave applicator which is used as the heating zone and in which it is heated to reaction temperature by means of microwaves that are emitted from the microwave generator into the microwave applicator. The material to be reacted, which is heated and optionally under pressure, is transferred from the microwave applicator to an isothermal reaction zone once it has left the heating zone, said reaction zone being arranged downstream of the heating zone, and is cooled once it has left the isothermal reaction zone.

Abstract: Disclosed are process and apparatus for vertical splitting of the oxygen supply to a post-oxidation reactor. Further disclosed are process and apparatus for supplying reaction medium to a post-oxidation reactor at a mid-level inlet. Such apparatus and process can assist in reducing oxygen pinch throughout the post-oxidation reactor.

Abstract: A fuel processing system for converting a logistical fuel and air into a liquid product comprising methanol. One such system comprises a fuel injection system configured to combine a logistical fuel and ambient air to produce a logistical fuel and air mixture, a synthesis gas production system configured to convert the logistical fuel and air mixture to synthesis gas, and a methanol synthesis system configured to convert the synthesis gas to a crude methanol liquid. Related methods are additionally disclosed.

Abstract: Devices for selective hydrogenation of azide and peroxide compounds include at least one porous element, for example a solid metallic structure positioned within a reaction tube of a tubular housing. The porous element includes a framework of interconnected elements establishing a plurality of shells respectively defining a plurality of hollow spaces of predetermined geometrical configuration. Each of the shells includes holes that fluid-connect adjacent ones of the spaces to thereby allow a cross-flow of the azide or peroxide compounds through the porous element.

Abstract: The present invention relates to a multifunctional module comprising one or more units selected from the group consisting of reactor units, filter units, membrane units, reactor-separator units, clarificator units, purificator units, extractor units, and mixer units. The units are connected parallel or in series or both to each other, and each unit has at least one member having a surface, which surface is rotating with the member. The member is rotating around an axis making the unit operate under centrifugal force. One or more chambers for fluids are co-rotating with the rotating member. The present invention relates further to units which could be used in a spinning multifunctional module, and use of a spinning multifunctional module.

Abstract: A biochip including conductive particle and a device for detecting target antigen comprising the biochip are disclosed. According to the present invention, a target antigen can be effectively detected using a small amount of target antigen alone, whereby nonspecific detection signal can be reduced and an amplified signal can be detected.

Abstract: A heat sink is used to absorb heat produced by a vehicle. The heat sink uses an endothermic catalytic alcohol dehydrogenation reaction to assist with the absorption of excess heat produced in the electronics of the vehicle. In some embodiments, the alcohol can be pre-heated by absorbing heat from various components of the vehicle. Excess heat from the various components or from the vehicle engine can be used to vaporize the reaction fluids in order to further absorb additional heat. Reaction fluids can also be sent to the vehicle's engine/burner for use as a supplemental fuel.

Abstract: What is described is a process of forming lipid-nucleic acid nanoparticles simply and reproducibly under aseptic conditions comprising single use components.

Abstract: A solids handling equipment rotary plough (200) includes an elongate metal body (201) with a leading face (210) and a trailing face (212). The body (201) is configured to be mounted to a rotary component for rotation about an axis of rotation at least in one direction which is an operative forward direction such that the leading face (210) leads the trailing face (212). At least the leading face (210) has at least two major operatively upwardly and outwardly extending surfaces (202.1, 204.1) which are not coplanar. A first major surface (202.1) is angled operatively rearwardly and upwardly relative to the forward direction of rotation at an angle of at least 1° to the vertical. A second major surface (204.1) is angled operatively forwardly and outwardly at an angle of at least 1° relative to a radius of a circle described in use by the rotary plough (200) when rotating in the operative forward direction.

Abstract: Multiple catalytic processing stations couple with a system which produces volatile gas streams from biomass decomposition at discrete increasing temperatures. These catalytic processing stations can be programmed to maximize conversion of biomass to useful renewable fuel components based on input feedstock and desired outputs.

Abstract: Embodiments of the invention provide an apparatus and a process for generating a chemical precursor used in a vapor deposition processing system. The apparatus includes a canister (e.g., ampoule) having a sidewall, a top, and a bottom encompassing an interior volume therein, inlet and outlet ports in fluid communication with the interior volume, and a thermally conductive coating disposed on or over the outside surface of the canister. The thermally conductive coating is more thermally conductive than the outside surface of the canister. The thermally conductive coating may contain aluminum, aluminum nitride, copper, brass, silver, titanium, silicon nitride, or alloys thereof. In some embodiments, an adhesion layer (e.g., titanium or tantalum) may be disposed between the outside surface of the canister and the thermally conductive coating. In other embodiments, the canister may contain a plurality of baffles or solid heat-transfer particles to help evenly heat a solid precursor therein.

Abstract: A cooled reactor for the production of dimethyl ether by catalytic dehydration of methanol in the gas phase, the reactor having an adiabatic catalyst bed as starting zone, a moderator zone cooled by direct or indirect heat exchange, and optionally an adiabatic catalyst bed as conditioning zone. The conversion of methanol to dimethyl ether is increased and the formation of undesired by-products is decreased.

Abstract: Disclosed herein is a continuous process for preparing a silica product, comprising: (a) continuously feeding an acidulating agent and an alkali metal silicate into a loop reaction zone comprising a stream of liquid medium; wherein at least a portion of the acidulating agent and the alkali metal silicate react to form a silica product in the liquid medium of the loop reaction zone; (b) continuously recirculating the liquid medium through the loop reaction zone; and (c) continuously discharging from the loop reaction zone a portion of the liquid medium comprising the silica product. Silica products and dentifrice compositions comprising the silica products are also disclosed. A continuous loop reactor is also disclosed.

Abstract: Methods and systems for on-site generation of peracid chemistry, namely peroxycarboxylic acids and peroxycarboxylic acid forming compositions, are disclosed. In particular, an adjustable biocide formulator or generator system is designed for on-site generation of peroxycarboxylic acids and peroxycarboxylic acid forming compositions from sugar esters. Methods of using the in situ generated peroxycarboxylic acids and peroxycarboxylic acid forming compositions are also disclosed.

Abstract: A novel method of making chlorine dioxide is provided. The method includes the steps of combining a hypochlorite salt and trichloroisocyanuric acid reactants in solid state in an aqueous reaction medium; and mixing the reaction medium with a gaseous carrier under conditions suitable to generate chlorine dioxide. A novel apparatus for use in generating chlorine dioxide is also provided.

Abstract: A gasification reactor comprising a gasifier with a tubular gastight wall arranged within a pressure vessel. The gasification reactor comprises one or more pressure responsive devices comprising a sleeve with a cooled section extending outwardly from an opening in the gastight wall. The pressure responsive devices can, e.g., include a pressure measurement device and/or a pressure equalizer. Method of using a pressure responsive device with such a gasifier, wherein a heat sluice is used formed by a sleeve with a cooled section extending outwardly from an opening in the gastight wall.

Abstract: An apparatus for generating hydrogen for fuel cells is provided. The apparatus includes a housing, a button, a first separating plate, a solid state reactant, and a separating membrane. The housing has an opening and a reservoir. The button connected to the housing covers the opening. The first separating plate disposed in the housing divides the reservoir into first and second sub-rooms. The opening communicates with the first sub-room and the first sub-room is suitable for storing a liquid reactant. The first separating plate has a through hole opposite to the button. The solid state reactant is disposed in the second sub-room. The separating membrane disposed on the through hole separates the first sub-room from the second sub-room. When the button is pushed, the button damages the separating membrane. Therefore, the liquid reactant flows to the second sub-room and reacts with the solid state reactant to generate hydrogen.

Abstract: An apparatus is disclosed for recovering hydroprocessing effluent from a hydroprocessing unit utilizing a hot stripper and a cold stripper. Only the hot hydroprocessing effluent is heated in a fired heater prior to product fractionation, resulting in substantial operating and capital savings.

Abstract: Disclosed are an apparatus and a method for manufacturing composite nanoparticles. The apparatus comprises: a first precursor supply unit vaporizing a first precursor and supplying it to a reaction unit; a second precursor supply unit vaporizing a second precursor and supplying it to the reaction unit; the reaction unit producing composite nanoparticles by reacting the vaporized first precursor with the vaporized second precursor; an oxygen supply line supplying an oxygen source to the reaction unit; and a collection unit collecting the composite nanoparticles produced by the reaction unit. Since gas phase synthesis occurs in different stages using the U-shaped reaction chamber, aggregation is prevented and composite nanoparticles of uniform size and high specific surface area can be produced easily.

Abstract: Disclosed are process and apparatus for vertical splitting of the oxygen supply to a post-oxidation reactor. Further disclosed are process and apparatus for supplying reaction medium to a post-oxidation reactor at a mid-level inlet. Such apparatus and process can assist in reducing oxygen pinch throughout the post-oxidation reactor.

Abstract: Disclosed are process and apparatus for vertical splitting of the oxygen supply to a post-oxidation reactor. Further disclosed are process and apparatus for supplying reaction medium to a post-oxidation reactor at a mid-level inlet. Such apparatus and process can assist in reducing oxygen pinch throughout the post-oxidation reactor.

Abstract: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, said apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of no less than 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10?22 bar and oxygen partial pressure of 10?10 bar, at a temperature of 1200° C.; wherein said refractory material has no less than 4 vol % formed porosity, measured at 20° C., based upon the bulk volume of said refractory material. In another embodiment, the refractory material has total porosity in the range of from 4 to 60 vol %.

Abstract: Disclosed are a method and a device for feeding and/or discharging fluids in microreactor arrays through one or several fluid ducts that extend into each individual microreactor and can be individually controlled and regulated, in order to control, regulate, influence, and/or verify processes. The fed or discharged amounts of fluid are introduced into or discharged from the volume of the reaction liquid during a continuous shaking process and are evenly mixed as a result of the shaking process. The continuous shaking process causes sufficient mass transfer and thorough mixing of the reaction partners or fluids while the reaction is not limited or restricted by the mass transfer conditions.

Abstract: A modular flow reactor is formed of a plurality of modules, wherein each module comprises a body having at least one conduit passing therethrough, and wherein a plurality of said modules are aligned along a longitudinal axis such that said conduits of said modules are aligned to form a passage for fluid, wherein each module has a length along said longitudinal axis which is less than the length of the module perpendicular to the longitudinal axis. The modules are “slices” rather than “tubes” and a plurality of said modules can be aligned linearly so that the conduits form a tube.

Abstract: An apparatus for preparing an electrode-active material, comprising a reactor that produces the electrode-active material by using a high-temperature high-pressure hydrothermal synthesis method; and decompression equipment that decreases the pressure of a fluid containing the electrode-active material. The decompression equipment includes a pipe-type or a tube-type decompressor.

Abstract: The invention discloses an apparatus and process for the reformation of hydrogen containing fluids to hydrogen and other constituents, more particularly, the reformation of hydrocarbons or mixtures of hydrocarbons in a cyclic flow inert porous media reactor for the production of hydrogen and other constituents. In an alternate embodiment, the apparatus and process can be used for the reformation of hydrogen sulfide to produce hydrogen and sulfur. The cyclic flow reactor comprises a reaction chamber filled with a porous media matrix containing an unconstrained reaction zone located in any portion of the reactor chamber. This reactor system employs valves to canalize the reactant mixture and product mixture during flow cycling channeling the reactant mixture through the porous media matrix, and reacting the reactant mixture.

Abstract: Provided are: a device and method for generating hydrogen from a hydrogen reservoir, whereby it is possible to produce two weight equivalents of the weight equivalent of the hydrogen which can be emitted from ammonia borane-based compounds, in other words a hydrogen storage capacity of 13.0%, in a short time at low temperature; a catalyst used with the same; and a device for using emitted hydrogen.

Abstract: A method for modernizing an ammonia synthesis loop (1) with a first converter (10) and a second converter (11) in series, the first converter (10) comprises a cartridge with one or more catalyst beds, the second converter (11) comprises a catalyst bed in direct contact with said vessel, the method comprising the steps of removing the second converter, and boosting the first converter by replacing the cartridge with a high-efficiency cartridge comprising a plurality of adiabatic catalyst beds and inter-bed heat exchangers, or an isothermal catalyst bed, and by reducing the concentration of inerts in said first converter.

Abstract: After absorbing oxygen together with carbon dioxide in an absorber 103, absorbing liquid 104a is supplied to oxygen collecting units 13 and 14. The oxygen collecting units 13 and 14 include silver to collect the oxygen in the absorbing liquid 104a and eliminate the oxygen from the absorbing liquid 104a. A regenerating unit 15 separates and recovers the oxygen collected in one of the two oxygen collecting units 13 and 14 to regenerate the oxygen collecting unit when the other oxygen collecting unit is supplied with the absorbing liquid 104a. A continuous operation can be achieved by switching and using the two oxygen collecting units 13 and 14.

Abstract: Described herein are embodiments of systems and methods for oxidizing gases. In some embodiments, a reaction chamber is configured to receive a fuel gas and maintain the gas at a temperature within the reaction chamber that is above an autoignition temperature of the gas. The reaction chamber may also be configured to maintain a reaction temperature within the reaction chamber below a flameout temperature. In some embodiments, heat and product gases from the oxidation process can be used, for example, to drive a turbine, reciprocating engine, and injected back into the reaction chamber.